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Alkenes, C15-20, polymers with lard oil and sulfurized Bu oleate
Alkenes, C15-20, polymers with lard oil and sulfurized Bu oleate. CAS No. 103819-04-1. Catalog: ACM103819041.
10-Methyl-9(10H)-acridinone
10-Methyl-9(10H)-acridinone is an intermediate in the synthesis of 9-Mesityl-10-methylacridinium Tetrafluoroborate (M258620). 9-Mesityl-10-methylacridinium Tetrafluoroborate can be used for the synthesis of γ-butyrolactones, γ-lactams and pyrrolidines and also it has been reported by Nicewicz et al. to mediate myriad transformations through Photoredox Catalysis. The applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoro methyl ation of styrenes using the Langlois reagent S673690. Group: Biochemicals. Grades: Highly Purified. CAS No. 719-54-0. Pack Sizes: 500mg, 1g. Molecular Formula: C14H11NO. US Biological Life Sciences.
Worldwide
1,1,1-Trichloro-Trifluoroethane
1,1,1-Trichlorotrifluoroethane is used in the synthesis of isosteres showing potential to be β-turn promoters. Also used in the synthesis of fluoro-containing alkenes. Synonyms: 1,1,1-Trifluoro-2,2,2-trichloroethane; 1,1,1-Trifluorotrichloroethane. Grades: > 95%. CAS No. 354-58-5. Molecular formula: C2Cl3F3. Mole weight: 187.38.
1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-phosphine is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate ligand and is noteworthy for having a particularly wide bite angle. Such ligands are useful in the hydroformylation of alkenes. Group: Biochemicals. Grades: Highly Purified. CAS No. 161265-03-8. Pack Sizes: 1g, 5 g. Molecular Formula: C39H32OP2. US Biological Life Sciences.
Worldwide
1,1'-Bis(dimethylsilyl)ferrocene
Catalytic co-initiator in free radical photopolymerization and free radical promoted cationic polymerization reactions Reactant for: Hydrosilylataion and hydroboration reactions Platinum/nickel catalyzed selective hydrosilylation of alkynes and alkenes Iron-catalyzed dehydrogenative coupling reactions Hydrosilylation and double silylation of carbonyl compounds. Group: Polymer/macromolecule. Alternative Names: 1,1-BIS(DIMETHYLSILYL)FERROCENE;1,1-Bis(dimethylsilyl)ferrocene 97%;Ferrocene,1,1-bis(dimethylsilyl)-. CAS No. 1295-15-4. Molecular formula: C14H22FeSi2 10*. Mole weight: 302.34. Catalog: ACM1295154.
1,1'-Bis(diphenylphosphino)ferrocene
Ligand for Pd-catalyzed cross-coupling. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures. Ligand for Ni-catalyzed amination of aryl chlorides. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles. Ligand for Ni-catalyzed Suzuki reactions. Ni-catalyzed hydroamination of 1,3-dienes. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones. Ligand for Ru-catalyzed reduction of nitriles to primary amines. Ligand for Rh-catalyzed alkyne head-to-tail dimerization. Ligand for Rh-catalyzed cross-coupling Ligand for Rh-catalyzed olefin isomerization Ligand for Ni or Rh-catalyzed borylation Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes. Group: Organic phosphine compounds. Alternative Names: 1,1'-Ferrocenediyl-bis(diphenylphosphine); DPPF. CAS No. 12150-46-8. Molecular formula: C34H28FeP2. Mole weight: 554.38. Appearance: Solid. Purity: 0.98. IUPACName: 1,1-Bis(diphenylphosphino)ferrocene. Catalog: ACM12150468-1.
1, 2-Dibromotetra chloroethane
1, 2-Dibromotetra chloroethane is used as halogenating reagent for the one-pot conversion of sulfones to alkenes by Ramberg-Bäcklund rearrangement. It is a useful brominating reagent for diaryl TeII species. Group: Biochemicals. Grades: Highly Purified. CAS No. 630-25-1. Pack Sizes: 5g, 10g. Molecular Formula: C2Br2Cl4, Molecular Weight: 325.64. US Biological Life Sciences.
Worldwide
1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidenegold(I) hydroxide, min. 97%
Catalyst used for the carboxylation of C-H bonds. Catalyst used for the hydrofluorination of alkynes. Gold-catalyzed synthesis of sulfinate derivatives Effective catalyst for the carboxylation/cyclization of propargylamines with carbon dioxide. Catalyst used for the polymerization of racemic β-butyrolactones. Catalyst used for the intermolecular mono and dihydroamination of activated alkenes. Group: Gold catalysts. Alternative Names: MFCD22666054;1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidenegold(I) hydroxide;1240328-73-7. CAS No. 1240328-73-7. Molecular formula: C27H38AuN2O. Mole weight: 603.581g/mol. IUPACName: 1,3-bis[2,6-di(propan-2-yl)phenyl]imidazole;gold;hydrate. Canonical SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N2C=CN ([C]2)C3=C (C=CC=C3C (C)C)C (C)C. O. [Au]. Catalog: ACM1240328737.
