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[1, 1'-Bis (di-cyclohexylphosphino) ferrocene]dichloropalladium (II)
1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides. Group: Palladium series catalysts. Alternative Names: PdCl2(dcypf). CAS No. 917511-90-1. Molecular formula: C34H52Cl2FeP2Pd. Mole weight: 755.9. Appearance: red crystalline powder. Purity: Pd >14.0%. IUPACName: dichloropalladium; dicyclohexyl(cyclopentyl)phosphane; iron. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. Cl[Pd]Cl. [Fe]. Catalog: ACM917511901.
Our company can provide customers with rich supported precious metal catalyst products such as palladium series, platinum series, rhodium series and ruthenium series. Our catalysts not only have high catalytic efficiency, strong selectivity, and recyclability, but also can be used in organic reactions such as hydrogenation, dehydrogenation, amination, and cyclization. In addition, some products can also be used as raw materials for various precious metal compounds. The company has formed a series of proprietary and characteristic process technologies, and is currently undergoing process improvement and upgrading. In short, our catalytic products can be widely used in medicine, new chemical materials, pesticides, dyes and pigments, environmental protection, new energy, electronics, basic chemicals and other fields. Uses: [1'1-bis (diphenylphosphino) ferrocene]dichloropalladium dichloromethane complex is used as the research compound. Group: Colloidal catalysts. CAS No. 95564-05-4. Mole weight: 816.64 g/mol. Appearance: Powder. Catalog: ACM95564054.
[1, 1'-Bis (di-tert-butylphosphino)ferrocene]palladium (II) Dichloride
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride is used as a catalyst for the preparation of chalcones. Group: Palladium series catalysts. Alternative Names: PdCl2(dtbpf). CAS No. 95408-45-0. Molecular formula: C26H44Cl2FeP2Pd. Mole weight: 651.75. Appearance: dark red crystals. Purity: Pd ≥16.3%. IUPACName: Dichloro[1, 1-Bis (di-Tert-Butylphosphino)Ferrocene]Palladium (II). Catalog: ACM95408450.
(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-i-Pr-DUPHOS-Rh
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination. Group: Heterocyclic organic compound. Alternative Names: 569650-64-2;1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R, R)-i-Pr-DUPHOS-Rh; DTXSID00514132; PUBCHEM_12964416; MFCD07369039; (+)-1, 2-Bis((2R, 5R)-2, 5-di-i-propylphospholano)benzene(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate; (+)-1, 2-Bis ( (2R, 5R)-2, 5-di-i-propylphospholano)benzene)1, 5-cyclooctadiene)rhodium (I)tetrafluoroborate. CAS No. 569650-64-2. Molecular formula: C34H56BF4P2Rh-. Mole weight: 716.479g/mol. IUPACName: (1Z, 5Z)-cycloocta
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination. Group: Rhodium series of catalysts. Alternative Names: 210057-23-1; MFCD01862466; 057B231; (-)-1, 2-Bis[ (2R, 5R)-dimethylphospholano]benzene (cyclooCtadiene)rhodium (I) tetrafluoroborate; 1, 2-Bis[ (2R, 5R)-2, 5-dimethylphospholano]benzene (cyclooctadiene)rhodium (I)tetrafluoroborate; (-)-1, 2-Bis ( (2R, 5R)-2, 5-dimethylphospholano)benzene (cyclooctadiene)rhodium (I) tetrafluoroborate; (-)-1, 2-Bis ( (2R, 5R)-2, 5-dimethylphospholano)benzene (cycloo. CAS No. 210057-23-1. Molecular formula: C26H40BF4P2Rh-. Mole weight: 604.263g/mol. IUPACName: cycloocta-1, 5-diene; (2R, 5
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination. Group: Rhodium series of catalysts. Alternative Names: (+)-1, 2-Bis ( (2S, 5S)-2, 5-dimethylphospholano)benzene (cyclooctadiene)Rh (I)tetrafluoroborate; (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane; MFCD01862467; 205064-10-4; AC1MC1E8. CAS No. 205064-10-4. Molecular formula: C26H40BF4P2Rh-. Mole weight: 604.263g/mol. IUPACName: cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-dimethylphospholan-1-yl]phenyl]-2, 5-dimethylphospholane; rhodium; tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. C1CC=C
[1, 2-Bis (diphenylphosphino) ethane]dichloropalladium (II)
Catalyst used for room temperature Suzuki-Miyaura couplings. Catalyst used for rapid, room temperature Buchwald-Hartwig and Suzuki-Miyaura coupling reactions. Group: Palladium series catalysts. Alternative Names: CX 31. CAS No. 884879-23-6. Molecular formula: C36H45ClN2Pd. Mole weight: 647.63. Appearance: yellow powder or crystals. Purity: 0.95. Catalog: ACM884879236-1.
