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| Product | Description | |
|---|---|---|
| 3-Chloro-3-methyl-1-butyne | 3-Chloro-3-methyl-1-butyne is a propargyl chloride used to alkylate methanol, ethanol, ammonia and amines to the corresponding propargylic ether and amines. Group: Biochemicals. Alternative Names: 2-Chloro-2-methyl-3-butyne; 2-Methyl-2-chloro-3-butyne; 2-Methyl-3-butyn-2-yl chloride; 3-Chloro-3-methylbutyne; 3-Methyl-1-butyn-3-yl chloride; 3-Methyl-3-chloro-1-butyne; 3-Methyl-3-chlorobutyne; NSC 16173; α,α-Dimethylpropargyl Chloride. Grades: Highly Purified. CAS No. 1111-97-3. Pack Sizes: 25g. US Biological Life Sciences. |  Worldwide |
| 6,7-Dihydro-2-phenyl-5H-pyrrolo[2,1-c]-1,2,4-triazolium chloride, min. 98% | Reagent used for the conversion of α-haloaldehydes into acylating agents via a catalyzed internal redox reaction. Reagent used for reduction of styryl and propargylic alcohols. Catalyst for the synthesis of 3-substituted phthalides. Group: Heterocyclic organic compound. Alternative Names: 828914-68-7; CTK5F0182; DTXSID40722618; 5H-Pyrrolo[2, 1-c]-1, 2, 4-triazoliuM, 6, 7-dihydro-2-phenyl-, chloride; 2-Phenyl-1, 2, 3, 5, 6, 7-hexahydropyrrolo[2, 1-c][1, 2, 4]triazol-4-ium chloride;5H-Pyrrolo[2,1-c]-1,2,4-triazolium,6,7-dihydro-2-phenyl-, chloride (1:1). CAS No. 828914-68-7. Molecular formula: C11H14ClN3. Mole weight: 223.704g/mol. IUPACName: 2-phenyl-3,5,6,7-tetrahydro-1H-pyrrolo[2,1-c][1,2,4]triazol-4-ium;chloride. Canonical SMILES: C1CC2=[N+](C1)CN(N2)C3=CC=CC=C3. [Cl-]. Catalog: ACM828914687. |  |
| (Oxybis(2,1-phenylene))bis(diphenylphosphine) | Useful as a ligand in the Pd-catalyzed formation of diaryl amines. Has been recently applied to the C3 benzylation of indoles. Has been recently applied to the monoallylation of ammonia. Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids. Ligand used in carbonylation of aryl iodides. Ligand used in the direct C-H arylation of benzothiodiazoles. Ligand used in stereo-retentive azacyclization of propargylic carbonates. Ligand used in palladium catalyzed benzyne trimerization. Group: Organic phosphine compounds. CAS No. 166330-10-5. Molecular formula: C36H28OP2. Mole weight: 538.567g/mol. IUPACName: [2- (2-diphenylphosphanylphenoxy) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1) P (C2=CC=CC=C2) C3=CC=CC=C3OC4=CC=CC=C4P (C5=CC=CC=C5) C6=CC=CC=C6. Catalog: ACM166330105. | |
| Tris(triphenylphosphine)rhodium(I) chloride | A homogeneous hydrogenation catalyst which operates under mild conditions. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reactions. Alkyne hydro-phosphorylation Heck-type reaction with α,β-unsaturated esters. Alkyne arylation Allylic alcohol-olefin coupling. Terminal alkenes from ketones. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. Reductive deprotection of silyl groups. Group: Rhodium series of catalysts. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Molecular formula: C54H45ClP3Rh. Mole weight: 925.21. Appearance: Magenta crystal. Purity: 0.98. IUPACName: rhodium;triphenylphosphane;chloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. ECNumber: 238-744-5. Catalog: ACM14694952-1. | |
| Tris(triphenylphosphine)rhodium(I) chloride | Tris(triphenylphosphine)rhodium(I) chloride. Uses: A homogeneous hydrogenation catalyst which operates under mild conditions. catalyst for the decarbonylation of aldehydes. catalyst for regio- and stereoselective allylic substitution reactions. alkyne hydro-phosphorylation heck-type reaction with α,β-unsaturated esters. alkyne arylation allylic alcohol-olefin coupling. terminal alkenes from ketones. rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. reductive deprotection of silyl groups. Group: Salt. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Product ID: rhodium; triphenylphosphane; chloride. Molecular formula: 925.21. Mole weight: C54H45ClP3Rh. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. InChI=1S/3C18H15P. ClH. Rh/c3*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; /h3*1-15H; 1H; /p-1. QBERHIJABFXGRZ-UHFFFAOYSA-M. 98%. |  |
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