1,3-Dibromo-5,5-dimethyl-2,4-imidazolidinedione
1,3-Dibromo-5,5-dimethyl-2,4-imidazolidinedione is a useful synthetic intermediate in aromatic bromination of alkoxybenzoic acids and in bromofluorination of alkenes. Group: Biochemicals. Grades: Highly Purified. CAS No. 77-48-5. Pack Sizes: 10g, 25g. Molecular Formula: C5H6Br2N2O2, Molecular Weight: 285.92. US Biological Life Sciences.
Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes Synthetic pyrethriods: catalyst for the Negishi coupling of (2, 2-dihaloethenyl) cyclopropanecarboxylates. Group: Palladium series catalysts. Alternative Names: Dichloro[bis (1, 4-diphenylphosphino)butane]palladium (II). CAS No. 29964-62-3. Molecular formula: C28H28Cl2P2Pd. Mole weight: 603.8. Appearance: White like powder. Purity: 0.99. IUPACName: dichloropalladium; 4-diphenylphosphanylbutyl (diphenyl)phosphane. Canonical SMILES: C1=CC=C (C=C1) P (CCCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Pd]Cl. Catalog: ACM29964623-1.
2,2,6,6-Tetramethylpiperidine-1,4-diol is related to 4-Hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxy (H956500), which is a free radical scavenger. 2,2,6,6-Tetramethylpiperidine-1,4-diol has also been shown to be an in vitro and in vivo radioprotector. It is used as a reagent in stereoselective preparation of tetrasubstituted triarylated olefins via Pd-catalyzed sequential oxidative Heck arylation of alkenes with arylboronic acids using nitroxides as oxidants. Group: Biochemicals. Grades: Highly Purified. CAS No. 4972-11-6. Pack Sizes: 50mg, 100mg. Molecular Formula: C9H20ClNO2. US Biological Life Sciences.
Worldwide
1-Tetradecene
Alkenes. Alternative Names: n-Tetradec-1-ene. CAS No. 1120-36-1. Molecular formula: C14H28. Mole weight: 196.37. Catalog: ACM1120361.
2,2,6,6-Tetramethylpiperidine-1,4-diol
2,2,6,6-Tetramethylpiperidine-1,4-diol is related to 4-Hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxy (H956500), which is a free radical scavenger. 2,2,6,6-Tetramethylpiperidine-1,4-diol has also been shown to be an in vitro and in vivo radioprotector. It is used as a reagent in stereoselective preparation of tetrasubstituted triarylated olefins via Pd-catalyzed sequential oxidative Heck arylation of alkenes with arylboronic acids using nitroxides as oxidants. Group: Biochemicals. Grades: Highly Purified. CAS No. 3637-10-3. Pack Sizes: 50mg, 100mg. Molecular Formula: C9H19NO2, Molecular Weight: 173.25. US Biological Life Sciences.
Worldwide
2, 2-Diphenylcyclopropane carbonitrile
2, 2-Diphenylcyclopropane carbonitrile is used in the synthetic preparation of cyclopropanation or metathesis products by reactions of diazo compds. with alkenes catalyzed by [RuCl(cod)(Cp)]. Group: Biochemicals. Grades: Highly Purified. CAS No. 30932-41-3. Pack Sizes: 50mg, 100mg. Molecular Formula: C31H24N2. US Biological Life Sciences.
Unlike Mo(C10H12)(C12H17N)(OC4H9)2, the bis(hexafluoro-t-butoxide) (MoF6) derivative will metathesize many ordinary olefins, especially terminal olefins, and will ROMP many norbornene or substituted norbornadiene monomers to give all cis, and often isotactic, polymers. Useful for the "ring-closing" of dienes or the coupling of terminal olefins. Useful for cross-metathesis of alphatic alkenes with 2-vinyl aromatics. Group: Heterocyclic organic compound. Alternative Names: SREMDTDVHCUUIZ-UHFFFAOYSA-N; SCHROCK'S CATALYST; SCHEMBL1634829; SC10923; MFCD00269857. CAS No. 139220-25-0. Molecular formula: C30H37F12MoNO2. Mole weight: 767.562g/mol. IUPACName: [2, 6-di(propan-2-yl)phenyl]imino-(2-methyl-2-phenylpropylidene)molybdenum;1, 1, 1, 3, 3, 3-hexafluoro-2-methylpropan-2-ol. Canonical SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N=[Mo]=CC (C) (C)C2=CC=CC=C2. CC (C (F) (F)F) (C (F) (F)F)O. CC (C (F) (F)F) (C (F) (F)F)O. Catalog: ACM139220250.
2-?Chloro-?1,?3,?2-?benzodioxaborole
2-?Chloro-?1,?3,?2-?benzodioxaborole is a coupling reagent used in the synthesis of alkenyl boronic esters, obtained from unfunctionalized alkenes. Group: Biochemicals. Grades: Highly Purified. CAS No. 55718-76-8. Pack Sizes: 100mg, 500mg. Molecular Formula: C6H4BClO2, Molecular Weight: 154.36. US Biological Life Sciences.
