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RuCl[(S,S)-Fsdpen](p-cymene)
Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture. Group: Ruthenium series catalysts. Alternative Names: RuCl[ (S, S) -FsDPEN] (p-cymene) ; 1026995-72-1; [ (S, S) -N- (2-Amino-1, 2-diphenylethyl) pentafluorobenzenesulfonamide]chloro (p-cymene) ruthenium (II) ; R0122; J-000770; Chloro (p-cymene) [ (S, S) -N- (pentafluorobenzenesulfonyl) -1, 2-diphenylethylenediamine]ruthenium (II) ; Chloro{[ (1S, 2S) - (+) -2-amino-1, 2-diphenylethyl] (pentafluorophenylsulfonyl) amido} (p-cymene) ruthenium (I. CAS No. 1026995-72-1. Molecular formula: C30H28ClF5N2O2RuS. Mole weight: 712.138g/mol. IUPACName: [(1S,2S)-2-amino-1,2-diphenylethyl]-(2,3,4,5,6-pentafluorophenyl)sulfonylazanide;1-methyl-4-propan-2-ylbenzene;ruthenium(2+);chloride. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. C1=CC=C (C=C1)C (C (C2=CC=CC=C2)[N-]S (=O) (=O)C3=C (C (=C (C (=C3F)F)F)F)F)N. [Cl-]. [Ru+2]. Catalog: ACM1026995721.
RuCl[(S,S)-Tsdpen](mesitylene)
Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture. Group: Ruthenium series catalysts. Alternative Names: RuCl[(S, S)-TsDPEN](mesitylene); 174813-81-1; CTK8E7375; KS-000018VY; RT-015463; J-011043; Ruthenium, [N-[(1S,2S)-2-(amino-kappaN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kappaN]chloro[(1,2,3,4,5,6-eta)-1,3,5-trimethylbenzene]-. CAS No. 174813-81-1. Molecular formula: C30H33ClN2O2RuS. Mole weight: 622.186g/mol. IUPACName: [(1S, 2S)-2-amino-1, 2-diphenylethyl]-(4-methylphenyl)sulfonylazanide; chlororuthenium(1+); 1, 3, 5-trimethylbenzene. Canonical SMILES: CC1=CC=C (C=C1)S (=O) (=O)[N-]C (C2=CC=CC=C2)C (C3=CC=CC=C3)N. CC1=CC (=CC (=C1)C)C. Cl[Ru+]. Catalog: ACM174813811.
Palladium precatalyst for fast Suzuki-Miyaura coupling reactions. Group: Palladium series catalysts. Alternative Names: Cerium(III) chloride, anhydrous. CAS No. 1375325-68-0. Molecular formula: C42H53ClNO2PPd. Mole weight: 776.73. Appearance: Powder. Purity: 0.98. Catalog: ACM1375325680-2.
RuPhos Pd G3
Palladium catalyst used for facile, C-N cross-coupling reactions. A practical synthesis of indoles via a Pd-catalyzed C-N ring formation. Group: Palladium series catalysts. Alternative Names: SY072913; (2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)(2-(2'-amino-1,1'-biphenyl))palladium(II) methanesulfonate; RuPhos Pd G3; RuPhos-Pd-G3; MFCD22572684 (95%); Methanesulfonato(2-dicyclohexylphosphino-2 inverted exclamation mark ,6 inverted exclamation mark -di-i-propoxy-1,1 inverted exclamation mark -biphenyl)(2 inverted exclamation mark -amino-1,1 inverted exclamation mark -biphenyl-2-yl)palladium(II). CAS No. 1445085-77-7. Molecular formula: C43H57NO5PPdS-. Mole weight: 837.385g/mol. IUPACName: dicyclohexyl-[2-[2, 6-di(propan-2-yloxy)phenyl]phenyl]phosphane; methanesulfonic acid;palladium;2-phenylaniline. Canonical SMILES: CC (C)OC1=C (C (=CC=C1)OC (C)C)C2=CC=CC=C2P (C3CCCCC3)C4CCCCC4. CS (=O) (=O)O. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. [Pd]. Catalog: ACM1445085777.
