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Product | Description | |
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1,10-Phenanthroline Nickel dibromide Quick inquiry Where to buy Suppliers range | 1,10-Phenanthroline Nickel dibromide is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols. Uses: Transition metal catalysts. Synonyms: Nickel, dibromo(1,10-phenanthroline-κN1,κN10)-; Dibromo(1,10-phenanthroline-κN1,κN10)nickel; Nickel, dibromo(1,10-phenanthroline)-; Nickel, dibromo(1,10-phenanthroline-N1,N10)-; Dibromo(1,10-phenanthroline-κN1,κN10)nickel; 1,10-Phenanthroline nickel (II) dibromide; Ni (phen) Br2; (phen)NiBr2. Grades: ≥95%. CAS No. 48165-50-0. Molecular formula: C12H8Br2N2Ni. Mole weight: 398.71. | |
1,1?-Bis(dicyclohexylphosphino)ferrocene Quick inquiry Where to buy Suppliers range | Orange-red powder. Uses: Ligand for palladium-catalyzed synthesis of oxindoles by amide ?-arylation. Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides. Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols. Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates. Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases. Group: Organic Phosphine Compounds. Alternative Names: 1,1?-Bis(dicyclohexylphosphino)ferrocene; 1,1-Bis(Dicyclohexylphosphino)Ferrocene; 1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE. Grades: 98%. CAS No. 146960-90-9. Molecular formula: C34H52FeP2. Mole weight: 578.57. IUPAC Name: dicyclohexyl(cyclopentyl)phosphane; iron. Exact Mass: 578.28900. Melting Point: 134-136ºC. SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. [Fe]. InChIKey: LVWMUECONASIMT-UHFFFAOYSA-N. | |
1,1'-Bis(diisopropylphosphino)ferrocene Quick inquiry Where to buy Suppliers range | Orange-yellow powder. Uses: Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO. Pd-catalyzed carbonylative ?-arylation of ketones with aryl iodides Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation Ligand for ruthenium-catalyzed C-C coupling reactions of fluorinated alcohols with allenes. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents. Group: Organic Phosphine Compounds. Alternative Names: 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE. Grades: 98%. CAS No. 97239-80-0. Molecular formula: C22H36FeP2. Mole weight: 418.32. IUPAC Name: 1,1-Bis(diisopropylphosphino)ferrocene. Exact Mass: 418.16400. Melting Point: 50-52ºC(lit.). Flash Point: >230 °F. Safty Description: 37/39-26. Hazard statements: Xi: Irritant. | |
1,1-Dimethylethyl Nitrite Quick inquiry Where to buy Suppliers range | ert-Butyl nitrite is an intermediate used for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It is also used to prepare aryl azides from aryl amines. Group: Biochemicals. Grades: Highly Purified. CAS No. 540-80-7. Pack Sizes: 1g, 10g. Molecular Formula: C4H9NO2. US Biological Life Sciences. | Worldwide |
1-(3-Methoxyphenyl)ethanol Quick inquiry Where to buy Suppliers range | 1-(3-Methoxyphenyl)ethanol (Rivastigmine EP Impurity G) is a versatile reactant used in the preparation of 2,3-dihydroimidazo[1,2-a]pyridines as enantioselective acyl transfer catalysts in kinetic resolution of alcohols. Also used in chemoselective preparation of aryl aldehydes/ketones via in situ generated TEMPO-copper(II) diimine catalyzed oxidation of benzylic alcohols in aqueous media. Group: Biochemicals. Grades: Highly Purified. CAS No. 23308-82-9. Pack Sizes: 50mg, 250mg. Molecular Formula: C9H12O2. US Biological Life Sciences. | Worldwide |
(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol Quick inquiry Where to buy Suppliers range | (1S,3S,4S)-(-)-3,5-dinitrobenzoate Menthol is an intermediate in the synthesis of (±)-Neoisomenthol (N389960) which is a useful synthetic intermediate. It is used to prepare alkyl and aryl esters by chemoselective acylation of alkyl and aryl alcohols with carboxylic acid anhydrides in the presence of magnesium bis (trifluoro methyl sulfonyl) amide under solvent-free conditions. Group: Biochemicals. Grades: Highly Purified. CAS No. 1195710-85-0. Pack Sizes: 50mg, 100mg. Molecular Formula: C17H22N2O6. US Biological Life Sciences. | Worldwide |
(1S)-1-Amino-2-methyl-1-phenylpropan-2-ol Quick inquiry Where to buy Suppliers range | (1S)-1-Amino-2-methyl-1-phenylpropan-2-ol can be used as reactant/reagent in stereoselective preparation of diaryl carbonyl compounds via palladium-catalyzed enantioselective redox-relay oxidative Heck arylation of arylboronic acids and homoallylic alcohols. Group: Biochemicals. Grades: Highly Purified. CAS No. 110480-86-9. Pack Sizes: 100mg, 250mg. Molecular Formula: C10H15NO, Molecular Weight: 165.23. US Biological Life Sciences. | Worldwide |
2,2?-Bis(diphenylphosphino)-1,1?-biphenyl Quick inquiry Where to buy Suppliers range | 2,2?-Bis(diphenylphosphino)-1,1?-biphenyl. Uses: Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Mole weight: 522.56. | |
