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A group of enzymes with broad specificity towards primary alcohols with an aromatic or cyclohex-1-ene ring, but with low or no activity towards short-chain aliphatic alcohols. Group: Enzymes. Synonyms: p-hydroxybenzyl alcohol dehydrogenase; benzyl alcohol dehydrogenase; coniferyl alcohol dehydrogenase. Enzyme Commission Number: EC 1.1.1.90. CAS No. 37250-26-3. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0374; aryl-alcohol dehydrogenase; EC 1.1.1.90; 37250-26-3; p-hydroxybenzyl alcohol dehydrogenase; benzyl alcohol dehydrogenase; coniferyl alcohol dehydrogenase. Cat No: EXWM-0374.
aryl-alcohol dehydrogenase (NADP+)
Also acts on some aliphatic aldehydes, but cinnamaldehyde was the best substrate found. Group: Enzymes. Synonyms: arylalcohol dehydrogenase (nicotinamide adenine dinucleotide phosphate); coniferyl alcohol dehydrogenase; NADPH-linked benzaldehyde reductase; aryl-alcohol dehydrogenase (NADP). Enzyme Commission Number: EC 1.1.1.91. CAS No. 37250-27-4. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0375; aryl-alcohol dehydrogenase (NADP+); EC 1.1.1.91; 37250-27-4; arylalcohol dehydrogenase (nicotinamide adenine dinucleotide phosphate); coniferyl alcohol dehydrogenase; NADPH-linked benzaldehyde reductase; aryl-alcohol dehydrogenase (NADP). Cat No: EXWM-0375.
aryl-alcohol oxidase
Oxidizes many primary alcohols containing an aromatic ring; best substrates are (2-naphthyl)methanol and 3-methoxybenzyl alcohol. Group: Enzymes. Synonyms: arylalcohol oxidase; veratryl alcohol oxidase; arom. alcohol oxidase. Enzyme Commission Number: EC 1.1.3.7. CAS No. 9028-77-7. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0425; aryl-alcohol oxidase; EC 1.1.3.7; 9028-77-7; arylalcohol oxidase; veratryl alcohol oxidase; arom. alcohol oxidase. Cat No: EXWM-0425.
1,10-Phenanthroline Nickel dibromide
1,10-Phenanthroline Nickel dibromide is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols. Uses: Transition metal catalysts. Synonyms: Nickel, dibromo(1,10-phenanthroline-κN1,κN10)-; Dibromo(1,10-phenanthroline-κN1,κN10)nickel; Nickel, dibromo(1,10-phenanthroline)-; Nickel, dibromo(1,10-phenanthroline-N1,N10)-; Dibromo(1,10-phenanthroline-κN1,κN10)nickel; 1,10-Phenanthroline nickel (II) dibromide; Ni (phen) Br2; (phen)NiBr2. Grades: ≥95%. CAS No. 48165-50-0. Molecular formula: C12H8Br2N2Ni. Mole weight: 398.71.
1, 1'-Bis (dicyclohexylphosphino)ferrocene
Ligand for palladium-catalyzed synthesis of oxindoles by amide ?-arylation. Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides. Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols. Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates. Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases. Group: Organic phosphine compounds. Alternative Names: 1,1-Bis(dicyclohexylphosphino)ferrocene; 1,1-Bis(Dicyclohexylphosphino)Ferrocene; 1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE. CAS No. 146960-90-9. Molecular formula: C34H52FeP2. Mole weight: 578.57. Appearance: Orange-red powder. Purity: 0.98. IUPACName: dicyclohexyl(cyclopentyl)phosphane; iron. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. [Fe]. Catalog: ACM146960909.
1, 1'-Bis (diisopropylphosphino)ferrocene
Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO. Pd-catalyzed carbonylative ?-arylation of ketones with aryl iodides Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation Ligand for ruthenium-catalyzed C-C coupling reactions of fluorinated alcohols with allenes. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents. Group: Organic phosphine compounds. Alternative Names: 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE. CAS No. 97239-80-0. Molecular formula: C22H36FeP2. Mole weight: 418.32. Appearance: Orange-yellow powder. Purity: 0.98. IUPACName: 1,1-Bis(diisopropylphosphino)ferrocene. Catalog: ACM97239800.
1,1-Dimethylethyl Nitrite
ert-Butyl nitrite is an intermediate used for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It is also used to prepare aryl azides from aryl amines. Group: Biochemicals. Grades: Highly Purified. CAS No. 540-80-7. Pack Sizes: 1g, 10g. Molecular Formula: C4H9NO2. US Biological Life Sciences.
Worldwide
1-(3-Methoxyphenyl)ethanol
1-(3-Methoxyphenyl)ethanol (Rivastigmine EP Impurity G) is a versatile reactant used in the preparation of 2,3-dihydroimidazo[1,2-a]pyridines as enantioselective acyl transfer catalysts in kinetic resolution of alcohols. Also used in chemoselective preparation of aryl aldehydes/ketones via in situ generated TEMPO-copper(II) diimine catalyzed oxidation of benzylic alcohols in aqueous media. Group: Biochemicals. Grades: Highly Purified. CAS No. 23308-82-9. Pack Sizes: 50mg, 250mg. Molecular Formula: C9H12O2. US Biological Life Sciences.
Worldwide
1-Heptanol purum
Watery colorless liquid with a weak alcohol odor. Floats on water. (USCG, 1999);Liquid;Liquid;COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.;colourless liquid/citrus odour. Group: Aryl. CAS No. 111-70-6. Molecular formula: C7H16O;CH3(CH2)6OH;C7H16O. Mole weight: 116.2g/mol. Purity: 0.99. IUPACName: heptan-1-ol. Canonical SMILES: CCCCCCCO. Density: 0.822 at 68 °F (USCG, 1999);d204 0.82;0.8219 at 20 °C/4 °C;0.82 g/cm³;Relative density of the vapour/air-mixture at 20 °C (air = 1): 1.01;0.820-1.824. ECNumber: 203-897-9;258-615-7. Catalog: ACM111706.
