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| Product | Description | |
|---|---|---|
| Allyl Alcohol | Allyl Alcohol is used in the synthesis of yohimbinoid alkaloids venenatine and alstovenine. Also used in the synthesis of (-)-nakadomarin A, a polycyclic alkaloid. Group: Biochemicals. Alternative Names: 2-Propen-1-ol;1-Hydroxy-2-propene; 1-Propen-3-ol; 2-Propenol; 2-Propenyl Alcohol; 3-Hydroxy-1-propene; 3-Hydroxypropene; Allylic Alcohol; NSC 6526; Shell Unkrauttod A; Vinylcarbinol. Grades: Highly Purified. CAS No. 107-18-6. Pack Sizes: 10g. US Biological Life Sciences. |  Worldwide |
| allyl-alcohol dehydrogenase | Also acts on saturated primary alcohols. Group: Enzymes. Enzyme Commission Number: EC 1.1.1.54. CAS No. 9028-58-4. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0339; allyl-alcohol dehydrogenase; EC 1.1.1.54; 9028-58-4. Cat No: EXWM-0339. |  |
| Poly(styrene-co-allyl alcohol) | Poly(styrene-co-allyl alcohol). Group: Hydrophobic polymers. CAS No. 25119-62-4. Product ID: prop-2-en-1-ol; styrene. Molecular formula: 162.23g/mol. Mole weight: C11H14O. C=CCO.C=CC1=CC=CC=C1. InChI=1S/C8H8. C3H6O/c1-2-8-6-4-3-5-7-8; 1-2-3-4/h2-7H, 1H2; 2, 4H, 1, 3H2. WXNYILVTTOXAFR-UHFFFAOYSA-N. |  |
| Poly(styrene-co-allyl alcohol) (average Mn ~1, 600, crystalline, allyl alcohol 33mol %) | Poly(styrene-co-allyl alcohol) (average Mn ~1, 600, crystalline, allyl alcohol 33mol %). Group: Polystyrene (ps). CAS No. 25119-62-4. Product ID: prop-2-en-1-ol; styrene. C=CCO.C=CC1=CC=CC=C1. InChI=1S/C8H8. C3H6O/c1-2-8-6-4-3-5-7-8; 1-2-3-4/h2-7H, 1H2; 2, 4H, 1, 3H2. WXNYILVTTOXAFR-UHFFFAOYSA-N. | |
| Poly(styrene-co-allyl alcohol) (average MW~2, 200, average Mn ~1, 200, allyl alcohol 40mol %) | Poly(styrene-co-allyl alcohol) (average MW~2, 200, average Mn ~1, 200, allyl alcohol 40mol %). Group: Polystyrene (ps). CAS No. 25119-62-4. Product ID: prop-2-en-1-ol; styrene. C=CCO.C=CC1=CC=CC=C1. InChI=1S/C8H8. C3H6O/c1-2-8-6-4-3-5-7-8; 1-2-3-4/h2-7H, 1H2; 2, 4H, 1, 3H2. WXNYILVTTOXAFR-UHFFFAOYSA-N. | |
| Styrene/allyl alcohol copolymer | Styrene/allyl alcohol copolymer. Group: Polymers. Alternative Names: 2-Propen-1-ol,polymerwithethenylbenzene; Aeroleinpolymerwithstyrene; POLY(STYRENE-CO-ALLYL ALCOHOL); SAA-100(TM), SAA-101(TM); STYRENE/ALLYL ALCOHOL COPOLYMER; STYRENE-ALLYL ALCOHOL COPOLYMERS; 2-Propen-1-ol/styrene copolymer; SAA 100. CAS No. 25119-62-4. Product ID: prop-2-en-1-ol; styrene. Molecular formula: 162.23g/mol. Mole weight: C11H14O. C=CCO.C=CC1=CC=CC=C1. InChI=1S/C8H8. C3H6O/c1-2-8-6-4-3-5-7-8; 1-2-3-4/h2-7H, 1H2; 2, 4H, 1, 3H2. WXNYILVTTOXAFR-UHFFFAOYSA-N. | |
| Trans-3-(Trimethylsilyl)allyl alcohol | Trans-3-(Trimethylsilyl)allyl alcohol. CAS No: 59376-64-6 |  Sarchem Laboratories New Jersey NJ |
| 1, 1'-Bis (diisopropylphosphino)ferrocene | Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO. Pd-catalyzed carbonylative ?-arylation of ketones with aryl iodides Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation Ligand for ruthenium-catalyzed C-C coupling reactions of fluorinated alcohols with allenes. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents. Group: Organic phosphine compounds. Alternative Names: 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE. CAS No. 97239-80-0. Molecular formula: C22H36FeP2. Mole weight: 418.32. Appearance: Orange-yellow powder. Purity: 0.98. IUPACName: 1,1-Bis(diisopropylphosphino)ferrocene. Catalog: ACM97239800. |  |
| 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene | The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides. Asymmetric hydrogenation of vinyl alcohols. Catalyst used for the asymmetric hydrogenation of enol phosphonates. Asymmetric hydrogenation of allylic alcohols. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Group: Heterocyclic organic compound. Alternative Names: (R,R)-1,2-Bis(2,5-dimethylphospholano)benzene; DTXSID20163641; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, kanata purity; H5W03D1HAQ; UNII-H5W03D1HAQ; (R,R)-Me-DUPHOS; AJNZWRKTWQLAJK-KLHDSHLOSA-N; (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene; (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, >=95.0%. CAS No. 147253-67-6. Molecular formula: C18H28P2. Mole weight: 306.37g/mol. IUPACName: (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane. Canonical SMILES: CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. ECNumber: 604-579-6. Catalog: ACM147253676. | |
