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Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes Synthetic pyrethriods: catalyst for the Negishi coupling of (2, 2-dihaloethenyl) cyclopropanecarboxylates. Group: Palladium series catalysts. Alternative Names: Dichloro[bis (1, 4-diphenylphosphino)butane]palladium (II). CAS No. 29964-62-3. Molecular formula: C28H28Cl2P2Pd. Mole weight: 603.8. Appearance: White like powder. Purity: 0.99. IUPACName: dichloropalladium; 4-diphenylphosphanylbutyl (diphenyl)phosphane. Canonical SMILES: C1=CC=C (C=C1) P (CCCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Pd]Cl. Catalog: ACM29964623-1.
A new, air and moisture-stable, palladium catalyst useful in a broad scope of C-C and C-N coupling reactions. The highlyactive catalyst can tolerate substrates containing a wide variety of functional groups such as alkyls, alkoxides, ketones, aldehydes, esters, amines, trifluoromethyl and nitro groups. Group: Heterocyclic organic compound. Alternative Names: MFCD03427335; YMZCYRNVJBOOCT-MUGRSZJDSA-M; chloro[2'-(dimethylamino)-2-biphenylyl]palladium (1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1]hept-2-yl]phosphane; 2'-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex, >=99.0% (C); chloro[2'-(dimethylamino)-2-biphenylyl]palladium 1(1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1 ]hept-2-yl]phosphane; 2 inverted exclamation marka-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex; chloro[2'-(dimethylamino)-2-biphenylyl]palladium 1(1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1]hept-2-yl]phosphane. CAS No. 359803-53-5. Molecular formula: C28H37ClNPPd. Mole weight: 560.455g/mol. IUPACName: [(1S, 4R)-2-bicyclo[2. 2. 1]heptanyl]-[(1R, 4S)-2-bicyclo[2. 2. 1]heptanyl]phosphane; chloropalladium(1+); N, N-dimethyl-2-phenylaniline. Canonical SMILES: CN(C)C1=CC=CC=C1C2=CC=CC=[C-]2. C1CC2CC1CC2PC3CC4CCC3C4. Cl[Pd+]. Catalog: ACM359803535.
(2-Methylallyl)palladium(II) chloride dimer
Catalyst for: &bull Asymmetric allylic alkylation reactions &bull Suzuki-Miyaura reactions &bull Reductive cleavage reactions &bull Reaction of alkenyloxiranes with carbon monoxide. Group: Palladium series catalysts. Alternative Names: Chloro(2-methylallyl)palladium(II) dimer. CAS No. 12081-18-4. Molecular formula: [CH2=C(CH3)CH2PdCl]2. Mole weight: 393.94. Appearance: yellow powder. Purity: 0.99. IUPACName: dichloropalladium; 2-methanidylprop-1-ene; palladium(2+). Catalog: ACM12081184.
Allylpalladium(II) chloride dimer
Precatalyst for the enantioselective hydrosilylation of olefins. Precatalyst for asymmetric allylic alkylation and amination. Used as a palladium source for cross-coupling reactions. Can be used with Trost ligands. Catalyst for the carbostannylation of alkynes. Used as a precatalyst for "-arylation of aldehydes. Group: Palladium series catalysts. Alternative Names: Di-mu-chlorodi-pi-allyldipalladium; NSC 151255; Bis(pi-allylpalladiumchloride) (VAN); MFCD00044874 (95%); Bis(mu-chloro)bis(eta3-2-propenyl)dipalladium; AK327212; 12012-95-2; Palladium, di-pi-allyldi-mu-chlorodi- (8CI); Bis((eta3-allyl)(chloro)palladium); SC10406. CAS No. 12012-95-2. Molecular formula: C6H10Cl2Pd2. Mole weight: 365.886g/mol. IUPACName: chloropalladium(1+);prop-1-ene. Canonical SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]. ECNumber: 234-579-8. Catalog: ACM12012952.
