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(2S, 3S)-(-)-Bis(diphenylphosphino)butane Useful as a ligand in the Ni-catalyzed asymmetric additions to allylic ketals. Group: Heterocyclic organic compound. Alternative Names: UNII-6QR78GZL9B; (2S,3S)-Butane-2,3-diylbis(diphenylphosphine); Phosphine, [(1S,2S)-1,2-dimethyl-1,2-ethanediyl]bis[diphenyl-; (-)-Chiraphos; (2S,3S)-2,3-Bis(diphenylphosphino)butane; 64896-28-2; 896B282; (2S,3S)-Chiraphos; B2704; (S,S)-Chiraphos [MI]. CAS No. 64896-28-2. Molecular formula: C28H28P2. Mole weight: 426.48g/mol. IUPACName: [(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane. Canonical SMILES: CC (C (C)P (C1=CC=CC=C1)C2=CC=CC=C2)P (C3=CC=CC=C3)C4=CC=CC=C4. Catalog: ACM64896282. Alfa Chemistry. 2
(S)-7,7'-bis(diphenylphosphino)-1,1'-spirobiindane((S)-SDP) Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity. Ligands used for palladium-catalyzed asymmetric allylic alkylations. Group: Heterocyclic organic compound. Alternative Names: (S)-SDP, >=95%; 7,7'-Bis(diphenylphosphino)-1,1'-spirobiindan; SCHEMBL29269; (R)-(+)-7,7'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-1,1'-spirobiindane; (R)-SDP; (4'-diphenylphosphino-3,3'-spirobi[1,2-dihydroindene]-4-yl)-diphenylphosphine; (S)-7,7 inverted exclamation marka-Bis(diphenylphosphino)-1,1 inverted exclamation marka-spirobiindane; A829281; FT-0729696; AKOS015899950. CAS No. 528521-86-0. Molecular formula: C41H34P2. Mole weight: 588.671g/mol. IUPACName: (4'-diphenylphosphanyl-3,3'-spirobi[1,2-dihydroindene]-4-yl)-diphenylphosphane. Canonical SMILES: C1CC2 (CCC3=C2C (=CC=C3) P (C4=CC=CC=C4) C5=CC=CC=C5) C6=C1C=CC=C6P (C7=CC=CC=C7) C8=CC=CC=C8. Catalog: ACM528521860. Alfa Chemistry. 2
(S)-(-)-BINAP (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. Ligand employed in rhodium-catalyzed 1,4-additions to enones. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. Ligand employed in palladium-catalyzed synthesis of chiral allenes. Group: Organic phosphine compounds. Alternative Names: (+)-2,2'-bis(diphenylphosphino)-1,1'binaphthyl; (R)-(+)-2,2 bis(diphenylphosphino)-1,1-binaphthyl; 13648-EP2311831A1; (R)-(+)-(1,1'-Binaphthalene-2,2'-diyl)bis(diphenylphosphine); FT-0604001; [2'-(diphenylphosphanyl)-[1, 1'-binaphthalene]-2-yl]diphenylphosphane; 1, 1'-[(1R)-… Alfa Chemistry. 2
[1, 1'-Bis (diphenylphosphino) ferrocene]palladium (II) Dichloride Dichloromethane Adduct [1, 1'-Bis (diphenylphosphino) ferrocene]palladium (II) Dichloride Dichloromethane Adduct. Uses: Catalyst for the borylation of aryl halides. β-alkyl suzuki-miyaura cross-coupling reactions with potassium alkyltrifluoroborates. catalyst for modified negishi coupling. synthesis of polyheterocycles by a pd-catalyzed intramolecular n-arylation/c-h bond activation/aryl-aryl bond-forming domino process. catalyst for stille allylation. catalyst for the amination of aryl bromides. Group: Salt. Alternative Names: Dichloro[1, 1'-bis (diphenylphosphino) ferrocene]palladium (II) Dichloromethane Adduct. CAS No. 95464-05-4. Product ID: [1, 1-Bis (diphenylphosphino) ferrocene]dichloropalladium (II) , complex wi. Molecular formula: 816.64. Mole weight: C34H28Cl2FeP2Pd·CH2Cl2. Pd ≥13.0%. Alfa Chemistry Materials 3