(1, 3-Bis (diphenylphosphino)propane)palladium (II) chloride
Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes Synthetic pyrethriods: catalyst for the Negishi coupling of (2, 2-dihaloethenyl) cyclopropanecarboxylates. Group: Palladium series catalysts. Alternative Names: Dichloro[bis (1, 4-diphenylphosphino)butane]palladium (II). CAS No. 29964-62-3. Molecular formula: C28H28Cl2P2Pd. Mole weight: 603.8. Appearance: White like powder. Purity: 0.99. IUPACName: dichloropalladium; 4-diphenylphosphanylbutyl (diphenyl)phosphane. Canonical SMILES: C1=CC=C (C=C1) P (CCCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Pd]Cl. Catalog: ACM29964623-1.
Catalyst for: &bull Asymmetric allylic alkylation reactions &bull Suzuki-Miyaura reactions &bull Reductive cleavage reactions &bull Reaction of alkenyloxiranes with carbon monoxide. Group: Palladium series catalysts. Alternative Names: Chloro(2-methylallyl)palladium(II) dimer. CAS No. 12081-18-4. Molecular formula: [CH2=C(CH3)CH2PdCl]2. Mole weight: 393.94. Appearance: yellow powder. Purity: 0.99. IUPACName: dichloropalladium; 2-methanidylprop-1-ene; palladium(2+). Catalog: ACM12081184.
(2'-Methylamino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer, min. 98%
Dimeric palladium precursor, that when treated with phosphines at room temperature in dichloromethane, provides Nsubstituted precatalysts. These catalysts are useful in the aminocarbonylation of (hetero)aryl bromides, and general C-C and C-N cross-coupling reactions. Group: Palladiumcatalysts. Alternative Names: MFCD29037176;(2'-Methylamino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer;1581285-85-9. CAS No. 1581285-85-9. Molecular formula: C28H30N2O6Pd2S2. Mole weight: 767.516g/mol. IUPACName: methanesulfonic acid;methyl-(2-phenylphenyl)azanide;palladium(2+). Canonical SMILES: C[N-]C1=CC=CC=C1C2=CC=CC=[C-]2. C[N-]C1=CC=CC=C1C2=CC=CC=[C-]2. CS(=O)(=O)O. CS(=O)(=O)O. [Pd+2]. [Pd+2]. Catalog: ACM1581285859.
2- (Trifluoromethyl) phenyl trifluoromethane sulfonate is used in the green synthetic preparation of N-aryl sulfonamides under mild reaction conditions with palladium nanoparticles as reusable catalysts. Group: Biochemicals. Grades: Highly Purified. CAS No. 199188-29-9. Pack Sizes: 250mg, 1g. Molecular Formula: C8H4F6O3S, Molecular Weight: 294.17. US Biological Life Sciences.