Benzylbis (triphenylphosphine) palladium (II) Chloride
Benzylbis (triphenylphosphine) palladium (II) Chloride. Group: Biochemicals. Alternative Names: Benzyl (chloro) bis (triphenylphosphine) palladium (II) . Grades: Highly Purified. CAS No. 22784-59-4. Pack Sizes: 100mg, 250mg, 500mg, 1g, 2g. US Biological Life Sciences.
Worldwide
Bis(acetonitrile)palladium(II) Dichloride
Bis(acetonitrile)palladium(II) Dichloride. Uses: Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. catalyst for the aza-michael reaction of carbamates with enones. catalyst for the rearrangement of allylic imidates to allylic amides. catalyst for the nazarov cyclization of α-alkoxy dienones. catalyst for the diamination of conjugated dienes. three component michael addition, cyclization, cross-coupling reaction. c-h activation of indoles. catalyst used for the direct c-h arylation of isoxazoles at the 5 position. Group: Salt. Alternative Names: Palladium(II) chloride diacetonitrile complex. CAS No. 14592-56-4. Product ID: acetonitrile; palladium(2+); dichloride. Molecular formula: 259.43. Mole weight: C4H6Cl2N2Pd. CC#N.CC#N.[Cl-].[Cl-].[Pd+2]. RBYGDVHOECIAFC-UHFFFAOYSA-L. 99%,Pd >41.
Bis(acetonitrile)palladium(II) Dichloride
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. Catalyst for the aza-Michael reaction of carbamates with enones. Catalyst for the rearrangement of allylic imidates to allylic amides. Catalyst for the Nazarov cyclization of α-alkoxy dienones. Catalyst for the diamination of conjugated dienes. Three component Michael addition, cyclization, cross-coupling reaction. C-H activation of indoles. Catalyst used for the direct C-H arylation of isoxazoles at the 5 position. Group: Palladium series catalysts. Alternative Names: Palladium(II) chloride diacetonitrile complex. CAS No. 14592-56-4. Molecular formula: C4H6Cl2N2Pd. Mole weight: 259.43. Appearance: orange powder. Purity: 99%,Pd >41. IUPACName: acetonitrile; palladium(2+); dichloride. Canonical SMILES: CC#N.CC#N.[Cl-].[Cl-].[Pd+2]. Catalog: ACM14592564.
Bis (Benzonitrile) palladium (II) chloride
Bis (Benzonitrile) palladium (II) chloride. Group: Biochemicals. Alternative Names: Palladium(II) chloride bis(benzonitrile) complex. Grades: Highly Purified. CAS No. 14220-64-5. Pack Sizes: 500mg, 1g, 2g, 5g. US Biological Life Sciences.
Worldwide
Bis (Benzonitrile) palladium (II) chloride ≥95%, (26% Palladium content)
Bis (Benzonitrile) palladium (II) chloride ≥95%, (26% Palladium content). Group: Biochemicals. Grades: Reagent Grade. CAS No. 14220-64-5. Pack Sizes: 1g, 5g. US Biological Life Sciences.
Worldwide
Bis(benzonitrile)palladium(II) Dichloride
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. Catalyst for the aza-Michael reaction of carbamates with enones. Catalyst for the rearrangement of allylic imidates to allylic amides. Catalyst for the Nazarov cyclization of α-alkoxy dienones. Catalyst for the diamination of conjugated dienes. Three component Michael addition, cyclization, cross-coupling reaction. C-H activation of indoles. Group: Palladium series catalysts. Alternative Names: ST24046185; bis(benzonitrile)-palladium(II) chloride; J-007619; bis(chloranyl)palladium; MFCD00013123 (95+%); SCHEMBL63930; Bis(phenylnitrile)dichloropalladium; NSC635160; PdCl2(PhCN)2; bis(benzonitrile)dichloro-palladium (II). CAS No. 14220-64-5. Molecular formula: C14H10Cl2N2Pd. Mole weight: 383.568g/mol. IUPACName: benzonitrile;dichloropalladium. Canonical SMILES: C1=CC=C(C=C1)C#N. C1=CC=C(C=C1)C#N. Cl[Pd]Cl. ECNumber: 238-085-3. Catalog: ACM14220645.
