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Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III). Uses: Precursor for several oled iridium compounds. has some use as a catalyst and in oleds. Group: Synthetic tools and reagents. Alternative Names: [(ppy)2IrCl]2. CAS No. 92220-65-0. Pack Sizes: Packaging 100, 500 mg in glass insert. Product ID: Iridium(3+); 2-phenylpyridine; chloride. Molecular formula: 1072.09. Mole weight: C22H16ClIrN2. C1=CC=C([C-]=C1)C2=CC=CC=N2. C1=CC=C([C-]=C1)C2=CC=CC=N2. [Cl-]. [Ir+3]. InChI=1S/2C11H8N. ClH. Ir/c2*1-2-6-10 (7-3-1)11-8-4-5-9-12-11; ; /h2*1-6, 8-9H; 1H; /q2*-1; ; +3/p-1. NARZJSRZFGZBIZ-UHFFFAOYSA-L. 95%+.
Dichlorotetrakis[3,5-difluoro-2-(2-pyridinyl)phenyl]diiridium(III). Uses: This material is a precursor to a wide range of oled emitters such as firpic. Group: Synthetic tools and reagents. Alternative Names: Di-μ-chlorotetrakis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl- κC]di-iridium. Pack Sizes: Packaging 1 g in glass bottle. Molecular formula: 1216.02. Cl[Ir]. Cl[Ir]. Fc1ccc(c(F)c1)-c2ccccn2. Fc3ccc(c(F)c3)-c4ccccn4. Fc5ccc(c(F)c5)-c6ccccn6. Fc7ccc(c(F)c7)-c8ccccn8. 1S/4C11H7F2N. 2ClH. 2Ir/c4*12-8-4-5-9 (10 (13)7-8)11-3-1-2-6-14-11; ; ; ; /h4*1-7H; 2*1H; ; /q; ; ; ; ; ; 2*+1/p-2. RXDKZUKXPWIFAN-UHFFFAOYSA-L.
Cyclometalated Ir complexes are good phosphorescent emitters. The strong spin-orbit coupling in the ir complex leads to phosphorescent lifetimes in the 1-10 μs range,high phosphorescent efficiencies at room temperature, and good color tunability of the emission energy.The applications of such Ir complexes are based on the fact that neutral Ir based complexes consist of distinct carrier transporting/blocking and emitting layers. Single active layer in cationic Ir complexes is responsible for both carrier transport and light emission. Studies on anionic Ir are mainly focused on their photophysics. Uses: Some applications include the use of neutral ir-based complexes in oled structures and cationic ir complexes in light-emitting electrochemical cells (lec). Group: Organic light-emitting diode (oled) materials synthetic tools and reagents. Alternative Names: Iridium phenylquinoline dichloro-bridged dimer,[(pq)2IrCl]2. CAS No. 435294-69-2. Pack Sizes: 1 g in glass bottle. Molecular formula: 1272.33. Cl[Ir]. Cl[Ir]. c1ccc (cc1)-c2nccc3ccccc23. c4ccc (cc4)-c5nccc6ccccc56. c7ccc (cc7)-c8nccc9ccccc89. c%10ccc (cc%10)-c%11nccc%12ccccc%11%12. 1S/4C15H11N. 2ClH. 2Ir/c4*1-2-7-13 (8-3-1)15-14-9-5-4-6-12 (14)10-11-16-15; ; ; ; /h4*1-11H; 2*1H; ; /q; ; ; ; ; ; 2*+1/p-2, ZUKCRERFHSESIM-UHFFFAOYSA-L. ZUKCRERFHSESIM-UHFFFAOYSA-L.
Chloro(1,5-cyclooctadiene)iridium(I) dimer
Chloro(1,5-cyclooctadiene)iridium(I) dimer. Uses: 1. precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins. 2. precursor to catalyst for enantioselective reduction of imines. 3. precursor to catalyst for allylic alkylation. 4. precursor to catalyst for allylic amination and etherification. 5. precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes. 6. ir-catalyzed addition of acid chlorides to terminal alkynes. 7. intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines. 8. enantioselective [2+2] cycloaddition. 9. silyl-directed, ir-catalyzed ortho-borylation of arenes. 10. ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates. 11. transfer hydrogenative c-c coupling. Additional or Alternative Names: Bis(1,5-cyclooctadiene)diiridium(I) dichloride. Product Category: Iridium series of catalysts. Appearance: Red brown powder. CAS No. 12112-67-3. Molecular formula: C16H24Cl2Ir2. Mole weight: 671.71. Purity: 0.99. IUPACName: (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride. Canonical SMILES: C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Ir].[Ir]. ECNumber: 235-170-7. Product ID: ACM12112673-4. Alfa Chemistry ISO 9001:2015 Certified.
Chlorobis(cyclooctene)iridium(I) Dimer
Chlorobis(cyclooctene)iridium(I) Dimer. Uses: Designed for use in research and industrial production. Additional or Alternative Names: MFCD00213465; CJJIQMGSHWWMCK-XFCUKONHSA-L; J-004808; chlorobis(cyclooctene)-iridium(I) dimer; Di-mu-chlorotetrakis(cyclooctene)diiridium(I); Chlorobis(cyclooctene)iridium(I)dimer; 12246-51-4. Product Category: Iridium series of catalysts. CAS No. 12246-51-4. Molecular formula: C32H56Cl2Ir2-2. Mole weight: 896.134g/mol. IUPACName: cyclooctene;iridium;dichloride. Canonical SMILES: C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.[Cl-].[Cl-].[Ir].[Ir]. Product ID: ACM12246514. Alfa Chemistry ISO 9001:2015 Certified.