4- (Vinyloxymethyl) cyclohexanemethanol is used as a reagent in the synthesis of acetic acid esters by catalytic oxidation of vinyl ethers with aqueous H2O2 solutions in the presence of palladiumcatalysts having phosphine ligands and amines. Also used in the synthesis of Si-containing monomers and 4-substituted cyclohexane carbaldehydes. Group: Biochemicals. Grades: Highly Purified. CAS No. 114651-37-5. Pack Sizes: 1g, 10g. Molecular Formula: C10H18O2, Molecular Weight: 170.25. US Biological Life Sciences.
Worldwide
8-(Di-tert-butylphosphinooxy)quinoline
PalladiumCatalysts. CAS No. 1100332-44-2. Mole weight: 289.35. Catalog: ACM1100332442.
This dimeric palladium complex is used in the chemoselective oxidation of polyols. Group: Palladiumcatalysts. Alternative Names: MFCD28411662;Acetato(2,9-dimethyl-1,10-phenanthroline)palladium(II) dimer bis(trifluoromethanesulfonate); 959698-19-2. CAS No. 959698-19-2. Molecular formula: C32H30N4O4Pd2+2. Mole weight: 747.456g/mol. IUPACName: 2, 9-dimethyl-1, 10-phenanthroline; palladium(2+); diacetate. Canonical SMILES: CC1=NC2=C(C=C1)C=CC3=C2N=C(C=C3)C. CC1=NC2=C(C=C1)C=CC3=C2N=C(C=C3)C. CC(=O)[O-]. CC(=O)[O-]. [Pd+2]. [Pd+2]. Catalog: ACM959698192.
Allyldiphenylphosphine
Cocatalyst in palladium catalyzed hydrocarboxylation reactions. Cocatalyst in Palladium catalyzed cross-coupling reactions. Ligand for hydroformylation catalysts. Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions. Catalyst precursor for alkene hydroboration. Group: Organic phosphine compounds. Alternative Names: Diphenyl-2-propenylphosphine. CAS No. 2741-38-0. Molecular formula: C15H15P. Mole weight: 226.25. Appearance: Liquid. Purity: 98%+. IUPACName: diphenyl(prop-2-enyl)phosphane. Canonical SMILES: C=CCP(C1=CC=CC=C1)C2=CC=CC=C2. Density: 1.049 g/mL at 25 °C (lit.). Catalog: ACM2741380-1.
Allylpalladium(II) chloride dimer
Precatalyst for the enantioselective hydrosilylation of olefins. Precatalyst for asymmetric allylic alkylation and amination. Used as a palladium source for cross-coupling reactions. Can be used with Trost ligands. Catalyst for the carbostannylation of alkynes. Used as a precatalyst for "-arylation of aldehydes. Group: Palladium series catalysts. Alternative Names: Di-mu-chlorodi-pi-allyldipalladium; NSC 151255; Bis(pi-allylpalladium chloride) (VAN); MFCD00044874 (95%); Bis(mu-chloro)bis(eta3-2-propenyl)dipalladium; AK327212; 12012-95-2; Palladium, di-pi-allyldi-mu-chlorodi- (8CI); Bis((eta3-allyl)(chloro)palladium); SC10406. CAS No. 12012-95-2. Molecular formula: C6H10Cl2Pd2. Mole weight: 365.886g/mol. IUPACName: chloropalladium(1+);prop-1-ene. Canonical SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]. ECNumber: 234-579-8. Catalog: ACM12012952.
Dichloro(norbornadiene)palladium(II) can be useful starting material for the in situ preparation of a variety of chiral and achiral palladiumcatalysts. Group: Palladium series catalysts. Alternative Names: TR-003664; (Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II), 98%; 2,5-Norbornadiene Palladium(II) Dichloride; SCHEMBL530639; CTK8A9533; NSC 176915; SC10472; AKOS015833821. CAS No. 12317-46-3. Molecular formula: C7H8Cl2Pd. Mole weight: 269.461g/mol. IUPACName: bicyclo[2.2.1]hepta-2,5-diene;dichloropalladium. Canonical SMILES: C1C2C=CC1C=C2.Cl[Pd]Cl. ECNumber: 235-583-2. Catalog: ACM12317463.