Bis (ethylenediamine) palladium (II) chloride
Bis (ethylenediamine) palladium (II) chloride. Group: Biochemicals. Alternative Names: Bis (ethylenediamine) dichloropalladium (II) . Grades: Highly Purified. CAS No. 13963-53-6. Pack Sizes: 250mg, 500mg, 1g. US Biological Life Sciences.
Worldwide
Bis(tri-o-tolylphosphine)palladium(II) Dichloride
Coupling reaction of aryl bromides with vinylic acetates. Group: Palladium series catalysts. Alternative Names: 5531AB; SC10409; MFCD00274659 (98%); dichlorobis(tri-o-tolyl-phosphine)palladium(II); dichlorobis(tri-O-tolylphosphine)-palladium (II); DICHLOROBIS(TRI-ORTHO-TOLYLPHOSPHINE)PALLADIUM(II); FT-0696077; bis[tri(ortho-tolyl)phosphine] palladiumchloride; Dichlorobis(tri-o-tolylphosphine)palladium; AK-76768. CAS No. 40691-33-6. Molecular formula: C42H42Cl2P2Pd. Mole weight: 786.066g/mol. IUPACName: dichloropalladium;tris(2-methylphenyl)phosphane. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. Cl[Pd]Cl. Catalog: ACM40691336.
Bis(triphenylphosphine)palladium(II) Dichloride
Bis(triphenylphosphine)palladium(II) Dichloride. Uses: Precatalyst for the carbonylative cyclization of malonate derivatives. catalyst used in the double allylation of activated olefins. precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans. precatalyst for the homocoupling of terminal alkynes. precatalyst in the cross-coupling of alkynylsilanols and aryl halides. catalyst for direct pd-catalyzed alkynylation of n-fused heterocycles. catalyst for a tandem heck reaction/c-h functionalization. catalyst for direct arylation of tautomerizable heterocycles. Group: Salt. Alternative Names: TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(II) dichloride; bis(triphenylphosphine) palladium (II) chloride; FC0823; EINECS 237-744-2. CAS No. 13965-03-2. Product ID: palladium(2+); triphenylphosphane; dichloride. Molecular formula: 701.904g/mol. Mole weight: C36H30Cl2P2Pd. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Cl-]. [Pd+2]. InChI=1S/2C18H15P. 2ClH. Pd/c2*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; ; ; /h2*1-15H; 2*1H; /q; ; ; ; +2/p-2. YNHIGQDRGKUECZ-UHFFFAOYSA-L.
Bis(triphenylphosphine)palladium(II) Dichloride
Precatalyst for the carbonylative cyclization of malonate derivatives. Catalyst used in the double allylation of activated olefins. Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans. Precatalyst for the homocoupling of terminal alkynes. Precatalyst in the cross-coupling of alkynylsilanols and aryl halides. Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles. Catalyst for a tandem Heck reaction/C-H functionalization. Catalyst for direct arylation of tautomerizable heterocycles. Group: Palladium series catalysts. Alternative Names: TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(II) dichloride; bis(triphenylphosphine) palladium (II) chloride; FC0823; EINECS 237-744-2. CAS No. 13965-03-2. Molecular formula: C36H30Cl2P2Pd. Mole weight: 701.904g/mol. IUPACName: palladium(2+); triphenylphosphane; dichloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Cl-]. [Pd+2]. ECNumber: 237-744-2. Catalog: ACM13965032.
Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common starting material in palladium chemistry - palladium-based catalysts are of particular value in organic synthesis. It is prepared by chlorination of palladium. Uses: C-h activation; carbonylation; cross coupling reactions with arenes→mizoroki heck coupling reaction; oxidation. Group: Electrolytes. Alternative Names: Palladiumchloride (PdCl2); dichloropalladium; Palladium(II) Chloride. CAS No. 7647-10-1. Product ID: dichloropalladium. Molecular formula: 177.31. Mole weight: Cl2Pd. Cl[Pd]Cl. InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2. PIBWKRNGBLPSSY-UHFFFAOYSA-L. Metal purity 99.95.
