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Product | Description | |
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1,1?-Bis(dicyclohexylphosphino)ferrocene Quick inquiry Where to buy Suppliers range | Orange-red powder. Uses: Ligand for palladium-catalyzed synthesis of oxindoles by amide ?-arylation. Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides. Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols. Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates. Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases. Group: Organic Phosphine Compounds. Alternative Names: 1,1?-Bis(dicyclohexylphosphino)ferrocene; 1,1-Bis(Dicyclohexylphosphino)Ferrocene; 1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE. Grades: 98%. CAS No. 146960-90-9. Molecular formula: C34H52FeP2. Mole weight: 578.57. IUPAC Name: dicyclohexyl(cyclopentyl)phosphane; iron. Exact Mass: 578.28900. Melting Point: 134-136ºC. SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. [Fe]. InChIKey: LVWMUECONASIMT-UHFFFAOYSA-N. | |
1,1'-Bis(diisopropylphosphino)ferrocene Quick inquiry Where to buy Suppliers range | Orange-yellow powder. Uses: Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO. Pd-catalyzed carbonylative ?-arylation of ketones with aryl iodides Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation Ligand for ruthenium-catalyzed C-C coupling reactions of fluorinated alcohols with allenes. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents. Group: Organic Phosphine Compounds. Alternative Names: 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE. Grades: 98%. CAS No. 97239-80-0. Molecular formula: C22H36FeP2. Mole weight: 418.32. IUPAC Name: 1,1-Bis(diisopropylphosphino)ferrocene. Exact Mass: 418.16400. Melting Point: 50-52ºC(lit.). Flash Point: >230 °F. Safty Description: 37/39-26. Hazard statements: Xi: Irritant. | |
1,1'-Bis(diphenylphosphino)ferrocene Quick inquiry Where to buy Suppliers range | yellow to orange powder. Uses: Ligand for Pd-catalyzed cross-coupling. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures. Ligand for Ni-catalyzed amination of aryl chlorides. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles. Ligand for Ni-catalyzed Suzuki reactions. Ni-catalyzed hydroamination of 1,3-dienes. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones. Ligand for Ru-catalyzed reduction of nitriles to primary amines. Ligand for Rh-catalyzed alkyne head-to-tail dimerization. Ligand for Rh-catalyzed cross-coupling Ligand for Rh-catalyzed olefin isomerization Ligand for Ni or Rh-catalyzed borylation Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes. Group: Organic Phosphine Compounds. Alternative Names: 1-Bis(diphenylphosphino)ferrocene; 1,1`-Bis(diphenylphosphino)ferrocene; 1,1-bis(diphenylphosphanyl)ferrocene; 1,1'-Bis(diphenylphosphino)ferrocene (DPPF); 1,1-BIS(DIPHENYLPHOSPHINO)ERROCENE; 1,1-Bis(diphenylphosphino)ferrocene; DPPF; Cyclopentadienyldiphenylphosphine; Zirconium ionophore I; 1,1-Bis(diphenylphosphiNA)ferrocene; 1,1-bis(diphenylphosphino)ferrocene palladium chloride; 1,1-Bis(diphenylpho; 1,1-bis(diphenyphosphino)ferrocene; bis-1,1-(diphenylphosphino)ferrocene; 1,1-Ferrocenebis(diphenylphosphine); 1,1-FERROCENEBIS(DIPHENYLPHOSPHINE); 1,1-Ferrocenediyl-bis(diphenylphosphine); 1,1'-Bis(diphenylphosphino)ferrocene. Grades: 96%. CAS No. 12150-46-8. Molecular formula: C34H28FeP2. Mole weight: 554.39. IUPAC Name: 1,1-Bis(diphenylphosphino)ferrocene. Exact Mass: 554.10200. Boiling Point: 363.8ºC at 760mmHg. Melting Point: 181-183ºC. Flash Point: 182.8ºC. Safty Description: S28-S45. Hazard statements: T: Toxic. | |