2,2'-Bis(diphenylphosphino)biphenyl Quick inquiry Where to buy Suppliers range | 2,2'-Bis(diphenylphosphino)biphenyl. Uses: Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Group: Organic Phosphine Compounds. Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1,1'-[[1,1'-BIPHENYL]-2,2'-DIYL]BIS[1,1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPAC Name: [2-(2-diphenylphosphanylphenyl)phenyl]-diphenylphosphane. Rotatable Bond Count: 7. Exact Mass: 522.167g/mol. SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P (C5=CC=CC=C5)C6=CC=CC=C6. InChI: InChI=1S/C36H28P2/c1-5-17-29(18-6-1)37(30-19-7-2-8-20-30)35-27-15-13-25-33(35)34-26-14-16-28-36(34)38(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H. InChIKey: GRTJBNJOHNTQBO-UHFFFAOYSA-N. Monoisotopic Mass: 522.167g/mol. | |
2-(Dibutylamino)-1-(2,7-dichloro-9H-fluoren-4-yl)ethanol Quick inquiry Where to buy Suppliers range | 2-(Dibutylamino)-1-(2,7-dichloror-9H-fluoren-4-yl)ethanol is an impurity formed during the synthesis of Lumefantrine (L474000), a fluorene (F462000) derivative belonging to the aryl amino alcohol class of anti-malarial drugs. Group: Biochemicals. Alternative Names: 2,7-Dichloro-α-[(dibutylamino)methyl]-9H-fluorene-4-methanol. Grades: Highly Purified. CAS No. 69759-61-1. Pack Sizes: 1g. US Biological Life Sciences. | Worldwide |
2-(Dibutylamino)-1-(2,7-dichloro-9H-fluoren-4-yl)ethanol Quick inquiry Where to buy Suppliers range | 2-(Dibutylamino)-1-(2,7-dichloror-9H-fluoren-4-yl)ethanol is an impurity formed during the synthesis of Lumefantrine, a fluorene derivative belonging to the aryl amino alcohol class of anti-malarial drugs. Synonyms: 2,7-Dichloro-α-[(dibutylamino)methyl]-9H-fluorene-4-methanol. Grades: > 95%. CAS No. 69759-61-1. Molecular formula: C23H29Cl2NO. Mole weight: 406.39. | |
2-(Dicyclohexylphosphino)biphenyl Quick inquiry Where to buy Suppliers range | 2-(Dicyclohexylphosphino)biphenyl. Uses: Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in Suzuki coupling reactions involving aryl chlorides, bromides and triflates. Useful ligand for the Pd-catalyzed oxidation of alcohols in the presence of chlorobenzenes. Useful ligand for the Pd-catalyzed amination with ammonia equivalents. Ligand for the gold(I)-catalyzed intramolecular [4+2] cycloadditions involving 1,3-enynes and arylalkynes with alkenes. Ligand used in the palladium-catalyzed borylation of aryl bromdies. Ligand used in the palladium-catalyzed siliylation of aryl chlorides. Group: Organic Phosphine Compounds. Alternative Names: FT-0084457; 2-(dicyclohexylphosphino) biphenyl; 14110-EP2298767A1; ANW-25534; S-2169; 2-(dicyclohexylphosphanyl)biphenyl; A25272; dicyclohexylphosphino biphenyl; 2-(dicyclohexyl phosphino)biphenyl; 2-(dicylcohexylphosphino)biphenyl. CAS No. 247940-06-3. Molecular formula: C24H31P. Mole weight: 350.486g/mol. IUPAC Name: dicyclohexyl-(2-phenylphenyl)phosphane. Rotatable Bond Count: 4. Exact Mass: 350.216g/mol. EC Number: 480-030-2. SMILES: C1CCC (CC1)P (C2CCCCC2)C3=CC=CC=C3C4=CC=CC=C4. InChI: InChI=1S/C24H31P/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2. InChIKey: LCSNDSFWVKMJCT-UHFFFAOYSA-N. Monoisotopic Mass: 350.216g/mol. | |
(2S,3R)-3,4-Dihydro-3-isopropyl-2-phenyl-2H-pyrimido[2,1-b]benzothiazole Quick inquiry Where to buy Suppliers range | (2S,3R)-3,4-Dihydro-3-isopropyl-2-phenyl-2H-pyrimido[2,1-b]benzothiazole. Uses: Isothiourea-mediated intermolecular Michael addition-lactonisation. Isothiourea-mediated, asymmetric, Michael-lactonisation of CF3 - enones. α-Functioalisation of 3-alkenoic acids. Isothiourea-catalyzed α-amination of carboxylic acids. Isothiourea-catalyzed O- to C- carboxyl transfer of furanyl carbonates. Isothiourea-catalyzed kinetic resolution of secondary alcohols. Isothiourea-catalyzed α-amination of carboxylic acidswith N-aryl-N-aroyldiazene. Alternative Names: ZINC169382070; OR51901; MFCD29037150; (2S,3R)-3-Isopropyl-2-phenyl-3,4-dihydro-2h-pyrimido[2,1-b][1,3]benzothiazole; D4808; 2alpha-Phenyl-3alpha-isopropyl-3,4-dihydro-2H-pyrimido[2,1-b]benzothiazole. CAS No. 1203507-02-1. Molecular formula: C19H20N2S. Mole weight: 308.443g/mol. IUPAC Name: (2S,3R)-2-phenyl-3-propan-2-yl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole. Rotatable Bond Count: 2. Exact Mass: 308.135g/mol. SMILES: CC (C) C1CN2C3=CC=CC=C3SC2=NC1C4=CC=CC=C4. InChI: InChI=1S/C19H20N2S/c1-13(2)15-12-21-16-10-6-7-11-17(16)22-19(21)20-18(15)14-8-4-3-5-9-14/h3-11,13,15,18H,12H2,1-2H3/t15-,18+/m0/s1. InChIKey: RPBRMANNSNGNFS-MAUKXSAKSA-N. H-Bond Acceptor: 2. Monoisotopic Mass: 308.135g/mol. | |
3,4,7,8-Tetramethyl-1,10-phenanthroline Nickel (II) dichloride Quick inquiry Where to buy Suppliers range | 3,4,7,8-Tetramethyl-1,10-phenanthroline Nickel (II) dichloride is a Ni catalyst used for a variety of cross-coupling reactions including the cross-electrophile coupling of benzyl alcohols and aryl halides. Uses: Transition metal catalysts. Synonyms: Nickel, dichloro(3,4,7,8-tetramethyl-1,10-phenanthroline-κN1,κN10)-; Dichloro(3,4,7,8-tetramethyl-1,10-phenanthroline-κN1,κN10)nickel; (Me4Phen)NiCl2. Grades: ≥95%. CAS No. 2254430-88-9. Molecular formula: C16H16Cl2N2Ni. Mole weight: 365.91. | |
3-Bromo-5-hydroxybenzyl Alcohol Quick inquiry Where to buy Suppliers range | 3-Bromo-5-hydroxybenzyl Alcohol is an intermediate used to prepare (isoxazolylphenyl) arylmethanols as inhibitors of the BET bromodomain family member BRD4(1) for potential use as antitumor agents. Group: Biochemicals. Grades: Highly Purified. CAS No. 1020336-51-9. Pack Sizes: 500mg, 1g. Molecular Formula: C7H7BrO2, Molecular Weight: 203.03. US Biological Life Sciences. | Worldwide |