Palladium(II) chloride
Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common starting material in palladium chemistry - palladium-based catalysts are of particular value in organic synthesis. It is prepared by chlorination of palladium. Uses: C-h activation; carbonylation; cross coupling reactions with arenes→mizoroki heck coupling reaction; oxidation. Group: Metal & ceramic materials. Alternative Names: Palladiumchloride (PdCl2); dichloropalladium; Palladium(II) Chloride. CAS No. 7647-10-1. Molecular formula: Cl2Pd. Mole weight: 177.31. Appearance: Dark brown powder. Purity: Metal purity 99.95. IUPACName: dichloropalladium. Canonical SMILES: Cl[Pd]Cl. Density: 4. ECNumber: 231-596-2. Catalog: ACM7647101-3.
Palladium(II)(π-cinnamyl) Chloride Dimer
Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds. Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides. Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols. Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes. Group: Palladium series catalysts. Alternative Names: 12131-44-1;Palladium(|Eth-cinnamyl) chloride dimer;AK136149;PALLADIUM(PI-CINNAMYL) CHLORIDE DIMER;Di- -chlorobis[(1,2,3- )-1-phenyl-2-propen-1-yl]dipalladium;Di-|I-chlorobis[(1,2,3-|C)-1-phenyl-2-propen-1-yl]dipalladium;Di-|I-chlorobis[(1,2,3-|C)-1-phenyl-2-propenyl]dipalladium(II);Di-mu-chlorobis[(1,2,3-eta)-1-phenyl-2-propen-1-yl]dipalladium. CAS No. 12131-44-1. Molecular formula: C18H18Cl2Pd2. Mole weight: 518.082g/mol. IUPACName: palladium(2+);prop-2-enylbenzene;dichloride. Canonical SMILES: C=C[CH-]C1=CC=CC=C1. C=C[CH-]C1=CC=CC=C1. [Cl-]. [Cl-]. [Pd+2]. [Pd+2]. Catalog: ACM12131441.
Allyl[1, 3-bis (2, 6-diisopropylphenyl) -2-imidazolidinylidene]chloropalladium (II)
Catalyst for the cross-coupling of aryl chlorides or bromides with aromatic amines. Catalyst for the α-arylation of ketones. Catalyst for anaerobic alcohol oxidation. Group: Heterocyclic organic compound. Alternative Names: ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM (II); Allylchloro[1, 3-bis (2, 6-di-i-propylphenyl)-4, 5-dihydroimidazol-2-ylidene]palladium (II), 97%; ALLYLCHLORO[1, 3-BIS- (DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM (II). CAS No. 478980-01-7. Molecular formula: C30H43ClN2Pd. Mole weight: 573.55. Purity: 0.96. IUPACName: Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylide. Catalog: ACM478980017.
Ammonium tetrachloropalladate (II)
Ammonium tetrachloropalladate (II). Group: Biochemicals. Alternative Names: Palladium(II)-ammonium chloride. Grades: Highly Purified. CAS No. 13820-40-1. Pack Sizes: 1g, 2g, 5g, 10g, 25g. Molecular Formula: (NH4)2PdCl4. US Biological Life Sciences.
Worldwide
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- [bis (4-fluorophenyl] phosphino] ferrocenyl] ethyldi-tert-butylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (bis (4-fluorophenyl) phosphinoferrocenyl]ethyl (di-t-butylphosphine) }nickel (II) is used for: 1.Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. 4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-37-3. Mole weight: 774.69. Catalog: ACM2049086373.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldiphenylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyl (diphenylphosphine)}nickel(II) is useful in these fields: Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-36-2. Mole weight: 790.79. Catalog: ACM2049086362.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II)
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II) has the following various uses:1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-34-0. Mole weight: 738.71. Catalog: ACM2049086340.
