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Diphenylphosphinicchloride. Group: Biochemicals. Grades: Highly Purified. CAS No. 1499-21-4. Pack Sizes: 5g, 10g, 25g, 50g, 100g. US Biological Life Sciences.
Worldwide
1,1'-Bis(diphenylphosphino)ferrocene
Ligand for Pd-catalyzed cross-coupling. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures. Ligand for Ni-catalyzed amination of aryl chlorides. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles. Ligand for Ni-catalyzed Suzuki reactions. Ni-catalyzed hydroamination of 1,3-dienes. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones. Ligand for Ru-catalyzed reduction of nitriles to primary amines. Ligand for Rh-catalyzed alkyne head-to-tail dimerization. Ligand for Rh-catalyzed cross-coupling Ligand for Rh-catalyzed olefin isomerization Ligand for Ni or Rh-catalyzed borylation Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes. Group: Organic phosphine compounds. Alternative Names: 1,1'-Ferrocenediyl-bis(diphenylphosphine); DPPF. CAS No. 12150-46-8. Molecular formula: C34H28FeP2. Mole weight: 554.38. Appearance: Solid. Purity: 0.98. IUPACName: 1,1-Bis(diphenylphosphino)ferrocene. Catalog: ACM12150468-1.
[1, 3-Bis (diphenylphosphino) propane]nickel (II) Chloride
[1, 3-Bis (diphenylphosphino) propane]nickel (II) Chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Group: Biochemicals. Grades: Highly Purified. CAS No. 15629-92-2. Pack Sizes: 2.5g, 5g. Molecular Formula: C27H26Cl2NiP2, Molecular Weight: 542.04. US Biological Life Sciences.
Worldwide
(1, 3-Bis (diphenylphosphino)propane)palladium (II) chloride
Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes Synthetic pyrethriods: catalyst for the Negishi coupling of (2, 2-dihaloethenyl) cyclopropanecarboxylates. Group: Palladium series catalysts. Alternative Names: Dichloro[bis (1, 4-diphenylphosphino)butane]palladium (II). CAS No. 29964-62-3. Molecular formula: C28H28Cl2P2Pd. Mole weight: 603.8. Appearance: White like powder. Purity: 0.99. IUPACName: dichloropalladium; 4-diphenylphosphanylbutyl (diphenyl)phosphane. Canonical SMILES: C1=CC=C (C=C1) P (CCCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Pd]Cl. Catalog: ACM29964623-1.
[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride is used as a catalyst in the asymmetric synthesis of UK 370106 (U700620); an MMP-3 inhibitor. It is also highly effective in the hydrogenation of 2-(6'-methoxy-2'-naphthyl)propenoic acid and β-ketoesters. Group: Biochemicals. Grades: Highly Purified. CAS No. 130004-33-0. Pack Sizes: 100mg, 250mg. Molecular Formula: C54H46Cl2P2Ru. US Biological Life Sciences.
Worldwide
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldiphenylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyl (diphenylphosphine)}nickel(II) is useful in these fields: Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-36-2. Mole weight: 790.79. Catalog: ACM2049086362.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II)
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II) has the following various uses:1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-34-0. Mole weight: 738.71. Catalog: ACM2049086340.
Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate, min. 97%
Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) , tetrakis(pentafluorophenyl)borate, min. 97%
Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen. Group: Ruthenium series catalysts. Alternative Names: (R)-RUCL[P-CYMENE(H8-BINAP)]CL; [RUCL(P-CYMENE)((S)-H8-BINAP)]CL; SC10137; MFCD09753016; CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; [RUCL(P-CYMENE)((R)-H8-BINAP)]CL. CAS No. 944451-26-7. Molecular formula: C54H54Cl2P2Ru. Mole weight: 936.944g/mol. IUPACName: dichlororuthenium;[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. C1CCC2=C (C1)C=CC (=C2C3=C (C=CC4=C3CCCC4)P (C5=CC=CC=C5)C6=CC=CC=C6)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Ru]Cl. Catalog: ACM944451267.
Chlorotris(1-methylethyl)silane is used as a catalyst in the preparation of (silyloxy)cyclobutene derivatives. Also used in the addition of diethylzinc to N-diphenylphosphinoyl imines. Group: Biochemicals. Alternative Names: Chlorotriisopropyl silane; Chlorotris(1-methylethyl)silane; Triisopropyl chlorosilane; Triisopropylsilyl Chloride. Grades: Highly Purified. CAS No. 13154-24-0. Pack Sizes: 25g. US Biological Life Sciences.
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products. Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals. Group: Palladium series catalysts. Alternative Names: ST24050377; 5353AA; DICHLORO[2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II); 115826-95-4; [(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM (II) CHLORIDE; FT-0696081; MFCD00075254; C44H32Cl2P2Pd; EBD2199625; PALLADIUM, [1, 1'-(1R)-[1, 1'-BINAPHTHALENE]-2, 2'-DIYLBIS[1, 1-DIPHENYLPHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)-. CAS No. 127593-28-6. Molecular formula: C44H32Cl2P2Pd. Mole weight: 800.008g/mol. IUPACName: dichloropalladium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Pd]Cl. Catalog: ACM127593286.
A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes. A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides. Group: Heterocyclic organic compound. Alternative Names: Bis(diphenylphosphino)phenoxazine; DTXSID70390703; TRA0045396; 4,6-bis(diphenylphosphino)-phenoxazine; N-XantPhos, 97%; BB0294709; B2717; 4,6-Bis(diphenylphosphino)phenoxazine; 10H-Phenoxazine, 4,6-bis(diphenylphosphino)-; DB-009532. CAS No. 261733-18-0. Molecular formula: C36H27NOP2. Mole weight: 551.566g/mol. IUPACName: (6-diphenylphosphanyl-10H-phenoxazin-4-yl)-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC4=C3OC5=C (N4)C=CC=C5P (C6=CC=CC=C6)C7=CC=CC=C7. Catalog: ACM261733180.
(Oxybis(2,1-phenylene))bis(diphenylphosphine)
Useful as a ligand in the Pd-catalyzed formation of diaryl amines. Has been recently applied to the C3 benzylation of indoles. Has been recently applied to the monoallylation of ammonia. Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids. Ligand used in carbonylation of aryl iodides. Ligand used in the direct C-H arylation of benzothiodiazoles. Ligand used in stereo-retentive azacyclization of propargylic carbonates. Ligand used in palladium catalyzed benzyne trimerization. Group: Organic phosphine compounds. CAS No. 166330-10-5. Molecular formula: C36H28OP2. Mole weight: 538.567g/mol. IUPACName: [2- (2-diphenylphosphanylphenoxy) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1) P (C2=CC=CC=C2) C3=CC=CC=C3OC4=CC=CC=C4P (C5=CC=CC=C5) C6=CC=CC=C6. Catalog: ACM166330105.