Allyl Diphenylphosphine Suppliers USA
Find where to buy products from suppliers in the USA, including: distributors, industrial manufacturers in America, bulk supplies and wholesalers of raw ingredients & finished goods.
Search for products or services, then visit the American suppliers website for prices, SDS or more information. You can also view suppliers in Australia, NZ or the UK.
Product | Description | |
---|---|---|
[1, 1'-Bis (diphenylphosphino) ferrocene]palladium (II) Dichloride Dichloromethane Adduct Quick inquiry Where to buy Suppliers range | orange-red crystals. Uses: Catalyst for the borylation of aryl halides. β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates. Catalyst for modified Negishi coupling. Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process. Catalyst for Stille allylation. Catalyst for the amination of aryl bromides. Group: Other. Alternative Names: Dichloro[1, 1'-bis (diphenylphosphino) ferrocene]palladium (II) Dichloromethane Adduct. Grades: Pd ≥13.0%. CAS No. 95464-05-4. Molecular formula: C34H28Cl2FeP2Pd·CH2Cl2. Mole weight: 816.64. IUPAC Name: [1, 1-Bis (diphenylphosphino) ferrocene]dichloropalladium (II) , complex wi. Exact Mass: 823.97400. Symbol: GHS07. Density: 1 g/cm3. Safty Description: Warning. Hazard statements: H302-H312-H315-H319-H332. | |
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene Quick inquiry Where to buy Suppliers range | 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene. Uses: The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides. Asymmetric hydrogenation of vinyl alcohols. Catalyst used for the asymmetric hydrogenation of enol phosphonates. Asymmetric hydrogenation of allylic alcohols. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Group: Heterocyclic Organic Compound. Alternative Names: (R,R)-1,2-Bis(2,5-dimethylphospholano)benzene; DTXSID20163641; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, kanata purity; H5W03D1HAQ; UNII-H5W03D1HAQ; (R,R)-Me-DUPHOS; AJNZWRKTWQLAJK-KLHDSHLOSA-N; (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene; (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, >=95.0%. CAS No. 147253-67-6. Molecular formula: C18H28P2. Mole weight: 306.37g/mol. IUPAC Name: (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane. Rotatable Bond Count: 2. Exact Mass: 306.167g/mol. EC Number: 604-579-6. SMILES: CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. InChI: InChI=1S/C18H28P2/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m1/s1. InChIKey: AJNZWRKTWQLAJK-KLHDSHLOSA-N. Monoisotopic Mass: 306.167g/mol. | |
(1S, 2S) -1, 2-Bis [ [ [2- (diphenylphosphino) naphthalen-1-yl] carbonyl] amino] cyclohexane Quick inquiry Where to buy Suppliers range | (1S, 2S) -1, 2-Bis [ [ [2- (diphenylphosphino) naphthalen-1-yl] carbonyl] amino] cyclohexane is an asymmetric allylic alkylation ligand. Group: Biochemicals. Grades: Highly Purified. CAS No. 205495-66-5. Pack Sizes: 25mg, 50mg. Molecular Formula: C52H44N2O2P2, Molecular Weight: 790.87. US Biological Life Sciences. | Worldwide |
1S,2S-DHAC-Phenyl Trost Ligand Quick inquiry Where to buy Suppliers range | 1S,2S-DHAC-Phenyl Trost Ligand. Uses: The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Alternative Names: N,N'-((1S,2S)-cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide); ROST LIGAND; (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL); SC11303; (S,S)-DACH-phenyl Trost ligand, 95%; 169689-05-8; (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N inverted exclamation marka-bis(2-diphenylphosphinobenzoyl); (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINOBENZOYL); N,N'-((1S,2S)-cyclohexane-1,2-diyl)bis(2-(diphenylphosphanyl)benzamide); ZINC169731035. CAS No. 169689-05-8. Molecular formula: C44H40N2O2P2. Mole weight: 690.764g/mol. IUPAC Name: 2-diphenylphosphanyl-N-[ (1S, 2S) -2-[ (2-diphenylphosphanylbenzoyl) amino]cyclohexyl]benzamide. Rotatable Bond Count: 10. Exact Mass: 690.257g/mol. SMILES: C1CCC (C (C1)NC (=O)C2=CC=CC=C2P (C3=CC=CC=C3)C4=CC=CC=C4)NC (=O)C5=CC=CC=C5P (C6=CC=CC=C6)C7=CC=CC=C7. InChI: InChI=1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1. InChIKey: AXMSEDAJMGFTLR-ZAQUEYBZSA-N. H-Bond Donor: 2. H-Bond Acceptor: 2. Monoisotopic Mass: 690.257g/mol. | |