Dichlorobis (triphenylphosphine) Palladium (II)
Dichlorobis (triphenylphosphine) Palladium (II) is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of metallacyclic complexes which show antiinflammatory and antifungal properties. Group: Biochemicals. Alternative Names: Bis (triphenylphosphine) dichloropalladium; Bis (triphenylphosphine) palladiumChloride; Bis (triphenylphosphine) palladium Dichloride; Bis (triphenylphosphine) palladium (II) Chloride; Bis (triphenylphosphine) palladium (II) Dichloride; Bis (triphenylphosphino) palladiumChloride; Dichlorobis (triphenylphosphine) palladium; Dichlorobis (triphenylphosphine) palladium (II) ; NSC 122924; Palladiumbis (triphenylphosphine) Dichloride. Grades: Highly Purified. CAS No. 13965-03-2. Pack Sizes: 2.5g. US Biological Life Sciences.
Worldwide
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products. Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals. Group: Palladium series catalysts. Alternative Names: ST24050377; 5353AA; DICHLORO[2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II); 115826-95-4; [(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM (II) CHLORIDE; FT-0696081; MFCD00075254; C44H32Cl2P2Pd; EBD2199625; PALLADIUM, [1, 1'-(1R)-[1, 1'-BINAPHTHALENE]-2, 2'-DIYLBIS[1, 1-DIPHENYLPHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)-. CAS No. 127593-28-6. Molecular formula: C44H32Cl2P2Pd. Mole weight: 800.008g/mol. IUPACName: dichloropalladium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Pd]Cl. Catalog: ACM127593286.
Methanesulfonato{ (R) - (-) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyldi-t-butylphosphine} (2'-amino-1, 1'-biphenyl-2-yl) palladium (II) , min. 98% [Josiphos Palladacycle Gen. 3]
Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides. Group: Organic phosphine compounds. Alternative Names: Bruno Palladacycle;Josiphos SL-J009-1 Pd G3;MFCD27978424;Josiphos SL-J009-2-G3-palladacycle, AldrichCPR; 1702311-34-9; Methanesulfonato[ (R) - (-) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyldi-t-butylphosphine] (2'-amino-1, 1'-biphenyl-2-yl) palladium (II). CAS No. 1702311-34-9. Molecular formula: C45H66FeNO3P2PdS-. Mole weight: 925.3g/mol. IUPACName: cyclopentane; ditert-butyl-[ (1S) -1- (2-dicyclohexylphosphanylcyclopentyl) ethyl]phosphane; iron; methanesulfonic acid;palladium;2-phenylaniline. Canonical SMILES: CC ([C]1[CH][CH][CH][C]1P (C2CCCCC2)C3CCCCC3)P (C (C) (C)C)C (C) (C)C. CS (=O) (=O)O. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. [CH]1[CH][CH][CH][CH]1. [Fe]. [Pd]. Catalog: ACM1702311349.
N,N'-[Bis(2,6-dimethylphenyl)-1,3-dimethyl-1,3-propanediylidene](methyl) (triethylphosphine)palladium(II), min. 97%
Catalyst used in the general method for the Heck and Buchwald-Hartwig coupling reactions of aryl chlorides. Extremely active and general catalyst for the Suzuki coupling reaction of unreactive aryl chlorides. Group: Palladium catalysts. Alternative Names: 1224879-40-6;N,N'-[Bis(2,6-dimethylphenyl)-1,3-dimethyl-1,3-propanediylidene](methyl) (triethylphosphine)palladium(II); MFCD22666041. CAS No. 1224879-40-6. Molecular formula: C28H44N2PPd+. Mole weight: 546.068g/mol. IUPACName: carbanide; (2, 6-dimethylphenyl)-[(Z)-4-(2, 6-dimethylphenyl)iminopent-2-en-2-yl]azanide; palladium(2+); triethylphosphanium. Canonical SMILES: [CH3-]. CC[PH+] (CC)CC. CC1=C (C (=CC=C1)C)[N-]C (=CC (=NC2=C (C=CC=C2C)C)C)C. [Pd+2]. Catalog: ACM1224879406.