[1, 1'-Bis (diphenylphosphino) ferrocene]palladium (II) Dichloride Dichloromethane Adduct Catalyst for the borylation of aryl halides. β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates. Catalyst for modified Negishi coupling. Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process. Catalyst for Stille allylation. Catalyst for the amination of aryl bromides. Group: Other. Alternative Names: Dichloro[1, 1'-bis (diphenylphosphino) ferrocene]palladium (II) Dichloromethane Adduct. CAS No. 95464-05-4. Molecular formula: C34H28Cl2FeP2Pd·CH2Cl2. Mole weight: 816.64. Appearance: orange-red crystals. Purity: Pd ≥13.0%. IUPACName: [1, 1-Bis (diphenylphosphino) ferrocene]dichloropalladium (II) , complex wi. Density: 1 g/cm³. Catalog: ACM95464054. Alfa Chemistry. 2
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides. Asymmetric hydrogenation of vinyl alcohols. Catalyst used for the asymmetric hydrogenation of enol phosphonates. Asymmetric hydrogenation of allylic alcohols. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Group: Heterocyclic organic compound. Alternative Names: (R,R)-1,2-Bis(2,5-dimethylphospholano)benzene; DTXSID20163641; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, kanata purity; H5W03D1HAQ; UNII-H5W03D1HAQ; (R,R)-Me-DUPHOS; AJNZWRKTWQLAJK-KLHDSHLOSA-N; (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene; (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, >=95.0%. CAS No. 147253-67-6. Molecular formula: C18H28P2. Mole weight: 306.37g/mol. IUPACName: (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane. Canonical SMILES: CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. ECNumber: 604-579-6. Catalog: ACM147253676. Alfa Chemistry. 2
(1S, 2S) -1, 2-Bis [ [ [2- (diphenylphosphino) naphthalen-1-yl] carbonyl] amino] cyclohexane (1S, 2S) -1, 2-Bis [ [ [2- (diphenylphosphino) naphthalen-1-yl] carbonyl] amino] cyclohexane is an asymmetric allylic alkylation ligand. Group: Biochemicals. Grades: Highly Purified. CAS No. 205495-66-5. Pack Sizes: 25mg, 50mg. Molecular Formula: C52H44N2O2P2, Molecular Weight: 790.87. US Biological Life Sciences. USBiological 9
Worldwide
1S,2S-DHAC-Phenyl Trost Ligand The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Group: Other nitrogen-donor ligands. Alternative Names: N, N'- ( (1S, 2S)-cyclohexane-1, 2-diyl)bis (2- (diphenylphosphino)benzamide); ROST LIGAND; (1S, 2S)-(-)-1, 2-DIAMINOCYCLOHEXANE-N, N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL); SC11303; (S,S)-DACH-phenyl Trost ligand, 95%; 169689-05-8; (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N inverted exclamation marka-bis(2-diphenylphosphinobenzoyl); (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINOBENZOYL); N, N'- ( (1S, 2S)-cyclohexane-1, 2-diyl)bis (2- (diphenylphosphanyl)benzamide); ZINC169731035. CAS No. 169689-05-8. Molecular formula: C44H40N2O2P2. Mole weight: 690.764g/mol. IUPACName: 2-diphenylphosphanyl-N-[ (1S, 2S) -2-[ (2-diphenylphosphanylbenzoyl) amino]cyclohexyl]benzamide. Canonical SMILES: C1CCC (C (C1)NC (=O)C2=CC=CC=C2P (C3=CC=CC=C3)C4=CC=CC=C4)NC (=O)C5=CC=CC=C5P (C6=CC=CC=C6)C7=CC=CC=C7. Catalog: ACM169689058. Alfa Chemistry. 2
2,2'-Bis(diphenylphosphino)biphenyl Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Group: Organic phosphine compounds. Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1, 1'-[[1, 1'-BIPHENYL]-2, 2'-DIYL]BIS[1, 1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPACName: [2- (2-diphenylphosphanylphenyl) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM84783642. Alfa Chemistry. 2
