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Allyl Alcohol is used in the synthesis of yohimbinoid alkaloids venenatine and alstovenine. Also used in the synthesis of (-)-nakadomarin A, a polycyclic alkaloid. Group: Biochemicals. Alternative Names: 2-Propen-1-ol;1-Hydroxy-2-propene; 1-Propen-3-ol; 2-Propenol; 2-Propenyl Alcohol; 3-Hydroxy-1-propene; 3-Hydroxypropene; Allylic Alcohol; NSC 6526; Shell Unkrauttod A; Vinylcarbinol. Grades: Highly Purified. CAS No. 107-18-6. Pack Sizes: 10g. US Biological Life Sciences.
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allyl-alcohol dehydrogenase
Also acts on saturated primary alcohols. Group: Enzymes. Enzyme Commission Number: EC 1.1.1.54. CAS No. 9028-58-4. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0339; allyl-alcohol dehydrogenase; EC 1.1.1.54; 9028-58-4. Cat No: EXWM-0339.
(Allyloxy)benzyl alcohol
(Allyloxy)benzyl alcohol. Uses: Designed for use in research and industrial production. Additional or Alternative Names: (Allyloxy)benzyl alcohol, Allyloxy(hydroxymethyl)benzene, Benzenemethanol, (2-propenyloxy)-, EINECS 249-127-5, Benzenemethanol, ar-(2-propenyloxy)-, CID6438212, Benzenemethanol, ar-(2-propen-1-yloxy)-, 28655-62-1. Product Category: Heterocyclic Organic Compound. CAS No. 28655-62-1. Molecular formula: C10H12O2. Mole weight: 164.201080 [g/mol]. Purity: 0.96. IUPACName: [2-[(E)-prop-1-enoxy]phenyl]methanol. Product ID: ACM28655621. Alfa Chemistry ISO 9001:2015 Certified.
trans-3-(Trimethylsilyl)allyl alcohol. Uses: Designed for use in research and industrial production. Product Category: Alkenes. CAS No. 59376-64-6. Mole weight: 130.26. Product ID: ACM59376646. Alfa Chemistry ISO 9001:2015 Certified.
Trans-3-(Trimethylsilyl)allyl alcohol
Trans-3-(Trimethylsilyl)allyl alcohol. CAS No: 59376-64-6
Sarchem Laboratories New Jersey NJ
1,1'-Bis(diisopropylphosphino)ferrocene
1,1'-Bis(diisopropylphosphino)ferrocene. Uses: Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes ligand for palladium-catalyzed aminocarbonylation of pyridyl tosylates by means of ex situ generation of co. pd-catalyzed carbonylative ?-arylation of ketones with aryl iodides ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-c-glycosylation ligand for ruthenium-catalyzed c-c coupling reactions of fluorinated alcohols with allenes. ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using n-3-picolin-2-yl aldimines as aldehyde equivalents. Additional or Alternative Names: 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE. Product Category: Organic Phosphine Compounds. Appearance: Orange-yellow powder. CAS No. 97239-80-0. Molecular formula: C22H36FeP2. Mole weight: 418.32. Purity: 0.98. IUPACName: 1,1-Bis(diisopropylphosphino)ferrocene. Product ID: ACM97239800. Alfa Chemistry ISO 9001:2015 Certified. Categories: 1,1\'-Bis(diisopropylphosphino)ferrocene.
2,2'-Bis(diphenylphosphino)biphenyl
2,2'-Bis(diphenylphosphino)biphenyl. Uses: Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. useful ligand for palladium-catalyzed amination and kumada cross-coupling reactions useful ligand for palladium-catalyzed synthesis of butatrenes. useful ligand for iridium-catalyzed c-c cross-coupling of allenes with primary alcohols via transfer hydrogenation. useful ligand for iridium-catalyzed c-c cross-coupling of dienes with primary alcohols via transfer hydrogenation. useful ligand for iridium-catalyzed c-c cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. ruthenium-catalyzed synthesis of indoles. ruthenium-catalyzed oxidative cyclization. rhodium-catalyzed boron arylation. Additional or Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1,1'-[[1,1'-BIPHENYL]-2,2'-DIYL]BIS[1,1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. Product Category: Organic Phosphine Compounds. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPACName: [2-(2-diphenylphosphanylphenyl)phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6. Product ID: ACM84783642.