3-(Hydroxymethyl)phenylboronic acid Quick inquiry Where to buy Suppliers range | Reactant involved in: Copper-mediated trifluoromethylation Copper-catalyzed transformations from arylboronic acids in water Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylateReactant involved in the synthesis of biologically active molecules including: Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions HIV protease inhibitors with antiviral activity against drug-resistant viruses Pyrrole derivatives for use as PDE4B inhibitors. Synonyms: 3-Boronobenzyl alcohol; 3-hydroxymethylbenzeneboronic acid; 3-hydroxymethylboronic acid; RARECHEM AH PB 0189; 3-HydroMethylphenylboronicacid; KS-000000LJ; m-(Hydroxymethyl)phenyl boronic acid. Grades: 97%. CAS No. 87199-15-3. Molecular formula: C7H9BO3. Mole weight: 151.96. | |
(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) Quick inquiry Where to buy Suppliers range | (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine). Uses: Ligand used for the hydroformylation of alkenes. Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides. Ligand used in the intermolecular coupling of amides with aryl halides or triflates. Ligand used in the coupling of heteroarylamines and aryl halides. Ligand used in the hydrophosphinylation of alkenes and alkynes. Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols. Ligand used for the sulfinylation of aryl iodides. Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines. Ligand used for the Ni-cataltzed alkynylcyanation of alkynes. Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole. Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes. Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides. Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles. Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes. Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates. Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones. Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines. Ligand used for the Cu-catalyzed intermolecular coupling of alkynes with aryl iodides. Ligand used for the Pd-catalyzed ene-type reaction of aldehydes with 1,3-diene. Ligand used for the Ru-catalyzed intermolecular addition of 2-phenylbenzoic acid onto unactivated olefins. Ligand used for the Pd/Cu-catalyzed direct arylation of heteroarenes. Ligand used for the Pd-catalyzed reaction of propargyl-substituted malonate esters with aryl halides. Ligand used for the Pd-catalyzed decarboxylative coupling of tertiary cyanoacetate salts with aryl halides and triflates. Ligand used for the Pd-catalyzed hydroesterification of alkynes. Ligand used for the Cu-catalyzed arylation of arylboronic acids with aldehydes. Ligand used for the Ru-catalyzed oxidative synthesis of heterocycles from alcohols. Ligand used for the Rh-catalyzed borylation of ni | |
ABC294640 Quick inquiry Where to buy Suppliers range | ABC294640 is an orally available, aryladamantane compound and selective inhibitor of sphingosine kinase-2 (SK2) with potential antineoplastic activity. Upon administration, ABC294640 competitively binds to and inhibits SK2, thereby preventing the phosphorylation of the pro-apoptotic amino alcohol sphingosine to sphingosine 1-phosphate (S1P), the lipid mediator that is pro-survival and critical for immunomodulation. Synonyms: ABC-294640; ABC294640; ABC 294640; Opaganib; 3-(4-chlorophenyl)-adamantane-1-carboxylic acid (pyridin-4-ylmethyl)amide. Grades: 0.98. CAS No. 915385-81-8. Molecular formula: C23H25ClN2O. Mole weight: 380.9104. | |
Allyl[1, 3-bis (2, 6-diisopropylphenyl)-2-imidazolidinylidene]chloropalladium (II) Quick inquiry Where to buy Suppliers range | Allyl[1, 3-bis (2, 6-diisopropylphenyl)-2-imidazolidinylidene]chloropalladium (II). Uses: Catalyst for the cross-coupling of aryl chlorides or bromides with aromatic amines. Catalyst for the α-arylation of ketones. Catalyst for anaerobic alcohol oxidation. Group: Heterocyclic Organic Compound. Alternative Names: ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM (II);Allylchloro[1, 3-bis(2, 6-di-i-propylphenyl)-4, 5-dihydroimidazol-2-ylidene]palladium(II), 97%;ALLYLCHLORO[1, 3-BIS-(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM(II). Grades: 96%. CAS No. 478980-01-7. Molecular formula: C30H43ClN2Pd. Mole weight: 573.55. IUPAC Name: Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylide. Exact Mass: 572.21500. Safty Description: 26-36/37/39. | |
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) Quick inquiry Where to buy Suppliers range | white solid. Uses: Catalyst for the cross-coupling of aryl chlorides with boronic acids. Catalyst for the diamination of conjugated dienes and trienes. Catalyst for the dehalogenation of aryl chlorides. Catalyst for anaerobic alcohol oxidation. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. Group: Organic Phosphine Compounds. Alternative Names: Palladium, [1,?3-bis[2,?6-bis(1-methylethyl)?phenyl]?-1,?3-dihydro-2H-imidazol-2-ylidene]?chloro(η3-2-propen-1-yl)?-. Grades: 98%, Pd>18.5%. CAS No. 478980-03-9. Molecular formula: C30H42ClN2Pd. Mole weight: 572.54. Symbol: GHS07. Melting Point: > 300 °C (> 572 °F). Hazard statements: H315-H319-H335. | |