Ligand for the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides Ligand for the Palladium-Catalyzed Fluorination of Aryl Triflates and Bromides. Group: Palladiumcatalysts. CAS No. 1805783-51-0. Mole weight: 1951.13. Catalog: ACM1805783510.
Bis (3, 5, 3', 5'-dimethoxydibenzylideneacetone) palladium (0)
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. Catalyst for the aza-Michael reaction of carbamates with enones. Catalyst for the rearrangement of allylic imidates to allylic amides. Catalyst for the Nazarov cyclization of α-alkoxy dienones. Catalyst for the diamination of conjugated dienes. Three component Michael addition, cyclization, cross-coupling reaction. C-H activation of indoles. Catalyst used for the direct C-H arylation of isoxazoles at the 5 position. Group: Palladium series catalysts. Alternative Names: Palladium(II) chloride diacetonitrile complex. CAS No. 14592-56-4. Molecular formula: C4H6Cl2N2Pd. Mole weight: 259.43. Appearance: orange powder. Purity: 99%,Pd >41. IUPACName: acetonitrile; palladium(2+); dichloride. Canonical SMILES: CC#N.CC#N.[Cl-].[Cl-].[Pd+2]. Catalog: ACM14592564.
Newly developed Pd catalyst for the enantioselective intermolecular Heck reaction of tri-substituted alkenyl alcohols with aryl boronic acids. Group: Palladiumcatalysts. Alternative Names: MFCD28167054; Bis(acetonitrile)palladium(II) p-toluenesulfonate, 98%;114757-66-3. CAS No. 114757-66-3. Molecular formula: C18H22N2O6PdS2. Mole weight: 532.922g/mol. IUPACName: acetonitrile;4-methylbenzenesulfonic acid;palladium. Canonical SMILES: CC#N. CC#N. CC1=CC=C(C=C1)S(=O)(=O)O. CC1=CC=C(C=C1)S(=O)(=O)O. [Pd]. Catalog: ACM114757663.
Bis(benzonitrile)palladium(II) Dichloride
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. Catalyst for the aza-Michael reaction of carbamates with enones. Catalyst for the rearrangement of allylic imidates to allylic amides. Catalyst for the Nazarov cyclization of α-alkoxy dienones. Catalyst for the diamination of conjugated dienes. Three component Michael addition, cyclization, cross-coupling reaction. C-H activation of indoles. Group: Palladium series catalysts. Alternative Names: ST24046185; bis(benzonitrile)-palladium(II) chloride; J-007619; bis(chloranyl)palladium; MFCD00013123 (95+%); SCHEMBL63930; Bis(phenylnitrile)dichloropalladium; NSC635160; PdCl2(PhCN)2; bis(benzonitrile)dichloro-palladium (II). CAS No. 14220-64-5. Molecular formula: C14H10Cl2N2Pd. Mole weight: 383.568g/mol. IUPACName: benzonitrile;dichloropalladium. Canonical SMILES: C1=CC=C(C=C1)C#N. C1=CC=C(C=C1)C#N. Cl[Pd]Cl. ECNumber: 238-085-3. Catalog: ACM14220645.
Bis (dibenzylideneacetone) palladium
Bis (dibenzylideneacetone) palladium is a compound used as a component of a potentiometric membrane sensor to selectively determine the presence of thiocyanate in the urine of cigarette smokers. Bis (dibenzylideneacetone) palladium is also used as one of the homogeneous catalysts in the synthesis of Tricyclopentadiene from Dicyclopentadiene (D439350). Group: Biochemicals. Grades: Highly Purified. CAS No. 32005-36-0. Pack Sizes: 1g, 2.5g. Molecular Formula: C34H28O2Pd. US Biological Life Sciences.