1,2,3,4-Tetraphenyl-1,3-cyclopentadiene Quick inquiry Where to buy Suppliers range | 1,2,3,4-Tetraphenyl-1,3-cyclopentadiene. Group: Olefin Ligands. Alternative Names: 1,2,3,4-Tetraphenylcyclopentadiene; Tetraphenylcyclopentadiene. Grades: 96%. CAS No. 15570-45-3. Product ID: ACM15570453-3. Molecular formula: C29H22. Mole weight: 370.50. IUPAC Name: (2,3,4-triphenylcyclopenta-1,3-dien-1-yl)benzene. Appearance: Solid. EC Number: 239-619-8. Density: 1.143 g/ml. SMILES: C1C (=C (C (=C1C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4) C5=CC=CC=C5. | |
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh Quick inquiry Where to buy Suppliers range | (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh. Uses: 1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation. 2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides. 3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents. 4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins. Group: Heterocyclic Organic Compound. Alternative Names: 528565-84-6;1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(R,R)-Ph-BPE-Rh;(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; MFCD07369037; DTXSID20746256; PUBCHEM_71310600; (-)-1, 2-Bis ( (2R, 5R)-2, 5-diphenylphospholano)ethane (1, 5-cyclooctadiene)rhodium (i)tetrafluoroborate. CAS No. 528565-84-6. Molecular formula: C42H48BF4P2Rh-. Mole weight: 804.503g/mol. IUPAC Name: (1Z, 5Z)-cycloocta-1, 5-diene; (2R, 5R)-1-[2-[(2R, 5R)-2, 5-diphenylphospholan-1-yl]ethyl]-2, 5-diphenylphospholane; rhodium; tetrafluoroborate. Rotatable Bond Count: 7. Exact Mass: 804.232g/mol. SMILES: [B-] (F) (F) (F) F. C1CC=CCCC=C1. C1CC (P (C1C2=CC=CC=C2) CCP3C (CCC3C4=CC=CC=C4) C5=CC=CC=C5) C6=CC=CC=C6. [Rh]. InChI: InChI=1S/C34H36P2.C8H12.BF4.Rh/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-20,31-34H,21-26H2;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t31-,32-,33-,34-;;;/m1./s1. InChIKey: ZNZBTPZGQIGMKZ-FMUQXVHFSA-N. H-Bond Acceptor: 5. Monoisotopic Mass: 804.232g/mol. | |
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh Quick inquiry Where to buy Suppliers range | (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh. Uses: Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins. Alternative Names: 849950-53-4; (S, S)-Ph-BPE-Rh; DTXSID60746255; PUBCHEM_71310599; MFCD07369038; (+)-1, 2-Bis (2S, 5S)-2, 5-diphenylphospholano)ethane- (1, 5-cyclooctadiene)rhodium (I)tetrafluoroborate; 1, 2-Bis[ (2S, 5S)-2, 5-diphenylphospholano]ethane (1, 5-cyclooctadiene)rhodium (I) tetrafluoroborate;1,2-Bis[(s,s)-2,5-diphenylphospholano]ethane-(1,5-cycloocta-diene)rhodium(I)tetrafluoroborate. CAS No. 849950-53-4. Molecular formula: C42H48BF4P2Rh-. Mole weight: 804.503g/mol. IUPAC Name: (1Z, 5Z)-cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-diphenylphospholan-1-yl]ethyl]-2, 5-diphenylphospholane; rhodium; tetrafluoroborate. Rotatable Bond Count: 7. Exact Mass: 804.232g/mol. SMILES: [B-] (F) (F) (F) F. C1CC=CCCC=C1. C1CC (P (C1C2=CC=CC=C2) CCP3C (CCC3C4=CC=CC=C4) C5=CC=CC=C5) C6=CC=CC=C6. [Rh]. InChI: InChI=1S/C34H36P2.C8H12.BF4.Rh/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-20,31-34H,21-26H2;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t31-,32-,33-,34-;;;/m0./s1. InChIKey: ZNZBTPZGQIGMKZ-NSSKQOQASA-N. H-Bond Acceptor: 5. Monoisotopic Mass: 804.232g/mol. | |