Bis(acetonitrile)palladium(II) p-toluenesulfonate, 98% Quick inquiry Where to buy Suppliers range | Bis(acetonitrile)palladium(II) p-toluenesulfonate, 98%. Uses: Newly developed Pd catalyst for the enantioselective intermolecular Heck reaction of tri-substituted alkenyl alcohols with aryl boronic acids. Alternative Names: MFCD28167054; Bis(acetonitrile)palladium(II) p-toluenesulfonate, 98%;114757-66-3. CAS No. 114757-66-3. Molecular formula: C18H22N2O6PdS2. Mole weight: 532.922g/mol. IUPAC Name: acetonitrile;4-methylbenzenesulfonic acid;palladium. Rotatable Bond Count: 2. Exact Mass: 531.995g/mol. SMILES: CC#N. CC#N. CC1=CC=C(C=C1)S(=O)(=O)O. CC1=CC=C(C=C1)S(=O)(=O)O. [Pd]. InChI: InChI=1S/2C7H8O3S.2C2H3N.Pd/c2*1-6-2-4-7(5-3-6)11(8,9)10;2*1-2-3;/h2*2-5H,1H3,(H,8,9,10);2*1H3; InChIKey: LVPBXJOLQSPWHW-UHFFFAOYSA-N. H-Bond Donor: 2. H-Bond Acceptor: 8. Monoisotopic Mass: 531.995g/mol. | |
Bis(dibenzylideneacetone)palladium, Pd : 18.4 wt.% Quick inquiry Where to buy Suppliers range | Bis(dibenzylideneacetone)palladium (Pd(dba)2) is an air-stable Pd0 complex. It is a reagent for the synthesis of allyl-substituted cyclopentadiene. It is a homogeneous catalyst that can catalyze the alkylation of allyl acetate by the action of various nucleophiles under mild conditions. Uses: ·Synthesis of isomer 2-aryl-2,5-dihydrofuran by Heck coupling reaction of aryl bromide with alkene using neopentylphosphine ligand; ·Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand; ·Allylation of stable anions; ·Cross-coupling of allyl, alkenyl and aryl halides with organotin compounds; ·Cross-coupling of vinyl halides with alkenyl zinc compounds; ·Carbonylation of alkenyl and aryl halides; ·Efficient oxidation of alcohols to aldehydes and ketones together with cyclic thiourea ligands. Group: Colloidal Catalysts. CAS No. 32005-36-0. Molecular Weight: 575 g/mol. SMILES: [Pd]. O=C(/C=C/c1ccccc1)\C=C\c2ccccc2. O=C(/C=C/c3ccccc3)\C=C\c4ccccc4. InChI: UKSZBOKPHAQOMP-SVLSSHOZSA-N. Boiling Point: 150 °C. | |
Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II) Quick inquiry Where to buy Suppliers range | Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II). Uses: Catalyst for the arylation (or alkenylation) of anthraquinone and PBI. Catalytic C-C bond formation. Transfer hydrogenative coupling of isoprene to alcohols or aldehydes. Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation. Catalyst for the conversion of primary alcohols and aldehydes into methyl esters. Precatalyst for hydrogen production by means of alcohol dehydrogenation. Group: Ruthenium series catalysts. Alternative Names: 25360-32-1; Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II); Carbonyldihydridotris (triphenylphosphine)ruthenium (II); Dihydridocarbonyltris (triphenylphosphine)ruthenium; C55H47OP3Ru; [ (C6H5)3P]3Ru (CO)H2; AKOS024258165; Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II). CAS No. 25360-32-1. Molecular formula: C55H49OP3Ru. Mole weight: 919.987g/mol. IUPAC Name: formaldehyde;ruthenium dihydride;triphenylphosphane. Rotatable Bond Count: 9. Exact Mass: 920.204g/mol. SMILES: C=O. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [RuH2]. InChI: InChI=1S/3C18H15P.CH2O.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;1H2;;; InChIKey: CEEYDFHDINQLNF-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 920.204g/mol. | |
Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II), 97% Quick inquiry Where to buy Suppliers range | Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II), 97%. Uses: Catalyst used for the intramolecular, direct arylation reaction with aryl chlorides. Catalyst used for aerobic oxidative kinetic resolution of secondary alcohols. Catalyst used for aryl amination. Highly active catalyst for the Mizoroki-Heck reaction. Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls. Alternative Names: FT-0683884; 2-(6-Methyl-pyridin-2-yl)-ethylamine; ZINC4202821; X7037; TRA0015781; 2-(2'-Aminoethyl)-6-methylpyridine; [2-(6-METHYLPYRIDIN-2-YL)ETHYL]AMINE; ANW-72514; AB1009078; CTK4E1305. CAS No. 444910-17-2. Molecular formula: C8H12N2. Mole weight: 136.198g/mol. IUPAC Name: 2-(6-methylpyridin-2-yl)ethanamine. Rotatable Bond Count: 2. Exact Mass: 136.1g/mol. SMILES: CC1=NC(=CC=C1)CCN. InChI: InChI=1S/C8H12N2/c1-7-3-2-4-8(10-7)5-6-9/h2-4H,5-6,9H2,1H3. InChIKey: CDTHKXWPZVCHBX-UHFFFAOYSA-N. H-Bond Donor: 1. H-Bond Acceptor: 2. Monoisotopic Mass: 136.1g/mol. | |
Dimethylbenzylcarbinol Quick inquiry Where to buy Suppliers range | Dimethylbenzylcarbinol. Group: Aryl. Alternative Names: AKOS009156717; Dimethylbenzylcarbinol; NSC27228; FEMA No. 2393; MFCD00004465; alpha,alpha-dimethylphenylethyl alcohol; DTXSID1047601; 2-Methyl-1-phenylpropan-2-ol; Phenethyl alcohol.alpha..alpha.-dimethyl-; WLN: QX1 & 1 & 1R. CAS No. 100-86-7. Molecular formula: C10H14O. Mole weight: 150.221g/mol. IUPAC Name: 2-methyl-1-phenylpropan-2-ol. Rotatable Bond Count: 2. Exact Mass: 150.104g/mol. EC Number: 202-896-0. Melting Point: 24.0°C;24°C. SMILES: CC(C)(CC1=CC=CC=C1)O. InChI: InChI=1S/C10H14O/c1-10(2,11)8-9-6-4-3-5-7-9/h3-7,11H,8H2,1-2H3. InChIKey: RIWRBSMFKVOJMN-UHFFFAOYSA-N. H-Bond Donor: 1. H-Bond Acceptor: 1. Monoisotopic Mass: 150.104g/mol. | |