Ligand used in the Pd-catalyzed Suzuki coupling and animation of unactivated aryl chlorides. The reactions generally occur at room temperature and give high yields of product. Ligand used in Pd-catalyzed C-N bond formation. A general synthesis of N6-aryl-2'deoxyadenosine analogues. Ligand used in Pd-catalyzed N-arylation of indoles. Ligand used in Pd-catalyzed synthesis of aryl-tert-butyl ethers. Effective ligand in the Pd-catalyzed arylation of ester enolates. Ligand employed in arylation of ketone enolates using ortho-halo nitrobenezenes. Ligand employed in the amination of aryl nonaflates using Pd catalysts. Ligand used for cascade alkenyl amination/Heck reaction for the synthesis of indoles. Ligand used in Pd-catalyzed Kumada-Corriu cross coupling at low temperatures. Ligand used in Rh-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. Ligand used in Au-catalyzed cycloisomerization of allenes. Group: Organic phosphine compounds. Alternative Names: 2-di-cyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl; 118492-EP2272832A1; (2'-dicyclohexylphosphanyl-biphenyl-2-yl)dimethyl-amine; 2-(Dicyclohexylphosphino)-2'-(N,N-diMethylaMino)biphenyl, 98% DavePhos; (2'-dicyclohexylphosphanyl -biphenyl-2-yl)-dimethyl-amine; Buchwald phosphine ligands, davephos phosphine ligand-; 2-dicyclohexylphosphino-2'-(N,N'-dimethylamino)biphe
2-(Dicyclohexylphosphino)biphenyl
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in Suzuki coupling reactions involving aryl chlorides, bromides and triflates. Useful ligand for the Pd-catalyzed oxidation of alcohols in the presence of chlorobenzenes. Useful ligand for the Pd-catalyzed amination with ammonia equivalents. Ligand for the gold(I)-catalyzed intramolecular [4+2] cycloadditions involving 1,3-enynes and arylalkynes with alkenes. Ligand used in the palladium-catalyzed borylation of aryl bromdies. Ligand used in the palladium-catalyzed siliylation of aryl chlorides. Group: Organic phosphine compounds. Alternative Names: Cyclohexyl JohnPhos. CAS No. 247940-06-3. Molecular formula: C24H31P. Mole weight: 350.48. Appearance: Solid. Purity: 0.98. IUPACName: dicyclohexyl-(2-phenylphenyl)phosphane. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)C3=CC=CC=C3C4=CC=CC=C4. ECNumber: 480-030-2. Catalog: ACM247940063-1.
3,4-Dihydro-2H-pyrano(3,2-b)pyridine
3,4-Dihydro-2H-pyrano(3,2-b)pyridine (CAS# 70381-92-9) is used in an iridium-based photoredox catalytic system for radical conjugate addition of nitrogen heterocycles to alkenes. Synonyms: dihydropyranopyridine. CAS No. 70381-92-9. Molecular formula: C8H9NO. Mole weight: 135.16.
3-Buten-1-ol is an aliphatic primary alcohol used as a reagent in organic synthesis. Uses: 3-buten-1-ol is an aliphatic primary alcohol used as a reagent in organic synthesis. Group: Alkenes. Alternative Names: 4-Hydroxy-1-butene; V6966; 79116-EP2305698A2; PubChem18909; UNII-3DB2KRM1I9; 3-Buten-1-O1; 627-27-0; ZINC1530356; KSC353Q2N; NSC60194. CAS No. 627-27-0. Molecular formula: C4H8O. Mole weight: 72.107g/mol. Appearance: Clear colorless liquid. IUPACName: but-3-en-1-ol. Canonical SMILES: C=CCCO. Density: 0.838. ECNumber: 210-991-3. Catalog: ACM627270.
4-Penten-1-ol is a reagent used in carbohydrate chemistry for n-Pentenyl Glycoside methodology for the rapid assembly of homoglycans exemplified with the nonasaccharide component of a high-mannose glycoprotein. Group: Alkenes. Alternative Names: S14-0957; UNII-W0558TQC6F; ACN-S003547; 4-Pentenol; TC-060303; InChI=1/C5H10O/c1-2-3-4-5-6/h2, 6H, 1, 3-5H2; ZINC1632700; A840248; 821-09-0; CH2=CHCH2CH2CH2OH. CAS No. 821-09-0. Molecular formula: C5H10O. Mole weight: 86.134g/mol. IUPACName: pent-4-en-1-ol. Canonical SMILES: C=CCCCO. ECNumber: 212-473-2. Catalog: ACM821090.
5-Ethylidene-2-norbornene mixture of endo and exo
Ethylidene norbornene is a colorless liquid with an odor of turpentine. Flash point 101°F. Floats on water.;Liquid;WHITE-TO-COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.;Colorless to white liquid with a turpentine-like odor.;Colorless to white liquid with a turpentine-like odor. Group: Alkenes. Alternative Names: ETHYLIDENE NORBORNENE;ETHYLIDENE-2-NORBORNENE;5-ETHYLIDENE-2-NORBORNENE;(5E)-5-Ethylidenebicyclo[2.2.1]hept-2-ene;2-Norbornene, 5-ethylidene-;2-norbornene,5-ethylidene-;5-Ethylidene bicyclo[2,2,1]heptene;5-ethylidene-2-norbornen. CAS No. 16219-75-3. Molecular formula: C9H12;C9H12. Mole weight: 120.19g/mol. IUPACName: 5-ethylidenebicyclo[2.2.1]hept-2-ene. Canonical SMILES: CC=C1CC2CC1C=C2. Density: 0.896 at 68 °F (USCG, 1999);0.8958 @ 20 °C;Relative density (water = 1): 0.9;0.90;0.90. ECNumber: 240-347-7. Catalog: ACM16219753.
