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| Product | Description | |
|---|---|---|
| [1'1-bis (diphenylphosphino) ferrocene]dichloropalladium dichloromethane complex, Pd : 13.0 wt.% | Our company can provide customers with rich supported precious metal catalyst products such as palladium series, platinum series, rhodium series and ruthenium series. Our catalysts not only have high catalytic efficiency, strong selectivity, and recyclability, but also can be used in organic reactions such as hydrogenation, dehydrogenation, amination, and cyclization. In addition, some products can also be used as raw materials for various precious metal compounds. The company has formed a series of proprietary and characteristic process technologies, and is currently undergoing process improvement and upgrading. In short, our catalytic products can be widely used in medicine, new chemical materials, pesticides, dyes and pigments, environmental protection, new energy, electronics, basic chemicals and other fields. Uses: [1'1-bis (diphenylphosphino) ferrocene]dichloropalladium dichloromethane complex is used as the research compound. Group: Colloidal catalysts. CAS No. 95564-05-4. Mole weight: 816.64 g/mol. Appearance: Powder. Catalog: ACM95564054. |  |
| (+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-i-Pr-DUPHOS-Rh | The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination. Group: Heterocyclic organic compound. Alternative Names: 569650-64-2;1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R, R)-i-Pr-DUPHOS-Rh; DTXSID00514132; PUBCHEM_12964416; MFCD07369039; (+)-1, 2-Bis((2R, 5R)-2, 5-di-i-propylphospholano)benzene(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate; (+)-1, 2-Bis ( (2R, 5R)-2, 5-di-i-propylphospholano)benzene)1, 5-cyclooctadiene)rhodium (I)tetrafluoroborate. CAS No. 569650-64-2. Molecular formula: C34H56BF4P2Rh-. Mole weight: 716.479g/mol. IUPACName: (1Z, 5Z)-cycloocta | |
| (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Me-DUPHOS-Rh | The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination. Group: Rhodium series of catalysts. Alternative Names: 210057-23-1; MFCD01862466; 057B231; (-)-1, 2-Bis[ (2R, 5R)-dimethylphospholano]benzene (cyclooCtadiene)rhodium (I) tetrafluoroborate; 1, 2-Bis[ (2R, 5R)-2, 5-dimethylphospholano]benzene (cyclooctadiene)rhodium (I)tetrafluoroborate; (-)-1, 2-Bis ( (2R, 5R)-2, 5-dimethylphospholano)benzene (cyclooctadiene)rhodium (I) tetrafluoroborate; (-)-1, 2-Bis ( (2R, 5R)-2, 5-dimethylphospholano)benzene (cycloo. CAS No. 210057-23-1. Molecular formula: C26H40BF4P2Rh-. Mole weight: 604.263g/mol. IUPACName: cycloocta-1, 5-diene; (2R, 5 | |
| (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Me-BPE-Rh | The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Group: Heterocyclic organic compound. Alternative Names: 305818-67-1; 1, 2-Bis[ (2R, 5R)-2, 5- (dimethylphospholano]ethane (cyclooctadiene)rhodium (I) tetrafluoroborate; (R, R)-Me-BPE-Rh; DTXSID30584863; PUBCHEM_16218294; MFCD04038741; J-018028; (+)-1, 2-Bis ( (2R, 5R)-2, 5-dimethylphospholano)ethane (cyclooctadiene)rhodium (I) tetrafluoroborate. CAS No. 305818-67-1. Molecular formula: C22H40BF4P2Rh-. Mole weight: 556.219g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; (2R, 5R)-1-[2-[(2R, 5R)-2, 5-dimethylphospholan-1-yl]ethyl]-2, 5-dimethylphospholane; rhodium; tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. CC1CCC(P1CCP2C(CCC2C)C)C. C1CC=CCCC=C1. [Rh]. Catalog: ACM305818671. | |