1,3,5-Triaza-7-phosphaadamantane Quick inquiry Where to buy Suppliers range | 1,3,5-Triaza-7-phosphaadamantane. Uses: Air-stable, water-soluble version of trimethylphosphine. Reagent used in the β-olefination of 2-alkynoates leading to trisubstituted 1,3-dienes. Ligand/rhodium catalyst used in the branch selective allylation of acetylacetone. Ligand/oxorhenium complex used as a catalyst for the Baeyer-Villiger oxidation of ketones. Group: Heterocyclic Organic Compound. Alternative Names: CTK1H0104; DTXSID40201812; 1,5:3,7-Dimethano-3,5,7-triaza-1-phosphacyclooctane; 1,3,5-Triaza-7-phosphaadamantane,min.97%; NSC266642; SCHEMBL270566; 1,3,5-triaza-7-phosphatricyclo[3.3.1.1^{3,7]decane; MFCD00154905; AKOS025214125; 1,3,5-Triaza-7-phosphaadamantane, 97%. CAS No. 53597-69-6. Molecular formula: C6H12N3P. Mole weight: 157.157g/mol. IUPAC Name: 1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane. Exact Mass: 157.077g/mol. SMILES: C1N2CN3CN1CP(C2)C3. InChI: InChI=1S/C6H12N3P/c1-7-2-9-3-8(1)5-10(4-7)6-9/h1-6H2. InChIKey: FXXRPTKTLVHPAR-UHFFFAOYSA-N. H-Bond Acceptor: 3. Monoisotopic Mass: 157.077g/mol. | |
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene Quick inquiry Where to buy Suppliers range | 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene. Uses: Ligand for copper-catalyzed regioselective formation of tri- and tetrasubstituted vinylboronates in air. Ligand for highly active ruthenium catalyst for hydrogenation of olefins. Electrophilic phosphonium cations component for ketone catalytic hydrodeoxygenation/hydrosilylation. Used in selective activation of fluoroalkenes to produce N-heterocyclic fluoroalkenes and polyfluoroalkenyl imidazolium salts. Alternative Names: C-2353; DTXSID20459319; 173035-11-5; FT-0700101; 1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene. CAS No. 173035-11-5. Molecular formula: C21H26N2. Mole weight: 306.453g/mol. IUPAC Name: 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-2H-imidazol-1-ium-2-ide. Rotatable Bond Count: 2. Exact Mass: 306.21g/mol. SMILES: CC1=CC(=C(C(=C1)C)N2CC[N+](=[C-]2)C3=C(C=C(C=C3C)C)C)C. InChI: InChI=1S/C21H26N2/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6/h9-12H,7-8H2,1-6H3. InChIKey: LSMWOQFDLBIYPM-UHFFFAOYSA-N. H-Bond Acceptor: 1. Monoisotopic Mass: 306.21g/mol. | |
1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydroimidazolium tetrafluoroborate Quick inquiry Where to buy Suppliers range | 1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydroimidazolium tetrafluoroborate. Uses: In-situ deprotonation leads to metal carbene species which acts as a catalyst in a variety of C-C and C-N bond forming reactions. Ligand used in the nickel or palladium-catalyzed coupling of aryl chlorides and amines. Ligand used for the palladium-catalyzed arylation of esters and amides. Ligand used for the palladium-catalyzed intermolecular amination of Csp3-H Bonds. Ligand used for the nickel-catalyzed hydrogenation of olefins. Group: Organic Phosphine Compounds. Alternative Names: DTXSID60463955; CTK1A1650; AN-29083; 1,3-Bis-(2,6-diisopropylphenyl)imidazolinium tetrafluoroborate; SC11685; SIPr.HBF4; AKOS015832942; SIPr-HBF4; I14-3250; 1,3-bis[2,6-di(propan-2-yl)phenyl]-4,5-dihydroimidazol-1-ium,tetrafluoroborate. CAS No. 282109-83-5. Molecular formula: C27H39BF4N2. Mole weight: 478.427g/mol. IUPAC Name: 1,3-bis[2,6-di(propan-2-yl)phenyl]-4,5-dihydroimidazol-1-ium;tetrafluoroborate. Rotatable Bond Count: 6. Exact Mass: 478.314g/mol. SMILES: [B-] (F) (F) (F)F. CC (C)C1=C (C (=CC=C1)C (C)C)N2CC[N+] (=C2)C3=C (C=CC=C3C (C)C)C (C)C. InChI: InChI=1S/C27H39N2.BF4/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2-1(3,4)5/h9-14,17-21H,15-16H2,1-8H3;/q+1;-1. InChIKey: KFZBJQUHHALFSR-UHFFFAOYSA-N. H-Bond Acceptor: 5. Monoisotopic Mass: 478.314g/mol. | |
