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1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-phosphine is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate ligand and is noteworthy for having a particularly wide bite angle. Such ligands are useful in the hydroformylation of alkenes. Group: Biochemicals. Grades: Highly Purified. CAS No. 161265-03-8. Pack Sizes: 1g, 5 g. Molecular Formula: C39H32OP2. US Biological Life Sciences.
Catalyst used in the selective hydration of substituted alkynes at room temperatures. Catalyst used in the hydroarylating/aromatization of arene-diynes. Highly-efficient and regio-selective catalyst for the selective carbonyl migration in alkynyl-substituted indole-3-carboxamides. Intermolecular gold(I) catalyzed alkyne carboalkoxylation reactions for the multicomponent assembly of β-alkoxy ketones. Gold(I)-catalyzed hydration of alkynylphosphonates: Efficient access to β-ketophosphonates. Gold-catalyzed intramolecular hydroamination reaction. Group: Gold catalysts. Alternative Names: MFCD21608485; 1121960-90-4; Bis(trifluoromethanesulfonyl)imide(2-dicyclohexylphosphino-2', 6'-dimethoxy-1, 1'-biphenyl)gold(I). CAS No. 1121960-90-4. Molecular formula: C28H36AuF6NO6PS2+. Mole weight: 888.648g/mol. IUPACName: bis(trifluoromethylsulfonyl)azanide; dicyclohexyl-[2-(2, 6-dimethoxyphenyl)phenyl]phosphanium; gold(1+). Canonical SMILES: COC1=C (C (=CC=C1)OC)C2=CC=CC=C2[PH+] (C3CCCCC3)C4CCCCC4. C (F) (F) (F)S (=O) (=O)[N-]S (=O) (=O)C (F) (F)F. [Au+]. Catalog: ACM1121960904.
2-Methoxyphenylphosphine
Heterocyclic Organic Compound. Alternative Names: 2-PHOSPHINOANISOLE;2-METHOXYPHOSPHINOBENZENE;2-METHOXYPHENYLPHOSPHINE. CAS No. 126590-38-3. Molecular formula: C7H9OP. Mole weight: 140.12. Catalog: ACM126590383.
4- (Di methyl amino) phenyl diphenyl phosphine. Group: Biochemicals. Alternative Names: 4- (Dimethylamino) triphenylphosphine; 4-(Diphenylphosphino)-N,N-dimethylaniline. Grades: Highly Purified. CAS No. 739-58-2. Pack Sizes: 2g, 5g, 10g, 25g, 50g. US Biological Life Sciences.
Worldwide
(4-Dimethylaminophenyl)di-tert-butylphosphine
(4-Dimethylaminophenyl)di-tert-butylphosphine. Uses: Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic light-emitting diode (oled) materials. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Product ID: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Molecular formula: 265.381g/mol. Mole weight: C16H28NP. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. InChI=1S/C16H28NP/c1-15 (2, 3)18 (16 (4, 5)6)14-11-9-13 (10-12-14)17 (7)8/h9-12H, 1-8H3. IQTHEAQKKVAXGV-UHFFFAOYSA-N.
(4-Dimethylaminophenyl)di-tert-butylphosphine
Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic phosphine compounds. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Molecular formula: C16H28NP. Mole weight: 265.381g/mol. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Catalog: ACM932710639.
Traceless Staudinger ligation reagent with borane protecting group. The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine. After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond. Used in the synthesis of cyclic peptides. Group: Heterocyclic organic compound. Alternative Names: AGN-PC-005LSK, boron;S-(diphenylphosphanylmethyl) ethanethioate, Acetylthiomethyl-diphenylphosphine borane complex, 446822-71-5. CAS No. 446822-71-5. Molecular formula: C15H18BOPS. Mole weight: 288.15. Purity: 0.96. IUPACName: boron;S-(diphenylphosphanylmethyl) ethanethioate. Canonical SMILES: [B]. CC(=O)SCP(C1=CC=CC=C1)C2=CC=CC=C2. Catalog: ACM446822715-1.
Allyldiphenylphosphine
Cocatalyst in palladium catalyzed hydrocarboxylation reactions. Cocatalyst in Palladium catalyzed cross-coupling reactions. Ligand for hydroformylation catalysts. Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions. Catalyst precursor for alkene hydroboration. Group: Organic phosphine compounds. Alternative Names: Diphenyl-2-propenylphosphine. CAS No. 2741-38-0. Molecular formula: C15H15P. Mole weight: 226.25. Appearance: Liquid. Purity: 98%+. IUPACName: diphenyl(prop-2-enyl)phosphane. Canonical SMILES: C=CCP(C1=CC=CC=C1)C2=CC=CC=C2. Density: 1.049 g/mL at 25 °C (lit.). Catalog: ACM2741380-1.
Organic Phosphine Compounds. Alternative Names: Palladium, bis(acetato-κ O)?bis[butylbis(tricycl?o[3.3.1.13, ?7]?dec-1-yl)?phosphine]?-, (SP-4-1)?-. CAS No. 1041005-57-5. Appearance: White to light brown powder. Purity: 98%, Pd>11.0%. Catalog: ACM1041005575.
