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1,2,3,6-Tetrahydropyridine Hydrochloride is used in the synthetic preparation of efficient water soluble olefinmetathesis catalyst. Group: Biochemicals. Grades: Highly Purified. CAS No. 18513-79-6. Pack Sizes: 500mg, 1g. Molecular Formula: C5H9N HCl, Molecular Weight: 83.1336459999999. US Biological Life Sciences.
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro (o-isopropoxyphenyl methyl ene) ruthenium is a cross-metathesis catalyst used for installation of S-allylcysteine in proteins for enabling olefinmetathesis on proteins. Group: Biochemicals. Grades: Highly Purified. CAS No. 301224-40-8. Pack Sizes: 100mg, 500mg. Molecular Formula: C31H38Cl2N2ORu. US Biological Life Sciences.
Enhanced activity ruthenium "boomerang" pre-catalyst used in the olefinmetathesis, enyne metathesis, and cross metathesis reactions, that can be recycled, and leaves reduced ruthenium in the product after silica gel chromatography. Group: Ruthenium series catalysts. Alternative Names: 1212008-99-5; MFCD12545950; (1, 3-bis (2, 6-diisopropylphenyl) imidazolidin-2-yliden; e) (2-isopropoxy-5- (2, 2, 2-trifluoroacetamido) benzylidene) ruthenium (VI) chloride; [1, 3-Bis (2, 6-di-i-propylphenyl) -4, 5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5- (trifluoroacetamido) phenyl]methyleneruthenium (II) dichloride; [1, 3-Bis (2, 6-di-i-propylphenyl) -4, 5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5- (trifluoroacetamido) phenyl]methyleneruthenium (II) dichloride M71-S1Pr. CAS No. 1212008-99-5. Molecular formula: C39H50Cl2F3N3O2Ru. Mole weight: 821.813g/mol. IUPACName: [1, 3-bis[2, 6-di (propan-2-yl) phenyl]imidazolidin-2-ylidene]-dichloro-[[2-propan-2-yloxy-5-[ (2, 2, 2-trifluoroacetyl) amino]phenyl]methylidene]ruthenium. Canonical SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N2CCN (C2=[Ru] (=CC3=C (C=CC (=C3)NC (=O)C (F) (F)F)OC (C)C) (Cl)Cl)C4=C (C=CC=C4C (C)C)C (C)C. Catalog: ACM1212008995.
[1, 3-Bis (2, 6-di-i-propylphenyl)imidazolidin-2-ylidene]{2-[[1- (methoxy (methyl)amino)-1-oxopropan-2-yl]oxy]benzylidene}ruthenium (II) dichloride greencat
Efficient, durable and reuseable olefinmetathesis catalyst with a high affinity to silica gel. Group: Ruthenium catalysts. Alternative Names: [1, 3-Bis[2, 6-di (propan-2-yl)phenyl]imidazolidin-2-ylidene]-dichloro-[[2-[1-[methoxy (methyl)amino]-1-oxopropan-2-yl]oxyphenyl]methylidene]ruthenium. CAS No. 1448663-06-6. Molecular formula: C39H53Cl2N3O3Ru. Mole weight: 783.33. Appearance: Green powder. Canonical SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N2CCN (C2=[Ru] (=CC3=CC=CC=C3OC (C)C (=O)N (C)OC) (Cl)Cl)C4=C (C=CC=C4C (C)C)C (C)C. Catalog: ACM1448663066-1.
1,5-Cyclooctadiene
1,5-Cyclooctadiene is used as an intermediate to prepare highly active ruthenium catalysts for olefinmetathesis. Group: Biochemicals. Grades: Highly Purified. CAS No. 111-78-4. Pack Sizes: 1g, 10g. Molecular Formula: C8H12. US Biological Life Sciences.
Worldwide
1-Bromo-2-naphthaldehyde
1-Bromo-2-naphthaldehyde is used as a reagent in the synthesis of Hoveyda-Grubbs type metathesis catalysts which are used in cross olefinmetathesis. 1-Bromo-2-naphthaldehyde is also used in the preparation of novel (-)-cercosporamide derivatives as potent selective PPARγ modulators. Group: Biochemicals. Grades: Highly Purified. CAS No. 3378-82-3. Pack Sizes: 250mg, 1g. Molecular Formula: C11H7BrO, Molecular Weight: 235.08. US Biological Life Sciences.
Unlike Mo(C10H12)(C12H17N)(OC4H9)2, the bis(hexafluoro-t-butoxide) (MoF6) derivative will metathesize many ordinary olefins, especially terminal olefins, and will ROMP many norbornene or substituted norbornadiene monomers to give all cis, and often isotactic, polymers. Useful for the "ring-closing" of dienes or the coupling of terminal olefins. Useful for cross-metathesis of alphatic alkenes with 2-vinyl aromatics. Group: Heterocyclic organic compound. Alternative Names: SREMDTDVHCUUIZ-UHFFFAOYSA-N; SCHROCK'S CATALYST; SCHEMBL1634829; SC10923; MFCD00269857. CAS No. 139220-25-0. Molecular formula: C30H37F12MoNO2. Mole weight: 767.562g/mol. IUPACName: [2, 6-di(propan-2-yl)phenyl]imino-(2-methyl-2-phenylpropylidene)molybdenum;1, 1, 1, 3, 3, 3-hexafluoro-2-methylpropan-2-ol. Canonical SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N=[Mo]=CC (C) (C)C2=CC=CC=C2. CC (C (F) (F)F) (C (F) (F)F)O. CC (C (F) (F)F) (C (F) (F)F)O. Catalog: ACM139220250.