Ligand used in the cobalt-catalyzed alkenylzincation of unfunctionalized alkynes. Ligand used in the cobalt-catalyzed alkylboration of alkenes. Ligand used in the palladium-catalyzed N-alkylation of amines using primary and secondary alcohols. Ligand used in the palladium-catalyzed methylation of alkynyl C(sp)-H bonds with dimethyl sulfonium ylides. Group: Organic phosphine compounds. Alternative Names: AX8240548; ditert-butyl-(5-ditert-butylphosphanyl-9,9-dimethylxanthen-4-yl)phosphane; SCHEMBL1315091; 4,5-bis(di-t-butylphosphino)-9,9-dimethylxanthene; 9,9-Dimethyl-4,5-bis(di-tert-butylphosphino)xanthene; FT-0728449; ZINC12359415; t-Bu-Xantphos; CS-W009619; DB-009564. CAS No. 856405-77-1. Molecular formula: C31H48OP2. Mole weight: 498.672g/mol. IUPACName: ditert-butyl-(5-ditert-butylphosphanyl-9,9-dimethylxanthen-4-yl)phosphane. Canonical SMILES: CC1 (C2=C (C (=CC=C2)P (C (C) (C)C)C (C) (C)C)OC3=C1C=CC=C3P (C (C) (C)C)C (C) (C)C)C. Catalog: ACM856405771.
Ligand used for the hydroformylation of alkenes. Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides. Ligand used in the intermolecular coupling of amides with aryl halides or triflates. Ligand used in the coupling of heteroarylamines and aryl halides. Ligand used in the hydrophosphinylation of alkenes and alkynes. Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols. Ligand used for the sulfinylation of aryl iodides. Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines. Ligand used for the Ni-cataltzed alkynylcyanation of alkynes. Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole. Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes. Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides. Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles. Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes. Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates. Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones. Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines. Ligand used fo
alkene monooxygenase
This bacterial binuclear non-heme iron enzyme is a multicomponent enzyme complex comprising an oxygenase, a reductase, and a Rieske-type ferredoxin. The enzyme from the bacterium Xanthobacter sp. strain Py2 contains an additional small protein of unknown function that is essential for activity. In general, the enzyme oxygenates C2 to C6 aliphatic alkenes, although enzymes from different organisms show different substrate range. With propene as substrate, the stereospecifity of the epoxypropane formed is 95% (R) and 5% (S). Group: Enzymes. Synonyms: alkene epoxygenase; etnABCD (gene names); amoABCDE (gene names). Enzyme Commission Number: EC 1.14.13.69. CAS No. 63439-50-9. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0875; alkene monooxygenase; EC 1.14.13.69; 63439-50-9; alkene epoxygenase; etnABCD (gene names); amoABCDE (gene names). Cat No: EXWM-0875.
Allylamine Hydrochloride
This product is suitable for scientific research. Group: Alkenesallyl monomers. Alternative Names: 3-Aminopropene Hydrochloride. CAS No. 10017-11-5. Molecular formula: C3H7N·HCl. Mole weight: 93.55 g/mol. Appearance: White to Light Yellow to Light Orange Powder to Crystal. Purity: 98.0%(T). IUPACName: prop-2-en-1-amine;hydrochloride. Canonical SMILES: Cl.NCC=C. ECNumber: 415-050-2;600-035-7;615-303-9. Catalog: ACM-MO-10017115.
Precursor to a palladacyclic catalyst for Suzuki, Stille and Heck processes. Ligand for Pd-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes. Ligand for Pt-catalyzed intramolecular silaboration of alkenes. Ligand for Ni-catalyzed aminocarbonylation of aryl halides. Ligand for the Au-catalyzed [4+2] intramolecular cycloaddition of allene-dienes. Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent. Alternative Names: Phenol,2,4-bis(1,1-dimethylethyl,phosphite(3:1). CAS No. 31570-04-4. Molecular formula: C42H63O3P. Mole weight: 646.92. Appearance: White solid. Purity: 0.98. Catalog: ACM31570044.
Biotinyl-phenylboronic acid is the functionalized arylboronic acid of biotin used for palladium-catalyzed oxidative Heck reaction to protein-bound alkenes and Suzuki-Miyaura cross-coupling for labeling of protein bound phenylhalides in high yields and with excellent chemoselectivity. Synonyms: [3-[5-(2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl)pentanoylamino]phenyl]boronic acid. Grades: 99%. CAS No. 1661014-48-7. Molecular formula: C16H22BN3O4S. Mole weight: 363.24.