| 2,2'-Bis(diphenylphosphino)biphenyl | Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Group: Organic phosphine compounds. Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1, 1'-[[1, 1'-BIPHENYL]-2, 2'-DIYL]BIS[1, 1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPACName: [2- (2-diphenylphosphanylphenyl) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM84783642. | |
| 2,3-Dibromo-1-propanol | Flame Retardant. Group: Brominated flame retardant. Alternative Names: DBP; USAF DO-42; Allyl alcohol dibromide; ß-Dibromohydrin; b-Dibromo hydrin; NSC 6203; 1,2-Dibromohydrin; DBP (flame retardant); Dibromopropanol; 2,3-dibromopropan-1-ol; NCI-C55436; 2,3-Dibromopropyl alcohol; Glycerol 1,2-dibromohydrin; beta-dibromohydrin; Brominex 257; ALPHA,BETA-DIBROMOHYDRIN; 1,2-Dibromopropan-3-ol; 2,3-Dibromo-1-propanol; GLYCEROL ALPHA,BETA-DIBROMOHYDRIN; 2,3-Dibromopropanol. CAS No. 96-13-9. Molecular formula: C3H6Br2O. Density: 2.12 g/mL at 25 °C. Catalog: ACM96139. | |
| (2E)-3-[4-(Phenylmethoxy)phenyl]-2-propen-1-ol | (2E)-3-[4-(Phenylmethoxy)phenyl]-2-propen-1-ol is used as a regeant in the synthesis for regioselectivity and stereoselective carboxylation of allylic alcohols.1. Group: Biochemicals. Grades: Highly Purified. CAS No. 84184-52-1. Pack Sizes: 10mg, 50mg. Molecular Formula: C16H16O2, Molecular Weight: 240.3. US Biological Life Sciences. | Worldwide |
| 2-Propen-1,1,2,3,3-d5-1-ol | 2-Propen-1,1,2,3,3-d5-1-ol is isotopically labelled form of Allyl Alcohol, which is used in the synthesis of yohimbinoid alkaloids venenatine and alstovenine. Also used in the synthesis of polycyclic alkaloid (-)-nakadomarin A. Group: Biochemicals. Grades: Highly Purified. CAS No. 102910-30-5. Pack Sizes: 5mg, 10mg. Molecular Formula: C3HD5O. US Biological Life Sciences. | Worldwide |
| (2R,5R)-(+)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone | (2R,5R)-(+)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone is a reactant used in the preparation of allyl heterocycles using palladium-catalyzed allylic amination of allylic alcohols with heterocycles. Group: Biochemicals. Grades: Highly Purified. CAS No. 877303-84-9. Pack Sizes: 50mg, 100mg. Molecular Formula: C16H18N2O2, Molecular Weight: 270.33. US Biological Life Sciences. | Worldwide |
| 3-Bromo-4-fluoro-5-nitrobenzoic Acid | 3-Bromo-4-fluoro-5-nitrobenzoic Acid is a derivative of m-Nitrobenzoic Acid (N494700), a reagent used in the coupling of allyl acetate to allylic, aliphatic and benzylic alcohols. Group: Biochemicals. Grades: Highly Purified. CAS No. 1290117-21-3. Pack Sizes: 250mg, 500mg. Molecular Formula: C7H3BrFNO4, Molecular Weight: 264.01. US Biological Life Sciences. | Worldwide |
| 3-Buten-1-ol | 3-Buten-1-ol is an aliphatic primary alcohol used as a reagent in organic synthesis. Group: Biochemicals. Alternative Names: 1-Buten-4-ol; 1-Hydroxy-3-butene; 3-Butenyl Alcohol; 4-Hydroxy-1-butene; Allylcarbinol; Homoallyl Alcohol; NSC 60194; β-Vinylethanol. Grades: Highly Purified. CAS No. 627-27-0. Pack Sizes: 5g. US Biological Life Sciences. | Worldwide |
| Allyl[1, 3-bis (2, 6-diisopropylphenyl) -2-imidazolidinylidene]chloropalladium (II) | Catalyst for the cross-coupling of aryl chlorides or bromides with aromatic amines. Catalyst for the α-arylation of ketones. Catalyst for anaerobic alcohol oxidation. Group: Heterocyclic organic compound. Alternative Names: ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM (II); Allylchloro[1, 3-bis (2, 6-di-i-propylphenyl)-4, 5-dihydroimidazol-2-ylidene]palladium (II), 97%; ALLYLCHLORO[1, 3-BIS- (DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM (II). CAS No. 478980-01-7. Molecular formula: C30H43ClN2Pd. Mole weight: 573.55. Purity: 0.96. IUPACName: Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylide. Catalog: ACM478980017. | |