(2E)-3-[4-(Phenylmethoxy)phenyl]-2-propen-1-ol
(2E)-3-[4-(Phenylmethoxy)phenyl]-2-propen-1-ol is used as a regeant in the synthesis for regioselectivity and stereoselective carboxylation of allylic alcohols.1. Group: Biochemicals. Grades: Highly Purified. CAS No. 84184-52-1. Pack Sizes: 10mg, 50mg. Molecular Formula: C16H16O2, Molecular Weight: 240.3. US Biological Life Sciences.
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2-Propen-1,1,2,3,3-d5-1-ol
2-Propen-1,1,2,3,3-d5-1-ol is isotopically labelled form of Allyl Alcohol, which is used in the synthesis of yohimbinoid alkaloids venenatine and alstovenine. Also used in the synthesis of polycyclic alkaloid (-)-nakadomarin A. Group: Biochemicals. Grades: Highly Purified. CAS No. 102910-30-5. Pack Sizes: 5mg, 10mg. Molecular Formula: C3HD5O. US Biological Life Sciences.
(2R,5R)-(+)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone is a reactant used in the preparation of allyl heterocycles using palladium-catalyzed allylic amination of allylic alcohols with heterocycles. Group: Biochemicals. Grades: Highly Purified. CAS No. 877303-84-9. Pack Sizes: 50mg, 100mg. Molecular Formula: C16H18N2O2, Molecular Weight: 270.33. US Biological Life Sciences.
Worldwide
3-Allyl-4-hydroxybenzaldehyde
3-Allyl-4-hydroxybenzaldehyde. Uses: Designed for use in research and industrial production. Additional or Alternative Names: CHEMBRDG-BB 6474172;3-ALLYL-4-HYDROXYBENZALDEHYDE. Product Category: Alcohols. CAS No. 41052-88-4. Molecular formula: C10H7BrO. Mole weight: 162.19. Product ID: ACM41052884. Alfa Chemistry ISO 9001:2015 Certified.
3-Bromo-4-fluoro-5-nitrobenzoic Acid
3-Bromo-4-fluoro-5-nitrobenzoic Acid is a derivative of m-Nitrobenzoic Acid (N494700), a reagent used in the coupling of allyl acetate to allylic, aliphatic and benzylic alcohols. Group: Biochemicals. Grades: Highly Purified. CAS No. 1290117-21-3. Pack Sizes: 250mg, 500mg. Molecular Formula: C7H3BrFNO4, Molecular Weight: 264.01. US Biological Life Sciences.
Worldwide
3-Buten-1-ol
3-Buten-1-ol is an aliphatic primary alcohol used as a reagent in organic synthesis. Group: Biochemicals. Alternative Names: 1-Buten-4-ol; 1-Hydroxy-3-butene; 3-Butenyl Alcohol; 4-Hydroxy-1-butene; Allylcarbinol; Homoallyl Alcohol; NSC 60194; β-Vinylethanol. Grades: Highly Purified. CAS No. 627-27-0. Pack Sizes: 5g. US Biological Life Sciences.
Worldwide
4-tert-Amylcyclohexanol,mixture of cis and trans
4-tert-Amylcyclohexanol,mixture of cis and trans. Uses: Designed for use in research and industrial production. Additional or Alternative Names: Allyl lactate, 4-tert-Pentylcyclohexanol, p-tert-Amylcyclohexanol, Cyclohexanol, 4-tert-pentyl-, trans-4-t-Pentylcyclohexanol, 412619_ALDRICH, NSC 1246, EINECS 226-311-3, NSC1246, MolPort-001-793-317, NSC 21165, CID79302, NSC21165, 4-tert-AMYLCYCLOHEXANOL, 99%, Cyclohexanol, 4-(1,1-dimethylpropyl)-, ZINC01591807, Cyclohexanol, 4-tert-pentyl- (8CI), BBV-142459, NCGC00164171-01, LS-57359. Product Category: Alcohols. CAS No. 5349-51-9. Molecular formula: C11H14ClNO. Mole weight: 170.29. Purity: 0.96. IUPACName: 4-(2-methylbutan-2-yl)cyclohexan-1-ol. Canonical SMILES: CCC(C)(C)C1CCC(CC1)O. Density: 0.914g/cm³. ECNumber: 226-311-3. Product ID: ACM5349519. Alfa Chemistry ISO 9001:2015 Certified.