(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane Quick inquiry Where to buy Suppliers range | (1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane. Uses: Reactant in preparation of derived ruthenium olefin metathesis catalysts 1 N-cyclic carbene ligand 2 Catalyst in: Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands 3 Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors 4 N-arylation of aromatic amines 5 Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions. Alternative Names: N,N'-Bis(2,6-diisopropylphenyl)ethanediimine; AKOS004909627; 1,2-bis(2,6-diisopropylphenylimino)ethane; RL04839; AKOS030229349; ZINC252616095; Glyoxal bis(2,6-diisopropylanil); J-502081; AJ-63795; (1E,2E)-N1,N2-bis[2,6-bis(propan-2-yl)phenyl]ethane-1,2-diimine. CAS No. 74663-75-5. Molecular formula: C26H36N2. Mole weight: 376.588g/mol. IUPAC Name: N,N'-bis[2,6-di(propan-2-yl)phenyl]ethane-1,2-diimine. Rotatable Bond Count: 7. Exact Mass: 376.288g/mol. SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N=CC=NC2=C (C=CC=C2C (C)C)C (C)C. InChI: InChI=1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3. InChIKey: JWVIIGXMTONOFR-UHFFFAOYSA-N. H-Bond Acceptor: 2. Monoisotopic Mass: 376.288g/mol. | |
1H-Cyclopenta[l]phenanthrene Quick inquiry Where to buy Suppliers range | 1H-Cyclopenta[l]phenanthrene. Group: Olefin Ligands. Grades: 95%. CAS No. 235-92-7. Product ID: ACM235927-2. Molecular formula: C17H12. Mole weight: 216.28. IUPAC Name: 1H-cyclopenta[l]phenanthrene. Density: 1.201±0.06 g/cm3(Predicted). SMILES: C1C=CC2=C1C3=CC=CC=C3C4=CC=CC=C24. | |
(1R,4R)-2,5-Diphenylbicyclo[2.2.2]octa-2,5-diene Quick inquiry Where to buy Suppliers range | (1R,4R)-2,5-Diphenylbicyclo[2.2.2]octa-2,5-diene. Group: Olefin Ligands. Alternative Names: Bicyclo[2.2.2]octa-2,5-diene, 2,5-diphenyl-, (1R,4R)-. CAS No. 796966-15-9. IUPAC Name: (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene. Molecular Weight: 258.36. Molecular Formula: C20H18. Flash Point: 97%. | |
2,3-Bis(2,6-diisopropylphenylimino)butane Quick inquiry Where to buy Suppliers range | 2,3-Bis(2,6-diisopropylphenylimino)butane. Uses: 1. Ligand used in the preparation of highly active metal catalysts for the polymerization of ethylene (ref 1, M=Ni, Pd) and olefins (ref 2, M=Pd; ref 3, M= Hf, Zr) Ligand for the iron catalyzed polymerization of styrene acrylate monomers Ligand for Yttrium complex that catalysis the ring-opening polymerization of cyclic esters Ligand for rare-earth dichloro and bis(alkyl) complexes for isoprene polymerization Ligand for cobalt catalyzed alkene hydroboration Ligand for nickel catalyzed alkene hydrosilylation. Group: Heterocyclic Organic Compound. Alternative Names: N-(2,6-diisopropylphenyl)-N-{2-[(2,6-diisopropylphenyl)imino]-1-methylpropylidene}amine; N-((E,2E)-2-[(2,6-Diisopropylphenyl)imino]-1-methylpropylidene)-2,6-diisopropylaniline #; TRA0127768; N,N inverted exclamation marka-Bis(2,6-diisopropylphenyl)-2,3-butanediimine; J-400165; AKOS025295710; N2,N3-bis[2,6-di(propan-2-yl)phenyl]butane-2,3-diimine; (N,N'E,N,N'E)-N,N'-(butane-2,3-diylidene)bis(2,6-diisopropylaniline); 74663-77-7; ZINC15230312. CAS No. 74663-77-7. Molecular formula: C28H40N2. Mole weight: 404.642g/mol. IUPAC Name: 2-N,3-N-bis[2,6-di(propan-2-yl)phenyl]butane-2,3-diimine. Rotatable Bond Count: 7. Exact Mass: 404.319g/mol. SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N=C (C)C (=NC2=C (C=CC=C2C (C)C)C (C)C)C. InChI: InChI=1S/C28H40N2/c1-17(2)23-13-11-14-24(18(3)4)27(23)29-21(9)22(10)30-28-25(19(5)6)15-12-16-26(28)20(7)8/h11-20H,1-10H3. InChIKey: YUFQUBWPYIPRHZ-UHFFFAOYSA-N. H-Bond Acceptor: 2. Monoisotopic Mass: 404.319g/mol. | |
2-Methyl-7-phenylindene Quick inquiry Where to buy Suppliers range | 2-Methyl-7-phenylindene is used for the preparation of metallocene complexes with heteroatom containing n-ligands as a catalyst for olefin polymerization. Group: Biochemicals. Grades: Highly Purified. CAS No. 153733-75-6. Pack Sizes: 250mg, 1g. Molecular Formula: C16H14, Molecular Weight: 206.28. US Biological Life Sciences. | Worldwide |