Ruthenium dioxide
Ruthenium dioxide is one of the primary oxygen catalysts used in a majority of chemical reactions such as the production of chlorine oxides. Ruthenium (IV) oxide is applied as an electrochemical supercapacitor agent as it has a high potential to store charge. Ruthenium dioxide is applied as a catalyst in the Deacon process where chlorine is produced through oxidation of hydrogen chloride. The high charge potential makes Ruthenium dioxide appropriate for use as an active agent in supercapacitors. The dispersion aspect of Ruthenium dioxide enhances the capacitance of nanocomposite electrode substances for supercapacitors. Ruthenium dioxide is widely used as a doping agent, as a catalyst, and as a coating material for titanium anodes, for the elimination of hydrogen sulfide from oil refineries. Hydrogen sulfide can be divided by light in the presence of a photocatalyst-containing CdS crystals doped with Ruthenium (IV) oxide. The hydrogen obtained could be essential in the synthesis of methanol, ammonia and potentially fuel an economy driven by hydrogen. Group: Nanoparticles & nanopowders. Alternative Names: Dioxoruthenium. CAS No. 12036-10-1. Molecular formula: O2Ru. Mole weight: 133.1. Appearance: Dark blue crystal. Purity: 0.98. IUPACName: dioxoruthenium. Canonical SMILES: O=[Ru]=O. ECNumber: 234-840-6. Catalog: ACM12036101-4.
Ruthenium(IV) oxide hydrate
Oxidation. Group: Metal & ceramic materials. Alternative Names: Hydrous ruthenium oxide. CAS No. 32740-79-7. Molecular formula: H2O3Ru. Mole weight: 151.08. Appearance: Black powder. Purity: 0.98. IUPACName: oxygen(2-);ruthenium(4+);hydrate. Canonical SMILES: O.[O-2].[O-2].[Ru+4]. Catalog: ACM32740797-1.
Ruthenium Red acts as an inhibitor of mitochondrial ETC complexes I and III. Inhibitor of mitochondrial calcium uniporter. Group: Heterocyclic organic compound. Alternative Names: AK175476; degrees +/->> AENo>> iE; 11103-72-3; SR-01000076250-2; Ruthenium Red, for microscopy, 85.0-115.0% (calc. on dry basis, AT); MFCD00011479; Ruthenium Red, Technical grade; Ruthenium Red, for microscopy, >=85% (calc. on dry substance, AT). CAS No. 11103-72-3. Molecular formula: Cl6H46N14O2Ru3. Mole weight: 790.374g/mol. IUPACName: azane; ruthenium(2+); hexachloride; dihydrate. Canonical SMILES: N. N. N. N. N. N. N. N. N. N. N. N. N. N. O. O. [Cl-]. [Cl-]. [Cl-]. [Cl-]. [Cl-]. [Cl-]. [Ru+2]. [Ru+2]. [Ru+2]. Catalog: ACM11103723.
Ruthenium trichloride
Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1. Group: Metal & ceramic materials. Alternative Names: RUTHENIUM(+3)CHLORIDE HYDRATE;RUTHENIUM CHLORIDE, HYDROUS;RUTHENIUM(III) CHLORIDE HYDRATE;RUTHENIUM(III) CHLORIDE N-HYDRATE;RUTHENIUM(III) CHLORIDE;RUTHENIUM TRICHLORIDE HYDRATE;RUTHENIUM TRICHLORIDE N-HYDRATE;RutheniumchloridehydrateRu. CAS No. 14898-67-0. Molecular formula: RuCl3·nH2O. Mole weight: 303.32. Appearance: black-brown crystals. Purity: Ru ≥37.0%. Catalog: ACM14898670.
(R)-(+)-XylBINAP
Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters. Ligand used in the enantioselective fluorination of oxindoles. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation. Asymmetric hydroboration of unsaturated imines. Group: Heterocyclic organic compound. CAS No. 137219-86-4. Molecular formula: C52H48P2. Mole weight: 734.904g/mol. IUPACName: [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane. Canonical SMILES: CC1=CC (=CC (=C1)P (C2=C (C3=CC=CC=C3C=C2)C4=C (C=CC5=CC=CC=C54)P (C6=CC (=CC (=C6)C)C)C7=CC (=CC (=C7)C)C)C8=CC (=CC (=C8)C)C)C. Catalog: ACM137219864.
Ryanodine
Heterocyclic Organic Compound. CAS No. 015662-33-6. Purity: N/A. Catalog: ACM015662336.
Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic organic compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM134484369.