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II). Uses: Catalyst for the cross-coupling of aryl chlorides with boronic acids. catalyst for the diamination of conjugated dienes and trienes. catalyst for the dehalogenation of aryl chlorides. catalyst for anaerobic alcohol oxidation. catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. Additional or Alternative Names: Palladium, [1,?3-bis[2,?6-bis(1-methylethyl)?phenyl]?-1,?3-dihydro-2H-imidazol-2-ylidene]?chloro(η3-2-propen-1-yl)?-. Product Category: Organic Phosphine Compounds. Appearance: white solid. CAS No. 478980-03-9. Molecular formula: C30H42ClN2Pd. Mole weight: 572.54. Purity: 98%, Pd>18.5%. Product ID: ACM478980039. Alfa Chemistry ISO 9001:2015 Certified.
Allyl heptanoate
Allyl heptanoate is an ester that is formed by the esterification of medium-chain fatty acids, heptanoic acid and allyl alcohol. The compound has a fruity smell and is commonly used as a flavoring in foods such as baked goods, candy and beverages. Uses: Scientific research. Group: Biochemical assay reagents. Alternative Names: Prop-2-en-1-yl heptanoate. CAS No. 142-19-8. Pack Sizes: 5 g; 25 g. Product ID: HY-W016976.
Bis(benzonitrile)dichloroplatinum(II)
Bis(benzonitrile)dichloroplatinum(II). Uses: Catalyst for: asymmetric hydroformylation reactions allylation reactions carbene insertion into o-h bonds of alcohols cyclopropanation reactions hydrosilylation reacttions. Additional or Alternative Names: AKOS015964364; cis-Di(benzonitrile)dichloroplatinum (II); 15617-19-3; dichloride; AC1L38NI. Product Category: Platinum series of catalysts. CAS No. 15617-19-3. Molecular formula: C14H10Cl2N2Pt. Mole weight: 472.232g/mol. IUPACName: benzonitrile;platinum(2+);dichloride. Canonical SMILES: C1=CC=C(C=C1)C#N.C1=CC=C(C=C1)C#N.[Cl-].[Cl-].[Pt+2]. ECNumber: 238-943-7. Product ID: ACM15617193. Alfa Chemistry ISO 9001:2015 Certified. Categories: 14873-63-3.
Cinnamyl acetate
Cinnamyl acetate. CAS No. 103-54-8. Pack Sizes: 250 mL in glass bottle. Product ID: CDC10-0194. Molecular formula: C11H12O2. Category: Flavoring Chemical Agents. Product Keywords: Cosmetic Ingredients; Flavoring Chemical Agents; Cinnamyl acetate; CDC10-0194; 103-54-8; C11H12O2; 203-121-9; MFCD00008722; 103-54-8. Purity: 0.99. EC Number: 203-121-9. Physical State: Powder. Solubility: alcohol: soluble(lit.). Quality Level: 100. Boiling Point: 265 °C (lit.). Melting Point: 30 °C. Density: 1.057 g/mL at 25 °C. Product Description: Cinnamyl acetate is a fragrance ingredient. Palladium catalyzed allylic alkylation of cinnamyl acetate using sodium diethyl 2-methylmalonate and novel ferrocenyl Schiff base has been investigated.
Dde-Lys(Fmoc)-OH
Quasi-orthogonally-protected Lys derivative. The Fmoc group can be removed selectively by treatment with piperidine; the Dde group is cleaved with 2% hydrazine in DMF. When removing Dde in the presence of allyl-based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Also available Fmoc-Lys(Dde)-OH 852057. This derivative has been employed in Fmoc SPPS to facilitate the introduction of biotin to the side-chain of lysine. Uses: Peptide synthesis. Additional or Alternative Names: Dde-Lys(Fmoc)-OH, N-α-1-(4,4-Dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl-N-ε-Fmoc-L-lysine. Product Category: Amino Acids. CAS No. 156648-40-7. Mole weight: 532.63. Product ID: ACM156648407. Alfa Chemistry ISO 9001:2015 Certified.
Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV). Uses: An efficient catalyst used for the isomerization of allylic alcohols into carbonyl compounds in organic or aqueous media. an efficient catalyst used for the deprotection of n-allylic amines. Additional or Alternative Names: Dichloro(2,6,10-dodecatriene-1,12-diyl)ruthenium(IV). Appearance: Orange xtl. CAS No. 12170-97-7. Molecular formula: C12H18Cl2Ru. Mole weight: 334.24. Product ID: ACM12170977-1. Alfa Chemistry ISO 9001:2015 Certified.
Fmoc-Dab(ivDde)-OH
This orthogonally-protected diaminobutyric acid derivative is based on the hindered Dde variant ivDde. The side-chain ivDde group is considerably more stable to piperidine than Dde and is less prone to migrate from protected to unprotected side-chains and from side-chain to γ-amino group.When removing ivDde in the presence of allyl-based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Additional or Alternative Names: Fmoc-Dab(ivDde)-OH, N-α-Fmoc-N-γ-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-L-diaminobutanoic acid. Product Category: Amino Acids. CAS No. 607366-21-2. Mole weight: 546.65. Product ID: ACM607366212. Alfa Chemistry ISO 9001:2015 Certified.
Fmoc-D-Dpr(ivDde)-OH
This orthogonally-protected derivative is based on the hindered Dde variant ivDde. It has very similar chemical properties to Fmoc-Lys(Dde)-OH, except that the side-chain ivDde group is considerably more stable to piperidine than Dde, and is less prone to migrate from protected to unprotected lysine side-chains. When removing ivDde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Guide to Selection of Orthogonally-Protected Building Blocks for Fmoc SPPS. Uses: Peptide synthesis. Additional or Alternative Names: Fmoc-D-Dpr(ivDde)-OH, N-α-Fmoc-N-β-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-D-diaminopropionic acid. Product Category: Amino Acids. CAS No. 1228900-15-9. Mole weight: 532.63. Product ID: ACM1228900159-1. Alfa Chemistry ISO 9001:2015 Certified.
Fmoc-D-Lys(ivDde)-OH
This orthogonally-protected lysine derivative is based on the hindered Dde variant ivDde. It has very similar chemical properties to Fmoc-Lys(Dde)-OH, except that the side-chain ivDde group is considerably more stable to piperidine than Dde, and is less prone to migrate from protected to unprotected lysine side-chains. When removing ivDde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Additional or Alternative Names: Fmoc-D-Lys(ivDde)-OH, N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3methylbutyl-D-lysine. Product Category: Amino Acids. CAS No. 1272755-33-5. Molecular formula: C34H42N2O6. Mole weight: 574.71. Density: 1.2±0.1 g/cm3. Product ID: ACM1272755335. Alfa Chemistry ISO 9001:2015 Certified.
Fmoc-Lys(Dde)-OH
Quasi-orthogonally-protected Lys derivative for Fmoc SPPS. The Fmoc group can be removed selectively by treatment with piperidine; the Dde group is cleaved with 2% hydrazine in DMF. When removing Dde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Lys(Dde) has been employed in the following applications: synthesis of branched peptides and di-epitopic peptides ; preparation of MAP core molecules and lipo-MAPs; construction of cyclic peptides , TASP molecules , templates for combinatorial chemistry and synthetic proteins ; preparation of peptides modified at the lysine side-chain.It has been reported that Dde can migrate from the side-chain of Lys to the unprotected side-chain of another Lys residue , and from the β-amino group to the α-amino group of Dpr. In the former instance, this problem can be overcome by using Fmoc-Lys(ivDde)-OH or using DBU/DMF (2:98) for Fmoc group removal.Full orthogonality of Dde with Fmoc has recently been demonstrated when hydroxylamine is used for Dde removal. Uses: Peptide synthesis. Additional or Alternative Names: Fmoc-Lys(Dde)-OH, N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl-L-lysine. Product Category: Amino Acids. CAS No. 150629-67-7. Molecular formula: C31H36N2O6. Mole weight: 532.63. Product ID: ACM150629677. Alfa Chemistry ISO 9001:2015
Fmoc-Lys(ivDde)-OH
This orthogonally-protected lysine derivative is based on the hindered Dde variant ivDde. It has very similar chemical properties to Fmoc-Lys(Dde)-OH, except that the side-chain ivDde group is considerably more stable to piperidine than Dde, and is less prone to migrate from protected to unprotected lysine side-chains.When removing ivDde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Additional or Alternative Names: Fmoc-Lys(ivDde)-OH, N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-L-lysine. Product Category: Amino Acids. CAS No. 204777-78-6. Molecular formula: C34H42N2O6. Mole weight: 574.71. IUPACName: (2S)-6-[[1-(4,4-dimethyl-2,6-dioxocyclohexylidene)-3-methylbutyl]amino]-2-(9H-fluoren-9-ylmethoxycarbonylamino)hexanoic acid. Canonical SMILES: CC(C)CC(=C1C(=O)CC(CC1=O)(C)C)NCCCCC(C(=O)O)NC(=O)OCC2C3=CC=CC=C3C4=CC=CC=C24. Density: 1.2±0.1 g/cm3. Product ID: ACM204777786. Alfa Chemistry ISO 9001:2015 Certified.
