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Air and thermally stable, one-component precatalyst for the amination of aryl halides. Group: Heterocyclic organic compound. Alternative Names: ACETATO(2'-DI-T-BUTYLPHOSPHINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II); 2-(2 inverted exclamation marka-Di-tert-butylphosphine)biphenylpalladium(II) acetate; SC10488; Palladium, (acetato-KappaO) [2'-[bis (1,1 dimethylethyl) phosphino-KappaP] [1,1'-biphenyl]-2-yl KappaC]; IEYDYAASBZOBOC-UHFFFAOYSA-M; Palladium, (acetato-| feminineO) [2 inverted exclamation marka-[bis (1,1 dimethylethyl) phosphino-| feminineP] [1,1 inverted exclamation marka-biphenyl]-2-yl | feminineC]; PALLADACYCLE; 577971-19-8. CAS No. 577971-19-8. Molecular formula: C22H30O2PPd-. Mole weight: 463.874g/mol. IUPACName: acetic acid;ditert-butyl-(2-phenylphenyl)phosphane;palladium. Canonical SMILES: CC (=O)O. CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=[C-]2)C (C) (C)C. [Pd]. Catalog: ACM577971198.
2- (2?-Di-tert-butylphosphine) biphenylpalladium (II) Acetate
2- (2?-Di-tert-butylphosphine) biphenylpalladium (II) Acetate is a precatalyst for Buchwald-Hartwig amination reaction. It is also used to prepare anticancer LPA2 antagonists. Group: Biochemicals. Grades: Highly Purified. CAS No. 577971-19-8. Pack Sizes: 100mg, 250mg. Molecular Formula: C22H29O2PPd, Molecular Weight: 462.86. US Biological Life Sciences.
Worldwide
(2-Biphenyl)di-tert-butylphosphine
(2-Biphenyl)di-tert-butylphosphine. Group: Biochemicals. Alternative Names: 2- (Di-tert-butylphosphino) biphenyl; JohnPhos. Grades: Highly Purified. CAS No. 224311-51-7. Pack Sizes: 500mg, 1g, 2g, 5g, 10g. Molecular Formula: C6H5C6H4P[C(CH3)3]2. US Biological Life Sciences.
Worldwide
(4-Dimethylaminophenyl)di-tert-butylphosphine
(4-Dimethylaminophenyl)di-tert-butylphosphine. Group: Biochemicals. Alternative Names: 4-(Di-tert-butylphosphino)-N,N-dimethylaniline. Grades: Highly Purified. CAS No. 932710-63-9. Pack Sizes: 500mg, 1g, 2g, 5g, 10g. US Biological Life Sciences.
Worldwide
(4-Dimethylaminophenyl)di-tert-butylphosphine
(4-Dimethylaminophenyl)di-tert-butylphosphine. Uses: Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic light-emitting diode (oled) materials. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Product ID: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Molecular formula: 265.381g/mol. Mole weight: C16H28NP. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. InChI=1S/C16H28NP/c1-15 (2, 3)18 (16 (4, 5)6)14-11-9-13 (10-12-14)17 (7)8/h9-12H, 1-8H3. IQTHEAQKKVAXGV-UHFFFAOYSA-N.
(4-Dimethylaminophenyl)di-tert-butylphosphine
Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic phosphine compounds. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Molecular formula: C16H28NP. Mole weight: 265.381g/mol. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Catalog: ACM932710639.
((4-TrifluoroMethyl)phenyl)di-tert-butylphosphine
Other Phosphine Ligands. Alternative Names: Di-Tert-Butyl (4- (Trifluoromethyl)Phenyl)Phosphine. CAS No. 1228182-34-0. Molecular formula: C15H22F3P. Mole weight: 290.3. Appearance: Solid. Purity: 0.97. IUPACName: ditert-butyl-[4- (trifluoromethyl)phenyl]phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)C (F) (F)F)C (C) (C)C. Catalog: ACM1228182340-1.