DL-Phenylglycinol Quick inquiry Where to buy Suppliers range | A chiral arylalkylamine used as organocatalysts. Used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid. Group: Biochemicals. Alternative Names: β-Aminobenzeneethanol; β-Aminophenethyl Alcohol; (RS)-Phenylglycinol; (±)-2-Amino-2-phenylethanol; (±)-Phenylglycinol; 2-Amino-2-phenylethanol; 2-Hydroxy-1-phenylethylamine; 2-Phenyl-2-aminoethanol; DL-α-Phenylglycinol; Phenylglycinol; α - (Hydroxymethyl) benzylamine. Grades: Highly Purified. CAS No. 7568-92-5. Pack Sizes: 10g. US Biological Life Sciences. | Worldwide |
Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 Quick inquiry Where to buy Suppliers range | Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols. Uses: Transition metal catalysts. Synonyms: Bis[2-(2-fluoro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)pyridine][4,4'-di-tert-butyl-2,2'-bipyridine] iridium(III) hexafluorophosphate; Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3-fluoro-5-(trifluoromethyl)-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1). Grades: ≥95%. CAS No. 2222402-20-0. Molecular formula: C44H34F14IrN4.F6P. Mole weight: 1221.93. | |
Me4tButylXphos Quick inquiry Where to buy Suppliers range | Me4tButylXphos. Uses: Ligand for the palladium-catalyzed amidation of aryl chlorides. Ligand for the palladium-catalyzed synthesis of phenols from aryl halides. Ligand for the palladium-catalyzed coupling of aryl halides and secondary alcohols. Group: Organic Phosphine Compounds. Alternative Names: Di-tert-butyl[3,4,5,6-tetramethyl-2',4',6'-tri(propan-2-yl)[1,1'-biphenyl]-2-yl]phosphane; Di-tert-butyl(2',4',6'-triisopropyl-3,4,5,6-tetramethyl-[1,1'-biphenyl]-2-yl)phosphine; Tetramethyl Di-tbutyl X-Phos; MFCD09038436; 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAMETHYL-2',4',6'-TRI ISOPROPYLIBIPHENYL; di-tert-butyl(2',4',6'-triisopropyl-3,4,5,6-tetramethyl-[1,1'-biphenyl]-2-yl)phosphane; 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&; 2-(di-tert-butylphosphino)-2',4',6'-triisopropyl-3,4,5,6-tetramethyl-1,1'-biphenyl; CS-W001169; ZINC56961829. CAS No. 857356-94-6. Molecular formula: C33H53P. Mole weight: 480.761g/mol. IUPAC Name: ditert-butyl-[2,3,4,5-tetramethyl-6-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Rotatable Bond Count: 7. Exact Mass: 480.388g/mol. SMILES: CC1=C (C (=C (C (=C1C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C)P (C (C) (C)C)C (C) (C)C)C)C. InChI: InChI=1S/C33H53P/c1-19(2)26-17-27(20(3)4)30(28(18-26)21(5)6)29-24(9)22(7)23(8)25(10)31(29)34(32(11, 12)13)33(14, 15)16/h17-21H, 1-16H3. InChIKey: RCRYEYMHBHPZQD-UHFFFAOYSA-N. Monoisotopic Mass: 480.388g/mol. | |
Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] Quick inquiry Where to buy Suppliers range | Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]. Uses: Palladium precatalyst used for the arylation of an aliphatic alcohol. Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions. Palladium precatalyst used for the intermolecular C-O bond formation with secondary and primary alcohols. Alternative Names: RockPhos Pd G3;[RockPhos Palladacycle];MFCD27952542;2009020-38-4;Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II). CAS No. 2009020-38-4. Molecular formula: C44H63NO4PPdS-. Mole weight: 839.445g/mol. IUPAC Name: ditert-butyl-[6-methoxy-3-methyl-2-[2, 4, 6-tri(propan-2-yl)phenyl]phenyl]phosphane; methanesulfonic acid;palladium;2-phenylaniline. Rotatable Bond Count: 9. Exact Mass: 838.325g/mol. SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. CS (=O) (=O)O. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. [Pd]. InChI: InChI=1S/C31H49OP. C12H10N. CH4O3S. Pd/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8, 9)10)31(11, 12)13; 13-12-9-5-4-8-11(12)10-6-2-1-3-7-10; 1-5(2, 3)4; /h15-21H, 1-14H3; 1-6, 8-9H, 13H2; 1H3, (H, 2, 3, 4); /q; -1; ;. InChIKey: QAHMIRGGAFFMDS-UHFFFAOYSA-N. H-Bond Donor: 2. H-Bond Acceptor: 6. Monoisotopic Mass: 838.325g/mol. | |
[NH2Me2][(RuCl((R)-binap))2(μ-Cl)3] Quick inquiry Where to buy Suppliers range | [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3]. Uses: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. Ligand employed in rhodium-catalyzed 1,4-additions to enones. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. Ligand employed in palladium-catalyzed synthesis of chiral allenes. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage. Group: Ruthenium series catalysts. Alternative Names: J-012887; (R)-[(RuCl(BINAP))2( -Cl)3][NH2Me2]; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); 199684-47-4; 199541-17-8; Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]; (R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); (R)-[(RuCl(BINAP))2(|I-Cl)3[NH2Me2]. CAS No. 199684-47-4. Molecular formula: C90H75Cl5NP4Ru | |