(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol
(1S,3S,4S)-(-)-3,5-dinitrobenzoate Menthol is an intermediate in the synthesis of (±)-Neoisomenthol (N389960) which is a useful synthetic intermediate. It is used to prepare alkyl and aryl esters by chemoselective acylation of alkyl and arylalcohols with carboxylic acid anhydrides in the presence of magnesium bis (trifluoro methyl sulfonyl) amide under solvent-free conditions. Group: Biochemicals. Grades: Highly Purified. CAS No. 1195710-85-0. Pack Sizes: 50mg, 100mg. Molecular Formula: C17H22N2O6. US Biological Life Sciences.
Worldwide
(1S)-1-Amino-2-methyl-1-phenylpropan-2-ol
(1S)-1-Amino-2-methyl-1-phenylpropan-2-ol can be used as reactant/reagent in stereoselective preparation of diaryl carbonyl compounds via palladium-catalyzed enantioselective redox-relay oxidative Heck arylation of arylboronic acids and homoallylic alcohols. Group: Biochemicals. Grades: Highly Purified. CAS No. 110480-86-9. Pack Sizes: 100mg, 250mg. Molecular Formula: C10H15NO, Molecular Weight: 165.23. US Biological Life Sciences.
Worldwide
2,2'-Bis(diphenylphosphino)biphenyl
Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Group: Organic phosphine compounds. Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1, 1'-[[1, 1'-BIPHENYL]-2, 2'-DIYL]BIS[1, 1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPACName: [2- (2-diphenylphosphanylphenyl) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM84783642.
2,4-Dimethoxybenzyl alcohol
2,4-Dimethoxybenzyl alcohol, an aromatic alcohol, is a substrate of glucose-methanol-choline (GMC) oxidoreductase. GMC oxidoreductase displays the characteristics of an aryl-alcohol oxidase [1]. Uses: Scientific research. Group: Signaling pathways. CAS No. 7314-44-5. Pack Sizes: 10 mM * 1 mL; 5 g; 10 g; 25 g. Product ID: HY-W007584.
2-(Dibutylamino)-1-(2,7-dichloror-9H-fluoren-4-yl)ethanol is an impurity formed during the synthesis of Lumefantrine, a fluorene derivative belonging to the aryl amino alcohol class of anti-malarial drugs. Synonyms: 2,7-Dichloro-α-[(dibutylamino)methyl]-9H-fluorene-4-methanol. Grades: > 95%. CAS No. 69759-61-1. Molecular formula: C23H29Cl2NO. Mole weight: 406.39.
2-(Dibutylamino)-1-(2,7-dichloror-9H-fluoren-4-yl)ethanol is an impurity formed during the synthesis of Lumefantrine (L474000), a fluorene (F462000) derivative belonging to the aryl amino alcohol class of anti-malarial drugs. Group: Biochemicals. Alternative Names: 2,7-Dichloro-α-[(dibutylamino)methyl]-9H-fluorene-4-methanol. Grades: Highly Purified. CAS No. 69759-61-1. Pack Sizes: 1g. US Biological Life Sciences.
Worldwide
2-(Dicyclohexylphosphino)biphenyl
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in Suzuki coupling reactions involving aryl chlorides, bromides and triflates. Useful ligand for the Pd-catalyzed oxidation of alcohols in the presence of chlorobenzenes. Useful ligand for the Pd-catalyzed amination with ammonia equivalents. Ligand for the gold(I)-catalyzed intramolecular [4+2] cycloadditions involving 1,3-enynes and arylalkynes with alkenes. Ligand used in the palladium-catalyzed borylation of aryl bromdies. Ligand used in the palladium-catalyzed siliylation of aryl chlorides. Group: Organic phosphine compounds. Alternative Names: Cyclohexyl JohnPhos. CAS No. 247940-06-3. Molecular formula: C24H31P. Mole weight: 350.48. Appearance: Solid. Purity: 0.98. IUPACName: dicyclohexyl-(2-phenylphenyl)phosphane. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)C3=CC=CC=C3C4=CC=CC=C4. ECNumber: 480-030-2. Catalog: ACM247940063-1.
Isothiourea-mediated intermolecular Michael addition-lactonisation. Isothiourea-mediated, asymmetric, Michael-lactonisation of CF3 - enones. α-Functioalisation of 3-alkenoic acids. Isothiourea-catalyzed α-amination of carboxylic acids. Isothiourea-catalyzed O- to C- carboxyl transfer of furanyl carbonates. Isothiourea-catalyzed kinetic resolution of secondary alcohols. Isothiourea-catalyzed α-amination of carboxylic acidswith N-aryl-N-aroyldiazene. Group: Chiral catalystschiral isothioureasnitrogen-containing catalysts. Alternative Names: ZINC169382070; OR51901; MFCD29037150; (2S,3R)-3-Isopropyl-2-phenyl-3,4-dihydro-2h-pyrimido[2,1-b][1,3]benzothiazole; D4808; 2alpha-Phenyl-3alpha-isopropyl-3,4-dihydro-2H-pyrimido[2,1-b]benzothiazole. CAS No. 1203507-02-1. Molecular formula: C19H20N2S. Mole weight: 308.443g/mol. IUPACName: (2S,3R)-2-phenyl-3-propan-2-yl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole. Canonical SMILES: CC (C) C1CN2C3=CC=CC=C3SC2=NC1C4=CC=CC=C4. Catalog: ACM1203507021.