| Allylbis (2-aminoethyldiphenylphosphino)ruthenium (II) tetrafluoroborate, 98% | A highly active catalyst for the hydrogenation of amides to alcohols and amines. Catalyst used for the hydrogenation of functionalized amides under basic and neutral conditions. Group: Ruthenium catalysts. Alternative Names: MFCD30475649; Allylbis (2-aminoethyldiphenylphosphino)ruthenium (II) tetrafluoroborate;1352633-94-3. CAS No. 1352633-94-3. Molecular formula: C31H37BF4N2P2Ru+. Mole weight: 687.472g/mol. IUPACName: 2-diphenylphosphanylethanamine; prop-1-ene; ruthenium(2+); tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. C=C[CH2]. C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2. C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2. [Ru+2]. Catalog: ACM1352633943. | |
| Allyl heptanoate | Allyl heptanoate is an ester that is formed by the esterification of medium-chain fatty acids, heptanoic acid and allyl alcohol. The compound has a fruity smell and is commonly used as a flavoring in foods such as baked goods, candy and beverages. Uses: Scientific research. Group: Biochemical assay reagents. Alternative Names: Prop-2-en-1-yl heptanoate. CAS No. 142-19-8. Pack Sizes: 5 g; 25 g. Product ID: HY-W016976. |  |
| Bis (benzonitrile)dichloroplatinum (II) | Catalyst for: Asymmetric hydroformylation reactions Allylation reactions Carbene insertion into O-H bonds of alcohols Cyclopropanation reactions Hydrosilylation reacttions. Group: Platinum series of catalysts. Alternative Names: AKOS015964364; cis-Di(benzonitrile)dichloroplatinum (II); 15617-19-3; dichloride; AC1L38NI. CAS No. 15617-19-3. Molecular formula: C14H10Cl2N2Pt. Mole weight: 472.232g/mol. IUPACName: benzonitrile; platinum(2+); dichloride. Canonical SMILES: C1=CC=C(C=C1)C#N. C1=CC=C(C=C1)C#N. [Cl-]. [Cl-]. [Pt+2]. ECNumber: 238-943-7. Catalog: ACM15617193. | |
| Bis(pyridine)(1,5-cyclooctadiene)iridium(I) hexafluorophosphate, 99% | This complex is used in the isomerization of primary allylic alcohols. The catalyst is used for ortho-directed hydrogen-isotope exchange. Group: Iridium catalysts. CAS No. 56678-60-5. Molecular formula: C18H22F6IrN2P. Mole weight: 603.56. Catalog: ACM56678605. | |
| Chloro[1,3-bis(t-butyl)-2H-imidazol-2-ylidene]gold(I), 98% | Catalyst for the rearrangement of allylic acetates Catalyst for the α-allylation of enals and enones with alcohols. Group: Gold catalysts. Alternative Names: MFCD29037187;Chloro[1,3-bis(1,1'-dimethylethyl)2H-imidazol-2-ylidene]gold(I);839722-07-5. CAS No. 839722-07-5. Molecular formula: C11H20AuClN2. Mole weight: 412.712g/mol. IUPACName: chloro-(1,3-ditert-butylimidazol-2-ylidene)gold. Canonical SMILES: CC(C)(C)N1C=CN(C1=[Au]Cl)C(C)(C)C. Catalog: ACM839722075. | |
| Cinnamyl acetate | Cinnamyl acetate. CAS No. 103-54-8. Pack Sizes: 250 mL in glass bottle. Product ID: CDC10-0194. Molecular formula: C11H12O2. Category: Flavoring Chemical Agents. Product Keywords: Cosmetic Ingredients; Flavoring Chemical Agents; Cinnamyl acetate; CDC10-0194; 103-54-8; C11H12O2; 203-121-9; MFCD00008722; 103-54-8. Purity: 0.99. EC Number: 203-121-9. Physical State: Powder. Solubility: alcohol: soluble(lit.). Quality Level: 100. Boiling Point: 265 °C (lit.). Melting Point: 30 °C. Density: 1.057 g/mL at 25 °C. Product Description: Cinnamyl acetate is a fragrance ingredient. Palladium catalyzed allylic alkylation of cinnamyl acetate using sodium diethyl 2-methylmalonate and novel ferrocenyl Schiff base has been investigated. |  |