Gold catalyst used in the regio-and stereoselective synthesis of functionalized benzo[b]oxepines. Gold catalyst used in the cyclization reactions of o-(buta-1,3-diyn-1-yl-)-substituted N-aryl ureas. Gold catalyst used in the cycloisomerization of 1,7-enyne esters to structurally diverse cis-tetrahydropyridin-4-yl ketones. Catalyst used in the synthesis of coumarin-containing natural products. Catalyst used in the synthesis of benzo[4,5]imidazo[1,2-a]quinazolinones. Group: Gold series of catalysts. Alternative Names: Acetonitrile; ditert-butyl-(2-phenylphenyl)phosphane; gold(1+); hexafluoroantimony(1-). CAS No. 866641-66-9. Molecular formula: C22H30AuF6NPSb. Mole weight: 772.2. Appearance: Powder. Purity: 0.99. IUPACName: acetonitrile; ditert-butyl-(2-phenylphenyl)phosphane; gold(1+); hexafluoroantimony(1-). Canonical SMILES: CC#N. CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. F[Sb-] (F) (F) (F) (F)F. [Au+]. Catalog: ACM866641669-1.
Bis (tri-t-butylphosphine) palladium bromide (I), dimer
Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids. Aryl bromide - silyl ketene acetal coupling. Catalyst for intermolecular α-arylation of zinc amide enolates. Catalyst for α-vinylation of carbonyl compounds. Catalyst for thiol coupling of heteroaromatic aryl bromides. Group: Palladium series catalysts. Alternative Names: MFCD04114019; 185812-86-6; CTK8C5468; palladium(I) tri-tertbutylphosphine bromide; PUBCHEM_71317307; Palladium(I) tri-tert-butylphosphine bromide. CAS No. 185812-86-6. Molecular formula: C12H27BrPPd-. Mole weight: 388.646g/mol. IUPACName: palladium;tritert-butylphosphane;bromide. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Br-]. [Pd]. Catalog: ACM185812866.
Bis (tri-tert-butylphosphine) palladium (0)
Bis (tri-tert-butylphosphine) palladium (0) . Group: Biochemicals. Alternative Names: Bis[tris (1, 1-dimethylethyl) phosphine]palladium; Bis (tri-tert-butylphosphine) palladium; Bis (tri-tert-butylphosphine) palladium (0) ; Bis (tri-tert-butylphosphino) palladium; Bis[tris (tert-butyl) phosphine]palladium; Palladium Bis(tri-tert-butylphosphine); BIs[tris (1, 1-dimethylethyl) phosphine]palladium. Grades: Highly Purified. CAS No. 53199-31-8. Pack Sizes: 500mg. Molecular Formula: C24H54P2Pd, Molecular Weight: 511.05. US Biological Life Sciences.
Worldwide
Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) is a biochemical reagent that can be used as a biological material or organic compound for life science related research. Uses: Scientific research. Group: Biochemical assay reagents. CAS No. 53199-31-8. Pack Sizes: 250 mg; 1 g. Product ID: HY-W010772.
Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) is also used in the preparation of G6P-T1 translocase inhibitors used in the treatment of diabetes. Also, its used to prepare new dibenzofulvenes. Uses: Introduced as an easier to handle pd/p(t-bu)3-based catalyst for the negishi cross-coupling of aryl/vinyl chlorides. a versatile catalyst for the cross-coupling of aryl and vinyl chlorides. catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases. useful catalyst for the cross-coupling of heteroaromatic carboxylic acids. pd-catalyzed newnan-kwart rearrangement of o-aryl thiocarbamates. cross-coupling of silanolates and halides. elimination/isomerization of enol triflates derived from β-ketoesters. Group: Palladium series catalysts. Alternative Names: palladium,tritert-butylphosphane;Pd(t-Bu3P)2. CAS No. 53199-31-8. Molecular formula: C24H54P2Pd. Mole weight: 511.064g/mol. Appearance: Off white crystalline solid. IUPACName: palladium;tritert-butylphosphane. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C. CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Pd]. Catalog: ACM53199318.
Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) is also used in the preparation of G6P-T1 translocase inhibitors used in the treatment of diabetes. Also, its used to prepare new dibenzofulvenes. Uses: Introduced as an easier to handle pd/p(t-bu)3-based catalyst for the negishi cross-coupling of aryl/vinyl chlorides. a versatile catalyst for the cross-coupling of aryl and vinyl chlorides. catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases. useful catalyst for the cross-coupling of heteroaromatic carboxylic acids. pd-catalyzed newnan-kwart rearrangement of o-aryl thiocarbamates. cross-coupling of silanolates and halides. elimination/isomerization of enol triflates derived from β-ketoesters. Group: Polymerization reagents. Alternative Names: palladium,tritert-butylphosphane; Pd(t-Bu3P)2. CAS No. 53199-31-8. Product ID: palladium; tritert-butylphosphane. Molecular formula: 511.064g/mol. Mole weight: C24H54P2Pd. CC(C)(C)P(C(C)(C)C)C(C)(C)C. CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Pd]. InChI=1S/2C12H27P.Pd/c2*1-10(2, 3)13(11(4, 5)6)12(7, 8)9;/h2*1-9H3; : MXQOYLRVSVOCQT-UHFFFAOYSA-N.
Bis (tri-tert-butylphosphine) platinum (0)
Bis (tri-tert-butylphosphine) platinum (0) . Group: Biochemicals. Grades: Highly Purified. CAS No. 60648-70-6. Pack Sizes: 25mg, 50mg, 100mg, 250mg, 500mg. US Biological Life Sciences.
Worldwide
CDi(1-adamantyl)-n-butylphosphine
CDi(1-adamantyl)-n-butylphosphine. Group: Biochemicals. Alternative Names: Cataxium A. Grades: Highly Purified. CAS No. 321921-71-5. Pack Sizes: 500mg, 1g, 2g, 5g, 10g. Molecular Formula: C24H39P. US Biological Life Sciences.
Highly active gold catalyst for the intramolecular exohydrofunctionalization of allenes. Catalyst used for the hydroarylation of allenes. Catalyst used for the intramolecular cyclization of monopropargyl triols. Synthesis of pyrroles via a gold-catalyzed cascade reaction. Gold-catalyzed carboalkoxylations of 2-ethynylbenzyl ethers. Gold-catalyzed annulations of allenes with N-hydroxy anilines. Group: Gold series of catalysts. Alternative Names: SC10751; JohnPhos AuCl; [[1,1 inverted exclamation marka-Biphenyl]-2-ylbis(t-butylphosphine]chlorogold; AKOS024259177; Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I), 98%; KS-000019BH; TRA0069872; Chloro[2-(di-t-butylphosphino)biphenyl]gold(I). CAS No. 854045-93-5. Molecular formula: C20H27AuClP. Mole weight: 530.826g/mol. IUPACName: chlorogold;ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Cl[Au]. Catalog: ACM854045935.
Amination→Buchwald-Hartwig Aminaton; Cross Coupling Reactions with Arenes→Suzuki-Miyaura Coupling Reaction. Group: Catalysts for pharmaceuticalamination. CAS No. 1779569-15-1. Molecular formula: C25H42ClPPd. Mole weight: 515.45. Catalog: ACM1779569151-1.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- [bis (4-fluorophenyl] phosphino] ferrocenyl] ethyldi-tert-butylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (bis (4-fluorophenyl) phosphinoferrocenyl]ethyl (di-t-butylphosphine) }nickel (II) is used for: 1.Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. 4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-37-3. Mole weight: 774.69. Catalog: ACM2049086373.
Chloro[ (tri-tert-butylphosphine) -2- (2-aminobiphenyl) ]palladium (II)
Chloro[ (tri-tert-butylphosphine) -2- (2-aminobiphenyl) ]palladium (II) . Group: Biochemicals. Grades: Highly Purified. CAS No. 1375325-71-5. Pack Sizes: 250mg, 500mg, 1g, 2g, 5g. US Biological Life Sciences.
Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates. Group: Palladium series catalysts. Alternative Names: Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II). CAS No. 1375325-71-5. Molecular formula: C24H37ClNPPd. Mole weight: 512.41. Appearance: off-white to pale yellow powder. Purity: 0.98. Catalog: ACM1375325715.
Chloro(tri-tert-butylphosphine)gold(I)
Catalyst used for cycloisomerization reactions of 2-(2-propynyl)pyridine N-oxides. Catalyst used for the cycloisomerization of 1,6-diynes. Catalyst used for cycloisomerizations terminated by sp3 C-H bond insertion Synthesis of aromatic ketones by a transition metal-catalyzed tandem sequence. Group: Gold series of catalysts. Alternative Names: Chlorogold;tritert-butylphosphane. CAS No. 69550-28-3. Molecular formula: C12H27AuClP. Mole weight: 434.73. Purity: 0.99. IUPACName: chlorogold;tritert-butylphosphane. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C.Cl[Au]. Catalog: ACM69550283-1.
Di-t-butylphosphine oxide. Uses: For analytical and research use. Group: Impurity standards. CAS No. 684-19-5. Molecular Formula: C8H19OP. Mole Weight: 162.21. Catalog: APB684195.
Methanesulfonato{ (R) - (-) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyldi-t-butylphosphine} (2'-amino-1, 1'-biphenyl-2-yl) palladium (II) , min. 98% [Josiphos Palladacycle Gen. 3]
Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides. Group: Organic phosphine compounds. Alternative Names: Bruno Palladacycle;Josiphos SL-J009-1 Pd G3;MFCD27978424;Josiphos SL-J009-2-G3-palladacycle, AldrichCPR; 1702311-34-9; Methanesulfonato[ (R) - (-) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyldi-t-butylphosphine] (2'-amino-1, 1'-biphenyl-2-yl) palladium (II). CAS No. 1702311-34-9. Molecular formula: C45H66FeNO3P2PdS-. Mole weight: 925.3g/mol. IUPACName: cyclopentane; ditert-butyl-[ (1S) -1- (2-dicyclohexylphosphanylcyclopentyl) ethyl]phosphane; iron; methanesulfonic acid;palladium;2-phenylaniline. Canonical SMILES: CC ([C]1[CH][CH][CH][C]1P (C2CCCCC2)C3CCCCC3)P (C (C) (C)C)C (C) (C)C. CS (=O) (=O)O. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. [CH]1[CH][CH][CH][CH]1. [Fe]. [Pd]. Catalog: ACM1702311349.
(R) - (-) -1-[ (S) -2-Diphenylphosphino) ferrocenyl]ethyldi-t-butylphosphine
(R) - (-) -1-[ (S) -2-Diphenylphosphino) ferrocenyl]ethyldi-t-butylphosphine is used as a catalyst in the synthesis of Sitagliptin, a potent inhibitor for the treatment of type 2 diabetes. Group: Biochemicals. Alternative Names: 2- (1- (Di-tert-butylphosphino) ethyl) -1- (diphenylphosphino) ?Ferrocene; Josiphos SL-J002-1; [ (R) -1- [ (S) -2- (Di-tert-butylphosphino) ferrocenyl] ethyl] ?Diphenylphosphine. Grades: Highly Purified. CAS No. 155830-69-6. Pack Sizes: 50mg. US Biological Life Sciences.
Catalyst used for the selective hydration of substituted alkynes at room temperature without acidic promoters. Gold(I) catalyzes bromination of terminal alkynes. Sequential O-H/C-H bond insertion of phenols initiated by the gold(I)-catalyzed cyclization of 1-bromo-1,5-enynes. Ligand-controlled gold-catalyzed cycloisomerization of 1,n-enyne esters toward synthesis of dihydronaphthalene. Group: Gold catalysts. Alternative Names: MFCD21363047; Tri-t-butylphosphine[bis (trifluoromethyl)sulfonylimido]gold (I); 1121960-93-7. CAS No. 1121960-93-7. Molecular formula: C14H28AuF6NO4PS2+. Mole weight: 680.432g/mol. IUPACName: bis(trifluoromethylsulfonyl)azanide; gold(1+); tritert-butylphosphanium. Canonical SMILES: CC (C) (C)[PH+] (C (C) (C)C)C (C) (C)C. C (F) (F) (F)S (=O) (=O)[N-]S (=O) (=O)C (F) (F)F. [Au+]. Catalog: ACM1121960937.