(S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(S)-TiPSY]
Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of indoles with imines. Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of pyrrole derivatives with N-acyl imines. Chiral phosphoric acid catalyst used for the enantioselective transfer hydrogenation of hydroxylactams providing enantioenriched tetrahydro-β-carbolines (in dioxane) at room temperature (up to 94% yield, 90% ee). [Rh2(OAc)4]/chiral phosphoric acid catalyst used for the enantioselective symmetric, three-component reaction of diazo compounds with imines and water yielding β-amino-α-hydroxy acid derivatives. Enantioselective desymmetrization of prochiral allenic diols via cooperative catalysis of Pd(OAc)2 and a chiral phosphoric acid. Group: Phosphorus catalysts. Alternative Names: (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide; Phosphoric acid (aR)-3,3'-bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diyl ester; (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1 inverted exclamation marka,2 inverted exclamation markaf]-[1,3,2]-dioxaphosphepin 4-oxide; (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate. CAS No. 929097-92-7. Molecular formula: C56H41O4PSi2. Mole weight: 865.084g/mol. IUPACName: (13-hydroxy-1
(S)-3,3'-Dibromo-1,1'-bi-2-naphthol
Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker reactions. Ligand used in the zinc-catalyzed enantioselective Hetero Diels-Alder reaction. Catalyst used in syn-selective diastereoselective Petasis reactions. Catalyst used in asymmetric propargylation of ketones. Group: Heterocyclic organic compound. Alternative Names: (S)-3,3'-Dibromo-2,2'-dihydroxy-1,1'-binaphthyl. CAS No. 119707-74-3. Molecular formula: C20H12Br2O2. Mole weight: 444.11. Appearance: White to off-white powder. Purity: 98%+. IUPACName: 3-bromo-1-(3-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol. Canonical SMILES: C1=CC=C2C (=C1)C=C (C (=C2C3=C (C (=CC4=CC=CC=C43)Br)O)O)Br. Catalog: ACM119707743-1.
[(S)-(-)-5, 5'-Bis(diphenylphosphino)-4, 4'-bi-1, 3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1, 2, 3-η-2-propenyl]iridium(III), min. 97%
1. Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. 2. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. 3. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. 4. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. 5. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. 6. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Heterocyclic organic compound. CAS No. 1221768-92-8. Molecular formula: C49H35IrN2O8P2. Mole weight: 1033.98. Catalog: ACM1221768928.
Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS. Group: Other. Alternative Names: AKOS015840981; (S)-1-methyl-3,3-diphenyltetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole; MFCD00078439; (S)- Methyl-CBS-oxazaborolidine; ZINC169743318; (S)-tetrahydro-1-methyl-3,3-diphenyl-1 H,3 H-pyrrolo[1,2-c][1,3,2] oxazaborole; (S)-1-methyl-3,3-diphenylhexahydropyrrolo-[1,2-c][1,3,2]oxazaborole; (S)-tetrahydro-1-methyl-3,3-diphenyl-1 H,3H-pyrrolo[1,2-c]-[1,3,2]oxazaborole; (S)-Me-CBS; Corey catalyst. CAS No. 112022-81-8. Molecular formula: C18H20BNO. Mole weight: 277.174g/mol. IUPACName: (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole. Canonical SMILES: B1 (N2CCCC2C (O1) (C3=CC=CC=C3)C4=CC=CC=C4)C. Catalog: ACM112022818.
(S)-5-Acetoxy-4-methylpentanoic Acid
The (S)-intermediate in the synthesis of (4R,8R)-4,8-Dimethyldecanal, the pheromone of flour beetles. Group: Pheromone ingredients. Alternative Names: (S)-5-(Acetyloxy)-4-methylpentanoic Acid. CAS No. 1346617-41-1. Molecular formula: C8H14O4. Mole weight: 174.09. Catalog: ACM1346617411.
(S)-5-Hexanolide
(S)-5-Hexanolide is the (S)-enatiomer of the 5-Hexanolide. (S)-5-Hexanolide is less common than the (R)-enantiomer, which is the preferably occuring genuine lactone found in dairy products. (S)-5-Hexanolide is used in the preparation of biologically active compounds such as pheromones. Group: Pheromone ingredients. Alternative Names: (S)-; (-)-(S)-5-Hexanolide; (-)-δ-Hexalactone; (S)-6-Methyltetrahydropyran-2-one; (S)-Dihydroparasorbic Acid; (S)-Tetrahydro-6-methyl-2H-pyran-2-one; (S)-δ-Hexalactone. CAS No. 16320-13-1. Molecular formula: C6H10O2. Mole weight: 114.14. Catalog: ACM16320131.
(S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol
Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker reactions. Ligand used in the zinc-catalyzed enantioselective Hetero Diels-Alder reaction. Ligand used in asymmetric Friedel-Crafts reactions of pyrroles with glyoxylates. Group: Bromine series. Alternative Names: FT-0605159; (S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol; (S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol, 98%; C20H12Br2O2; 6, 6'-Dibromo[1, 1'-binaphthalene]-2, 2'-diol; BC003318; BCP10043; KS-000013V2; BCP10042; (R)-(-)-6,6'-DIBROMO-1,1'-BI-NAPHTHOL. CAS No. 80655-81-8. Molecular formula: C20H12Br2O2. Mole weight: 444.122g/mol. IUPACName: 6-bromo-1-(6-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol. Canonical SMILES: C1=CC2=C (C=CC (=C2C3=C (C=CC4=C3C=CC (=C4)Br)O)O)C=C1Br. Catalog: ACM80655818.