Catalyst used for the enantioselective carboalumination of unactivated alkenes. Catalyst used for the enantioselective synthesis of methyl-substituted alkanols and their derivatives. Reagent for the synthesis of reduced polypropionates via "one pot" Zr-catalyzed asymmetric carboalumination Pd-catalyzed cross-coupling tandem process. Catalyst used for the asymmetric carboalumination of internally hydroxylated terminal alkenes. Group: Heterocyclic organic compound. Alternative Names: Dichlorozirconium(2+);1-[(1S,2R,5R)-5-methyl-2-propan-2-ylcyclohexyl]indene. CAS No. 148347-90-4. Molecular formula: C38H50Cl2Zr. Mole weight: 668.9. Appearance: Powder. Purity: 0.95. IUPACName: dichlorozirconium(2+);1-[(1S,2R,5R)-5-methyl-2-propan-2-ylcyclohexyl]indene. Canonical SMILES: CC1CCC (C (C1)[C]2[CH][CH][C]3[C]2C=CC=C3)C (C)C. CC1CCC (C (C1)[C]2[CH][CH][C]3[C]2C=CC=C3)C (C)C. Cl[Zr+2]Cl. Catalog: ACM148347904-1.
Bis (dibenzylideneacetone)palladium (0)
Bis (dibenzylideneacetone)palladium (0). Uses: Palladium-catalyzed acylation of unsaturated halides by anions of enol ethers. asymmmetric allylation reactions. intramolecular reactions with alkenes. carbonylation reactions. cross coupling reactions. Group: Salt. Alternative Names: CB-706; MFCD00051942; Bis (dibenzylideneacetone)palladium (0); (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium; GC10019; RW2139; bis(dibenzylidene-acetone)palladium; bis (dibenzylideneacetone)palladium; PubChem14428; J-400823. CAS No. 32005-36-0. Product ID: (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one; palladium. Molecular formula: 575.016g/mol. Mole weight: C34H28O2Pd. C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2. C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2. [Pd]. InChI=1S/2C17H14O. Pd/c2*18-17 (13-11-15-7-3-1-4-8-15) 14-12-16-9-5-2-6-10-16; /h2*1-14H; /b2*13-11+, 14-12+;. UKSZBOKPHAQOMP-SVLSSHOZSA-N.
Bis (dibenzylideneacetone)palladium (0)
Palladium-catalyzed acylation of unsaturated halides by anions of enol ethers. Asymmmetric Allylation reactions. Intramolecular reactions with alkenes. Carbonylation reactions. Cross Coupling reactions. Group: Palladium series catalysts. Alternative Names: CB-706; MFCD00051942; Bis (dibenzylideneacetone)palladium (0); (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium; GC10019; RW2139; bis(dibenzylidene-acetone)palladium; bis (dibenzylideneacetone)palladium; PubChem14428; J-400823. CAS No. 32005-36-0. Molecular formula: C34H28O2Pd. Mole weight: 575.016g/mol. IUPACName: (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium. Canonical SMILES: C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2. C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2. [Pd]. ECNumber: 608-691-6. Catalog: ACM32005360.
Copper-catalyzed coupling of imidazoles and pyrazoles with 1,1-dibromo-1-alkenes: a distinct approach for direct Nalkynylation of heteroarenes. Synthesis of benzoindoloquinolizines via a Cu(I)-mediated C-N bond formation. Efficient synthesis of 1,4-disubstituted triazolyl N-carboxamides via a simple and convenient MCR using basic alumina as a solid support. Cu(I) complexes with diethoxyphosphoryl-1,10-phenanthrolines in catalysis of C-C and C-heteroatom bond formation. Alternative Names: Bromocopper;1,10-phenanthroline;triphenylphosphane. CAS No. 25753-84-8. Molecular formula: C30H23BrCuN2P. Mole weight: 585.9. Appearance: Powder. Purity: 0.98. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC2=C (C3=C (C=CC=N3)C=C2)N=C1. [Cu]Br. Catalog: ACM25753848-1.
Butyltriphenylphosphonium bromide
Reactant for: Free radical 5-exo-dig cyclization Intramolecular hydroacylalkoxylation Wittig reactions for stereoselective synthesis of alkenes Dimerization of α-olefins Alkylidenation of hydrazides for synthesis of indoles Tandem cyclization and 1,2-thiolate shift of nitrogen ylides. Group: Bromine series. Alternative Names: (1-Butyl)triphenylphosphonium bromide. CAS No. 1779-51-7. Molecular formula: C22H24BrP. Mole weight: 399.3. Appearance: White crystalline powder. IUPACName: butyl(triphenyl)phosphanium;bromide. Canonical SMILES: CCCC[P+] (C1=CC=CC=C1) (C2=CC=CC=C2)C3=CC=CC=C3. [Br-]. ECNumber: 918-205-7. Catalog: ACM1779517-3.
Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II)
Catalyst for the arylation (or alkenylation) of anthraquinone and PBI. Catalytic C-C bond formation. Transfer hydrogenative coupling of isoprene to alcohols or aldehydes. Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation. Catalyst for the conversion of primary alcohols and aldehydes into methyl esters. Precatalyst for hydrogen production by means of alcohol dehydrogenation. Group: Ruthenium series catalysts. Alternative Names: 25360-32-1; Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II); Carbonyldihydridotris (triphenylphosphine)ruthenium (II); Dihydridocarbonyltris (triphenylphosphine)ruthenium; C55H47OP3Ru; [ (C6H5)3P]3Ru (CO)H2; AKOS024258165; Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II). CAS No. 25360-32-1. Molecular formula: C55H49OP3Ru. Mole weight: 919.987g/mol. IUPACName: formaldehyde;ruthenium dihydride;triphenylphosphane. Canonical SMILES: C=O. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [RuH2]. Catalog: ACM25360321.
Catalyst for the carboheterofunctionalization of alkenes with arylboronic acids Catalyst for the synthesis of 1-substituted benzo[b][1,4]diazepines. Group: Gold catalysts. Alternative Names: MFCD29037185;Chloro[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene]gold(I);852445-82-0. CAS No. 852445-82-0. Molecular formula: C21H26AuClN2. Mole weight: 538.87g/mol. IUPACName: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-chlorogold. Canonical SMILES: CC1=CC (=C (C (=C1)C)N2CCN (C2=[Au]Cl)C3=C (C=C (C=C3C)C)C)C. Catalog: ACM852445820.
Chloro(1,5-cyclooctadiene)iridium(I) dimer
1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins. 2. Precursor to catalyst for enantioselective reduction of imines. 3. Precursor to catalyst for allylic alkylation. 4. Precursor to catalyst for allylic amination and etherification. 5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes. 6. Ir-catalyzed addition of acid chlorides to terminal alkynes. 7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines. 8. Enantioselective [2+2] cycloaddition. 9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes. 10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates. 11. Transfer hydrogenative C-C coupling. Group: Iridium series of catalysts. Alternative Names: Bis(1,5-cyclooctadiene)diiridium(I) dichloride. CAS No. 12112-67-3. Molecular formula: C16H24Cl2Ir2. Mole weight: 671.71. Appearance: Red brown powder. Purity: 0.99. IUPACName: (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride. Canonical SMILES: C1CC=CCCC=C1. C1CC=CCCC=C1. [Cl-]. [Cl-]. [Ir]. [Ir]. ECNumber: 235-170-7. Catalog: ACM12112673-4.
An air-stable nickel precatalyst for the Internally-selective benzylation of terminal alkenes. Group: Nickel catalysts. CAS No. 1419179-26-2. Molecular formula: C43H61ClNiP2. Mole weight: 734.04. Catalog: ACM1419179262.
Chlorobis (dicyclohexylphenylphosphino) (2-methylphenyl)nickel (II), 99%. Uses: An air-stable nickel precatalyst for the internally-selective benzylation of terminal alkenes. Group: other glass and ceramic materials. CAS No. 1419179-26-2. Molecular formula: 734.04. Mole weight: C43H61ClNiP2.
Cinnamyl alcohol purum
Alkenes. CAS No. 104-54-1. Mole weight: 134.18. Catalog: ACM104541.
Alkenes. Alternative Names: Nerol. CAS No. 106-25-2. Molecular formula: C10H18O. Mole weight: 154.25. Purity: 0.97. Canonical SMILES: CC(=CCC/C(=C\\CO)/C)C. Catalog: ACM106252.
Cis-3-Hexen-1-Ol
Liquid;Liquid;colourless liquid with a powerful, grassy-green odour. Group: Alkenes. Alternative Names: Leaf alcohol. CAS No. 928-96-1. Molecular formula: C6H12O. Mole weight: 100.16. Appearance: Colorless liquid. Purity: 99%+. IUPACName: (Z)-Hex-3-en-1-ol. Canonical SMILES: CCC=CCCO. Density: 0.848 g/mL at 25 °C(lit.). ECNumber: 213-192-8. Catalog: ACM928961.
Cobalt Carbonyl
Cobalt Carbonyl is a metal carbonyl used as a reagent and catalyst in organometallic chemistry and organic synthesis. Cobalt Carbonyl is commonly used as a hydroformylation catalyst for the conversion of alkenes to aldehydes. Group: Biochemicals. Alternative Names: Cobalt octacarbonyl (Co2(CO)8); Cobalt Tetracarbonyl Dimer; Di- μ -carbonyl hexacarbonyl dicobalt; Dicobalt Carbonyl; Dicobalt Octacarbonyl; Octacarbonyldicobalt. Grades: Highly Purified. CAS No. 10210-68-1. Pack Sizes: 1g. US Biological Life Sciences.