Tri-tert-butylphosphine
Tri-tert-butylphosphine. Group: Biochemicals. Grades: Highly Purified. CAS No. 13716-12-6. Pack Sizes: 1g, 2g, 5g, 10g. Molecular Formula: C12H27P. US Biological Life Sciences.
Worldwide
Tri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate. CAS No. 131274-22-1. Categories: tri-tert-butylphosphonium tetrafluoroborate.
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Tri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate. Group: Biochemicals. Grades: Highly Purified. CAS No. 131274-22-1. Pack Sizes: 1g, 2g, 5g, 10g, 25g. Molecular Formula: C12H28BF4P. US Biological Life Sciences.
Worldwide
Tri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate is a biochemical reagent that can be used as a biological material or organic compound for life science related research. Uses: Scientific research. Group: Biochemical assay reagents. CAS No. 131274-22-1. Pack Sizes: 25 g. Product ID: HY-34451.
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in a very active and general catalyst for Suzuki coupling reactions using aryl chlorides, bromides and triflates. Ligand used in palladium-catalyzed synthesis of oxindoles from α-chloroacetanilides. Effective ligand used in palladium-catalyzed arylation of thiazoles. Used in the formation of 2-benzylindolines via sequential palladium-catalyzed N-arylation/cyclization/C-arylation. Selective in the palladium-catalyzed arylation of silyl enol ethers formed from copper-catalyzed reduction of enones. Group: Organic phosphine compounds. Alternative Names: (2-Biphenylyl)-Di-Tert-Butylphosphine. CAS No. 224311-51-7. Molecular formula: C20H27P. Mole weight: 298.4. Appearance: Solid. Purity: 0.98. IUPACName: ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Density: 1 g/cm3. Catalog: ACM224311517-1.
Heterocyclic Organic Compound. Alternative Names: Di-tert-butylphosphine compound with borane (1:1); Di-tert-butylphosphine borane; (Di-tert-butylphosphine)trihydroboron. CAS No. 128363-76-8. Molecular formula: C8H22PBH. Mole weight: 160.05. Appearance: Solid. Purity: 0.98. Catalog: ACM128363768-1.
Butyldi-1-adamantylphosphine
Butyldi-1-adamantylphosphine (CAS# 321921-71-5 ) is a useful research chemical. Synonyms: Catacxium A; nbutyl-di(1-adamantyl)phosphine; Di(1-adamantyl)-n-butylphosphine. CAS No. 321921-71-5. Molecular formula: C24H39P. Mole weight: 358.54.
cBRIDP
Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. Group: Heterocyclic organic compound. Alternative Names: di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine; di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl) phosphine; Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphine cBRIDP; Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphane; SCHEMBL377365; 742103-27-1; di-t-butyl-(2,2-diphenyl-1-methylcyclopropyl)-phosphine; di-t-butyl (2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; (1-Methyl-2,2-diphenylcyclopropyl)di-tert-butylphosphine. CAS No. 742103-27-1. Molecular formula: C24H33P. Mole weight: 352.502g/mol. IUPACName: ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane. Canonical SMILES: CC1 (CC1 (C2=CC=CC=C2)C3=CC=CC=C3)P (C (C) (C)C)C (C) (C)C. Catalog: ACM742103271.