Fmoc-Orn(ivDde)-OH
This orthogonally-protected ornithine derivative is based on the hindered Dde variant ivDde. The side-chain ivDde group is considerably more stable to piperidine than Dde and is less prone to migrate from protected to unprotected side-chains. When removing ivDde in the presence of allyl-based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Additional or Alternative Names: Fmoc-Orn(ivDde)-OH, N-α-Fmoc-N-δ-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-L-ornithine. Product Category: Amino Acids. CAS No. 1198321-33-3. Mole weight: 560.68. Product ID: ACM1198321333-1. Alfa Chemistry ISO 9001:2015 Certified.
Manganese(IV) Oxide
Manganese(IV) Oxide is used in dry-cell batteries such as alkaline battery and the zinc-carbon battery. It is also used in the oxidation of allylic alcohols. Group: Biochemicals. Grades: Highly Purified. CAS No. 1313-13-9. Pack Sizes: 25g, 100g. Molecular Formula: MnO2, Molecular Weight: 86.94. US Biological Life Sciences.
Worldwide
monoterpenyl-diphosphatase
A group of enzymes with varying specificity for the monoterpenol moiety. One has the highest activity on sterically hindered compounds such as (+)-bornyl diphosphate; another has highest activity on the diphosphates of primary allylic alcohols such as geraniol. Group: Enzymes. Synonyms: bornyl pyrophosphate hydrolase; monoterpenyl-pyrophosphatase. Enzyme Commission Number: EC 3.1.7.3. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-3764; monoterpenyl-diphosphatase; EC 3.1.7.3; bornyl pyrophosphate hydrolase; monoterpenyl-pyrophosphatase. Cat No: EXWM-3764.
P-Coumaryl Alcohol
P-Coumaryl Alcohol. Uses: Designed for use in research and industrial production. Additional or Alternative Names: p-Coumaryl alcohol;3-(4-hydroxyphenyl)-1-propane;3-(4-Hydroxyphenyl)allyl alcohol;3-(p-Hydroxyphenyl)-2-propen-1-ol;4-(3-Hydroxy-1-propenyl)phenol;p-Coumaric alcohol;p-Hydroxycinnamic alcohol. Appearance: White powder. CAS No. 3690-5-9. Molecular formula: C9H10O2. Mole weight: 150.2. Purity: 0.98. IUPACName: 4-[(E)-3-hydroxyprop-1-enyl]phenol. Canonical SMILES: C1=CC(=CC=C1C=CCO)O. Density: 1.188g/cm³. ECNumber: 609-308-5. Product ID: ACM3690059. Alfa Chemistry ISO 9001:2015 Certified.
perillyl-alcohol dehydrogenase
Oxidizes a number of primary alcohols with the alcohol group allylic to an endocyclic double bond and a 6-membered ring, either aromatic or hydroaromatic. Group: Enzymes. Synonyms: perillyl alcohol dehydrogenase. Enzyme Commission Number: EC 1.1.1.144. CAS No. 37250-73-0. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0048; perillyl-alcohol dehydrogenase; EC 1.1.1.144; 37250-73-0; perillyl alcohol dehydrogenase. Cat No: EXWM-0048.