3,4,7,8-Tetramethyl-1,10-phenanthroline Nickel (II) dichloride
3,4,7,8-Tetramethyl-1,10-phenanthroline Nickel (II) dichloride is a Ni catalyst used for a variety of cross-coupling reactions including the cross-electrophile coupling of benzyl alcohols and aryl halides. Uses: Transition metal catalysts. Synonyms: Nickel, dichloro(3,4,7,8-tetramethyl-1,10-phenanthroline-κN1,κN10)-; Dichloro(3,4,7,8-tetramethyl-1,10-phenanthroline-κN1,κN10)nickel; (Me4Phen)NiCl2. Grades: ≥95%. CAS No. 2254430-88-9. Molecular formula: C16H16Cl2N2Ni. Mole weight: 365.91.
3-Bromo-5-hydroxybenzyl Alcohol
3-Bromo-5-hydroxybenzyl Alcohol is an intermediate used to prepare (isoxazolylphenyl) arylmethanols as inhibitors of the BET bromodomain family member BRD4(1) for potential use as antitumor agents. Group: Biochemicals. Grades: Highly Purified. CAS No. 1020336-51-9. Pack Sizes: 500mg, 1g. Molecular Formula: C7H7BrO2, Molecular Weight: 203.03. US Biological Life Sciences.
Worldwide
3-(Hydroxymethyl)phenylboronic acid
Reactant involved in: Copper-mediated trifluoromethylation Copper-catalyzed transformations from arylboronic acids in water Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylateReactant involved in the synthesis of biologically active molecules including: Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions HIV protease inhibitors with antiviral activity against drug-resistant viruses Pyrrole derivatives for use as PDE4B inhibitors. Synonyms: 3-Boronobenzyl alcohol; 3-hydroxymethylbenzeneboronic acid; 3-hydroxymethylboronic acid; RARECHEM AH PB 0189; 3-HydroMethylphenylboronicacid; KS-000000LJ; m-(Hydroxymethyl)phenyl boronic acid. Grades: 97%. CAS No. 87199-15-3. Molecular formula: C7H9BO3. Mole weight: 151.96.
5-(hydroxymethyl)furfural oxidase
The enzyme, characterized from the bacterium Methylovorus sp. strain MP688, is involved in the degradation and detoxification of 5-(hydroxymethyl)furfural. The enzyme acts only on alcohol groups and requires the spontaneous hydration of aldehyde groups for their oxidation. The enzyme has a broad substrate range that overlaps with EC 1.1.3.7, aryl-alcohol oxidase. Group: Enzymes. Enzyme Commission Number: EC 1.1.3.47. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-0420; 5-(hydroxymethyl)furfural oxidase; EC 1.1.3.47. Cat No: EXWM-0420.
5-Methyl-1-hexanol
Iso heptyl alcohol appears as a clear colorless liquid with a pleasant odor. Less dense than water and insoluble in water. Vapors heavier than air. Used to make other chemicals, as a solvent, and in cosmetic formulations. Group: Aryl. Alternative Names: 5-Methylhexan-1-ol;5-METHYL-1-HEXANOL;627-98-5;5-methylhexanol;Isoheptanol;Isoheptan-1-ol;1-Hexanol, 5-methyl-; 51774-11-9; 5-Methyl-hexan-1-ol; UNII-1PLY0QE25K; 1PLY0QE25K; UNII-Q766MX3689; MFCD00072703; Q766MX3689; EINECS 257-413-6;isoheptyl alcohol;EINECS 211-023-2;5-Methylhexanol-[d7];ACMC-1AXQ8;Isoheptanol (mixed isomers);5-Methyl-1-hexanol, 97%; SCHEMBL104527; DTXSID4075326; ZINC2031628; GEO-01853; AKOS009156368; FS-5402; SY083602; BB 0258104;FT-0671815;FT-0671816;R1957;W-109236. CAS No. 627-98-5. Molecular formula: C7H16O;C7H16O. Mole weight: 116.20g/mol. IUPACName: 5-methylhexan-1-ol. Canonical SMILES: CC(C)CCCCO. ECNumber: 211-023-2;257-413-6. Catalog: ACM627985.
Ligand used for the hydroformylation of alkenes. Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides. Ligand used in the intermolecular coupling of amides with aryl halides or triflates. Ligand used in the coupling of heteroarylamines and aryl halides. Ligand used in the hydrophosphinylation of alkenes and alkynes. Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols. Ligand used for the sulfinylation of aryl iodides. Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines. Ligand used for the Ni-cataltzed alkynylcyanation of alkynes. Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole. Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes. Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides. Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles. Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes. Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates. Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones. Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines. Ligand used fo
ABC294640
ABC294640 is an orally available, aryladamantane compound and selective inhibitor of sphingosine kinase-2 (SK2) with potential antineoplastic activity. Upon administration, ABC294640 competitively binds to and inhibits SK2, thereby preventing the phosphorylation of the pro-apoptotic amino alcohol sphingosine to sphingosine 1-phosphate (S1P), the lipid mediator that is pro-survival and critical for immunomodulation. Synonyms: ABC-294640; ABC294640; ABC 294640; Opaganib; 3-(4-chlorophenyl)-adamantane-1-carboxylic acid (pyridin-4-ylmethyl)amide. Grades: 0.98. CAS No. 915385-81-8. Molecular formula: C23H25ClN2O. Mole weight: 380.9104.
acetylsalicylate deacetylase
Not identical with EC 3.1.1.1 (carboxylesterase), EC 3.1.1.2 (arylesterase), EC 3.1.1.7 (acetylcholinesterase) or EC 3.1.1.8 (cholinesterase). The activity of the liver cytosol enzyme is highest with acetyl esters of arylalcohols, and thioesters are also hydrolysed; the microsomal enzyme also hydrolyses some other negatively charged esters, with highest activity on esters of salicylate with long-chain alcohols. Group: Enzymes. Synonyms: aspirin esterase; aspirin esterase; acetylsalicylic acid esterase; aspirin hydrolase. Enzyme Commission Number: EC 3.1.1.55. CAS No. 87348-04-7. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-3483; acetylsalicylate deacetylase; EC 3.1.1.55; 87348-04-7; aspirin esterase; aspirin esterase; acetylsalicylic acid esterase; aspirin hydrolase. Cat No: EXWM-3483.