Worldwide
Copper(II) trifluoromethanesulfonate
Ring-Opening of epoxides and aziridines. Asymmetric conjugate addition of organozinc reagents to α,β-unsaturated ketones. Electrophilic addition of olefins. Asymmetric aziridination of olefins. Asymmetric cycloadditions and aldol condensations. Asymmetric Kharasch oxidation. Asymmetric Michael addition of enamides. Asymmetric O-H or O-R insertion reactions. Enantioselective intramolecular aminooxygenation of alkenes. Enantioselective addition of dialkylzinc reagents to N-acylpyridinium salts. Pd-catalyzed C-H functionalizations of oximes with arylboronic acids. Used as a Lewis acid in the Nazarov cyclization. Catalyst in the diacetoxylation olefins. Catalyst in the meta-selective direct arylation of α-aryl carbonyl compounds. Catalyst in the three-component coupling of amines, aldehydes, and alkynes. Group: Organic copper. Alternative Names: Copper(II) triflate. CAS No. 34946-82-2. Molecular formula: C2CuF6O6S2. Mole weight: 361.7. Appearance: Powder. Purity: 99%+. IUPACName: copper;trifluoromethanesulfonate. Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-]. C(F)(F)(F)S(=O)(=O)[O-]. [Cu+2]. ECNumber: 252-300-8. Catalog: ACM34946822-1.
CP (Chlorinated Paraffin)
Chlorinated paraffin is a complex chemical compound that is used as a flame retardant, plasticizer, and lubricant in a variety of industrial and consumer products. It is a white or pale yellow, waxy solid that has a strong, chlorine-like odor. Uses: CP is typically used in the production of rubber, plastics, paints, and coatings. It is also used as a flame retardant in textiles, as a lubricant in metalworking fluids, and as a plasticizer in PVC and other polymers. Group: Synthetic. Alternative Names: Chlorinated alkanesChlorinated alkenesChlorinated paraffinsPolychlorinated n-alkanesPolychlorinated n-alkenes. Grades: Technical Grade. CAS No. 85535-85-9.
Dichloro[5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphinato]ruthenium(IV), min. 98%
Catalyst used for the oxidation of 1-alkenes to aldehydes using air or oxygen. Catalyst used for the oxidation of amides. Group: Heterocyclic organic compound. Alternative Names: MFCD18827641;Dichloro[5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphinato]ruthenium(IV);145698-90-4. CAS No. 145698-90-4. Molecular formula: C56H52Cl2N4Ru. Mole weight: 953.03g/mol. IUPACName: dichlororuthenium(2+);5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphyrin-22,24-diide. Canonical SMILES: CC1=CC (=C (C (=C1)C)C2=C3C=CC (=C (C4=NC (=C (C5=CC=C ([N-]5)C (=C6C=CC2=N6)C7=C (C=C (C=C7C)C)C)C8=C (C=C (C=C8C)C)C)C=C4)C9=C (C=C (C=C9C)C)C)[N-]3)C. Cl[Ru+2]Cl. Catalog: ACM145698904.
Dichlorobis (dicyclohexylphenylphosphine)nickel (II)
Catalyst used for the coupling of alkenes, aldehydes, and silyl triflates. Catalyst used for the cross-coupling of aryl Grignard reagents with aromatic ethers. Group: Couplingnickel catalysts. Alternative Names: Bis (dicyclohexylphenylphosphino)nickel (II) dichloride. CAS No. 19232-03-2. Molecular formula: C36H56Cl2NiP2. Mole weight: 680.4. Appearance: Orange to brown to dark purple powder to crystal. Purity: 95%+. IUPACName: dichloronickel; dicyclohexyl(phenyl)phosphanium. Canonical SMILES: C1CCC (CC1)[PH+] (C2CCCCC2)C3=CC=CC=C3. C1CCC (CC1)[PH+] (C2CCCCC2)C3=CC=CC=C3. Cl[Ni]Cl. Catalog: ACM19232032-1.
Dichlorobis (μ -methanethioato) bis (pentamethylcyclopentadienyl) diruthenium (III) , 99% (minimum 90% syn isomer)
Our company can provide customers with rich supported precious metal catalyst products such as palladium series, platinum series, rhodium series and ruthenium series. Our catalysts not only have high catalytic efficiency, strong selectivity, and recyclability, but also can be used in organic reactions such as hydrogenation, dehydrogenation, amination, and cyclization. In addition, some products can also be used as raw materials for various precious metal compounds. The company has formed a series of proprietary and characteristic process technologies, and is currently undergoing process improvement and upgrading. In short, our catalytic products can be widely used in medicine, new chemical materials, pesticides, dyes and pigments, environmental protection, new energy, electronics, basic chemicals and other fields. Uses: ·for ruthenium-catalyzed hydrogenation; ·for the preparation of wolfoss-type ferrocene aryl diphosphine ligands; ·for enantioselective hydrogenation of ketones and alkenes. Group: Ruthenium series catalysts. Alternative Names: Di-μ-iodobis(p-cymene)iodoruthenium(II). CAS No. 90614-07-6. Molecular formula: C20H30I4Ru2. Mole weight: 978.19 g/mol. Appearance: Solid. Purity: 0.97. Canonical SMILES: I[Ru]1[I][Ru](I)[I]1. C[C]2[CH][CH][C]([CH][CH]2)C(C)C. C[C]3[CH][CH][C]([CH][CH]3)C(C)C. Catalog: ACM90614076-2.
Addition to electron-deficient alkenes using a photoredox catalyst. Group: Iridium catalysts. CAS No. 870987-64-7. Molecular formula: C48H20Cl2F20Ir2N4. Mole weight: 1488.01. Catalog: ACM870987647.