6, 6?-[(3, 3?-Di-tert-butyl-5, 5?-dimethoxy-1, 1?-biphenyl-2, 2?-diyl)bis(oxy)]bis(dibenzo[d, f][1, 3, 2]dioxaphosphepin) Quick inquiry Where to buy Suppliers range | 6, 6?-[(3, 3?-Di-tert-butyl-5, 5?-dimethoxy-1, 1?-biphenyl-2, 2?-diyl)bis(oxy)]bis(dibenzo[d, f][1, 3, 2]dioxaphosphepin). Uses: With rhodium forms a highly active catalyst for the hydroformylation of α-olefins. The hydroformylation of functionalized α-olefins is highly regioselective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality. Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step. Alternative Names: 2,2'-Bis[(1,1'-biphenyl-2,2'-diyl)phosphite]-3,3'-di-tert-butyl-5,5'-dimethoxy-1,1'-biphenyl; 6, 6-[(3, 3-Di-tert-butyl-5, 5-dimethoxy-1, 1-biphenyl-2, 2-diyl)bis(oxy)]bis(dibenzo[d, f][1, 3, 2]dioxaphosphepin); BiPhePhos; ZINC150353045; WUFGFUAXCBPGOL-UHFFFAOYSA-N; Y0547; 6, 6'-[(3, 3'-Di-tert-butyl-5, 5'-dimethoxy-1, 1'-biphenyl-2, 2'-diyl)bis(oxy)]bis(dibenzo[d, f][1, 3, 2]dioxaphosphepin), 97%. CAS No. 121627-17-6. Molecular formula: C46H44O8P2. Mole weight: 786.798g/mol. IUPAC Name: 6-[2-(2-benzo[d][1, 3, 2]benzodioxaphosphepin-6-yloxy-3-tert-butyl-5-methoxyphenyl)-6-tert-butyl-4-methoxyphenoxy]benzo[d][1, 3, 2]benzodioxaphosphepine. Rotatable Bond Count: 9. Exact Mass: 786.251g/mol. EC Number: 700-178-6. SMILES: CC (C) (C) C1=C (C (=CC (=C1) OC) C2=CC (=CC (=C2OP3OC4=CC=CC=C4C5=CC=CC=C5O3) C (C) (C) C) OC) OP6OC7=CC=CC=C7C8=CC=CC=C8O6. InChI: InChI=1S/C46H44O8P2/c1-45(2,3)37-27-29(47-7)25-35(43(37)53-55-49-39-21-13-9-17-31(39)32-18-10-14-22-40(32)50-55)36-26-30(48-8)28-38(46(4,5)6)44(36)54-56-51-41-23-15-11-19-33(41)34-20-12-16-24-42(34)52-56/h9-28H,1-8H3. InChIKey: WUFGFUAXCBPGOL-UHFFFAOYSA-N. H-Bond Acceptor: 8. Monoisotopic Mass: 786.251g/mol. | |
(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) Quick inquiry Where to buy Suppliers range | (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine). Uses: Ligand used for the hydroformylation of alkenes. Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides. Ligand used in the intermolecular coupling of amides with aryl halides or triflates. Ligand used in the coupling of heteroarylamines and aryl halides. Ligand used in the hydrophosphinylation of alkenes and alkynes. Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols. Ligand used for the sulfinylation of aryl iodides. Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines. Ligand used for the Ni-cataltzed alkynylcyanation of alkynes. Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole. Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes. Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides. Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles. Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes. Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates. Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones. Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines. Ligand used for the Cu-catalyzed intermolecular coupling of alkynes with aryl iodides. Ligand used for the Pd-catalyzed ene-type reaction of aldehydes with 1,3-diene. Ligand used for the Ru-catalyzed intermolecular addition of 2-phenylbenzoic acid onto unactivated olefins. Ligand used for the Pd/Cu-catalyzed direct arylation of heteroarenes. Ligand used for the Pd-catalyzed reaction of propargyl-substituted malonate esters with aryl halides. Ligand used for the Pd-catalyzed decarboxylative coupling of tertiary cyanoacetate salts with aryl halides and triflates. Ligand used for the Pd-catalyzed hydroesterification of alkynes. Ligand used for the Cu-catalyzed arylation of arylboronic acids with aldehydes. Ligand used for the Ru-catalyzed oxidative synthesis of heterocycles from alcohols. Ligand used for the Rh-catalyzed borylation of ni | |