Allyl[1, 3-bis (2, 6-diisopropylphenyl) -2-imidazolidinylidene]chloropalladium (II)
Catalyst for the cross-coupling of aryl chlorides or bromides with aromatic amines. Catalyst for the α-arylation of ketones. Catalyst for anaerobic alcohol oxidation. Group: Heterocyclic organic compound. Alternative Names: ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM (II); Allylchloro[1, 3-bis (2, 6-di-i-propylphenyl)-4, 5-dihydroimidazol-2-ylidene]palladium (II), 97%; ALLYLCHLORO[1, 3-BIS- (DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM (II). CAS No. 478980-01-7. Molecular formula: C30H43ClN2Pd. Mole weight: 573.55. Purity: 0.96. IUPACName: Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylide. Catalog: ACM478980017.
Catalyst for the cross-coupling of aryl chlorides with boronic acids. Catalyst for the diamination of conjugated dienes and trienes. Catalyst for the dehalogenation of aryl chlorides. Catalyst for anaerobic alcohol oxidation. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. Group: Organic phosphine compounds. Alternative Names: Palladium, [1, ?3-bis [2, ?6-bis (1- methyl ethyl) ?phenyl] ?-1, ?3-dihydro-2H-imidazol-2-ylide ne ] ?chloro ( η 3-2-propen-1-yl) ?-. CAS No. 478980-03-9. Molecular formula: C30H42ClN2Pd. Mole weight: 572.54. Appearance: white solid. Purity: 98%, Pd>18.5%. Catalog: ACM478980039.
Newly developed Pd catalyst for the enantioselective intermolecular Heck reaction of tri-substituted alkenyl alcohols with aryl boronic acids. Group: Palladium catalysts. Alternative Names: MFCD28167054; Bis(acetonitrile)palladium(II) p-toluenesulfonate, 98%;114757-66-3. CAS No. 114757-66-3. Molecular formula: C18H22N2O6PdS2. Mole weight: 532.922g/mol. IUPACName: acetonitrile;4-methylbenzenesulfonic acid;palladium. Canonical SMILES: CC#N. CC#N. CC1=CC=C(C=C1)S(=O)(=O)O. CC1=CC=C(C=C1)S(=O)(=O)O. [Pd]. Catalog: ACM114757663.
Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II)
Catalyst for the arylation (or alkenylation) of anthraquinone and PBI. Catalytic C-C bond formation. Transfer hydrogenative coupling of isoprene to alcohols or aldehydes. Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation. Catalyst for the conversion of primary alcohols and aldehydes into methyl esters. Precatalyst for hydrogen production by means of alcohol dehydrogenation. Group: Ruthenium series catalysts. Alternative Names: 25360-32-1; Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II); Carbonyldihydridotris (triphenylphosphine)ruthenium (II); Dihydridocarbonyltris (triphenylphosphine)ruthenium; C55H47OP3Ru; [ (C6H5)3P]3Ru (CO)H2; AKOS024258165; Carbonyl (dihydrido)tris (triphenylphosphine)ruthenium (II). CAS No. 25360-32-1. Molecular formula: C55H49OP3Ru. Mole weight: 919.987g/mol. IUPACName: formaldehyde;ruthenium dihydride;triphenylphosphane. Canonical SMILES: C=O. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [RuH2]. Catalog: ACM25360321.
coniferin β-glucosidase
Also hydrolyses syringin, 4-cinnamyl alcohol β-glucoside and, more slowly, some other aryl β-glycosides. A plant cell-wall enzyme involved in the biosynthesis of lignin. Group: Enzymes. Synonyms: coniferin-hydrolyzing β-glucosidase. Enzyme Commission Number: EC 3.2.1.126. CAS No. 83869-30-1. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-3809; coniferin β-glucosidase; EC 3.2.1.126; 83869-30-1; coniferin-hydrolyzing β-glucosidase. Cat No: EXWM-3809.
A chiral arylalkylamine used as organocatalysts. Used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid. Group: Biochemicals. Alternative Names: β-Aminobenzeneethanol; β-Aminophenethyl Alcohol; (RS)-Phenylglycinol; (±)-2-Amino-2-phenylethanol; (±)-Phenylglycinol; 2-Amino-2-phenylethanol; 2-Hydroxy-1-phenylethylamine; 2-Phenyl-2-aminoethanol; DL-α-Phenylglycinol; Phenylglycinol; α - (Hydroxymethyl) benzylamine. Grades: Highly Purified. CAS No. 7568-92-5. Pack Sizes: 10g. US Biological Life Sciences.
