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| Product | Description | |
|---|---|---|
| (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% | Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and -esters with aryl bromides. Photocatalyst used in the cross-coupling of trifluoroalkylboranes. Group: Iridium catalysts. CAS No. 1092775-62-6. Molecular formula: C34H18F16IrN4P. Mole weight: 1009.7. Catalog: ACM1092775626. |  |
| Chloro(1,5-cyclooctadiene)iridium(I) dimer | 1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins. 2. Precursor to catalyst for enantioselective reduction of imines. 3. Precursor to catalyst for allylic alkylation. 4. Precursor to catalyst for allylic amination and etherification. 5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes. 6. Ir-catalyzed addition of acid chlorides to terminal alkynes. 7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines. 8. Enantioselective [2+2] cycloaddition. 9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes. 10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates. 11. Transfer hydrogenative C-C coupling. Group: Iridium series of catalysts. Alternative Names: Bis(1,5-cyclooctadiene)diiridium(I) dichloride. CAS No. 12112-67-3. Molecular formula: C16H24Cl2Ir2. Mole weight: 671.71. Appearance: Red brown powder. Purity: 0.99. IUPACName: (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride. Canonical SMILES: C1CC=CCCC=C1. C1CC=CCCC=C1. [Cl-]. [Cl-]. [Ir]. [Ir]. ECNumber: 235-170-7. Catalog: ACM12112673-4. | |
| Triphenylphosphine, polymer-bound | 100-200 mesh, extent of labeling: ~1.6 mmol/g loading. Uses: Triphenylphosphine, polymer-bound is used as a polymer support to synthesize dipeptides, olefins, aryl-alkyl ethers, and in the esterification of alkylphosphonic acids. it acts as a lewis acid, and dehydrating agent when complexed with halogen, hence useful in the acetonation of sugars. Group: Polymer-bound. Alternative Names: Copolymer of styrene and divinylbenzene, diphenylphosphinated; Diphenylphosphino-polystyrene; Polystyrene crosslinked with divinylbenzene, diphenylphosphinated. CAS No. 39319-11-4. Mole weight: -C6H4P(C6H5)2. InChI=1S/C18H15P/c1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18/h1-15H. RIOQSEWOXXDEQQ-UHFFFAOYSA-N. |  |
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