[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3] Quick inquiry Where to buy Suppliers range | [NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]. Uses: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. 3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. 4. Ligand employed in rhodium-catalyzed 1,4-additions to enones. 5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. 6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. 7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. 8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. 9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. 10. Ligand employed in palladium-catalyzed synthesis of chiral allenes. 11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives. 12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols. 13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones. 14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols. 15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage. Group: Ruthenium series catalysts. Alternative Names: (S)-[(RuCl(BINAP))2( -Cl)3][NH2Me2]; Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]; (S)-[(RUCL(BINAP))2(MU-CL)3][NH2ME2]; [NH2ME2][[RUCL((S)-BINAP)]2(MU-CL)3]; (R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]; Dimethylammonium dichlorotri(|I-chloro)bis[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]diruthenate(II); Dimethylammonium dichlorotri(|I-chloro)bis[(R)-(+)-2,2 inverted ex | |
PhDave-Phos Quick inquiry Where to buy Suppliers range | PhDave-Phos. Uses: Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl bromides. Ligand used for the Cu-catalyzed phosphorylation of alcohols. Ligand for Pd-catalyzed C-H benzylation. Ligand for palladium-catalyzed [4 + 2] benzannulation reaction. Group: Organic Phosphine Compounds. Alternative Names: SY030636; 2'-(DIPHENYLPHOSPHINO)-N,N-DIMETHYLBIPHENYL-2-AMINE; 2-Dimethylamino-2'-(diphenylphosphino)biphenyl; RL02764; AKOS015840665; 2-(Diphenylphosphino)-2 inverted exclamation mark -(N,N-dimethylamino)biphenyl; 2'-(DIPHENYLPHOSPHINO)-N,N'-DIMETHYL-(1,1'-BIPHENYL)-2-AMINE; 2'-(diphenylphosphanyl)-N,N-dimethyl-[1,1'-biphenyl]-2-amine; 2-DIPHENYLPHOSPHINO-2'-DIMETHYLAMINOBIPHENYL; AN-11455. CAS No. 240417-00-9. Molecular formula: C26H24NP. Mole weight: 381.459g/mol. IUPAC Name: 2-(2-diphenylphosphanylphenyl)-N,N-dimethylaniline. Rotatable Bond Count: 5. Exact Mass: 381.165g/mol. SMILES: CN (C)C1=CC=CC=C1C2=CC=CC=C2P (C3=CC=CC=C3)C4=CC=CC=C4. InChI: InChI=1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3. InChIKey: JGFXUYLYPITYGR-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 381.165g/mol. | |
(R) -1-[ (SP) -2- (Dicyclohexylphosphino) ferrocenyl]ethyldi-tert-butylphosphine Quick inquiry Where to buy Suppliers range | (R) -1-[ (SP) -2- (Dicyclohexylphosphino) ferrocenyl]ethyldi-tert-butylphosphine. Uses: Ligand for Palladium-catalyzed C-N cross-coupling. Ligand for Palladium-catalyzed C-S cross-coupling. Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates. Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method. Ligand for Palladium-catalyzed C-O cross-coupling. Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes. Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation. CAS No. 158923-11-6. Molecular formula: C32H52FeP2 10*. Mole weight: 554.55. | |
(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl Quick inquiry Where to buy Suppliers range | (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl. Uses: 1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols. 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters. 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes. 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins. 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction. Group: Heterocyclic Organic Compound. CAS No. 145964-33-6. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPAC Name: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Rotatable Bond Count: 5. Exact Mass: 468.164g/mol. SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. InChI: InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3. InChIKey: KRWTWSSMURUMDE-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 468.164g/mol. | |
(R)-(-)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine Quick inquiry Where to buy Suppliers range | (R)-(-)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine. Uses: Chiral amino alcohol assisted asymmetric, enantioselective, aryl transfer of triphenylboroxin to a set of aryl aldehydes in the presence of chiral amino alcohols derived from (S)-proline. Pyrrolidinylmethanol compound used for the zinc-catalyzed addition of arylboronic acids to aromatic aldehydes, proceeding in high yields and high enantioselectivities (up to 98% ee). Group: Heterocyclic Organic Compound. Alternative Names: (R)-DPMPM; [(2R)-1-methylpyrrolidin-2-yl]-diphenyl-methanol; (r)-n-methyl-alpha,alpha-diphenyl-2-pyrrolidinemethanol; AJ-20718; alpha,alpha-Diphenyl-N-methyl-D-prolinol; OR10013; AKOS007930843; (R)-alpha,alpha-Diphenyl-N-methyl-2-pyrrolidinemethanol; ((r)-1-methylpyrrolidin-2-yl)diphenylmethanol; KS-00000IVK. CAS No. 144119-12-0. Molecular formula: C18H21NO. Mole weight: 267.372g/mol. IUPAC Name: [(2R)-1-methylpyrrolidin-2-yl]-diphenylmethanol. Rotatable Bond Count: 3. Exact Mass: 267.162g/mol. SMILES: CN1CCCC1C (C2=CC=CC=C2) (C3=CC=CC=C3)O. InChI: InChI=1S/C18H21NO/c1-19-14-8-13-17(19)18(20,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17,20H,8,13-14H2,1H3/t17-/m1/s1. InChIKey: XIJAGFLYYNXCAB-QGZVFWFLSA-N. H-Bond Donor: 1. H-Bond Acceptor: 2. Monoisotopic Mass: 267.162g/mol. | |