| Dde-Lys(Fmoc)-OH | Quasi-orthogonally-protected Lys derivative. The Fmoc group can be removed selectively by treatment with piperidine; the Dde group is cleaved with 2% hydrazine in DMF. When removing Dde in the presence of allyl-based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Also available Fmoc-Lys(Dde)-OH 852057. This derivative has been employed in Fmoc SPPS to facilitate the introduction of biotin to the side-chain of lysine. Uses: Peptide synthesis. Group: Amino acids. Alternative Names: Dde-Lys(Fmoc)-OH, N-α-1-(4,4-Dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl-N-ε-Fmoc-L-lysine. CAS No. 156648-40-7. Mole weight: 532.63. Catalog: ACM156648407. | |
| Esermethole | Esermethole is an analytical method that is used for the separation of racemic oxindoles. It is a powerful tool that can be used to synthesize a wide range of compounds with various functional groups and enantiomers. It also has the ability to allylate amines, which are important in the synthesis of pharmaceuticals. Esermethole is an analytical method that can be used in the preparation of samples for analysis by NMR spectroscopy, gas chromatography, or mass spectrometry. The asymmetric synthesis process involves three steps: (1) reaction of an alcohol with sodium carbonate to produce a chiral alcohol; (2) reaction of the chiral alcohol with an alkyl halide to produce a chiral acid; and (3) condensation of the chiral acid with an amine to produce the desired product. Group: Indole alkaloids. CAS No. 65166-97-4. Canonical SMILES: C[C@@]12CCN ([C@@H]1N (C3=C2C=C (C=C3)OC)C)C. Catalog: ACM65166974. | |
| Fmoc-Dab(ivDde)-OH | This orthogonally-protected diaminobutyric acid derivative is based on the hindered Dde variant ivDde. The side-chain ivDde group is considerably more stable to piperidine than Dde and is less prone to migrate from protected to unprotected side-chains and from side-chain to γ-amino group.When removing ivDde in the presence of allyl-based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Group: Amino acids. Alternative Names: Fmoc-Dab(ivDde)-OH, N-α-Fmoc-N-γ-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-L-diaminobutanoic acid. CAS No. 607366-21-2. Mole weight: 546.65. Catalog: ACM607366212. | |
| Fmoc-D-Lys(ivDde)-OH | This orthogonally-protected lysine derivative is based on the hindered Dde variant ivDde. It has very similar chemical properties to Fmoc-Lys(Dde)-OH, except that the side-chain ivDde group is considerably more stable to piperidine than Dde, and is less prone to migrate from protected to unprotected lysine side-chains. When removing ivDde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Group: Amino acids. Alternative Names: Fmoc-D-Lys(ivDde)-OH, N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3methylbutyl-D-lysine. CAS No. 1272755-33-5. Molecular formula: C34H42N2O6. Mole weight: 574.71. Density: 1.2±0.1 g/cm3. Catalog: ACM1272755335. | |
| Fmoc-Lys(Dde)-OH | Quasi-orthogonally-protected Lys derivative for Fmoc SPPS. The Fmoc group can be removed selectively by treatment with piperidine; the Dde group is cleaved with 2% hydrazine in DMF. When removing Dde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Lys(Dde) has been employed in the following applications: synthesis of branched peptides and di-epitopic peptides ; preparation of MAP core molecules and lipo-MAPs; construction of cyclic peptides , TASP molecules , templates for combinatorial chemistry and synthetic proteins ; preparation of peptides modified at the lysine side-chain.It has been reported that Dde can migrate from the side-chain of Lys to the unprotected side-chain of another Lys residue , and from the β-amino group to the α-amino group of Dpr. In the former instance, this problem can be overcome by using Fmoc-Lys(ivDde)-OH or using DBU/DMF (2:98) for Fmoc group removal.Full orthogonality of Dde with Fmoc has recently been demonstrated when hydroxylamine is used for Dde removal. Uses: Peptide synthesis. Group: Amino acids. Alternative Names: Fmoc-Lys(Dde)-OH, N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl-L-lysine. CAS No. 150629-67-7. Molecular formula: C31H36N2O6. Mole weight: 532.63. Catalog: ACM150629677. | |