Tri-tert-butylphosphonium tetrafluoroborate
Air-stable, non-pyrophoric precursor of the Tri-t-butylphosphine ligand which is used in a variety of catalytic processes. Ligand for Suzuki cross-couplings. Ligand for Heck Reactions. Ligand for Stille Cross-couplings. Ligand for α-Arylation and vinylation of arylmandelic acid derivatives. Ligand for direct arylation of hetercycles Synthesis of benzocyclobutenes by C-H activation. Cross-coupling of Grignard reagents and aryl bromides. Palladium catalyzed annulation of haloanilines. Palladium-Catalyzed Acylation. Palladium Catalyzed Carbonylative Heck Reaction. Palladium-catalyzed aminosulfonylation. Palladium-catalyzed intramolecular C-O bond formation. Ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acid. Group: Borate. Alternative Names: Fluoroboric Acid Tri-Tert-Butylphosphine Adduct. CAS No. 131274-22-1. Molecular formula: C12H28BF4P. Mole weight: 290.13. Appearance: Solid. Purity: 0.98. IUPACName: tritert-butylphosphanium;tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. CC(C)(C)[PH+](C(C)(C)C)C(C)(C)C. Catalog: ACM131274221-1.
TrixiePhos
Ligand for the Pd-catalyzed formation of oxygen heterocycles. Ligand for the intermolecular Pd-catalyzed synthesis of aryl ethers. Ligand for the intramolecular Pd-catalyzed synthesis of aryl ethers. Ligand for the synthesis of carbazoles by Pd-catalyzed double N-arylation reaction. Ligand for the Pd-catalyzed cyanation of (hetero)arylchlorides. Ligand for the Pd-catalyzed intramolecular synthesis of carbazoles via C-H functionalization. Group: Organic phosphine compounds. Alternative Names: racemic 2-(di-tert-butylphosphino)-1,1'-binaphthyl; RACEMIC-2-DI-TERT-BUTYLPHOSPHINO-1,1-BINAPHTHYL; 1,1'-binaphthyl-2-yl di-tert-butylphosphine; racemic 2-di-tert-butylphosphino-1,1'-binaphthyl; AK-48836; AX8150194; 2-(di-ter-butylphosphino)-1,1'-binaphthyl; 2-(DI-TERT-BUTYLPHOSPHINO)-1,1-BINAPHTHYL; 2-(di-t-butylphosphino)-1,1'-binaphtyl; 2-(di-tert-butylphosphino)-1,1'-binapthyl. CAS No. 255836-67-0. Molecular formula: C28H31P. Mole weight: 398.53g/mol. IUPACName: ditert-butyl-(1-naphthalen-1-ylnaphthalen-2-yl)phosphane. Canonical SMILES: CC (C) (C) P (C1=C (C2=CC=CC=C2C=C1) C3=CC=CC4=CC=CC=C43) C (C) (C) C. Catalog: ACM255836670.
1, 1'-Bis (di-tert-butylphosphino) ferrocene
1, 1'-Bis (di-tert-butylphosphino) ferrocene. Group: Biochemicals. Grades: Highly Purified. CAS No. 84680-95-5. Pack Sizes: 1g, 2g, 5g, 10g, 25g. Molecular Formula: 2C13H23P·Fe. US Biological Life Sciences.
Worldwide
1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis(di-tert-butylphosphino)ferrocene is used in method for preparing bis-Aromatic compound through Suzuki coupling reaction. Group: Organic phosphine compounds. Alternative Names: 1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene; 1,1'-Bis(di-tert-butylphosphino)ferrocene; 1,1'-Bis[bis(tert-butyl)phosphino]ferrocene; DTBPF. CAS No. 84680-95-5. Molecular formula: C26H44FeP2. Mole weight: 474.42. Appearance: Solid. Purity: 0.98. IUPACName: 1,1-Bis(di-tert-butylphosphino)ferrocene. Catalog: ACM84680955-1.
[1, 1'-Bis (di-tert-butylphosphino) ferrocene] dichloropalladium (II)
[1, 1'-Bis (di-tert-butylphosphino) ferrocene] dichloropalladium (II) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives. Group: Biochemicals. Grades: Highly Purified. CAS No. 95408-45-0. Pack Sizes: 500mg, 1g. Molecular Formula: C26H44Cl2FeP2Pd. US Biological Life Sciences.
