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Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines. Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading. Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines. Ligand for the Suziki-Miyaura coupling of tosylates and mesylates. Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides. Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides. Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids. Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation. Group: Organic phosphine compounds. Alternative Names: C35H53O2P; dicyclohexyl-(2',4',6'-triisopropyl-3,6-dimethoxy-biphenyl-2-yl)-phosphane; BrettPhos; 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl; ZINC43220891; ST24046493; 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISOPROPYL-3,6-DIMETHOXYBIPHENYL; AS-19342; 2-(Dicyclohexylphosphino)3,6-dimethoxy-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation. CAS No. 1070663-78-3. Molecular formula: C35H53O2P. Mole weight: 536.781g/mol. IUPACName: dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=C (C=CC (=C2P (C3CCCCC3)C4CCCCC4)OC)OC)C (C)C. Catalog: ACM1070663783.
AdBrettPhos
AdBrettPhos. Group: Biochemicals. Alternative Names: Di-Ad-BrettPhos. Grades: Highly Purified. CAS No. 1160861-59-5. Pack Sizes: 100mg, 500mg, 1g, 2g. Molecular Formula: C43H61O2P. US Biological Life Sciences.
Worldwide
Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II), min. 98% [BrettPhos Palladacycle Gen. 1]
Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines. Catalyst for rapid C-N bond-forming processes at low catalyst loading. Cross-coupling of 3-Bromo-2-aminopyridine with primary amines. Group: Palladium series catalysts. Alternative Names: BrettPhos Palladacycle. CAS No. 1148148-01-9. Molecular formula: C43H63ClNO2PPd. Mole weight: 798.81. Appearance: white to off-white powder or crystals. Purity: 0.97. Catalog: ACM1148148019.
Chloro(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 2]
Palladium precatalyst for fast Suzuki-Miyaura coupling reactions. Coupling of chloropyrazoles with boronic acis. Group: Palladium catalysts. Alternative Names: BrettPhos Palladacycle Gen. 2;MFCD22666410;1451002-39-3. CAS No. 1451002-39-3. Molecular formula: C47H63ClNO2PPd. Mole weight: 846.87g/mol. IUPACName: chloropalladium(1+);dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;2-phenylaniline. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=C (C=CC (=C2P (C3CCCCC3)C4CCCCC4)OC)OC)C (C)C. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. Cl[Pd+]. Catalog: ACM1451002393.
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4]
Catalyst used for the N-arylation of amines. Group: Organic phosphine compounds. Alternative Names: Palladium, [dicyclohexyl [3, ?6-dimethoxy-2', ?4', ?6'-tris (1-methylethyl) ? [1, ?1'-biphenyl] ?-2-yl] ?phosphine-κ P] ? (methanesulfonato-κ O) ? [2'- (methylamino-κ N) ? [1, ?1'-biphenyl] ?-2-yl-κ C] ?-, (SP-4-3)?-. CAS No. 1599466-83-7. Molecular formula: C49H68NO5PPdS. Mole weight: 920.53. Appearance: off-white to beige powder. Catalog: ACM1599466837.