2,2?-Bis(diphenylphosphino)-1,1?-biphenyl Quick inquiry Where to buy Suppliers range | 2,2?-Bis(diphenylphosphino)-1,1?-biphenyl. Uses: Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Mole weight: 522.56. | |
2,2'-Bis(diphenylphosphino)biphenyl Quick inquiry Where to buy Suppliers range | 2,2'-Bis(diphenylphosphino)biphenyl. Uses: Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Group: Organic Phosphine Compounds. Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1,1'-[[1,1'-BIPHENYL]-2,2'-DIYL]BIS[1,1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPAC Name: [2-(2-diphenylphosphanylphenyl)phenyl]-diphenylphosphane. Rotatable Bond Count: 7. Exact Mass: 522.167g/mol. SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P (C5=CC=CC=C5)C6=CC=CC=C6. InChI: InChI=1S/C36H28P2/c1-5-17-29(18-6-1)37(30-19-7-2-8-20-30)35-27-15-13-25-33(35)34-26-14-16-28-36(34)38(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H. InChIKey: GRTJBNJOHNTQBO-UHFFFAOYSA-N. Monoisotopic Mass: 522.167g/mol. | |
(2S,3S)-(-)-Bis(diphenylphosphino)butane Quick inquiry Where to buy Suppliers range | (2S,3S)-(-)-Bis(diphenylphosphino)butane. Uses: Useful as a ligand in the Ni-catalyzed asymmetric additions to allylic ketals. Group: Heterocyclic Organic Compound. Alternative Names: UNII-6QR78GZL9B; (2S,3S)-Butane-2,3-diylbis(diphenylphosphine); Phosphine, [(1S,2S)-1,2-dimethyl-1,2-ethanediyl]bis[diphenyl-; (-)-Chiraphos; (2S,3S)-2,3-Bis(diphenylphosphino)butane; 64896-28-2; 896B282; (2S,3S)-Chiraphos; B2704; (S,S)-Chiraphos [MI]. CAS No. 64896-28-2. Molecular formula: C28H28P2. Mole weight: 426.48g/mol. IUPAC Name: [(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane. Rotatable Bond Count: 7. Exact Mass: 426.167g/mol. SMILES: CC (C (C)P (C1=CC=CC=C1)C2=CC=CC=C2)P (C3=CC=CC=C3)C4=CC=CC=C4. InChI: InChI=1S/C28H28P2/c1-23(29(25-15-7-3-8-16-25)26-17-9-4-10-18-26)24(2)30(27-19-11-5-12-20-27)28-21-13-6-14-22-28/h3-24H,1-2H3/t23-,24-/m0/s1. InChIKey: FWXAUDSWDBGCMN-ZEQRLZLVSA-N. Monoisotopic Mass: 426.167g/mol. | |
Dichloro[1, 2-bis (diphenylphosphino)ethane]iron (II), 98% Quick inquiry Where to buy Suppliers range | Dichloro[1, 2-bis (diphenylphosphino)ethane]iron (II), 98%. Uses: Catalyst used for the coupling of alkyl, benzyl and allyl halides with arylboronic esters. Catalyst used for general cross-coupling reactions. Group: Heterocyclic Organic Compound. Alternative Names: AKOS025402108; DTXSID70449048; 536B189; AC-4997; dichloroiron; R670; [1, 2-Bis (diphenyphosphino) ethane]dichloroiron (II) ; 41536-18-9. CAS No. 41536-18-9. Molecular formula: C26H24Cl2FeP2. Mole weight: 525.171g/mol. IUPAC Name: dichloroiron; 2-diphenylphosphanylethyl (diphenyl)phosphane. Rotatable Bond Count: 7. Exact Mass: 524.008g/mol. SMILES: C1=CC=C (C=C1) P (CCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Fe]Cl. InChI: InChI=1S/C26H24P2.2ClH.Fe/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2. InChIKey: ZXTCSIQSHINKKY-UHFFFAOYSA-L. Monoisotopic Mass: 524.008g/mol. | |
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3] Quick inquiry Where to buy Suppliers range | Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3]. Uses: Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents. Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose. Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters. Group: Organic Phosphine Compounds. Alternative Names: XANTPHOS PD G3;1445085-97-1;Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II);XantPhos Pd G3, 95%;KS-00000SRJ;MFCD22572675;AK164245. CAS No. 1445085-97-1. Molecular formula: C52H46NO4P2PdS-. Mole weight: 949.371g/mol. IUPAC Name: (5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane;methanesulfonic acid;palladium;2-phenylaniline. Rotatable Bond Count: 7. Exact Mass: 948.166g/mol. SMILES: CC1 (C2=C (C (=CC=C2) P (C3=CC=CC=C3) C4=CC=CC=C4) OC5=C1C=CC=C5P (C6=CC=CC=C6) C7=CC=CC=C7) C. CS (=O) (=O) O. C1=CC=C ([C-]=C1) C2=CC=CC=C2N. [Pd]. InChI: InChI=1S/C39H32OP2. C12H10N. CH4O3S. Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32; 13-12-9-5-4-8-11(12)10-6-2-1-3-7-10; 1-5(2, 3)4; /h3-28H, 1-2H3; 1-6, 8-9H, 13H2; 1H3, (H, 2, 3, 4); /q; -1; ;. InChIKey: JIMOHYWEUIAPAA-UHFFFAOYSA-N. H-Bond Donor: 2. H-Bond Acceptor: 6. Monoisotopic Mass: 948.166g/mol. | |
