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[1, 1'-Bis (di-cyclohexylphosphino) ferrocene]dichloropalladium (II)
1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides. Group: Palladium series catalysts. Alternative Names: PdCl2(dcypf). CAS No. 917511-90-1. Molecular formula: C34H52Cl2FeP2Pd. Mole weight: 755.9. Appearance: red crystalline powder. Purity: Pd >14.0%. IUPACName: dichloropalladium; dicyclohexyl(cyclopentyl)phosphane; iron. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. Cl[Pd]Cl. [Fe]. Catalog: ACM917511901.
Catalyst used in the selective hydration of substituted alkynes at room temperatures. Catalyst used in the hydroarylating/aromatization of arene-diynes. Highly-efficient and regio-selective catalyst for the selective carbonyl migration in alkynyl-substituted indole-3-carboxamides. Intermolecular gold(I) catalyzed alkyne carboalkoxylation reactions for the multicomponent assembly of β-alkoxy ketones. Gold(I)-catalyzed hydration of alkynylphosphonates: Efficient access to β-ketophosphonates. Gold-catalyzed intramolecular hydroamination reaction. Group: Gold catalysts. Alternative Names: MFCD21608485; 1121960-90-4; Bis(trifluoromethanesulfonyl)imide(2-dicyclohexylphosphino-2', 6'-dimethoxy-1, 1'-biphenyl)gold(I). CAS No. 1121960-90-4. Molecular formula: C28H36AuF6NO6PS2+. Mole weight: 888.648g/mol. IUPACName: bis(trifluoromethylsulfonyl)azanide; dicyclohexyl-[2-(2, 6-dimethoxyphenyl)phenyl]phosphanium; gold(1+). Canonical SMILES: COC1=C (C (=CC=C1)OC)C2=CC=CC=C2[PH+] (C3CCCCC3)C4CCCCC4. C (F) (F) (F)S (=O) (=O)[N-]S (=O) (=O)C (F) (F)F. [Au+]. Catalog: ACM1121960904.
Ligand used in the Pd-catalyzed Suzuki coupling and animation of unactivated aryl chlorides. The reactions generally occur at room temperature and give high yields of product. Ligand used in Pd-catalyzed C-N bond formation. A general synthesis of N6-aryl-2'deoxyadenosine analogues. Ligand used in Pd-catalyzed N-arylation of indoles. Ligand used in Pd-catalyzed synthesis of aryl-tert-butyl ethers. Effective ligand in the Pd-catalyzed arylation of ester enolates. Ligand employed in arylation of ketone enolates using ortho-halo nitrobenezenes. Ligand employed in the amination of aryl nonaflates using Pd catalysts. Ligand used for cascade alkenyl amination/Heck reaction for the synthesis of indoles. Ligand used in Pd-catalyzed Kumada-Corriu cross coupling at low temperatures. Ligand used in Rh-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. Ligand used in Au-catalyzed cycloisomerization of allenes. Group: Organic phosphine compounds. Alternative Names: 2-di-cyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl; 118492-EP2272832A1; (2'-dicyclohexylphosphanyl-biphenyl-2-yl)dimethyl-amine; 2-(Dicyclohexylphosphino)-2'-(N,N-diMethylaMino)biphenyl, 98% DavePhos; (2'-dicyclohexylphosphanyl -biphenyl-2-yl)-dimethyl-amine; Buchwald phosphine ligands, davephos phosphine ligand-; 2-dicyclohexylphosphino-2'-(N,N'-dimethylamino)biphe
N, N-Dicyclohexyl carbodiimide
N, N'-Dicyclohexyl carbodiimide is a carbodiimide used to couple amino acids during peptide synthesis. N, N'-Dicyclohexyl carbodiimide is used as a dehydrating agent for the preparation of amides, ketones, nitriles as well as in the inversion and esterification of secondary alcohols. Group: Biochemicals. Alternative Names: 1, 3-Dicyclohexyl carbodiimide ; Bis (cyclohexyl) carbodiimide; DCC; DCCD; DCCI; Dicyclohexyl carbodiimide ; N, N-Methanetetraylbis [cyclohexanamine]; NSC 30022; NSC 53373; NSC 57182. Grades: Highly Purified. CAS No. 538-75-0. Pack Sizes: 10g. US Biological Life Sciences.
Worldwide
XPhos Pd G1
Catalyst for cross-coupling reactions of electron-deficient anilines with aryl chlorides. Catalyst for rapid C-N bond-forming process at low catalyst loading. Catalyst for C-N cross-coupling reactions, at or below room temperature. Catalyst for the synthesis of tetracyclic indoles via intermolecular α-arylation of ketones. Catalyst for the cross-coupling of benzyl chlorides with cyclopropanol-derived ketone homoenolates. Group: Palladium series catalysts. Alternative Names: (2-Dicyclohexylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-1,1 inverted exclamation marka-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II) chloride; XPhos precatalyst; J-520016; Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II); BP-21201; Chloro(2-dicyclohexylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-1,1 inverted exclamation marka-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II); (XPhos) palladium(II) phenethylamine chloride. CAS No. 1028206-56-5. Molecular formula: C41H59ClNPPd. Mole weight: 738.774g/mol. IUPACName: chloropalladium(1+); dicyclohexyl-[2-[2, 4, 6-tri(propan-2-yl)phenyl]phenyl]phosphane; 2-phenylethanamine. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=CC=CC=C2P (C3CCCCC3)C4CCCCC4)C (C)C. C1=CC=C ([C-]=C1)CCN. Cl[Pd+]. Catalog: ACM1028206565.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl]palladium (II)
Catalyst used in the α-arylation of ketones. Catalyst used in the Suzuki cross-coupling of aryl chlorides with boronic acid-substituted benzofurans. Group: Palladium catalysts. CAS No. 1779569-06-0. Molecular formula: C46H64ClPPd. Mole weight: 789.85. Appearance: Orange powder. Catalog: ACM1779569060-1.
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