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[2-(5-Methyl-1H-pyrazol-3-yl-κN2)pyridinato-κN](η3-2-propenyl)palladium Tetrafluoroborate is an coordination complex used as an catalyst in he synthesis of cyclopropanation of ketene silyl acetal with allylic acetates. Group: Biochemicals. Grades: Highly Purified. CAS No. 215323-63-0. Pack Sizes: 10mg, 100mg. Molecular Formula: C12H12BF4N3Pd. US Biological Life Sciences.
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betaine reductase
The reaction is observed only in the direction of betaine reduction. The enzyme from Eubacterium acidaminophilum consists of subunits A, B and C. Subunit B contains selenocysteine and a pyruvoyl group, and is responsible for betaine binding and trimethylamine release. Subunit A, which also contains selenocysteine, is reduced by thioredoxin, and is needed to convert the carboxymethyl group into a ketene equivalent, in turn used by subunit C to produce acetyl phosphate. Only subunit B distinguishes this enzyme from EC 1.21.4.2 (glycine reductase) and EC 1.21.4.3 (sarcosine reductase). Group: Enzymes. Synonyms: acetyl-phosphate trimethylamine:thioredoxin disulfide oxidoreductase (N,N,N-trimethylglycine-forming). Enzyme Commission Number: EC 1.21.4.4. CAS No. 125752-87-6. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1259; betaine reductase; EC 1.21.4.4; 125752-87-6; acetyl-phosphate trimethylamine:thioredoxin disulfide oxidoreductase (N,N,N-trimethylglycine-forming). Cat No: EXWM-1259.
Bis (tri-t-butylphosphine) palladium bromide (I), dimer
Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids. Aryl bromide - silyl ketene acetal coupling. Catalyst for intermolecular α-arylation of zinc amide enolates. Catalyst for α-vinylation of carbonyl compounds. Catalyst for thiol coupling of heteroaromatic aryl bromides. Group: Palladium series catalysts. Alternative Names: MFCD04114019; 185812-86-6; CTK8C5468; palladium(I) tri-tertbutylphosphine bromide; PUBCHEM_71317307; Palladium(I) tri-tert-butylphosphine bromide. CAS No. 185812-86-6. Molecular formula: C12H27BrPPd-. Mole weight: 388.646g/mol. IUPACName: palladium;tritert-butylphosphane;bromide. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Br-]. [Pd]. Catalog: ACM185812866.
glycine reductase
The reaction is observed only in the direction of glycine reduction. The enzyme from Eubacterium acidaminophilum consists of subunits A, B and C. Subunit B contains selenocysteine and a pyruvoyl group, and is responsible for glycine binding and ammonia release. Subunit A, which also contains selenocysteine, is reduced by thioredoxin, and is needed to convert the carboxymethyl group into a ketene equivalent, in turn used by subunit C to produce acetyl phosphate. Only subunit B distinguishes this enzyme from EC 1.21.4.3 (sarcosine reductase) and EC 1.21.4.4 (betaine reductase). Group: Enzymes. Enzyme Commission Number: EC 1.21.4.2. CAS No. 39307-24-9. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1257; glycine reductase; EC 1.21.4.2; 39307-24-9. Cat No: EXWM-1257.