Polyallylamine hydrochloride is a cationic polyelectrolyte prepared by the polymerization of allylamine. Uses: Soluble in water, lower alcohols, ethylene glycol and formamide. Group: Hydrophilic polymers. Alternative Names: PAH. CAS No. 30551-89-4. Pack Sizes: Packaging 1, 5, 25 g in poly bottle. Product ID: prop-2-en-1-amine. Molecular formula: average Mw ~15,000. Mole weight: [CH2CH(CH2NH2)]n. NCC=C. 1S/C3H7N/c1-2-3-4/h2H,1,3-4H2. VVJKKWFAADXIJK-UHFFFAOYSA-N.
p-Toluenesulfonamide
p-Toluenesulfonamide. CAS No. 70-55-3. Pack Sizes: 1 kg. Product ID: CDC10-0254. Molecular formula: C7H9NO2S. Category: Cosmetic Plasticizers. Product Keywords: Cosmetic Ingredients; Cosmetic Plasticizers; p-Toluenesulfonamide; CDC10-0254; 70-55-3; C7H9NO2S; 200-741-1; MFCD00011692; 70-55-3. Purity: 0.99. Color: White Crystalline Powder. EC Number: 200-741-1. Physical State: Powder. Application: p-Toluenesulfonamide undergoes FeCl3-catalyzed direct substitution reaction with benzylic and allylic alcohols.It is employed as nucleophile in tetrabutylammonium fluoride (TBAF) catalyzed vinyl aziridine opening reaction. Boiling Point: 221°C (10 mmHg). Melting Point: 136-140°C. Density: 1.271 g/cm3. Product Description: p-Toluenesulfonamide undergoes FeCl3-catalyzed direct substitution reaction with benzylic and allylic alcohols.It is employed as nucleophile in tetrabutylammonium fluoride (TBAF) catalyzed vinyl aziridine opening reaction.
Rhodium(II) acetate dimer
Rhodium(II) acetate dimer. Uses: Catalyst for insertion into c-h and x-h bonds. catalyst for ylide generation. doyle-kirmse reaction of allylic sulfides with diazoalkane claisen rearrangement. epoxides from aldehydes. synthesis of aziridines from allylic n-tosyloxycarbamates. rh/nhc catalyzed direct intermolecular arylation of c-h bonds. chiral bronsted acid-rh catalyzed three component reactions of diazo compounds with alcohols and imines. rh-catalyzed cyclopropenations of ynamides. tandem asymmetric aza-darzens/ring-opening reactions. Group: Salt electrolytessolution deposition precursors. Alternative Names: Tetrakis-(mu-acetato)dirhodium. CAS No. 15956-28-2. Product ID: rhodium(2+); tetraacetate. Molecular formula: 441.99. Mole weight: C8H12O8Rh2. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. [Rh+2]. [Rh+2]. InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4; /h4*1H3, (H, 3, 4); /q; 2*+2/p-4. SYBXSZMNKDOUCA-UHFFFAOYSA-J. 98%.
Silver trifluoromethanesulfonate
Silver trifluoromethanesulfonate. Uses: Silver precatalyst for the asymmetric allylation of aldehydes silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins silver catalyst for the fluorination of boronic acids silver catalyst for the fluorination of functionalized aryl stannanes silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate. Additional or Alternative Names: KSC491Q9D; Silver trifluoromethanesulfonate, >=99%; silver(1+) ion trifluoromethanesulfonate; silver(I)trifluoromethanesulfonate; TRIFLUOROMETHANESULFONATE SILVER SALT; trifluormethanesulfonic acid silver salt; silver(I) trifluoromethanesulphonate; ANW-26574; QRUBYZBWAOOHSV-UHFFFAOYSA-M; X7226. Product Category: Silver series of catalysts. Appearance: Powder. CAS No. 2923-28-6. Molecular formula: CAgF3O3S. Mole weight: 256.94. Purity: 0.98. IUPACName: silver;trifluoromethanesulfonate. Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].[Ag+]. ECNumber: 220-882-2. Product ID: ACM2923286-1. Alfa Chemistry ISO 9001:2015 Certified.
t-BuDavePhos
t-BuDavePhos. Uses: Useful ligand for pd-catalyzed carbon-oxygen bond forming reactions. ligand used selective pd-catalyzed arylation of ammonia. application to the synthesis of dibenzodiazepines. ligand used for selective pd-catalyzed silylation of aryl chlorides. ligand used for pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. Additional or Alternative Names: 2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179. Product Category: Organic Phosphine Compounds. CAS No. 224311-49-3. Molecular formula: C22H32NP. Mole weight: 341.479g/mol. IUPACName: 2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline. Canonical SMILES: CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2N(C)C)C(C)(C)C. Product ID: ACM224311493. Alfa Chemistry ISO 9001:2015 Certified. Categories: 2-di-tert-butylphosphino-2'-(N,N-dimethylamino)biphenyl.