Potassium tetrachloropalladate (II)
Potassium tetrachloropalladate (II). Group: Biochemicals. Alternative Names: Potassium palladium(II) chloride. Grades: Highly Purified. CAS No. 10025-98-6. Pack Sizes: 1g, 2g, 5g. US Biological Life Sciences.
Worldwide
[RuCl(p-cymene)((S)-tolbinap)]Cl
1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C
RuPhos Pd G2
Palladium precatalyst for fast Suzuki-Miyaura coupling reactions. Group: Palladium series catalysts. Alternative Names: Cerium(III) chloride, anhydrous. CAS No. 1375325-68-0. Molecular formula: C42H53ClNO2PPd. Mole weight: 776.73. Appearance: Powder. Purity: 0.98. Catalog: ACM1375325680-2.
Sensitizer
Sensitizer. Uses: Tetraamminepalladium(II) chloride monohydrate is used to prepare trans-diamminedichloropalladium(II). it is also utilized in the preparation of mesoporous carbon supporting palladium nanoparticles by using graphite oxide. it is used as catalysts, reagents, and analytical reagents. Group: Salt. Alternative Names: Tetraamminepalladium(II) chloride monohydrate; KS-00000H5G; AKOS027250697; chloride hydrate; MFCD00151033; Palladium(2+), tetraammine-, dichloride, monohydrate, (SP-4-1)- (9CI); TETRAAMMINEPALLADIUM (II) CHLORIDE; Sensitizer; ST24050111. CAS No. 13933-31-8. Product ID: azane; dichloropalladium; hydrate. Molecular formula: 263.459g/mol. Mole weight: Cl2H14N4OPd. N.N.N.N.O.Cl[Pd]Cl. InChI=1S/2ClH.4H3N.H2O.Pd/h2*1H; 4*1H3; 1H2; /q; ; ; ; ; ; ; +2/p-2. WVCXSPJPERKPJS-UHFFFAOYSA-L.
Sensitizer
Tetraamminepalladium(II) chloride monohydrate is used to prepare trans-diamminedichloropalladium(II). It is also utilized in the preparation of mesoporous carbon supporting palladium nanoparticles by using graphite oxide. It is used as catalysts, reagents, and analytical reagents. Group: Metal & ceramic materials. Alternative Names: Tetraamminepalladium(II) chloride monohydrate; KS-00000H5G; AKOS027250697; chloride hydrate; MFCD00151033; Palladium(2+), tetraammine-, dichloride, monohydrate, (SP-4-1)- (9CI); TETRAAMMINEPALLADIUM (II) CHLORIDE; Sensitizer; ST24050111. CAS No. 13933-31-8. Molecular formula: Cl2H14N4OPd. Mole weight: 263.459g/mol. IUPACName: azane;dichloropalladium;hydrate. Canonical SMILES: N.N.N.N.O.Cl[Pd]Cl. Catalog: ACM13933318.
trans-Diamminedichloro palladium (II)
trans-Diamminedichloro palladium (II) . Group: Biochemicals. Alternative Names: Palladium(II) diammine chloride. Grades: Highly Purified. CAS No. 13782-33-7. Pack Sizes: 500mg, 1g, 2g, 5g. US Biological Life Sciences.
Worldwide
XPhos Pd G1
Catalyst for cross-coupling reactions of electron-deficient anilines with aryl chlorides. Catalyst for rapid C-N bond-forming process at low catalyst loading. Catalyst for C-N cross-coupling reactions, at or below room temperature. Catalyst for the synthesis of tetracyclic indoles via intermolecular α-arylation of ketones. Catalyst for the cross-coupling of benzyl chlorides with cyclopropanol-derived ketone homoenolates. Group: Palladium series catalysts. Alternative Names: (2-Dicyclohexylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-1,1 inverted exclamation marka-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II) chloride; XPhos precatalyst; J-520016; Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II); BP-21201; Chloro(2-dicyclohexylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-1,1 inverted exclamation marka-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II); (XPhos) palladium(II) phenethylamine chloride. CAS No. 1028206-56-5. Molecular formula: C41H59ClNPPd. Mole weight: 738.774g/mol. IUPACName: chloropalladium(1+); dicyclohexyl-[2-[2, 4, 6-tri(propan-2-yl)phenyl]phenyl]phosphane; 2-phenylethanamine. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=CC=CC=C2P (C3CCCCC3)C4CCCCC4)C (C)C. C1=CC=C ([C-]=C1)CCN. Cl[Pd+]. Catalog: ACM1028206565.