Dichloro[1, 2-bis (diphenylphosphino)ethane]iron (II), 98% Catalyst used for the coupling of alkyl, benzyl and allyl halides with arylboronic esters. Catalyst used for general cross-coupling reactions. Group: Heterocyclic organic compound. Alternative Names: AKOS025402108; DTXSID70449048; 536B189; AC-4997; dichloroiron; R670; [1, 2-Bis (diphenyphosphino) ethane]dichloroiron (II) ; 41536-18-9. CAS No. 41536-18-9. Molecular formula: C26H24Cl2FeP2. Mole weight: 525.171g/mol. IUPACName: dichloroiron; 2-diphenylphosphanylethyl (diphenyl)phosphane. Canonical SMILES: C1=CC=C (C=C1) P (CCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Fe]Cl. Catalog: ACM41536189. Alfa Chemistry. 2
Methanesulfonato[9, 9-dimethyl-4, 5-bis (diphenylphosphino) xanthene][2'-amino-1, 1'-biphenyl]palladium (II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3] Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents. Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose. Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters. Group: Organic phosphine compounds. Alternative Names: XANTPHOS PD G3;1445085-97-1;Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II);XantPhos Pd G3, 95%;KS-00000SRJ;MFCD22572675;AK164245. CAS No. 1445085-97-1. Molecular formula: C52H46NO4P2PdS-. Mole weight: 949.371g/mol. IUPACName: (5-diphenylphosphanyl-9, 9-dimethylxanthen-4-yl)-diphenylphosphane; methanesulfonic acid;palladium;2-phenylaniline. Canonical SMILES: CC1 (C2=C (C (=CC=C2) P (C3=CC=CC=C3) C4=CC=CC=C4) OC5=C1C=CC=C5P (C6=CC=CC=C6) C7=CC=CC=C7) C. CS (=O) (=O) O. C1=CC=C ([C-]=C1) C2=CC=CC=C2N. [Pd]. Catalog: ACM1445085971. Alfa Chemistry. 2
(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl 1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols. 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters. 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes. 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins. 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction. Group: Heterocyclic organic compound. CAS No. 145964-33-6. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM145964336. Alfa Chemistry. 2
[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97% Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Iridium catalysts. Alternative Names: MFCD20922908;Krische Ir Catalyst: (S)-SEGPHOS, 4-cyano-3-nitrobenzoate ligated, AldrichCPR;[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3- -2-propenyl]Ir(III);[(R)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3--2-propenyl]Ir(III);1208092-27-6. CAS No. 1208092-27-6. Molecular formula: C49H36IrN2O8P2-. Mole weight: 1034.998g/mol. IUPACName: 4-cyano-3-nitrobenzene-6-ide-1-carboxylic acid; [4-(5-diphenylphosphanyl-1, 3-benzodioxol-4-yl)-1, 3-b… Alfa Chemistry. 2
(S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic organic compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM134484369. Alfa Chemistry. 2
[(S)-(-)-5, 5'-Bis(diphenylphosphino)-4, 4'-bi-1, 3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1, 2, 3-η-2-propenyl]iridium(III), min. 97% 1. Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. 2. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. 3. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. 4. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. 5. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. 6. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Heterocyclic organic compound. CAS No. 1221768-92-8. Molecular formula: C49H35IrN2O8P2. Mole weight: 1033.98. Catalog: ACM1221768928. Alfa Chemistry. 2

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