Allylpalladium(II) chloride dimer Quick inquiry Where to buy Suppliers range | Allylpalladium(II) chloride dimer. Uses: Precatalyst for the enantioselective hydrosilylation of olefins. Precatalyst for asymmetric allylic alkylation and amination. Used as a palladium source for cross-coupling reactions. Can be used with Trost ligands. Catalyst for the carbostannylation of alkynes. Used as a precatalyst for "-arylation of aldehydes. Group: Palladium series catalysts. Alternative Names: Di-mu-chlorodi-pi-allyldipalladium; NSC 151255; Bis(pi-allylpalladium chloride) (VAN); MFCD00044874 (95%); Bis(mu-chloro)bis(eta3-2-propenyl)dipalladium; AK327212; 12012-95-2; Palladium, di-pi-allyldi-mu-chlorodi- (8CI); Bis((eta3-allyl)(chloro)palladium); SC10406. CAS No. 12012-95-2. Molecular formula: C6H10Cl2Pd2. Mole weight: 365.886g/mol. IUPAC Name: chloropalladium(1+);prop-1-ene. Exact Mass: 365.823g/mol. EC Number: 234-579-8. SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]. InChI: InChI=1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q2*-1;;;2*+2/p-2. InChIKey: PENAXHPKEVTBLF-UHFFFAOYSA-L. H-Bond Acceptor: 2. Monoisotopic Mass: 363.823g/mol. | |
Cyclooctene Quick inquiry Where to buy Suppliers range | Cyclooctene. Group: Olefin Ligands. Alternative Names: cis-Cyclooctene; (Z)-Cyclooctene. CAS No. 931-88-4. IUPAC Name: cyclooctene. Molecular Weight: 110.20. Molecular Formula: C8H14. Flash Point: 95%+. | |
(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine Quick inquiry Where to buy Suppliers range | (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine. Uses: Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition. Group: Heterocyclic Organic Compound. Alternative Names: (R)-(-)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE; 9699AA; (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a; FT-0701641; 3,4-a']dinaphthalen-4-yl)dimethylamine; A116071; A116070; 4CH-018602; SY226298; AX8210337. CAS No. 157488-65-8. Molecular formula: C22H18NO2P. Mole weight: 359.365g/mol. IUPAC Name: N, N-dimethyl-12, 14-dioxa-13-phosphapentacyclo[13.8.0.02, 11.03, 8.018, 23]tricosa-1(15), 2(11), 3, 5, 7, 9, 16, 18, 20, 22-decaen-13-amine. Rotatable Bond Count: 1. Exact Mass: 359.108g/mol. SMILES: CN (C)P1OC2=C (C3=CC=CC=C3C=C2)C4=C (O1)C=CC5=CC=CC=C54. InChI: InChI=1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3. InChIKey: QCHAVHXSBZARBO-UHFFFAOYSA-N. H-Bond Acceptor: 3. Monoisotopic Mass: 359.108g/mol. | |
(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine Quick inquiry Where to buy Suppliers range | (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine. Uses: A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins. Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral allylic esters. Asymmetric hydrogenation. Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles. Asymmetric hydrovinylation. Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation. Palladium-catalyzed enantioselective diamination of alkyl dienes. Alternative Names: SC11361; (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT; (R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine; 918D911; (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT; 415918-91-1; (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A\']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT. CAS No. 415918-91-1. Molecular formula: C37H32Cl2NO2P. Mole weight: 624.542g/mol. IUPAC Name: N, N-bis[(1R)-1-phenylethyl]-12, 14-dioxa-13-phosphapentacyclo[13.8.0.02, 11.03, 8.018, 23]tricosa-1(15), 2(11), 3, 5, 7, 9, 16, 18, 20, 22-decaen-13-amine;dichloromethane. Rotatable Bond Count: 5. Exact Mass: 623.155g/mol. SMILES: CC (C1=CC=CC=C1)N (C (C)C2=CC=CC=C2)P3OC4=C (C5=CC=CC=C5C=C4)C6=C (O3)C=CC7=CC=CC=C76. C (Cl)Cl. InChI: InChI=1S/C36H30NO2P.CH2Cl2/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40;2-1-3/h3-26H,1-2H3;1H2/t25-,26-;/m1./s1. InChIKey: PQTVIIOJNJVQOL-JUJAXGASSA-N. H-Bond Acceptor: 3. Monoisotopic Mass: 623.155g/mol. | |