(R)-(+)-BINAP Quick inquiry Where to buy Suppliers range | (R)-(+)-BINAP. Uses: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester. Useful ligand in asymmetric Heck processes. Ligand employed in palladium-catalyzed asymmetric arylation of ketones. Ligand employed in rhodium-catalyzed 1,4-additions to enones. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction. Ligand employed in rhodium-catalyzed kinetic resolution of enynes. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers. Ligand employed in palladium-catalyzed synthesis of chiral allenes. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage. Ligand employed in the iridium-catalyzed asymmetric cyclopropane-mediated carbonyl allylation of primary alcohols. Ligand employed in the nickel-catalyzed asymmetric α-arylation of tetralones. Ligand employed in the copper-catalyzed asymmetric propargylation of ketones. Ligand employed in the cobalt-catalyzed asymmetric reductive coupling of alkynes with alkenes. Ligand employed in the rhodium-catalyzed asymmetric 1,4-addition of arylalanes on trisubstituted enones. Ruthenium-catalyzed asymmetric hydrocyanation of imines. Palladium-catalyzed asymmetric intermolecular cyclization. Group: Organic Phosphine Compounds. Alternative Names: -Bis(d | |
Rhodium(II) Acetate Dimer Quick inquiry Where to buy Suppliers range | Rhodium(II) Acetate Dimer. Uses: Catalyst for insertion into C-H and X-H bonds. Catalyst for Ylide generation. Doyle-Kirmse Reaction of Allylic Sulfides with Diazoalkane Claisen rearrangement. Epoxides from aldehydes. Synthesis of aziridines from allylic N-tosyloxycarbamates. Rh/NHC catalyzed direct intermolecular arylation of C-H bonds. Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines. Rh-catalyzed cyclopropenations of ynamides. Tandem asymmetric aza-Darzens/ring-opening reactions. Group: Micro/NanoElectronics. Alternative Names: Dirhodium tetraacetate; Rhodium(II) acetate, dimer, Premion®; Rhodium, tetrakis(mu-acetato)di-; Rhodium acetate, dimer; Rhodium(II) acetate dimer; Tetrakis(mu-(acetato-O:O'))dirhodium; A830446; SY010327; SC-26584; TETRAKIS(ACETO)DIRHODIUM(II). CAS No. 15956-28-2. Molecular formula: C8H12O8Rh2. Mole weight: 441.987g/mol. IUPAC Name: rhodium(2+);tetraacetate. Exact Mass: 441.864g/mol. EC Number: 240-084-8. SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Rh+2].[Rh+2]. InChI: InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4. InChIKey: SYBXSZMNKDOUCA-UHFFFAOYSA-J. H-Bond Acceptor: 8. Monoisotopic Mass: 441.864g/mol. | |
RockPhos Quick inquiry Where to buy Suppliers range | RockPhos. Uses: Ligand used in the palladium-catalyzed C-O bond forming reactions of secondary and primary alcohols with a range of aryl halides. Heterocyclic halides and, for the first time, electron-rich aryl halides can be coupled with secondary alcohols. Group: Organic Phosphine Compounds. Alternative Names: ZINC95910984; 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2'-4'-6'-tri-i-propyl-1,1'-biphenyl; RockPhos, 97%; di-tert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane; Y-200021; Di-tert-butyl(2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-3-methoxy-6-methyl-[1,1 inverted exclamation marka-biphenyl]-2-yl)phosphine; CVLLAKCGAFNZHJ-UHFFFAOYSA-N; 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopropyl-1,1'-biphenyl; SCHEMBL12929986; AX8242285. CAS No. 1262046-34-3. Molecular formula: C31H49OP. Mole weight: 468.706g/mol. IUPAC Name: ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Rotatable Bond Count: 8. Exact Mass: 468.352g/mol. SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. InChI: InChI=1S/C31H49OP/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8, 9)10)31(11, 12)13/h15-21H, 1-14H3. InChIKey: CVLLAKCGAFNZHJ-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 468.352g/mol. | |
[RuCl(p-cymene)((S)-tolbinap)]Cl Quick inquiry Where to buy Suppliers range | [RuCl(p-cymene)((S)-tolbinap)]Cl. Uses: 1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPAC Name: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Rotatable Bond Count: 8. Exact Mass: 984.212g/mol. SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. Cl[Ru]Cl. InChI: InChI=1S/C48H40P2.C10H14.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-8(2)10-6-4-9(3)5-7-10;;;/h5-32H,1-4H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2. InChIKey: BHIUOOHVIWKUTN-UHFFFAOYSA-L. Monoisotopic Mass: 984.212g/mol. | |
(S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl Quick inquiry Where to buy Suppliers range | (S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl. Uses: Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic Organic Compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPAC Name: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Rotatable Bond Count: 5. Exact Mass: 468.164g/mol. SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. InChI: InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3. InChIKey: KRWTWSSMURUMDE-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 468.164g/mol. | |
Silver Trifluoromethanesulfonate Quick inquiry Where to buy Suppliers range | Silver Trifluoromethanesulfonate. Uses: Silver precatalyst for the asymmetric allylation of aldehydes Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins Silver catalyst for the fluorination of boronic acids Silver catalyst for the fluorination of functionalized aryl stannanes Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate. Group: Silver series of catalysts. Alternative Names: KSC491Q9D; Silver trifluoromethanesulfonate, >=99%; silver(1+) ion trifluoromethanesulfonate; silver(i)trifluoromethanesulfonate; TRIFLUOROMETHANESULFONATE SILVER SALT; trifluormethanesulfonic acid silver salt; silver(i) trifluoromethanesulphonate; ANW-26574; QRUBYZBWAOOHSV-UHFFFAOYSA-M; X7226. CAS No. 2923-28-6. Molecular formula: CAgF3O3S. Mole weight: 256.931g/mol. IUPAC Name: silver;trifluoromethanesulfonate. Exact Mass: 255.857g/mol. EC Number: 220-882-2. SMILES: C(F)(F)(F)S(=O)(=O)[O-].[Ag+]. InChI: InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1. InChIKey: QRUBYZBWAOOHSV-UHFFFAOYSA-M. | |