Elemene Liposome
Elemene is a mixture of sesquiterpene alkenes, dominated by β-elemene, with broad-spectrum antitumor effects. This product is a pre-formulated liposome with elemene. It is only for research purposes. Group: Drug-loaded liposome. Categories: liposomes, niosomes, ethosomes, and transfersomes.
Formyl Polystyrene, Type1
This "polymeric benzaldehyde" reversibly binds e.g. amines or diols. Uses: The resin has been used to prepare 2,5-disubstituted tetrahydrofurans via electrophilic rearrangement of isoxazolines produced by the [3+2] addition of nitrile oxides to resin-bound alkenes and in the synthesis of new resins for chemical ligation and cyclization of unprotected peptides. Group: Formyl polystyrene resins. Pack Sizes: 5g, 25g, 100g.
Formyl Polystyrene, Type2
This "polymeric benzaldehyde" reversibly binds e.g. amines or diols. Uses: The resin has been used to prepare 2,5-disubstituted tetrahydrofurans via electrophilic rearrangement of isoxazolines produced by the [3+2] addition of nitrile oxides to resin-bound alkenes and in the synthesis of new resins for chemical ligation and cyclization of unprotected peptides. Group: Formyl polystyrene resins. Pack Sizes: 5g, 25g, 100g.
Geranyllinalool
Alkenes. Alternative Names: 3,7,11,15-Tetramethyl-1,6,10,14-Hexadecatetraen-3-Ol. CAS No. 1113-21-9. Molecular formula: C20H34O. Mole weight: 290.48. Purity: 0.9. Canonical SMILES: CC (=CCC/C (=C/CC/C (=C/CCC (C) (C=C)O)/C)/C)C. Catalog: ACM1113219.
Isophytol
Isophytol was used to study the acidities and acidity-catalytic activity relationships for sulfonic acid-functionalized ionic liquids with pyridinium cations.?Regioselective condesation of trimethylhydroquinone with isophytol produced (±)?-α-tocopherol (vitamin E; Tf= CF3SO2)?. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package. Group: Alkenes. Alternative Names: 3,7,11,15-Tetramethyl-1-hexadecene-3-ol. CAS No. 505-32-8. Molecular formula: C20H40O. Mole weight: 296.53. Appearance: Clear liquid. Purity: 0.98. IUPACName: 3,7,11,15-Tetramethylhexadec-1-en-3-ol. Canonical SMILES: CC(C)CCCC(C)CCCC(C)CCCC(C)(C=C)O. Density: 0.841 g/mL at 25 °C(lit.). Catalog: ACM505328.
methane monooxygenase (soluble)
The enzyme is soluble, in contrast to the particulate enzyme, EC 1.14.18.3. Broad specificity; many alkanes can be hydroxylated, and alkenes are converted into the corresponding epoxides; CO is oxidized to CO2, ammonia is oxidized to hydroxylamine, and some aromatic compounds and cyclic alkanes can also be hydroxylated, but more slowly. Group: Enzymes. Synonyms: methane hydroxylase. Enzyme Commission Number: EC 1.14.13.25. CAS No. 51961-97-8. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0833; methane monooxygenase (soluble); EC 1.14.13.25; 51961-97-8; methane hydroxylase. Cat No: EXWM-0833.
Methyl(triphenylphosphine)gold(I)
Catalyst used for the addition of water to alkynes. Highly efficient catalyst for the intermolecular hydroamination of alkynes. Relay catalysis using a gold(I) complex/ Bronsted acid binary system for the synthesis of benzoxasiloles. Gold(I) catalyzed intermolecular hydroarylation of alkenes with indoles. Group: Gold series of catalysts. Alternative Names: Carbanide; gold(1+); triphenylphosphane. CAS No. 23108-72-7. Molecular formula: C19H18AuP. Mole weight: 474.3. Appearance: Crystal. Purity: 0.99. IUPACName: carbanide; gold(1+); triphenylphosphane. Canonical SMILES: [CH3-]. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Au+]. Catalog: ACM23108727-1.
Myrcene analytical standard
Alkenes. CAS No. 123-35-3. Mole weight: 136.23. Catalog: ACM123353.
N-(3-Methoxypropyl)acrylamide contains mehq as inhibitor
A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes. A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides. Group: Heterocyclic organic compound. Alternative Names: Bis(diphenylphosphino)phenoxazine; DTXSID70390703; TRA0045396; 4,6-bis(diphenylphosphino)-phenoxazine; N-XantPhos, 97%; BB0294709; B2717; 4,6-Bis(diphenylphosphino)phenoxazine; 10H-Phenoxazine, 4,6-bis(diphenylphosphino)-; DB-009532. CAS No. 261733-18-0. Molecular formula: C36H27NOP2. Mole weight: 551.566g/mol. IUPACName: (6-diphenylphosphanyl-10H-phenoxazin-4-yl)-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC4=C3OC5=C (N4)C=CC=C5P (C6=CC=CC=C6)C7=CC=CC=C7. Catalog: ACM261733180.
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