| Fmoc-Lys(ivDde)-OH | This orthogonally-protected lysine derivative is based on the hindered Dde variant ivDde. It has very similar chemical properties to Fmoc-Lys(Dde)-OH, except that the side-chain ivDde group is considerably more stable to piperidine than Dde, and is less prone to migrate from protected to unprotected lysine side-chains.When removing ivDde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group. Uses: Peptide synthesis. Group: Amino acids. Alternative Names: Fmoc-Lys(ivDde)-OH, N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl-L-lysine. CAS No. 204777-78-6. Molecular formula: C34H42N2O6. Mole weight: 574.71. IUPACName: (2S)-6-[[1-(4,4-dimethyl-2,6-dioxocyclohexylidene)-3-methylbutyl]amino]-2-(9H-fluoren-9-ylmethoxycarbonylamino)hexanoic acid. Canonical SMILES: CC (C)CC (=C1C (=O)CC (CC1=O) (C)C)NCCCCC (C (=O)O)NC (=O)OCC2C3=CC=CC=C3C4=CC=CC=C24. Density: 1.2±0.1 g/cm3. Catalog: ACM204777786. | |
| Manganese(IV) Oxide | Manganese(IV) Oxide is used in dry-cell batteries such as alkaline battery and the zinc-carbon battery. It is also used in the oxidation of allylic alcohols. Group: Biochemicals. Grades: Highly Purified. CAS No. 1313-13-9. Pack Sizes: 25g, 100g. Molecular Formula: MnO2, Molecular Weight: 86.94. US Biological Life Sciences. | Worldwide |
| monoterpenyl-diphosphatase | A group of enzymes with varying specificity for the monoterpenol moiety. One has the highest activity on sterically hindered compounds such as (+)-bornyl diphosphate; another has highest activity on the diphosphates of primary allylic alcohols such as geraniol. Group: Enzymes. Synonyms: bornyl pyrophosphate hydrolase; monoterpenyl-pyrophosphatase. Enzyme Commission Number: EC 3.1.7.3. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-3764; monoterpenyl-diphosphatase; EC 3.1.7.3; bornyl pyrophosphate hydrolase; monoterpenyl-pyrophosphatase. Cat No: EXWM-3764. | |
| perillyl-alcohol dehydrogenase | Oxidizes a number of primary alcohols with the alcohol group allylic to an endocyclic double bond and a 6-membered ring, either aromatic or hydroaromatic. Group: Enzymes. Synonyms: perillyl alcohol dehydrogenase. Enzyme Commission Number: EC 1.1.1.144. CAS No. 37250-73-0. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0048; perillyl-alcohol dehydrogenase; EC 1.1.1.144; 37250-73-0; perillyl alcohol dehydrogenase. Cat No: EXWM-0048. | |
| Poly(allylamine) solution | Polyallylamine hydrochloride is a cationic polyelectrolyte prepared by the polymerization of allylamine. Uses: Soluble in water, lower alcohols, ethylene glycol and formamide. Group: Hydrophilic polymers. Alternative Names: PAH. CAS No. 30551-89-4. Pack Sizes: Packaging 1, 5, 25 g in poly bottle. Product ID: prop-2-en-1-amine. Molecular formula: average Mw ~15,000. Mole weight: [CH2CH(CH2NH2)]n. NCC=C. 1S/C3H7N/c1-2-3-4/h2H,1,3-4H2. VVJKKWFAADXIJK-UHFFFAOYSA-N. | |
| p-Toluenesulfonamide | p-Toluenesulfonamide. CAS No. 70-55-3. Pack Sizes: 1 kg. Product ID: CDC10-0254. Molecular formula: C7H9NO2S. Category: Cosmetic Plasticizers. Product Keywords: Cosmetic Ingredients; Cosmetic Plasticizers; p-Toluenesulfonamide; CDC10-0254; 70-55-3; C7H9NO2S; 200-741-1; MFCD00011692; 70-55-3. Purity: 0.99. Color: White Crystalline Powder. EC Number: 200-741-1. Physical State: Powder. Application: p-Toluenesulfonamide undergoes FeCl3-catalyzed direct substitution reaction with benzylic and allylic alcohols.It is employed as nucleophile in tetrabutylammonium fluoride (TBAF) catalyzed vinyl aziridine opening reaction. Boiling Point: 221°C (10 mmHg). Melting Point: 136-140°C. Density: 1.271 g/cm3. Product Description: p-Toluenesulfonamide undergoes FeCl3-catalyzed direct substitution reaction with benzylic and allylic alcohols.It is employed as nucleophile in tetrabutylammonium fluoride (TBAF) catalyzed vinyl aziridine opening reaction. | |