Methyl 2-acetamidoacrylate
Conjugated addition of secondary amines, imidazole and pyrazole to methyl 2 methyl 2-acetamidoacrylate in the presence of a catalyst results in the formation of β-Dialkylamino-α-alanine and β-(N-heteroaryl)-α-alanine derivatives. Methyl-2-acetamidoacrylate (M2AA) is an anti-inflammatory agent. The catalytic reaction of methyl 2-acetamidoacrylate with Grignard's reagents affords α-amino esters. M2AA can form thermosensitive copolymers with methyl acrylate. Methyl ester of 2-acetamidoacrylate. methyl 2-acetamidoacrylate (Me-2-AA) is a di-unsaturated α-amino acid derivative. methyl-2-acetamidoacrylate exihibits anti -inflammatory properties, it is very effective against lipopolysaccharide (LPS)- induced nitric oxide production by RAW 264. Uses: Methyl 2-acetamidoacrylate can undergo [2+2] cycloaddition (michael-dieckmann-type reaction) with ketene diethyl acetal to yield the cyclobutane core. it may be used in rhodium-catalyzed 2-alkenylpyrrole formation. Group: Polymer/macromolecule. Alternative Names: 2-ACETAMIDOACRYLIC ACID METHYL ESTER;METHYL 2-ACETAMIDOACRYLATE;Ac-DL-Dha-OMe~2-Acetamidoacrylic acid methyl ester~N-Acetyldehydroalanine methyl ester;2-ACETAMIDOACRYLIC ACID METHYL ESTER 95+%;ac-dl-dha-ome;2-Acetylaminoacrylic acid methyl ester;Methyl 2-. CAS No. 35356-70-8. Molecular formula: H2C=C(NHCOCH3)CO2CH3. Mole weight: 143.14. Canonical SMILES: COC(=O)C(=C)NC(C)=O. Catalo
Methyl (triphenylphosphoranylidene)acetate
(Methoxycarbonylmethylene) triphenylphosphorane is used in olefination reactions. Wittig reagent for the two-carbon homologation of aldehydes to α,β-unsaturated esters. it undergoes the Wittig reaction with aldehydes to give substituted methyl acrylates. used in an efficient synthesis of pyrazoles via reaction with methyl diazoacetate in the presence of triethylamine. It is used in the preparation of (triphenylphosphoranylidene)-ketene. The Wittig reaction we performed in class involved the reaction of 2-nitrobenzaldehyde (1) with methyl (triphenylphosphoranylidene) acetate (2) to produce methyl (2E)-3-(2-nitrophenyl) acrylate (3) with a triphenylphosphine oxide (4) side product, and took place in a silica gel matrix to ensure even product dispersion for chromatography. Group: Heterocyclic organic compound. Alternative Names: 1-(Triphenylphosphonio)-2-oxo-2-methoxyethan-1-ide; methyl (triphenylphosphoranylideneacetate); RTR-011791; NCGC00161084-02; (methoxycarbonylmethylene) triphenylphosphorane; triphenyl phosphanyliden-acetic acid methyl ester; (Carbomethoxymethylene) triphenylphosphorane; NSC-117573; Methyl (triphenyphosphoranylidene)acetate; ST2413263. CAS No. 2605-67-6. Molecular formula: C21H19O2P. Mole weight: 334.355g/mol. IUPACName: methyl 2-(triphenyl-λ5-phosphanylidene)acetate. Canonical SMILES: COC (=O)C=P (C1=CC=CC=C1) (C2=CC=CC=C2)C3=CC=CC=C3. ECNumber: 220-018-4.
Permethrinic Acid Methyl Ester
Permethrinic Acid Methyl Ester is an impurity of the insecticide Permethrin (P288500), which is synthetic pyrethroid insecticide with low mammalian toxicity. Permethrinic Acid Methyl Ester is also used as a reactant in preperation of β-ketoesters via sodium hydroxide catalyzed crossed Claisen condensation of ketene silyl acetals and methyl esters. Group: Biochemicals. Grades: Highly Purified. CAS No. 61898-95-1. Pack Sizes: 50mg, 100mg. Molecular Formula: C9H12Cl2O2. US Biological Life Sciences.
Worldwide
sarcosine reductase
The reaction is observed only in the direction of sarcosine reduction. The enzyme from Eubacterium acidaminophilum consists of subunits A, B and C. Subunit B contains selenocysteine and a pyruvoyl group, and is responsible for sarcosine binding and methylamine release. Subunit A, which also contains selenocysteine, is reduced by thioredoxin, and is needed to convert the carboxymethyl group into a ketene equivalent, in turn used by subunit C to produce acetyl phosphate. Only subunit B distinguishes this enzyme from EC 1.21.4.2 (glycine reductase) and EC 1.21.4.4 (betaine reductase). Group: Enzymes. Enzyme Commission Number: EC 1.21.4.3. CAS No. 125752-88-7. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1258; sarcosine reductase; EC 1.21.4.3; 125752-88-7. Cat No: EXWM-1258.
Ketanserin
An antihypertensive, with affinity for multiple GPCR receptors. Group: Biochemicals. Alternative Names: 3-[2-[4-(4-Fluorobenzoyl)-1-piperidinyl]ethyl]-2,4(1H,3H)-quinazolinedione; Ketensin; R 41468. Grades: Highly Purified. CAS No. 74050-98-9. Pack Sizes: 50mg. US Biological Life Sciences.
Worldwide
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