Worldwide
[1, 1'-Bis (di-tert-butylphosphino) ferrocene]palladium (II) Dichloride
[1, 1'-Bis (di-tert-butylphosphino) ferrocene]palladium (II) Dichloride. Group: Biochemicals. Alternative Names: [1, 1'-Bis (di-tert-butylphosphino) ferrocene] dichloropalladium (II) ; Dichloro[1, 1'-bis (di-tert-butylphosphino) ferrocene]palladium (II) . Grades: Highly Purified. CAS No. 95408-45-0. Pack Sizes: 100mg, 250mg, 500mg, 1g, 2g. US Biological Life Sciences.
Worldwide
[1, 1'-Bis (di-tert-butylphosphino)ferrocene]palladium (II) Dichloride
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride is used as a catalyst for the preparation of chalcones. Group: Palladium series catalysts. Alternative Names: PdCl2(dtbpf). CAS No. 95408-45-0. Molecular formula: C26H44Cl2FeP2Pd. Mole weight: 651.75. Appearance: dark red crystals. Purity: Pd ≥16.3%. IUPACName: Dichloro[1, 1-Bis (di-Tert-Butylphosphino)Ferrocene]Palladium (II). Catalog: ACM95408450.
Ligand used in the preparation of active Pd catalysts for C-C, C-N and C-O bond formation. Ligand used in Pd-catalyzed α-arylation of azlactones. Pd-catalyzed α-arylation of esters, amides and aldehydes. Group: Organic phosphine compounds. Alternative Names: Q-PHOS; CTC-Q-PHOS; 1,2,3,4,5-pentaphenyl-1-di-tert-butylphosphinoferrocene; 1,2,3,4,5-Pentaphenyl-1-(di-tert-butylphosphino)ferrocene. CAS No. 312959-24-3. Molecular formula: C48H47FeP. Mole weight: 710.72. Purity: 0.96. IUPACName: 1,2,3,4,5-PENTAPHENYL-1-(DI-TERT-BUTYLPHOSPHINO)FERROCENE. Catalog: ACM312959243.
2-(Di-tert-butylphosphino)-1,1'-binaphthyl 98% TrixiePhos is a reagent used as ligand in palladium-catalyzed C-O, C-N, and C-C bond forming reactions. Group: Biochemicals. Grades: Highly Purified. CAS No. 255836-67-0. Pack Sizes: 100mg, 250mg. Molecular Formula: C28H31P, Molecular Weight: 398.52. US Biological Life Sciences.
Useful ligand for the Pd-catalyzed amination reaction. Ligand used for the Pd-catalyzed arylation of phenols. Useful ligand for the Suzuki-Miyaura coupling. Ligand used for the Sonagashira reaction of aryl bromides. Group: Other phosphine ligands. Alternative Names: CTK8C6146; [cataCXium(R) POMetB]; SC11196; 2-(Di-tert-butylphosphanyl)-1-(2-methoxyphenyl)-1H-pyrrole; 1-(2-Methoxyphenyl)-2-(di-tert-butylphosphino)-1H-pyrrole; ZINC40450111; CATACXIUM(R) POMETB; 2-(Di.-tert.-butylphosphino)-1-(2-methoxy-phenyl)-1H-pyrrole; AKOS016000550; ACMC-20aon8. CAS No. 1053658-91-5. Molecular formula: C19H28NOP. Mole weight: 317.413g/mol. IUPACName: ditert-butyl-[1-(2-methoxyphenyl)pyrrol-2-yl]phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CN1C2=CC=CC=C2OC)C (C) (C)C. Catalog: ACM1053658915.
2-(Di-tert-butylphosphino)-1-phenylindole
Useful ligand for the Pd-catalyzed amination reaction. Ligand used for the Pd-catalyzed arylation of phenols. Useful ligand for the Suzuki-Miyaura coupling. Ligand used for the Sonagashira reaction of aryl bromides. Group: Heterocyclic organic compound. Alternative Names: ACMC-20aon6; CATACXIUM(R) PINTB; SC11197; N-PHENYL-2-(DI-T-BUTYLPHOSPHINO)INDOL; CTK5D9325; AKOS016012152; 1-Phenyl-2-(ditert-butylphosphino)-1H-indole; MFCD06798302; 740815-37-6; BP-12235. CAS No. 740815-37-6. Molecular formula: C22H28NP. Mole weight: 337.44. IUPACName: ditert-butyl-(1-phenylindol-2-yl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC2=CC=CC=C2N1C3=CC=CC=C3)C (C) (C)C. Catalog: ACM740815376.
Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles. Ligand used in the Pd-catalyzed synthesis of phenols from aryl halides and KOH. Ligand used in the Pd-catalyzed of benzoic acids from aryl halides and CO2. Ligand used in the Pd-catalyzed trifluoromethylation of vinyl sulfonates. Ligand used in the Pd-catalyzed arylation of nitroacetates. Ligand used in the Pd-catalyzed Suzuki-Miyaura cross-coupling of allylboronates and aryl halides. Ligand used in the Pd-catalyzed cyanation of (hetero)arylchlorides and bromides. Ligand used in the Pd-catalyzed C-N cross coupling of sulfinamides and aryl halides. Ligand used in the Pd-catalyzed arylation of cyanamides. Group: Organic phosphine compounds. Alternative Names: DTXSID70469549; t-Bu XPhos; FT-0689983; TC-121258; 2-Di-tert-butylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropylbiphenyl; tBuXPhos; ditert-butyl-[2-(2,4,6-triisopropylphenyl)phenyl]phosphane; ZINC56961724; 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl; 2-(di-tert-butylphosphino)-2', 4',6'-triisopropylbiphenyl. CAS No. 564483-19-8. Molecular formula: C29H45P. Mole weight: 424.653g/mol. IUPACName: ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=CC=CC=C2P (C (C) (C)C)C (C) (C)C)C (C)C. Catalog: ACM5644
2- (Di-tert-butylphosphino) biphenyl (also known as JohnPhos) is a Buchwald ligand that is highly efficient in palladium-catalyzed reactions. Group: Biochemicals. Grades: Highly Purified. CAS No. 224311-51-7. Pack Sizes: 500mg, 1g. Molecular Formula: C20H27P, Molecular Weight: 298.399999999999. US Biological Life Sciences.
Gold Catalysts. Alternative Names: Bis(trifluoromethylsulfonyl)azanide; ditert-butyl-(2-phenylphenyl)phosphanium; gold(1+). CAS No. 1036000-94-8. Molecular formula: C22H28AuF6NO4PS2. Mole weight: 776.5. Purity: 0.98. Canonical SMILES: CC (C) (C)[PH+] (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. C (F) (F) (F)S (=O) (=O)[N-]S (=O) (=O)C (F) (F)F. [Au+]. Catalog: ACM1036000948-1.
2-(Di-tert-butylphosphino)dimethylaminobenzene
Ligand for the Copper-Catalyzed Suzuki-Miyaura Coupling of Arylboronate Esters and Aryl Iodides Ligand for the Copper-Catalyzed Coupling of Triaryl- and Trialkylindium reagents with Aryl Iodides and Bromides. Group: Other phosphine ligands. CAS No. 415941-58-1. Mole weight: 265.37. Catalog: ACM415941581.
[2- (Di-tert-butylphosphinomethyl) -6- (diethylaminomethyl) pyridine] carbonylchlorohydridoruthenium (II)
Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone. Group: Ruthenium series catalysts. Alternative Names: Carbonylchlorohydrido[6- (di-t-butylphosphinomethyl)-2- (N, N-diethylaminomethyl)pyridine]ruthenium (II); 863971-62-4. CAS No. 863971-62-4. Molecular formula: C20H37ClN2OPRu. Mole weight: 489.023g/mol. IUPACName: chlororuthenium;N-[[6-(ditert-butylphosphanylmethyl)pyridin-2-yl]methyl]-N-ethylethanamine;formaldehyde. Canonical SMILES: CCN (CC)CC1=NC (=CC=C1)CP (C (C) (C)C)C (C) (C)C. C=O. Cl[Ru]. Catalog: ACM863971624.