Worldwide
Bis (dibenzylideneacetone)palladium (0)
Palladium-catalyzed acylation of unsaturated halides by anions of enol ethers. Asymmmetric Allylation reactions. Intramolecular reactions with alkenes. Carbonylation reactions. Cross Coupling reactions. Group: Palladium series catalysts. Alternative Names: CB-706; MFCD00051942; Bis (dibenzylideneacetone)palladium (0); (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium; GC10019; RW2139; bis(dibenzylidene-acetone)palladium; bis (dibenzylideneacetone)palladium; PubChem14428; J-400823. CAS No. 32005-36-0. Molecular formula: C34H28O2Pd. Mole weight: 575.016g/mol. IUPACName: (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium. Canonical SMILES: C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2. C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2. [Pd]. ECNumber: 608-691-6. Catalog: ACM32005360.
Bis(diethylamino)phenylphosphine
Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites. Group: Heterocyclic organic compound. Alternative Names: Phenylphosphonous tetraethyldiamide; Phosphonous diamide,N,N,N',N'-tetraethyl-P-phenyl-; Phenylbis(diethylamino)phosphine; TC-167706; SCHEMBL2226790; N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine; Bis(diethylamino)phenylphosphine, 97%; AC1L39YI; ACMC-20almr; ZINC404189. CAS No. 1636-14-2. Molecular formula: C14H25N2P. Mole weight: 252.342g/mol. IUPACName: N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine. Canonical SMILES: CCN(CC)P(C1=CC=CC=C1)N(CC)CC. Catalog: ACM1636142.
Bis (di-tert-butyl (4-dimethylaminophenyl) phosphine) dichloropalladium (II)
Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides. Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate. Group: Palladium series catalysts. Alternative Names: 4-Ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium. CAS No. 887919-35-9. Molecular formula: C32H56Cl2N2P2Pd. Mole weight: 708.1. Appearance: Powder. Purity: 0.98. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Cl[Pd]Cl. Catalog: ACM887919359-2.
Bis (tricyclohexylphosphine)palladium (II) Dichloride
Coupling reaction of aryl bromides with vinylic acetates. Group: Palladium series catalysts. Alternative Names: 5531AB; SC10409; MFCD00274659 (98%); dichlorobis(tri-o-tolyl-phosphine)palladium(II); dichlorobis(tri-O-tolylphosphine)-palladium (II); DICHLOROBIS(TRI-ORTHO-TOLYLPHOSPHINE)PALLADIUM(II); FT-0696077; bis[tri(ortho-tolyl)phosphine] palladium chloride; Dichlorobis(tri-o-tolylphosphine)palladium; AK-76768. CAS No. 40691-33-6. Molecular formula: C42H42Cl2P2Pd. Mole weight: 786.066g/mol. IUPACName: dichloropalladium;tris(2-methylphenyl)phosphane. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. Cl[Pd]Cl. Catalog: ACM40691336.
Bis(triphenylphosphine)palladium(II) Diacetate
suzuki reaction. Group: Palladium series catalysts. Alternative Names: bis(triphenyl phosphine)palladium(II) acetate; M-7910; AC1L37OG; bis(triphenylphosphine) palladium(II)acetate; Palladium, bis(acetato-kO)bis(triphenylphosphine)- (9CI); EINECS 238-628-4; AKOS015898550; bis(triphenylphosphine)-palladium (II) acetate; palladium(2+); I10-0287. CAS No. 14588-08-0. Molecular formula: C40H36O4P2Pd. Mole weight: 749.092g/mol. IUPACName: palladium(2+); triphenylphosphane; diacetate. Canonical SMILES: CC (=O)[O-]. CC (=O)[O-]. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Pd+2]. ECNumber: 238-628-4. Catalog: ACM14588080.