| (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl | 1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols. 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters. 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes. 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins. 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction. Group: Heterocyclic organic compound. CAS No. 145964-33-6. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM145964336. | |
| [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97% | Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Iridium catalysts. Alternative Names: MFCD20922908;Krische Ir Catalyst: (S)-SEGPHOS, 4-cyano-3-nitrobenzoate ligated, AldrichCPR;[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3- -2-propenyl]Ir(III);[(R)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3--2-propenyl]Ir(III);1208092-27-6. CAS No. 1208092-27-6. Molecular formula: C49H36IrN2O8P2-. Mole weight: 1034.998g/mol. IUPACName: 4-cyano-3-nitrobenzene-6-ide-1-carboxylic acid; [4-(5-diphenylphosphanyl-1, 3-benzodioxol-4-yl)-1, 3-b | |
| Rhodium(II) acetate dimer | Catalyst for insertion into C-H and X-H bonds. Catalyst for Ylide generation. Doyle-Kirmse Reaction of Allylic Sulfides with Diazoalkane Claisen rearrangement. Epoxides from aldehydes. Synthesis of aziridines from allylic N-tosyloxycarbamates. Rh/NHC catalyzed direct intermolecular arylation of C-H bonds. Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines. Rh-catalyzed cyclopropenations of ynamides. Tandem asymmetric aza-Darzens/ring-opening reactions. Group: Micro/nanoelectronics. Alternative Names: Tetrakis-(mu-acetato)dirhodium. CAS No. 15956-28-2. Molecular formula: C8H12O8Rh2. Mole weight: 441.99. Appearance: Fresh green crystal. Purity: 0.98. IUPACName: rhodium(2+);tetraacetate. Canonical SMILES: CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. [Rh+2]. [Rh+2]. ECNumber: 240-084-8. Catalog: ACM15956282-1. | |
| Rhodium(II) acetate dimer | Rhodium(II) acetate dimer. Uses: Catalyst for insertion into c-h and x-h bonds. catalyst for ylide generation. doyle-kirmse reaction of allylic sulfides with diazoalkane claisen rearrangement. epoxides from aldehydes. synthesis of aziridines from allylic n-tosyloxycarbamates. rh/nhc catalyzed direct intermolecular arylation of c-h bonds. chiral bronsted acid-rh catalyzed three component reactions of diazo compounds with alcohols and imines. rh-catalyzed cyclopropenations of ynamides. tandem asymmetric aza-darzens/ring-opening reactions. Group: Salt electrolytessolution deposition precursors. Alternative Names: Tetrakis-(mu-acetato)dirhodium. CAS No. 15956-28-2. Product ID: rhodium(2+); tetraacetate. Molecular formula: 441.99. Mole weight: C8H12O8Rh2. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. [Rh+2]. [Rh+2]. InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4; /h4*1H3, (H, 3, 4); /q; 2*+2/p-4. SYBXSZMNKDOUCA-UHFFFAOYSA-J. 98%. | |
| (S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl | Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic organic compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM134484369. | |
| [(S)-(-)-5, 5'-Bis(diphenylphosphino)-4, 4'-bi-1, 3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1, 2, 3-η-2-propenyl]iridium(III), min. 97% | 1. Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. 2. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. 3. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. 4. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. 5. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. 6. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Heterocyclic organic compound. CAS No. 1221768-92-8. Molecular formula: C49H35IrN2O8P2. Mole weight: 1033.98. Catalog: ACM1221768928. | |