(R)-tert-Butylsulfinamide Quick inquiry Where to buy Suppliers range | (R)-tert-Butylsulfinamide is a chiral ligand used in pharmaceutical compositions. (R)-tert-Butylsulfinamide can be readily transformed into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.(R)-(+)-2-Methyl-2-propanesulfinamide may be used to prepare N-(1-cyclohexylmethylidene)-2-methylpropane-2-sulfinamide via copper mediated condensation with cyclohexane carboxaldehyde. It may also be used to prepare (20E)-N-[t-butyl-(R)-sulfinyl]-3 β-(t-butyldimethylsilyloxy)-pregn-5-en-20-imine, an intermediate for the development of androgen receptor antagonists. Group: Biochemicals. Alternative Names: (R)-(+)-2-Methyl-2-propanesulfinamide; (R)-N-tert-Butanesulfinamide;(R)-tert-Butanesulfinamide; (R)-(+)-t-Butyl sulfinamide. Grades: Highly Purified. CAS No. 196929-78-9. Pack Sizes: 1g, 5g, 10g, 25g. Molecular Formula: C4H11NOS, Molecular Weight: 121.2. US Biological Life Sciences. | Worldwide |
Tetraphenylcyclopentadienone Quick inquiry Where to buy Suppliers range | Tetraphenylcyclopentadienone. Group: Olefin Ligands. Alternative Names: Tetracyclone; 2,3,4,5-Tetraphenylcyclopenta-2,4-dienone. CAS No. 479-33-4. IUPAC Name: 2,3,4,5-tetraphenylcyclopenta-2,4-dien-1-one. Molecular Weight: 384.47. Molecular Formula: C29H20O. Flash Point: 98%+. | |
Tri(2-furyl)phosphine Quick inquiry Where to buy Suppliers range | Tri(2-furyl)phosphine. Uses: Useful ligand for C-C coupling reactions. Ligand used for the alkynylation of thioesters. Ligand used for enol ester formation. Ligand for palladium-catalyzed 3-Component coupling. Ligand for palladium-catalyzed C-C coupling reaction. Ligand for trans-olefin formation. Olefin formation from N-tosylhydrazones and benzyl halides. C-H arylation/alkenylation of 1-substituted tetrazoles. Group: Organic Phosphine Compounds. Alternative Names: Tri(2-furyl)phosphine; CS-D1394; X3001; C12H9O3P; trifuran-2-yl-phosphane; tri(2-furyl)phospine; M-6648; 4CH-007747; FT-0656985; ST2414021. CAS No. 5518-52-5. Molecular formula: C12H9O3P. Mole weight: 232.175g/mol. IUPAC Name: tris(furan-2-yl)phosphane. Rotatable Bond Count: 3. Exact Mass: 232.029g/mol. SMILES: C1=COC(=C1)P(C2=CC=CO2)C3=CC=CO3. InChI: InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H. InChIKey: DLQYXUGCCKQSRJ-UHFFFAOYSA-N. H-Bond Acceptor: 3. Monoisotopic Mass: 232.029g/mol. | |
Tricyclohexylphosphine Quick inquiry Where to buy Suppliers range | Tricyclohexylphosphine. Uses: Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds. As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry. Group: Organic Phosphine Compounds. Alternative Names: (Cy)3P; I14-4059; MFCD00003853; CTK1A6004; NSC 158657; CS-0020124; AKOS015840835; J-016328; KS-00000US7; tricydohexyl phosphine. CAS No. 2622-14-2. Molecular formula: C18H33P. Mole weight: 280.436g/mol. IUPAC Name: tricyclohexylphosphane. Rotatable Bond Count: 3. Exact Mass: 280.232g/mol. EC Number: 220-069-2. SMILES: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. InChI: InChI=1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2. InChIKey: WLPUWLXVBWGYMZ-UHFFFAOYSA-N. Monoisotopic Mass: 280.232g/mol. |