Worldwide
Esterase from Bacillus subtilis, Recombinant
An esterase is a hydrolase that splits esters into acids and alcohols. Applications: Esterase, from bacillus subtilis, may be used in protein engineering research as well as to study the kinetic resolution of acetates of arylaliphatic tertiary alcohols. this product is recombinant and expressed in e. coli (> 10 units/mg). Group: Enzymes. Synonyms: EC 3.1.1.1; ali-esterase; B-esterase; monobutyrase; cocaine esterase; procaine esterase; methylbutyrase; vitamin A esterase; butyryl esterase; carboxyesterase; carboxylate esterase; carboxylic esterase; methylbutyrate esterase; triacet. Enzyme Commission Number: EC 3.1.1.1. CAS No. 9016-18-6. Esterase. Activity: Type I, > 10 units/mg; Type II, > 0.8 units/mg. Storage: -20°C. Source: E. coli. Species: Bacillus subtilis. EC 3.1.1.1; ali-esterase; B-esterase; monobutyrase; cocaine esterase; procaine esterase; methylbutyrase; vitamin A esterase; butyryl esterase; carboxyesterase; carboxylate esterase; carboxylic esterase; methylbutyrate esterase; triacetin esterase; carboxyl ester hydrolase; butyrate esterase; methylbutyrase; α-carboxylesterase; propionyl esterase; nonspecific carboxylesterase; esterase D; esterase B; esterase A; serine esterase; carboxylic acid esterase; cocaine esterase; 9016-18-6. Pack: Bottomless glass bottle. Contents are inside inserted fused cone. Cat No: NATE-0242.
Ir[FCF3(CF3)ppy]2(dtbbpy)PF6
Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols. Uses: Transition metal catalysts. Synonyms: Bis[2-(2-fluoro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)pyridine][4,4'-di-tert-butyl-2,2'-bipyridine] iridium(III) hexafluorophosphate; Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3-fluoro-5-(trifluoromethyl)-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1). Grades: ≥95%. CAS No. 2222402-20-0. Molecular formula: C44H34F14IrN4.F6P. Mole weight: 1221.93.
Me4tButylXphos
Ligand for the palladium-catalyzed amidation of aryl chlorides. Ligand for the palladium-catalyzed synthesis of phenols from aryl halides. Ligand for the palladium-catalyzed coupling of aryl halides and secondary alcohols. Group: Organic phosphine compounds. Alternative Names: Di-tert-butyl[3,4,5,6-tetramethyl-2',4',6'-tri(propan-2-yl)[1,1'-biphenyl]-2-yl]phosphane; Di-tert-butyl(2',4',6'-triisopropyl-3,4,5,6-tetramethyl-[1,1'-biphenyl]-2-yl)phosphine; Tetramethyl Di-tbutyl X-Phos; MFCD09038436; 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAMETHYL-2',4',6'-TRI ISOPROPYLIBIPHENYL; di-tert-butyl(2',4',6'-triisopropyl-3,4,5,6-tetramethyl-[1,1'-biphenyl]-2-yl)phosphane; 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&; 2-(di-tert-butylphosphino)-2',4',6'-triisopropyl-3,4,5,6-tetramethyl-1,1'-biphenyl; CS-W001169; ZINC56961829. CAS No. 857356-94-6. Molecular formula: C33H53P. Mole weight: 480.761g/mol. IUPACName: ditert-butyl-[2,3,4,5-tetramethyl-6-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC1=C (C (=C (C (=C1C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C)P (C (C) (C)C)C (C) (C)C)C)C. Catalog: ACM857356946.
Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
Palladium precatalyst used for the arylation of an aliphatic alcohol. Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions. Palladium precatalyst used for the intermolecular C-O bond formation with secondary and primary alcohols. Group: Palladium catalysts. Alternative Names: RockPhos Pd G3;[RockPhos Palladacycle]; MFCD27952542; 2009020-38-4; Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl)(2'-amino-1, 1'-biphenyl-2-yl)palladium(II). CAS No. 2009020-38-4. Molecular formula: C44H63NO4PPdS-. Mole weight: 839.445g/mol. IUPACName: ditert-butyl-[6-methoxy-3-methyl-2-[2, 4, 6-tri(propan-2-yl)phenyl]phenyl]phosphane; methanesulfonic acid;palladium;2-phenylaniline. Canonical SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. CS (=O) (=O)O. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. [Pd]. Catalog: ACM2009020384.
Native Abalone Sulfatase
Sulfatases EC 3.1.6.1 are enzymes of the esterase class that catalyze the hydrolysis of sulfate esters. These may be found on a range of substrates, including steroids, carbohydrates and proteins. Sulfate esters may be formed from various alcohols and amines. In the latter case the resultant N-sulfates can also be termed sulfamates. Sulfatases play important roles in the cycling of sulfur in the environment, in the degradation of sulfated glycosaminoglycans and glycolipids in the lysosome, and in remodelling sulfated glycosaminoglycans in the extracellular space. Together with sulfotransferases, sulfatases form the major catalytic machinery for the synthesis and breakage of sulfa...ne conjugates from hamster embryo fibroblasts. Group: Enzymes. Synonyms: EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Enzyme Commission Number: EC 3.1.6.1. CAS No. 9016-17-5. Sulfatases. Activity: 20-40 units/mg solid. Storage: -20°C. Form: lyophilized powder. Source: Abalone entrails. Species: Abalone. EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Cat No: NATE-0685.