Bis(diethylamino)phenylphosphine
Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites. Group: Heterocyclic organic compound. Alternative Names: Phenylphosphonous tetraethyldiamide; Phosphonous diamide,N,N,N',N'-tetraethyl-P-phenyl-; Phenylbis(diethylamino)phosphine; TC-167706; SCHEMBL2226790; N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine; Bis(diethylamino)phenylphosphine, 97%; AC1L39YI; ACMC-20almr; ZINC404189. CAS No. 1636-14-2. Molecular formula: C14H25N2P. Mole weight: 252.342g/mol. IUPACName: N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine. Canonical SMILES: CCN(CC)P(C1=CC=CC=C1)N(CC)CC. Catalog: ACM1636142.
dichloridobis (triphenylphosphane)nickel (II) is a metal phosphine complex with the formula NiCl2[P(C6H5)3]2. It is a dark blue crystalline solid. It is used as a catalyst for organic synthesis. Uses: Ni(pph3)2cl2 may be used to undertake nickel assisted phosphination of biaryl o,n triflates with chlorodiphenylphosphine. Group: Vapor deposition precursorspolymerization reagents. Alternative Names: Dichlorobis (triphenylphosphine)nickel (II), NiCl2(PPh3)2, Nickel(II)bis(triphenylphosphine) dichloride. CAS No. 14264-16-5. Pack Sizes: 10 g in glass bottle. Product ID: dichloronickel; triphenylphosphane. Molecular formula: 654.17. Mole weight: C36H32Cl2NiP2-. Cl[Ni]Cl. c1ccc(cc1)P(c2ccccc2)c3ccccc3. c4ccc(cc4)P(c5ccccc5)c6ccccc6. 1S/2C18H15P. 2ClH. Ni/c2*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; ; ; /h2*1-15H; 2*1H; /q; ; ; ; +2/p-2, ZBRJXVVKPBZPAN-UHFFFAOYSA-L. ZBRJXVVKPBZPAN-UHFFFAOYSA-L.
Bis(triphenylphosphine)palladium(II) Diacetate
suzuki reaction. Group: Palladium series catalysts. Alternative Names: bis(triphenyl phosphine)palladium(II) acetate; M-7910; AC1L37OG; bis(triphenylphosphine) palladium(II)acetate; Palladium, bis(acetato-kO)bis(triphenylphosphine)- (9CI); EINECS 238-628-4; AKOS015898550; bis(triphenylphosphine)-palladium (II) acetate; palladium(2+); I10-0287. CAS No. 14588-08-0. Molecular formula: C40H36O4P2Pd. Mole weight: 749.092g/mol. IUPACName: palladium(2+); triphenylphosphane; diacetate. Canonical SMILES: CC (=O)[O-]. CC (=O)[O-]. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Pd+2]. ECNumber: 238-628-4. Catalog: ACM14588080.
Bis (tri-tert-butylphosphine) palladium (0)
Bis (tri-tert-butylphosphine) palladium (0) . Group: Biochemicals. Alternative Names: Bis[tris (1, 1-dimethylethyl) phosphine]palladium; Bis (tri-tert-butylphosphine) palladium; Bis (tri-tert-butylphosphine) palladium (0) ; Bis (tri-tert-butylphosphino) palladium; Bis[tris (tert-butyl) phosphine]palladium; Palladium Bis(tri-tert-butylphosphine); BIs[tris (1, 1-dimethylethyl) phosphine]palladium. Grades: Highly Purified. CAS No. 53199-31-8. Pack Sizes: 500mg. Molecular Formula: C24H54P2Pd, Molecular Weight: 511.05. US Biological Life Sciences.
Worldwide
Borane-di(tert-butyl)phosphine complex
Heterocyclic Organic Compound. Alternative Names: Di-tert-butylphosphine compound with borane (1:1); Di-tert-butylphosphine borane; (Di-tert-butylphosphine)trihydroboron. CAS No. 128363-76-8. Molecular formula: C8H22PBH. Mole weight: 160.05. Appearance: Solid. Purity: 0.98. Catalog: ACM128363768-1.
Bromotris(triphenylphosphine)rhodium
Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes. Rhodium- catalyzed hydrophosphinylation. Group: Rhodium series of catalysts. Alternative Names: bromide; Bromotris (triphenylphosphine)rhodium; EINECS 239-050-5; Bromotris (triphenylphosphine)rhodium (I); Jsp002843; phosphine, triphenyl-, bromide, rhodium salt(3:1); RL01906; AC1Q1R7U; triphenylphosphane. CAS No. 14973-89-8. Molecular formula: C54H45BrP3Rh-. Mole weight: 969.685g/mol. IUPACName: rhodium;triphenylphosphane;bromide. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Br-]. [Rh]. ECNumber: 239-050-5. Catalog: ACM14973898.
Butyldi-1-adamantylphosphine
Butyldi-1-adamantylphosphine (CAS# 321921-71-5 ) is a useful research chemical. Synonyms: Catacxium A; nbutyl-di(1-adamantyl)phosphine; Di(1-adamantyl)-n-butylphosphine. CAS No. 321921-71-5. Molecular formula: C24H39P. Mole weight: 358.54.
Highly-efficient and regio-selective catalyst for the selective carbonyl migration in alkynyl-substituted indole-3-carboxamides. Catalyst used in the hydroarylation/aromatization of arene-diynes. Catalyst used in the selective hydration of substituted alkynes at room temperatures. Group: Gold catalysts. Alternative Names: MFCD21608486;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)gold(I);854045-95-7. CAS No. 854045-95-7. Molecular formula: C26H36AuClO2P+. Mole weight: 643.962g/mol. IUPACName: chlorogold;dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphanium. Canonical SMILES: COC1=C (C (=CC=C1)OC)C2=CC=CC=C2[PH+] (C3CCCCC3)C4CCCCC4. Cl[Au]. Catalog: ACM854045957.
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