[NH2Me2][(RuCl((R)-binap))2(μ-Cl)3] Quick inquiry Where to buy Suppliers range | [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3]. Uses: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. Ligand employed in rhodium-catalyzed 1,4-additions to enones. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. Ligand employed in palladium-catalyzed synthesis of chiral allenes. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage. Group: Ruthenium series catalysts. Alternative Names: J-012887; (R)-[(RuCl(BINAP))2( -Cl)3][NH2Me2]; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); 199684-47-4; 199541-17-8; Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]; (R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); (R)-[(RuCl(BINAP))2(|I-Cl)3[NH2Me2]. CAS No. 199684-47-4. Molecular formula: C90H75Cl5NP4Ru | |
[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3] Quick inquiry Where to buy Suppliers range | [NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]. Uses: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. 3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. 4. Ligand employed in rhodium-catalyzed 1,4-additions to enones. 5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. 6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. 7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. 8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. 9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. 10. Ligand employed in palladium-catalyzed synthesis of chiral allenes. 11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives. 12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols. 13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones. 14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols. 15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage. Group: Ruthenium series catalysts. Alternative Names: (S)-[(RuCl(BINAP))2( -Cl)3][NH2Me2]; Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]; (S)-[(RUCL(BINAP))2(MU-CL)3][NH2ME2]; [NH2ME2][[RUCL((S)-BINAP)]2(MU-CL)3]; (R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]; Dimethylammonium dichlorotri(|I-chloro)bis[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]diruthenate(II); Dimethylammonium dichlorotri(|I-chloro)bis[(R)-(+)-2,2 inverted ex | |
(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl Quick inquiry Where to buy Suppliers range | (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl. Uses: 1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols. 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters. 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes. 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins. 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction. Group: Heterocyclic Organic Compound. CAS No. 145964-33-6. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPAC Name: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Rotatable Bond Count: 5. Exact Mass: 468.164g/mol. SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. InChI: InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3. InChIKey: KRWTWSSMURUMDE-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 468.164g/mol. | |
[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97% Quick inquiry Where to buy Suppliers range | [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%. Uses: Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Alternative Names: MFCD20922908;Krische Ir Catalyst: (S)-SEGPHOS, 4-cyano-3-nitrobenzoate ligated, AldrichCPR;[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3- -2-propenyl]Ir(III);[(R)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3--2-propenyl]Ir(III);1208092-27-6. CAS No. 1208092-27-6. Molecular formula: C49H36IrN2O8P2-. Mole weight: 1034.998g/mol. IUPAC Name: 4-cyano-3-nitrobenzene-6-ide-1-carboxylic acid;[4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl)-1,3-benzodioxol-5-yl]-diphenylphosphane;iridium;propane. Rotatable Bond Count: 7. Exact Mass: 1035.158g/mol. SMILES: [CH2][CH][CH2]. C1OC2=C (O1)C (=C (C=C2)P (C3=CC=CC=C3)C4=CC=CC=C4)C5=C (C=CC6=C5OCO6)P (C7=CC=CC=C7)C8=CC=CC=C8. C1=[C-]C (=CC (=C1C#N)[N+] (=O)[O-])C (=O)O. [Ir]. InChI: InChI=1S/C38H28O4P2. C8H3N2O4. C3H5. Ir/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30; 9-4-6-2-1-5(8(11)12)3-7(6)10(13)14; 1-3-2; /h1-24H, 25-26H2; 2-3H, (H, 11, 12); 3H, 1-2H2; /q; -1; ;. InChIKey: WNUGBSVEKALVKR-UHFFFAOYSA-N. H-Bond Donor: 1. H-Bond Acceptor: 10. Monoisotopic Mass: 1035.158g/mol. | |