[1, 1'-Bis (di-cyclohexylphosphino) ferrocene]dichloropalladium (II)
1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides. Group: Palladium series catalysts. Alternative Names: PdCl2(dcypf). CAS No. 917511-90-1. Molecular formula: C34H52Cl2FeP2Pd. Mole weight: 755.9. Appearance: red crystalline powder. Purity: Pd >14.0%. IUPACName: dichloropalladium; dicyclohexyl(cyclopentyl)phosphane; iron. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. Cl[Pd]Cl. [Fe]. Catalog: ACM917511901.
Catalyst for the cross-coupling of aryl chlorides with boronic acids. Catalyst for the diamination of conjugated dienes and trienes. Catalyst for the dehalogenation of aryl chlorides. Catalyst for anaerobic alcohol oxidation. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. Group: Organic phosphine compounds. Alternative Names: Palladium, [1, ?3-bis [2, ?6-bis (1- methyl ethyl) ?phenyl] ?-1, ?3-dihydro-2H-imidazol-2-ylide ne ] ?chloro ( η 3-2-propen-1-yl) ?-. CAS No. 478980-03-9. Molecular formula: C30H42ClN2Pd. Mole weight: 572.54. Appearance: white solid. Purity: 98%, Pd>18.5%. Catalog: ACM478980039.
Bis (di-tert-butyl (4-dimethylaminophenyl) phosphine) dichloropalladium (II)
Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides. Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate. Group: Palladium series catalysts. Alternative Names: 4-Ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium. CAS No. 887919-35-9. Molecular formula: C32H56Cl2N2P2Pd. Mole weight: 708.1. Appearance: Powder. Purity: 0.98. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Cl[Pd]Cl. Catalog: ACM887919359-2.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl]palladium (II)
Catalyst used in the α-arylation of ketones. Catalyst used in the Suzuki cross-coupling of aryl chlorides with boronic acid-substituted benzofurans. Group: Palladium catalysts. CAS No. 1779569-06-0. Molecular formula: C46H64ClPPd. Mole weight: 789.85. Appearance: Orange powder. Catalog: ACM1779569060-1.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 6'-di-i-propoxy-1, 1'-biphenyl]palladium (II)
Catalyst used in the Buchwald-Hartwig cross-coupling of substituted aryl chlorides with secondary amines. Group: Palladium catalysts. CAS No. 1779569-08-2. Molecular formula: C43H58ClO2PPd. Mole weight: 779.77. Appearance: Orange powder. Catalog: ACM1779569082-1.
Extremely active palladium catalyst for Suzuki-Miyaura coupling of aryl chlorides. Group: Palladium catalysts. CAS No. 1905460-13-0. Molecular formula: C41H48ClN3Pd. Mole weight: 724.71. Appearance: Pale yellow powder. Purity: 0.97. Catalog: ACM1905460130-1.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldicyclohexylphosphine] nickel (II)
Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-35-1. Mole weight: 802.88. Catalog: ACM2049086351.
Methanesulfonato(tri-t-butylphosphino)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98% [P(t-Bu)3 Palladacycle Gen. 3]
Pd-catalyzed cross-coupling reaction of s-BuB(OH)2 and 4-chloroanisole. Pd-catalyzed cross-coupling reaction of secondary alkylboronic acids and aryl chlorides. Pd-catalyzed cross-coupling reaction of secondary alkyltrifluoroborates and aryl chlorides. Group: Palladium catalysts. CAS No. 1445086-17-8. Molecular formula: C25H40NO3PPdS. Mole weight: 572.05. Catalog: ACM1445086178.
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