Native Aerobacter aerogenes Sulfatase
Sulfatases EC 3.1.6.1 are enzymes of the esterase class that catalyze the hydrolysis of sulfate esters. These may be found on a range of substrates, including steroids, carbohydrates and proteins. Sulfate esters may be formed from various alcohols and amines. In the latter case the resultant N-sulfates can also be termed sulfamates. Sulfatases play important roles in the cycling of sulfur in the environment, in the degradation of sulfated glycosaminoglycans and glycolipids in the lysosome, and in remodelling sulfated glycosaminoglycans in the extracellular space. Together with sulfotransferases, sulfatases form the major catalytic machinery for the synthesis and breakage o...17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Enzyme Commission Number: EC 3.1.6.1. CAS No. 9016-17-5. Sulfatases. Activity: 2-5 units/mg protein (biuret), 10-20 units/mL. Storage: -20°C. Form: buffered aqueous glycerol solution; Solution in 50% glycerol containing 0.01 M Tris, pH 7.5. Source: Aerobacter aerogenes. EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Cat No: NATE-0686.
Native Helix pomatia Sulfatase
Sulfatases EC 3.1.6.1 are enzymes of the esterase class that catalyze the hydrolysis of sulfate esters. These may be found on a range of substrates, including steroids, carbohydrates and proteins. Sulfate esters may be formed from various alcohols and amines. In the latter case the resultant N-sulfates can also be termed sulfamates. Sulfatases play important roles in the cycling of sulfur in the environment, in the degradation of sulfated glycosaminoglycans and glycolipids in the lysosome, and in remodelling sulfated glycosaminoglycans in the extracellular space. Together with sulfotransferases, sulfatases form the major catalytic machinery for the synthesis and breakage of su...n. Group: Enzymes. Synonyms: EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Enzyme Commission Number: EC 3.1.6.1. CAS No. 9016-17-5. Sulfatases. Activity: Type I, > 10 ,000 units/g solid; Type II, > 2 ,000 units/mL. Storage: -20°C. Form: Type I, powder; Type II, aqueous solution. Source: Helix pomatia. EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Cat No: NATE-0687.
Native Patella vulgata (keyhole limpet) Sulfatase
Sulfatases EC 3.1.6.1 are enzymes of the esterase class that catalyze the hydrolysis of sulfate esters. These may be found on a range of substrates, including steroids, carbohydrates and proteins. Sulfate esters may be formed from various alcohols and amines. In the latter case the resultant N-sulfates can also be termed sulfamates. Sulfatases play important roles in the cycling of sulfur in the environment, in the degradation of sulfated glycosaminoglycans and glycolipids in the lysosome, and in remodelling sulfated glycosaminoglycans in the extracellular space. Together with sulfotransferases, sulfatases form the major catalytic machinery for the synthesis and breakage of sulfate esters. Group: Enzymes. Synonyms: EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbellifery. Enzyme Commission Number: EC 3.1.6.1. CAS No. 9016-17-5. Sulfatases. Activity: Type I, > 10 units/mg solid; Type II, > 5 units/mg solid. Storage: -20°C. Form: essentially salt-free, lyophilized powder. Source: Patella vulgata (keyhole limpet). EC 3.1.6.1; 9016-17-5; sulfatase; nitrocatechol sulfatase; phenolsulfatase; phenylsulfatase; p-nitrophenyl sulfatase; arylsulfohydrolase; 4-methylumbelliferyl sulfatase; estrogen sulfatase; arylsulfatase. Cat No: NATE-0688.
PhDave-Phos
Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl bromides. Ligand used for the Cu-catalyzed phosphorylation of alcohols. Ligand for Pd-catalyzed C-H benzylation. Ligand for palladium-catalyzed [4 + 2] benzannulation reaction. Group: Organic phosphine compounds. Alternative Names: SY030636; 2'-(DIPHENYLPHOSPHINO)-N,N-DIMETHYLBIPHENYL-2-AMINE; 2-Dimethylamino-2'-(diphenylphosphino)biphenyl; RL02764; AKOS015840665; 2-(Diphenylphosphino)-2 inverted exclamation mark -(N,N-dimethylamino)biphenyl; 2'-(DIPHENYLPHOSPHINO)-N, N'-DIMETHYL-(1, 1'-BIPHENYL)-2-AMINE; 2'-(diphenylphosphanyl)-N,N-dimethyl-[1,1'-biphenyl]-2-amine; 2-DIPHENYLPHOSPHINO-2'-DIMETHYLAMINOBIPHENYL; AN-11455. CAS No. 240417-00-9. Molecular formula: C26H24NP. Mole weight: 381.459g/mol. IUPACName: 2-(2-diphenylphosphanylphenyl)-N,N-dimethylaniline. Canonical SMILES: CN (C)C1=CC=CC=C1C2=CC=CC=C2P (C3=CC=CC=C3)C4=CC=CC=C4. Catalog: ACM240417009.
1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols. 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters. 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes. 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins. 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction. Group: Heterocyclic organic compound. CAS No. 145964-33-6. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM145964336.
Chiral amino alcohol assisted asymmetric, enantioselective, aryl transfer of triphenylboroxin to a set of aryl aldehydes in the presence of chiral amino alcohols derived from (S)-proline. Pyrrolidinylmethanol compound used for the zinc-catalyzed addition of arylboronic acids to aromatic aldehydes, proceeding in high yields and high enantioselectivities (up to 98% ee). Group: Heterocyclic organic compound. Alternative Names: (R)-DPMPM; [(2R)-1-methylpyrrolidin-2-yl]-diphenyl-methanol; (r)-n-methyl-alpha,alpha-diphenyl-2-pyrrolidinemethanol; AJ-20718; alpha,alpha-Diphenyl-N-methyl-D-prolinol; OR10013; AKOS007930843; (R)-alpha,alpha-Diphenyl-N-methyl-2-pyrrolidinemethanol; ((r)-1-methylpyrrolidin-2-yl)diphenylmethanol; KS-00000IVK. CAS No. 144119-12-0. Molecular formula: C18H21NO. Mole weight: 267.372g/mol. IUPACName: [(2R)-1-methylpyrrolidin-2-yl]-diphenylmethanol. Canonical SMILES: CN1CCCC1C (C2=CC=CC=C2) (C3=CC=CC=C3)O. Catalog: ACM144119120.