Fmoc-(R)-2-(7-octenyl)Ala-OH
Olefinic alpha-methyl amino acid for peptide stapling. Upon incorporation of this amino acid into a peptide, along with another of the same or derivative with a different length of the olefinic side chain, the two can be 'stapled' via a ring closing metathesis reaction with Grubb's catalyst (product # 579726). The resulting stapled peptide macrocycle has been shown to stabilize the alpha-helical structure of peptides, which can lead to favorable biological characteristics such as increased proteolytic stability and cellular uptake. Group: Amino acids. Alternative Names: (R)-N-Fmoc-α-(7-Octenyl)alanine, Fmoc-(R)-2-(7-octenyl)alanine, Fmoc-(R)-2-amino-2-methyl-dec-6-enoic acid. CAS No. 945212-26-0. Molecular formula: C26H31NO4. Mole weight: 421.53. Canonical SMILES: O=C (OCC1C (C=CC=C2)=C2C3=C1C=CC=C3)N[C@@] (CCCCCCC=C) (C)C (O)=O. Catalog: ACM945212260.
Grubbs Catalyst, 2nd Generation
Grubbs Catalyst, 2nd Generation is a ruthenium-based olefinmetathesis catalyst. Group: Biochemicals. Grades: Highly Purified. CAS No. 246047-72-3. Pack Sizes: 250mg, 500 mg. Molecular Formula: C46H65Cl2N2PRu. US Biological Life Sciences.
Worldwide
Nitro-grela
Nitro-grela. Uses: This catalyst is used for an efficient synthesis of hcv protease inhibitor, biln 2061. the nitro-grela catalyst is a stable olefinmetathesis initiator active in various ring-closing, cross, and enyne metathesis reactions. its efficiency has been proven in numerous total syntheses of natural and biologically active compounds, and in material science. Group: Polymerization catalystspolymerization reagents. Alternative Names: [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[(2-isopropoxy-5-nitrobenzylidene)]ruthenium(II). CAS No. 502964-52-5. Product ID: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(5-nitro-2-propan-2-yloxyphenyl)methylidene]ruthenium. Molecular formula: 671.63. Mole weight: C31H37Cl2N3O3Ru. CC1=CC (=C (C (=C1)C)N2CCN (C2=[Ru] (=CC3=C (C=CC (=C3)[N+] (=O)[O-])OC (C)C) (Cl)Cl)C4=C (C=C (C=C4C)C)C)C. InChI=1S/C21H26N2. C10H11NO3. 2ClH. Ru/c1-14-9-16 (3)20 (17 (4)10-14)22-7-8-23 (13-22)21-18 (5)11-15 (2)12-19 (21)6; 1-7 (2)14-10-5-4-9 (11 (12)13)6-8 (10)3; /h9-12H, 7-8H2, 1-6H3; 3-7H, 1-2H3; 2*1H; /q; +2/p-2. RQQSRSPQJIAORC-UHFFFAOYSA-L. 97%+.
Nitro-grela
This catalyst is used for an efficient synthesis of HCV Protease Inhibitor, BILN 2061. The nitro-Grela catalyst is a stable olefinmetathesis initiator active in various ring-closing, cross, and enyne metathesis reactions. Its efficiency has been proven in numerous total syntheses of natural and biologically active compounds, and in material science. Group: Olefinmetathesisruthenium catalysts. Alternative Names: [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[(2-isopropoxy-5-nitrobenzylidene)]ruthenium(II). CAS No. 502964-52-5. Molecular formula: C31H37Cl2N3O3Ru. Mole weight: 671.63. Appearance: Green to dark green powder to crystal. Purity: 97%+. IUPACName: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(5-nitro-2-propan-2-yloxyphenyl)methylidene]ruthenium. Canonical SMILES: CC1=CC (=C (C (=C1)C)N2CCN (C2=[Ru] (=CC3=C (C=CC (=C3)[N+] (=O)[O-])OC (C)C) (Cl)Cl)C4=C (C=C (C=C4C)C)C)C. Catalog: ACM502964525-1.
Tricyclohexylphosphine
Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds. As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefinmetathesis in synthetic organic chemistry. Group: Promotional products. Alternative Names: Phosphine, tricyclohexyl-. CAS No. 2622-14-2. Molecular formula: C18H33P. Mole weight: 280.44. Appearance: liquid. Purity: 95+%. IUPACName: tricyclohexylphosphane. Canonical SMILES: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. ECNumber: 220-069-2. Catalog: ACM2622142-2.
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