Bis(triphenylphosphine)palladium(II) Dichloride
Precatalyst for the carbonylative cyclization of malonate derivatives. Catalyst used in the double allylation of activated olefins. Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans. Precatalyst for the homocoupling of terminal alkynes. Precatalyst in the cross-coupling of alkynylsilanols and aryl halides. Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles. Catalyst for a tandem Heck reaction/C-H functionalization. Catalyst for direct arylation of tautomerizable heterocycles. Group: Palladium series catalysts. Alternative Names: TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(II) dichloride; bis(triphenylphosphine) palladium (II) chloride; FC0823; EINECS 237-744-2. CAS No. 13965-03-2. Molecular formula: C36H30Cl2P2Pd. Mole weight: 701.904g/mol. IUPACName: palladium(2+); triphenylphosphane; dichloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Cl-]. [Pd+2]. ECNumber: 237-744-2. Catalog: ACM13965032.
Bis (tri-t-butylphosphine) palladium bromide (I), dimer
Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids. Aryl bromide - silyl ketene acetal coupling. Catalyst for intermolecular α-arylation of zinc amide enolates. Catalyst for α-vinylation of carbonyl compounds. Catalyst for thiol coupling of heteroaromatic aryl bromides. Group: Palladium series catalysts. Alternative Names: MFCD04114019; 185812-86-6; CTK8C5468; palladium(I) tri-tertbutylphosphine bromide; PUBCHEM_71317307; Palladium(I) tri-tert-butylphosphine bromide. CAS No. 185812-86-6. Molecular formula: C12H27BrPPd-. Mole weight: 388.646g/mol. IUPACName: palladium;tritert-butylphosphane;bromide. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Br-]. [Pd]. Catalog: ACM185812866.
Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) is also used in the preparation of G6P-T1 translocase inhibitors used in the treatment of diabetes. Also, its used to prepare new dibenzofulvenes. Uses: Introduced as an easier to handle pd/p(t-bu)3-based catalyst for the negishi cross-coupling of aryl/vinyl chlorides. a versatile catalyst for the cross-coupling of aryl and vinyl chlorides. catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases. useful catalyst for the cross-coupling of heteroaromatic carboxylic acids. pd-catalyzed newnan-kwart rearrangement of o-aryl thiocarbamates. cross-coupling of silanolates and halides. elimination/isomerization of enol triflates derived from β-ketoesters. Group: Palladium series catalysts. Alternative Names: palladium,tritert-butylphosphane;Pd(t-Bu3P)2. CAS No. 53199-31-8. Molecular formula: C24H54P2Pd. Mole weight: 511.064g/mol. Appearance: Off white crystalline solid. IUPACName: palladium;tritert-butylphosphane. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C. CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Pd]. Catalog: ACM53199318.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl]palladium (II)
Catalyst used in the α-arylation of ketones. Catalyst used in the Suzuki cross-coupling of aryl chlorides with boronic acid-substituted benzofurans. Group: Palladiumcatalysts. CAS No. 1779569-06-0. Molecular formula: C46H64ClPPd. Mole weight: 789.85. Appearance: Orange powder. Catalog: ACM1779569060-1.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 6'-di-i-propoxy-1, 1'-biphenyl]palladium (II)
Catalyst used in the Buchwald-Hartwig cross-coupling of substituted aryl chlorides with secondary amines. Group: Palladiumcatalysts. CAS No. 1779569-08-2. Molecular formula: C43H58ClO2PPd. Mole weight: 779.77. Appearance: Orange powder. Catalog: ACM1779569082-1.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 6'-dimethoxy-1, 1'-biphenyl]palladium (II)
Catalyst used in the Suzuki cross-coupling of 3-chloroindazole or 3-chlorobenzimidazole with arylboronic acids. Group: Palladiumcatalysts. CAS No. 1779569-07-1. Molecular formula: C39H50ClO2PPd. Mole weight: 723.66. Appearance: Orange powder. Purity: 0.98. Catalog: ACM1779569071-1.
Extremely active palladium catalyst for Suzuki-Miyaura coupling of aryl chlorides. Group: Palladiumcatalysts. CAS No. 1905460-13-0. Molecular formula: C41H48ClN3Pd. Mole weight: 724.71. Appearance: Pale yellow powder. Purity: 0.97. Catalog: ACM1905460130-1.
Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II), methyl-t-butylether adduct, min. 98% [RuPhos Palladacycle Gen. 1]
Catalyst used in the thermal dehydrogenative Diels-Alder reaction of styrenes. Catalyst used for the CN-cross coupling reactions of 3-halo-2-aminopyridines. Catalyst used for the domino reaction of two aryl iodides, involving two C-H functionizations. Group: Palladium series catalysts. Alternative Names: Chloro-(2-Dicyclohexylphosphino-2a 6a diisopropoxy-1,1a biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) - methyl-t-butyl ether adduct (RuPhos Precatalyst 1st Gen); 1028206-60-1; Chloro-(2-Dicyclohexylphosphino-2 inverted exclamation marka,6 inverted exclamation marka-diisopropoxy-1,1 inverted exclamation marka-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) - methyl-t-butyl ether adduct; KS-0000005C. CAS No. 1028206-60-1. Molecular formula: C43H65ClNO3PPd. Mole weight: 816.841g/mol. IUPACName: chloropalladium(1+); dicyclohexyl-[2-[2, 6-di(propan-2-yloxy)phenyl]phenyl]phosphane; 2-methoxy-2-methylpropane; 2-phenylethanamine. Canonical SMILES: CC (C)OC1=C (C (=CC=C1)OC (C)C)C2=CC=CC=C2P (C3CCCCC3)C4CCCCC4. CC (C) (C)OC. C1=CC=C ([C-]=C1)CCN. Cl[Pd+]. Catalog: ACM1028206601.
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butylether adduct, min. 98% [SPhos Palladacycle Gen. 1]
Palladium series catalysts. Alternative Names: SPhos Palladacycle. CAS No. 1028206-58-7. Molecular formula: C34H45ClNO2PPd. Mole weight: 672.57. Appearance: white to off-white powder or crystals. Catalog: ACM1028206587.
Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II), min. 98% [BrettPhos Palladacycle Gen. 1]
Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines. Catalyst for rapid C-N bond-forming processes at low catalyst loading. Cross-coupling of 3-Bromo-2-aminopyridine with primary amines. Group: Palladium series catalysts. Alternative Names: BrettPhos Palladacycle. CAS No. 1148148-01-9. Molecular formula: C43H63ClNO2PPd. Mole weight: 798.81. Appearance: white to off-white powder or crystals. Purity: 0.97. Catalog: ACM1148148019.
Chloro(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 2]
Palladium precatalyst for fast Suzuki-Miyaura coupling reactions. Coupling of chloropyrazoles with boronic acis. Group: Palladiumcatalysts. Alternative Names: BrettPhos Palladacycle Gen. 2;MFCD22666410;1451002-39-3. CAS No. 1451002-39-3. Molecular formula: C47H63ClNO2PPd. Mole weight: 846.87g/mol. IUPACName: chloropalladium(1+);dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;2-phenylaniline. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=C (C=CC (=C2P (C3CCCCC3)C4CCCCC4)OC)OC)C (C)C. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. Cl[Pd+]. Catalog: ACM1451002393.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- [bis (4-fluorophenyl] phosphino] ferrocenyl] ethyldi-tert-butylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (bis (4-fluorophenyl) phosphinoferrocenyl]ethyl (di-t-butylphosphine) }nickel (II) is used for: 1.Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. 4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-37-3. Mole weight: 774.69. Catalog: ACM2049086373.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldicyclohexylphosphine] nickel (II)
Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-35-1. Mole weight: 802.88. Catalog: ACM2049086351.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldiphenylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyl (diphenylphosphine)}nickel(II) is useful in these fields: Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-36-2. Mole weight: 790.79. Catalog: ACM2049086362.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II)
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II) has the following various uses:1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-34-0. Mole weight: 738.71. Catalog: ACM2049086340.
Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates. Group: Palladium series catalysts. Alternative Names: Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II). CAS No. 1375325-71-5. Molecular formula: C24H37ClNPPd. Mole weight: 512.41. Appearance: off-white to pale yellow powder. Purity: 0.98. Catalog: ACM1375325715.
Catalyst used for the copolymerization of ethene with carbon monoxide. Catalyst used in the Heck reactions of vinyl ethers. Group: Palladium series catalysts. Alternative Names: Pd (OAc)2 (dppp); 149796-59-8; MFCD14155705; Diacetato[1, 3-bis (diphenylphosphino)propane]palladium (II). CAS No. 149796-59-8. Molecular formula: C31H34O4P2Pd. Mole weight: 638.977g/mol. IUPACName: acetic acid; 3-diphenylphosphanylpropyl (diphenyl)phosphane; palladium. Canonical SMILES: CC (=O) O. CC (=O) O. C1=CC=C (C=C1) P (CCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. [Pd]. Catalog: ACM149796598.
This Palladium-complex is used for the asymmetric cross-coupling of allylboron reagents with allylic electrophiles. The catalyst is used for the kinetic resolution of propargylic acetates to give enantioenriched 1,5-enynes. Group: Palladiumcatalysts. Alternative Names: [2-[2-[Bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]-3-methoxyphenyl]-bis(furan-2-yl)phosphane; palladium(2+); dichloride. CAS No. 1338245-54-7. Molecular formula: C30H24Cl2O6P2Pd. Mole weight: 719.78. Appearance: Pale yellow powder. Purity: 0.98. Canonical SMILES: COC1=C (C (=CC=C1)P (C2=CC=CO2)C3=CC=CO3)C4=C (C=CC=C4P (C5=CC=CO5)C6=CC=CO6)OC. [Cl-]. [Cl-]. [Pd+2]. Catalog: ACM1338245547-1.
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products. Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals. Group: Palladium series catalysts. Alternative Names: ST24050377; 5353AA; DICHLORO[2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II); 115826-95-4; [(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM (II) CHLORIDE; FT-0696081; MFCD00075254; C44H32Cl2P2Pd; EBD2199625; PALLADIUM, [1, 1'-(1R)-[1, 1'-BINAPHTHALENE]-2, 2'-DIYLBIS[1, 1-DIPHENYLPHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)-. CAS No. 127593-28-6. Molecular formula: C44H32Cl2P2Pd. Mole weight: 800.008g/mol. IUPACName: dichloropalladium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Pd]Cl. Catalog: ACM127593286.
Diiodo(p-cymene)ruthenium(II) dimer
Our company can provide customers with rich supported precious metal catalyst products such as palladium series, platinum series, rhodium series and ruthenium series. Our catalysts not only have high catalytic efficiency, strong selectivity, and recyclability, but also can be used in organic reactions such as hydrogenation, dehydrogenation, amination, and cyclization. In addition, some products can also be used as raw materials for various precious metal compounds. The company has formed a series of proprietary and characteristic process technologies, and is currently undergoing process improvement and upgrading. In short, our catalytic products can be widely used in medicine, new chemical materials, pesticides, dyes and pigments, environmental protection, new energy, electronics, basic chemicals and other fields. Uses: ·for ruthenium-catalyzed hydrogenation; ·for the preparation of wolfoss-type ferrocene aryl diphosphine ligands; ·for enantioselective hydrogenation of ketones and alkenes. Group: Ruthenium series catalysts. Alternative Names: Di-μ-iodobis(p-cymene)iodoruthenium(II). CAS No. 90614-07-6. Molecular formula: C20H30I4Ru2. Mole weight: 978.19 g/mol. Appearance: Solid. Purity: 0.97. Canonical SMILES: I[Ru]1[I][Ru](I)[I]1. C[C]2[CH][CH][C]([CH][CH]2)C(C)C. C[C]3[CH][CH][C]([CH][CH]3)C(C)C. Catalog: ACM90614076-2.
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