Rhodium(II) acetate dimer
Catalyst for insertion into C-H and X-H bonds. Catalyst for Ylide generation. Doyle-Kirmse Reaction of Allylic Sulfides with Diazoalkane Claisen rearrangement. Epoxides from aldehydes. Synthesis of aziridines from allylic N-tosyloxycarbamates. Rh/NHC catalyzed direct intermolecular arylation of C-H bonds. Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines. Rh-catalyzed cyclopropenations of ynamides. Tandem asymmetric aza-Darzens/ring-opening reactions. Group: Micro/nanoelectronics. Alternative Names: Tetrakis-(mu-acetato)dirhodium. CAS No. 15956-28-2. Molecular formula: C8H12O8Rh2. Mole weight: 441.99. Appearance: Fresh green crystal. Purity: 0.98. IUPACName: rhodium(2+);tetraacetate. Canonical SMILES: CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. [Rh+2]. [Rh+2]. ECNumber: 240-084-8. Catalog: ACM15956282-1.
Rhodium(II) acetate dimer
Rhodium(II) acetate dimer. Uses: Catalyst for insertion into c-h and x-h bonds. catalyst for ylide generation. doyle-kirmse reaction of allylic sulfides with diazoalkane claisen rearrangement. epoxides from aldehydes. synthesis of aziridines from allylic n-tosyloxycarbamates. rh/nhc catalyzed direct intermolecular arylation of c-h bonds. chiral bronsted acid-rh catalyzed three component reactions of diazo compounds with alcohols and imines. rh-catalyzed cyclopropenations of ynamides. tandem asymmetric aza-darzens/ring-opening reactions. Group: Salt electrolytessolution deposition precursors. Alternative Names: Tetrakis-(mu-acetato)dirhodium. CAS No. 15956-28-2. Product ID: rhodium(2+); tetraacetate. Molecular formula: 441.99. Mole weight: C8H12O8Rh2. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. CC(=O)[O-]. [Rh+2]. [Rh+2]. InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4; /h4*1H3, (H, 3, 4); /q; 2*+2/p-4. SYBXSZMNKDOUCA-UHFFFAOYSA-J. 98%.
RockPhos
Ligand used in the palladium-catalyzed C-O bond forming reactions of secondary and primary alcohols with a range of aryl halides. Heterocyclic halides and, for the first time, electron-rich aryl halides can be coupled with secondary alcohols. Group: Organic phosphine compounds. Alternative Names: ZINC95910984; 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2'-4'-6'-tri-i-propyl-1,1'-biphenyl; RockPhos, 97%; di-tert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane; Y-200021; Di-tert-butyl(2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-3-methoxy-6-methyl-[1,1 inverted exclamation marka-biphenyl]-2-yl)phosphine; CVLLAKCGAFNZHJ-UHFFFAOYSA-N; 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopropyl-1,1'-biphenyl; SCHEMBL12929986; AX8242285. CAS No. 1262046-34-3. Molecular formula: C31H49OP. Mole weight: 468.706g/mol. IUPACName: ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. Catalog: ACM1262046343.
[RuCl(p-cymene)((S)-tolbinap)]Cl
1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C
Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic organic compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM134484369.
Silver trifluoromethanesulfonate
Silver precatalyst for the asymmetric allylation of aldehydes Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins Silver catalyst for the fluorination of boronic acids Silver catalyst for the fluorination of functionalized aryl stannanes Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate. Group: Silver series of catalysts. Alternative Names: KSC491Q9D; Silver trifluoromethanesulfonate, >=99%; silver(1+) ion trifluoromethanesulfonate; silver(I)trifluoromethanesulfonate; TRIFLUOROMETHANESULFONATE SILVER SALT; trifluormethanesulfonic acid silver salt; silver(I) trifluoromethanesulphonate; ANW-26574; QRUBYZBWAOOHSV-UHFFFAOYSA-M; X7226. CAS No. 2923-28-6. Molecular formula: CAgF3O3S. Mole weight: 256.94. Appearance: Powder. Purity: 0.98. IUPACName: silver;trifluoromethanesulfonate. Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].[Ag+]. ECNumber: 220-882-2. Catalog: ACM2923286-1.
(S)-(-)-TolBINAP
Useful ligand for palladium-catalyzed carbon-oxygen bond formation. Ligand for palladium-catalyzed α-arylation of ketones. Ligand for Cu-catalyzed asymmetric conjugate reduction. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. Enantioselective conjugate reduction of lactones and lactams. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. Catalytic Aldol reaction to ketones. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. Rhodium-catalyzed cross cyclotrimerization. Group: Heterocyclic organic compound. CAS No. 100165-88-6. Molecular formula: C48H40P2. Mole weight: 678.796g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. Catalog: ACM100165886.
t-BuDavePhos
Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines. Ligand used for selective Pd-catalyzed silylation of aryl chlorides. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. Group: Organic phosphine compounds. Alternative Names: 2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179. CAS No. 224311-49-3. Molecular formula: C22H32NP. Mole weight: 341.479g/mol. IUPACName: 2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2N (C)C)C (C) (C)C. Catalog: ACM224311493.