| Silver trifluoromethanesulfonate | Silver precatalyst for the asymmetric allylation of aldehydes Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins Silver catalyst for the fluorination of boronic acids Silver catalyst for the fluorination of functionalized aryl stannanes Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate. Group: Silver series of catalysts. Alternative Names: KSC491Q9D; Silver trifluoromethanesulfonate, >=99%; silver(1+) ion trifluoromethanesulfonate; silver(I)trifluoromethanesulfonate; TRIFLUOROMETHANESULFONATE SILVER SALT; trifluormethanesulfonic acid silver salt; silver(I) trifluoromethanesulphonate; ANW-26574; QRUBYZBWAOOHSV-UHFFFAOYSA-M; X7226. CAS No. 2923-28-6. Molecular formula: CAgF3O3S. Mole weight: 256.94. Appearance: Powder. Purity: 0.98. IUPACName: silver;trifluoromethanesulfonate. Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].[Ag+]. ECNumber: 220-882-2. Catalog: ACM2923286-1. | |
| t-BuDavePhos | Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines. Ligand used for selective Pd-catalyzed silylation of aryl chlorides. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. Group: Organic phosphine compounds. Alternative Names: 2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179. CAS No. 224311-49-3. Molecular formula: C22H32NP. Mole weight: 341.479g/mol. IUPACName: 2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2N (C)C)C (C) (C)C. Catalog: ACM224311493. | |
| Trimethylsulfonium Iodide | Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. Group: Battery materials dye-sensitized solar cell (dssc) materials. Alternative Names: S111 I. CAS No. 2181-42-2. Product ID: trimethylsulfanium; iodide. Molecular formula: 204.07. Mole weight: C3H9IS. C[S+](C)C.[I-]. InChI=1S/C3H9S.HI/c1-4(2)3; /h1-3H3; 1H/q+1; /p-1. VFJYIHQDILEQNR-UHFFFAOYSA-M. >98.0%T. | |
| Trimethylsulfonium Iodide | Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. Group: Heterocyclic organic compound. Alternative Names: S111 I. CAS No. 2181-42-2. Molecular formula: C3H9IS. Mole weight: 204.07. Appearance: White to Almost white powder to crystal. Purity: >98.0%T. IUPACName: trimethylsulfanium;iodide. Canonical SMILES: C[S+](C)C.[I-]. ECNumber: 218-555-4. Catalog: ACM2181422. | |
| Tris (acetonitrile) cyclopentadienylruthenium (II) hexafluorophosphate | Catalyst used for the coupling of allene with activated olefines to form 1,3-diene. Catalyst used for the dimerization of propargyl alcohols. Catalyst used in the Trost's ruthenium-catalyzed ene-yne cross-coupling reaction. Catalyst for asymmetric cyclization of ω-hydroxy allyl alcohols to give α-alkenyl cyclic ethers. Catalyst for synthesis of furans from bis(alkynes) and DMSO. Group: Ruthenium series catalysts. Alternative Names: (Cyclopentadienyltris (acetonitrile)ruthenium hexafluorophosphate. CAS No. 80049-61-2. Molecular formula: C11H14F6N3PRu. Mole weight: 434.3. Appearance: yellow to orange powder. Purity: 0.98. Canonical SMILES: CC#N. CC#N. CC#N. C1=C[CH]C=C1. F[P-](F)(F)(F)(F)F. [Ru+]. Catalog: ACM80049612-1. | |
| Tris(triphenylphosphine)rhodium(I) chloride | A homogeneous hydrogenation catalyst which operates under mild conditions. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reactions. Alkyne hydro-phosphorylation Heck-type reaction with α,β-unsaturated esters. Alkyne arylation Allylic alcohol-olefin coupling. Terminal alkenes from ketones. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. Reductive deprotection of silyl groups. Group: Rhodium series of catalysts. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Molecular formula: C54H45ClP3Rh. Mole weight: 925.21. Appearance: Magenta crystal. Purity: 0.98. IUPACName: rhodium;triphenylphosphane;chloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. ECNumber: 238-744-5. Catalog: ACM14694952-1. | |
| Tris(triphenylphosphine)rhodium(I) chloride | Tris(triphenylphosphine)rhodium(I) chloride. Uses: A homogeneous hydrogenation catalyst which operates under mild conditions. catalyst for the decarbonylation of aldehydes. catalyst for regio- and stereoselective allylic substitution reactions. alkyne hydro-phosphorylation heck-type reaction with α,β-unsaturated esters. alkyne arylation allylic alcohol-olefin coupling. terminal alkenes from ketones. rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. reductive deprotection of silyl groups. Group: Salt. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Product ID: rhodium; triphenylphosphane; chloride. Molecular formula: 925.21. Mole weight: C54H45ClP3Rh. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. InChI=1S/3C18H15P. ClH. Rh/c3*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; /h3*1-15H; 1H; /p-1. QBERHIJABFXGRZ-UHFFFAOYSA-M. 98%. | |