(S)-(-)-TolBINAP Quick inquiry Where to buy Suppliers range | (S)-(-)-TolBINAP. Uses: Useful ligand for palladium-catalyzed carbon-oxygen bond formation. Ligand for palladium-catalyzed α-arylation of ketones. Ligand for Cu-catalyzed asymmetric conjugate reduction. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. Enantioselective conjugate reduction of lactones and lactams. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. Catalytic Aldol reaction to ketones. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. Rhodium-catalyzed cross cyclotrimerization. Group: Heterocyclic Organic Compound. CAS No. 100165-88-6. Molecular formula: C48H40P2. Mole weight: 678.796g/mol. IUPAC Name: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane. Rotatable Bond Count: 7. Exact Mass: 678.261g/mol. SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. InChI: InChI=1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3. InChIKey: IOPQYDKQISFMJI-UHFFFAOYSA-N. Monoisotopic Mass: 678.261g/mol. | |
t-BuDavePhos Quick inquiry Where to buy Suppliers range | t-BuDavePhos. Uses: Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines. Ligand used for selective Pd-catalyzed silylation of aryl chlorides. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. Group: Organic Phosphine Compounds. Alternative Names: 2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179. CAS No. 224311-49-3. Molecular formula: C22H32NP. Mole weight: 341.479g/mol. IUPAC Name: 2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline. Rotatable Bond Count: 5. Exact Mass: 341.227g/mol. SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2N (C)C)C (C) (C)C. InChI: InChI=1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3. InChIKey: PHLPNEHPCYZBNZ-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 341.227g/mol. | |
Tris(triphenylphosphine)rhodium(I) Chloride Quick inquiry Where to buy Suppliers range | Tris(triphenylphosphine)rhodium(I) Chloride. Uses: A homogeneous hydrogenation catalyst which operates under mild conditions. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reactions. Alkyne hydro-phosphorylation Heck-type reaction with α,β-unsaturated esters. Alkyne arylation Allylic alcohol-olefin coupling. Terminal alkenes from ketones. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. Reductive deprotection of silyl groups. Group: Rhodium series of catalysts. Alternative Names: Wilkinson's catalyst Tris(triphenylphosphine)rhodium(I) chloride C54H45ClP3Rh 925.23 ca 250 degrees dec. 14694-95-2 "14,10047" 238-744-5 MFCD00010016 P273-P501a; Tris(triphenylphosphine)rhodium chloride; AS-12487; AN-15374; Tris(triphenylphosphine)rhodium monochloride; 16592-65-7; RhCl(PPh3)3, Rhodium(I) tris(triphenylphosphine) chloride, Wilkinson's catalyst, NSC 124140; chlorotris(triphenylphosphine)-rhodium(i); RTR-005847; tris(triphenylphosphine)-rhodium (I) chloride. CAS No. 14694-95-2. Molecular formula: C54H45ClP3Rh-. Mole weight: 925.231g/mol. IUPAC Name: rhodium;triphenylphosphane;chloride. Rotatable Bond Count: 9. Exact Mass: 924.148g/mol. EC Number: 238-744-5. SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. InChI: InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1. InChIKey: QBERHIJABFXGRZ-UHFFFAOYSA-M. H-Bond Acceptor: 1. Monoisotopic Mass: 924.148g/mol. | |
Tyloxapol, USP Quick inquiry Where to buy Suppliers range | Tyloxapol is a nonionic liquid polymer of the alkyl aryl polyether alcohol type. It is used as a surfactant to aid liquefaction and removal of mucopurulent[citation needed] (containing mucus and pus) bronchopulmonary secretions,[1][2] administered by inhalation through a nebulizer[3] or with a stream of oxygen. With intraperitoneal injection, tyloxapol also blocks plasma lipolytic activity, and thus the breakdown of triglyceride-rich lipoproteins. This mechanism is used to induce experimental hyperlipidemia in animals.[4] Tyloxapol is the main active ingredient of the medical device Tacholiquin®. Tacholiquin® is an expectorant designated for inhalation and instillation reaching the upper and lower airways. Group: Biochemicals. Alternative Names: p- (1, 1, 3, 3-Tetramethylbutyl) Phenol Polymer with Ethylene Oxide and Formaldehyde; Ethylene Oxide Polymer with Formaldehyde and p- (1, 1, 3, 3-Tetramethylbutyl) phenol; Oxirane Polymer with Formaldehyde and 4- (1, 1, 3, 3-tetramethylbutyl) phenol; Ethylene oxide-formaldehyde-4- (1, 1, 3, 3-tetramethylbutyl) phenol copolymer; Ethylene oxide-formaldehyde-p-octylphenol Copolymer; NSC 90255; Superinone; Triton A 20; Triton WR 1339; Tyloxapol; p-Isooctyl polyoxyethyl ene phenol Formaldehyde Polymer. Grades: USP. CAS No. 25301-02-4. Pack Sizes: 1g, 5g, 25g. Molecular Formula: (C17H30O4)n, Molecular Weight: As reported. US Biological Life Sciences. | Worldwide |