Tris(triphenylphosphine)rhodium(I) chloride
A homogeneous hydrogenation catalyst which operates under mild conditions. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reactions. Alkyne hydro-phosphorylation Heck-type reaction with α,β-unsaturated esters. Alkyne arylation Allylic alcohol-olefin coupling. Terminal alkenes from ketones. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. Reductive deprotection of silyl groups. Group: Rhodium series of catalysts. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Molecular formula: C54H45ClP3Rh. Mole weight: 925.21. Appearance: Magenta crystal. Purity: 0.98. IUPACName: rhodium;triphenylphosphane;chloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. ECNumber: 238-744-5. Catalog: ACM14694952-1.
Tris(triphenylphosphine)rhodium(I) chloride
Tris(triphenylphosphine)rhodium(I) chloride. Uses: A homogeneous hydrogenation catalyst which operates under mild conditions. catalyst for the decarbonylation of aldehydes. catalyst for regio- and stereoselective allylic substitution reactions. alkyne hydro-phosphorylation heck-type reaction with α,β-unsaturated esters. alkyne arylation allylic alcohol-olefin coupling. terminal alkenes from ketones. rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. reductive deprotection of silyl groups. Group: Salt. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Product ID: rhodium; triphenylphosphane; chloride. Molecular formula: 925.21. Mole weight: C54H45ClP3Rh. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. InChI=1S/3C18H15P. ClH. Rh/c3*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; /h3*1-15H; 1H; /p-1. QBERHIJABFXGRZ-UHFFFAOYSA-M. 98%.
Tyloxapol
Tyloxapol, is a nonionic liquid polymer of the alkyl aryl polyether alcohol type. It is used as a surfactant to aid liquefaction and removal of mucopurulent (containing mucus and pus) bronchopulmonary secretions. Tyloxapol also blocks plasma lipolytic activity. Group: Others. Alternative Names: Ethoxylated p-tert-octylphenol formaldehyde polymer. CAS No. 25301-02-4. Molecular formula: C8H11NO. Mole weight: 137.18. Appearance: Viscous amber liquid. Purity: 0.99. IUPACName: formaldehyde;oxirane;4-(2,4,4-trimethylpentan-2-yl)phenol. Canonical SMILES: CC(C)(C)CC(C)(C)C1=CC=C(C=C1)O. C=O. C1CO1. Catalog: ACM25301024.
Tyloxapol
Tyloxapol is a nonionic liquid polymer of the alkyl aryl polyether alcohol type, used as a surface active stabilizer. Tyloxapol is used to induce hyperlipidemia in animals [1] [2]. Uses: Scientific research. Group: Signaling pathways. CAS No. 25301-02-4. Pack Sizes: 500 mg; 1 g. Product ID: HY-B1068.
Tyloxapol
Tyloxapol. Uses: Tyloxapol, is a nonionic liquid polymer of the alkyl aryl polyether alcohol type. it is used as a surfactant to aid liquefaction and removal of mucopurulent (containing mucus and pus) bronchopulmonary secretions. tyloxapol also blocks plasma lipolytic activity. Group: Polymers. Alternative Names: Ethoxylated p-tert-octylphenol formaldehyde polymer. CAS No. 25301-02-4. Product ID: formaldehyde; oxirane; 4-(2,4,4-trimethylpentan-2-yl)phenol. Molecular formula: 137.18. Mole weight: C8H11NO. CC(C)(C)CC(C)(C)C1=CC=C(C=C1)O. C=O. C1CO1. InChI=1S/C14H22O.C2H4O.CH2O/c1-13(2, 3)10-14(4, 5)11-6-8-12(15)9-7-11; 1-2-3-1; 1-2/h6-9, 15H, 10H2, 1-5H3; 1-2H2; 1H2. MDYZKJNTKZIUSK-UHFFFAOYSA-N. 99%.
Tyloxapol, USP
Tyloxapol is a nonionic liquid polymer of the alkyl aryl polyether alcohol type. It is used as a surfactant to aid liquefaction and removal of mucopurulent[citation needed] (containing mucus and pus) bronchopulmonary secretions,[1][2] administered by inhalation through a nebulizer[3] or with a stream of oxygen. With intraperitoneal injection, tyloxapol also blocks plasma lipolytic activity, and thus the breakdown of triglyceride-rich lipoproteins. This mechanism is used to induce experimental hyperlipidemia in animals.[4] Tyloxapol is the main active ingredient of the medical device Tacholiquin®. Tacholiquin® is an expectorant designated for inhalation and instillation reaching the upper and lower airways. Group: Biochemicals. Alternative Names: p- (1, 1, 3, 3-Tetramethylbutyl) Phenol Polymer with Ethylene Oxide and Formaldehyde; Ethylene Oxide Polymer with Formaldehyde and p- (1, 1, 3, 3-Tetramethylbutyl) phenol; Oxirane Polymer with Formaldehyde and 4- (1, 1, 3, 3-tetramethylbutyl) phenol; Ethylene oxide-formaldehyde-4- (1, 1, 3, 3-tetramethylbutyl) phenol copolymer; Ethylene oxide-formaldehyde-p-octylphenol Copolymer; NSC 90255; Superinone; Triton A 20; Triton WR 1339; Tyloxapol; p-Isooctyl polyoxyethyl ene phenol Formaldehyde Polymer. Grades: USP. CAS No. 25301-02-4. Pack Sizes: 1g, 5g, 25g. Molecular Formula: (C17H30O4)n, Molecular Weight: As reported. US Biological Life Sciences.
Worldwide
(R)-4-Fluoro-α-methylbenzyl alcohol
Aryl Fluorinated Building Blocks. CAS No. 101219-68-5. Mole weight: 140.15. Catalog: ACM101219685.
(S)-4-Fluoro-α-methylbenzyl alcohol
Aryl Fluorinated Building Blocks. CAS No. 101219-73-2. Molecular formula: C8H7BrF2. Mole weight: 140.15. Catalog: ACM101219732.
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