| Vanadium(III) chloride tetrahydrofuran complex (1:3) | Catalyst used for oxidation of a wide variety allylic alcohols. Group: Metal & ceramic materials. Alternative Names: Trichlorotris (tetrahydrofuran)vanadium; 19559-06-9; Vanadium (III) chloride-tetrahydrofuran complex (1:3), 0.5M solution in methylene chloride, AcroSeal(R); MFCD00145515; SCHEMBL7929736; Vanadium(III) chloride tetrahydrofuran adduct;Vanadium(III) chloride tetrahydrofuran complex (1:3), 97%. CAS No. 19559-06-9. Molecular formula: C4H8Cl3OV. Mole weight: 229.398g/mol. IUPACName: oxolane;trichlorovanadium. Canonical SMILES: C1CCOC1.Cl[V](Cl)Cl. Catalog: ACM19559069. | |
| Vanadium(III) chloride tetrahydrofuran complex (1:3) | Vanadium(III) chloride tetrahydrofuran complex (1:3). Uses: Catalyst used for oxidation of a wide variety allylic alcohols. Group: Electrolytes. Alternative Names: Trichlorotris (tetrahydrofuran)vanadium; 19559-06-9; Vanadium(III) chloride-tetrahydrofuran complex (1:3), 0.5M solution in methylene chloride, AcroSeal(R); MFCD00145515; SCHEMBL7929736; Vanadium(III) chloride tetrahydrofuran adduct; Vanadium(III) chloride tetrahydrofuran complex (1:3), 97%. CAS No. 19559-06-9. Product ID: oxolane; trichlorovanadium. Molecular formula: 229.398g/mol. Mole weight: C4H8Cl3OV. C1CCOC1.Cl[V](Cl)Cl. InChI=1S/C4H8O.3ClH.V/c1-2-4-5-3-1; ; ; ; /h1-4H2; 3*1H; /q; ; ; ; +3/p-3. WARDLUZTYLPMGJ-UHFFFAOYSA-K. | |
| vanillyl-alcohol oxidase | Vanillyl-alcohol oxidase from Penicillium simplicissimum contains covalently bound FAD. It converts a wide range of 4-hydroxybenzyl alcohols and 4-hydroxybenzylamines into the corresponding aldehydes. The allyl group of 4-allylphenols is also converted into the -CH=CH-CH2OH group. Group: Enzymes. Synonyms: 4-hydroxy-2-methoxybenzyl alcohol oxidase. Enzyme Commission Number: EC 1.1.3.38. CAS No. 143929-24-2. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0410; vanillyl-alcohol oxidase; EC 1.1.3.38; 143929-24-2; 4-hydroxy-2-methoxybenzyl alcohol oxidase. Cat No: EXWM-0410. | |
| Yttrium(III) tris(isopropoxide) | Yttrium(III) tris(isopropoxide). Uses: Catalyst for: stereoselective conjugate addition reactions ring-opening polymerizations generation of reactive enolates by enantioselective protonation reactions cyano-phosphorylation of enone and allylic substitution synthesis of nanocompositesreactant for the preparation of flat hfo2 films. Group: Vapor deposition precursors. Alternative Names: 2-Propanol yttrium(III) salt, Isopropyl alcohol yttrium(III) salt, Tris(isopropoxy) yttrium(III). CAS No. 2172-12-5. Pack Sizes: 500 mg in glass bottle. Product ID: propan-2-olate; yttrium(3+). Molecular formula: 266.17. Mole weight: Y(OCH(CH3)2)3. CC(C)O[Y](OC(C)C)OC(C)C. 1S/3C3H7O.Y/c3*1-3(2)4;/h3*3H, 1-2H3;/q3*-1;+3, PYLIDHFYDYRZSC-UHFFFAOYSA-N. PYLIDHFYDYRZSC-UHFFFAOYSA-N. | |
| Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) | Catalyst for the cross-coupling of aryl chlorides with boronic acids. Catalyst for the diamination of conjugated dienes and trienes. Catalyst for the dehalogenation of aryl chlorides. Catalyst for anaerobic alcohol oxidation. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. Group: Organic phosphine compounds. Alternative Names: Palladium, [1, ?3-bis [2, ?6-bis (1- methyl ethyl) ?phenyl] ?-1, ?3-dihydro-2H-imidazol-2-ylide ne ] ?chloro ( η 3-2-propen-1-yl) ?-. CAS No. 478980-03-9. Molecular formula: C30H42ClN2Pd. Mole weight: 572.54. Appearance: white solid. Purity: 98%, Pd>18.5%. Catalog: ACM478980039. | |
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