Chiral Oxazaborolidines Suppliers USA
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(S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine Quick inquiry Where to buy Suppliers range | (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine. Uses: Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS. Group: Other. Alternative Names: AKOS015840981; (S)-1-methyl-3,3-diphenyltetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole; MFCD00078439; (S)- Methyl-CBS-oxazaborolidine; ZINC169743318; (S)-tetrahydro-1-methyl-3,3-diphenyl-1 H,3 H-pyrrolo[1,2-c][1,3,2] oxazaborole; (S)-1-methyl-3,3-diphenylhexahydropyrrolo-[1,2-c][1,3,2]oxazaborole; (S)-tetrahydro-1-methyl-3,3-diphenyl-1 H,3H-pyrrolo[1,2-c]-[1,3,2]oxazaborole; (S)-Me-CBS; Corey catalyst. CAS No. 112022-81-8. Molecular formula: C18H20BNO. Mole weight: 277.174g/mol. IUPAC Name: (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole. Rotatable Bond Count: 2. Exact Mass: 277.164g/mol. SMILES: B1 (N2CCCC2C (O1) (C3=CC=CC=C3)C4=CC=CC=C4)C. InChI: InChI=1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1. InChIKey: VMKAFJQFKBASMU-KRWDZBQOSA-N. H-Bond Acceptor: 2. Monoisotopic Mass: 277.164g/mol. |