Trimethylsulfonium Iodide
Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. Group: Battery materials dye-sensitized solar cell (dssc) materials. Alternative Names: S111 I. CAS No. 2181-42-2. Product ID: trimethylsulfanium; iodide. Molecular formula: 204.07. Mole weight: C3H9IS. C[S+](C)C.[I-]. InChI=1S/C3H9S.HI/c1-4(2)3; /h1-3H3; 1H/q+1; /p-1. VFJYIHQDILEQNR-UHFFFAOYSA-M. >98.0%T.
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate. Uses: Catalyst used for the coupling of allene with activated olefines to form 1,3-diene. catalyst used for the dimerization of propargyl alcohols. catalyst used in the trost's ruthenium-catalyzed ene-yne cross-coupling reaction. catalyst for asymmetric cyclization of ω-hydroxy allyl alcohols to give α-alkenyl cyclic ethers. catalyst for synthesis of furans from bis(alkynes) and dmso. Additional or Alternative Names: (Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate. Product Category: Ruthenium series catalysts. Appearance: yellow to orange powder. CAS No. 80049-61-2. Molecular formula: C11H14F6N3PRu. Mole weight: 434.3. Purity: 0.98. Canonical SMILES: CC#N.CC#N.CC#N.C1=C[CH]C=C1.F[P-](F)(F)(F)(F)F.[Ru+]. Product ID: ACM80049612-1. Alfa Chemistry ISO 9001:2015 Certified.
Tris(triphenylphosphine)rhodium(I) chloride
Tris(triphenylphosphine)rhodium(I) chloride. Uses: A homogeneous hydrogenation catalyst which operates under mild conditions. catalyst for the decarbonylation of aldehydes. catalyst for regio- and stereoselective allylic substitution reactions. alkyne hydro-phosphorylation heck-type reaction with α,β-unsaturated esters. alkyne arylation allylic alcohol-olefin coupling. terminal alkenes from ketones. rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. reductive deprotection of silyl groups. Group: Salt. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Product ID: rhodium; triphenylphosphane; chloride. Molecular formula: 925.21. Mole weight: C54H45ClP3Rh. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. InChI=1S/3C18H15P. ClH. Rh/c3*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; /h3*1-15H; 1H; /p-1. QBERHIJABFXGRZ-UHFFFAOYSA-M. 98%.
Vanillyl-alcohol oxidase from Penicillium simplicissimum contains covalently bound FAD. It converts a wide range of 4-hydroxybenzyl alcohols and 4-hydroxybenzylamines into the corresponding aldehydes. The allyl group of 4-allylphenols is also converted into the -CH=CH-CH2OH group. Group: Enzymes. Synonyms: 4-hydroxy-2-methoxybenzyl alcohol oxidase. Enzyme Commission Number: EC 1.1.3.38. CAS No. 143929-24-2. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0410; vanillyl-alcohol oxidase; EC 1.1.3.38; 143929-24-2; 4-hydroxy-2-methoxybenzyl alcohol oxidase. Cat No: EXWM-0410.
Yttrium(III) tris(isopropoxide)
Yttrium(III) tris(isopropoxide). Uses: Catalyst for: stereoselective conjugate addition reactions ring-opening polymerizations generation of reactive enolates by enantioselective protonation reactions cyano-phosphorylation of enone and allylic substitution synthesis of nanocompositesreactant for the preparation of flat hfo2 films. Group: Vapor deposition precursors. Alternative Names: 2-Propanol yttrium(III) salt, Isopropyl alcohol yttrium(III) salt, Tris(isopropoxy) yttrium(III). CAS No. 2172-12-5. Pack Sizes: 500 mg in glass bottle. Product ID: propan-2-olate; yttrium(3+). Molecular formula: 266.17. Mole weight: Y(OCH(CH3)2)3. CC(C)O[Y](OC(C)C)OC(C)C. 1S/3C3H7O.Y/c3*1-3(2)4;/h3*3H, 1-2H3;/q3*-1;+3, PYLIDHFYDYRZSC-UHFFFAOYSA-N. PYLIDHFYDYRZSC-UHFFFAOYSA-N.
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