(S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl Quick inquiry Where to buy Suppliers range | (S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl. Uses: Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic Organic Compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPAC Name: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Rotatable Bond Count: 5. Exact Mass: 468.164g/mol. SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. InChI: InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3. InChIKey: KRWTWSSMURUMDE-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 468.164g/mol. | |
[(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenyl]iridium(III), min. 97% Quick inquiry Where to buy Suppliers range | [(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenyl]iridium(III), min. 97%. Uses: 1. Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. 2. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. 3. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. 4. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. 5. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. 6. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Heterocyclic Organic Compound. CAS No. 1221768-92-8. Molecular formula: C49H35IrN2O8P2. Mole weight: 1033.98. | |
(S) - 7,7?-bis(diphenylphosphino)-1,1?-spirobiindane((S)-SDP) Quick inquiry Where to buy Suppliers range | (S) - 7,7?-bis(diphenylphosphino)-1,1?-spirobiindane((S)-SDP). Uses: Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity. Ligands used for palladium-catalyzed asymmetric allylic alkylations. Alternative Names: (S)-SDP, >=95%; 7,7'-Bis(diphenylphosphino)-1,1'-spirobiindan; SCHEMBL29269; (R)-(+)-7,7'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-1,1'-spirobiindane; (R)-SDP; (4'-diphenylphosphino-3,3'-spirobi[1,2-dihydroindene]-4-yl)-diphenylphosphine; (S)-7,7 inverted exclamation marka-Bis(diphenylphosphino)-1,1 inverted exclamation marka-spirobiindane; A829281; FT-0729696; AKOS015899950. CAS No. 528521-86-0. Product ID: ACM528521860. Molecular formula: C41H34P2. Mole weight: 588.671g/mol. IUPAC Name: (4'-diphenylphosphanyl-3,3'-spirobi[1,2-dihydroindene]-4-yl)-diphenylphosphane. SMILES: C1CC2 (CCC3=C2C (=CC=C3) P (C4=CC=CC=C4) C5=CC=CC=C5) C6=C1C=CC=C6P (C7=CC=CC=C7) C8=CC=CC=C8. InChI: InChI=1S/C41H34P2/c1-5-17-33(18-6-1)42(34-19-7-2-8-20-34)37-25-13-15-31-27-29-41(39(31)37)30-28-32-16-14-26-38(40(32)41)43(35-21-9-3-10-22-35)36-23-11-4-12-24-36/h1-26H,27-30H2. InChIKey: DKZNVWNOOLQCMJ-UHFFFAOYSA-N. | |
(S)-(-)-BINAP Quick inquiry Where to buy Suppliers range | (S)-(-)-BINAP. Uses: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. Ligand employed in rhodium-catalyzed 1,4-additions to enones. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. Ligand employed in palladium-catalyzed synthesis of chiral allenes. Group: Organic Phosphine Compounds. Alternative Names: (+)-2,2'-bis(diphenylphosphino)-1,1'binaphthyl; (R)-(+)-2,2 bis(diphenylphosphino)-1,1-binaphthyl; 13648-EP2311831A1; (R)-(+)-(1,1'-Binaphthalene-2,2'-diyl)bis(diphenylphosphine); FT-0604001; [2'-(diphenylphosphanyl)-[1,1'-binaphthalene]-2-yl]diphenylphosphane; 1,1'-[(1R)-[1,1'-BINAPHTHALENE]-2,2'-DIYL]BIS[1,1-DIPHENYL]-PHOSPHINE; 13648-EP2286811A1; racemic-2,2'-bis(diphenylphosphino)-1,1' binaphthyl; 2,2'-Bis (diphenylphosphino)-1,1'-binaphtyl. CAS No. 76189-56-5. Molecular formula: C44H32P2. Mole weight: 622.688g/mol. IUPAC Name: [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Rotatable Bond Count: 7. Exact Mass: 622.198g/mol. EC Number: 616-304-7. SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=CC=C7)C8=CC=CC=C8. InChI: InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H. InChIKey: MUALRAIOVNYAIW-UHFFFAOYSA-N. Monoisotopic Mass: 622.198g/mol. |