| (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh | Ligand used in asymmetric hydrogenation of 2-methylenesuccinamic acid. Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-aminomethylacrylates. Group: Rhodium catalysts. Alternative Names: (S, S)-Et-DUPHOS-Rh; 213343-64-7; 1, 2-Bis ( (2S, 5S)-2, 5-diethylphospholano)benzene (cyclooctadiene)rhodium (I) tetrafluoroborate, 97%;DTXSID60451539;XIOPHSBHVOCZMM-ZCTOJWETSA-N;J-014000;1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate. CAS No. 213343-64-7. Molecular formula: C30H48BF4P2Rh-. Mole weight: 660.371g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-diethylphospholan-1-yl]phenyl]-2, 5-diethylphospholane; rhodium; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F)F. CCC1CCC (P1C2=CC=CC=C2P3C (CCC3CC)CC)CC. C1CC=CCCC=C1. [Rh]. Catalog: ACM213343647. | |
| (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh | The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination. Group: Rhodium series of catalysts. Alternative Names: (+)-1, 2-Bis ( (2S, 5S)-2, 5-dimethylphospholano)benzene (cyclooctadiene)Rh (I)tetrafluoroborate; (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane; MFCD01862467; 205064-10-4; AC1MC1E8. CAS No. 205064-10-4. Molecular formula: C26H40BF4P2Rh-. Mole weight: 604.263g/mol. IUPACName: cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-dimethylphospholan-1-yl]phenyl]-2, 5-dimethylphospholane; rhodium; tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. C1CC=C | |
| (+)-1, 2-Bis ( (2S, 5S)-2, 5-dimethylphospholano)benzene (1, 5-cyclooctadiene)rhodium (I)trifluoromethanesulfonate, 98+% (S,S)-Me-DUPHOS-Rh | Catalyst for the enantioselective [2+2+2] cycloaddition of triynes. Group: Rhodium catalysts. Alternative Names: 1, 2-Bis[ (2S, 5S)-2, 5-dimethylphospholano]benzene (cyclooctadiene)rhodium (I) trifluoromethanesulfonate, 97%; MFCD00269863; (1Z,5Z)-cycloocta-1,5-diene; (2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane; (+)-1, 2-Bis ( (2S, 5S)-2, 5-dimethylphospholano)benzene (cyclooctadiene)rhodium (I) trifluoromethanesulfonate; 136705-75-4. CAS No. 136705-75-4. Molecular formula: C27H40F3O3P2RhS-. Mole weight: 666.522g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-dimethylphospholan-1-yl]phenyl]-2, 5-dimethylphospholane; rhodium; trifluoromethanesulfonate. Canonical SMILES: CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. C1CC=CCCC=C1. C(F)(F)(F)S(=O)(=O)[O-]. [Rh]. Catalog: ACM136705754. | |
| (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh | The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Group: Heterocyclic organic compound. Alternative Names: (-)-1, 2-Bis ( (2S, 5S)-2, 5-dimethylphospholano)ethane (cyclooctadiene)-rhodium (I) tetrafluoroborate; (-)-1, 2-bis ( (2S, 5S)-2, 5-dimethylphospholano)ethane (cyclooctadiene)-rhodium (I) tetrafluoroborate; PUBCHEM_12964417; LKVIVYCYPYTYSO-ASDDUFFSSA-N; 1, 2-Bis[ (2S, 5S)-2, 5-dimethylphospholano]ethane (cyclooctadiene)rhodium (I) tetrafluoroborate; (-)-1, 2-Bis ( (2S, 5S)-2, 5-dimethylphospholano)ethane (cyclooctadiene)rhodium (I) tetrafluoroborate; (S,S)-Me-BPE-Rh. CAS No. 213343-65-8. Molecular formula: C22H40BF4P2Rh-. Mole weight: 556.219g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-dimethylphospholan-1-yl]ethyl]-2, 5-dimethylphospholane; rhodium; tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. CC1CCC(P1CCP2C(CCC2C)C)C. C1CC=CCCC=C1. [Rh]. Catalog: ACM213343658. | |
| (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh | Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins. Group: Rhodium catalysts. Alternative Names: 849950-53-4; (S, S)-Ph-BPE-Rh; DTXSID60746255; PUBCHEM_71310599; MFCD07369038; (+)-1, 2-Bis (2S, 5S)-2, 5-diphenylphospholano)ethane- (1, 5-cyclooctadiene)rhodium (I)tetrafluoroborate; 1, 2-Bis[ (2S, 5S)-2, 5-diphenylphospholano]ethane (1, 5-cyclooctadiene)rhodium (I) tetrafluoroborate;1,2-Bis[(s,s)-2,5-diphenylphospholano]ethane-(1,5-cycloocta-diene)rhodium(I)tetrafluoroborate. CAS No. 849950-53-4. Molecular formula: C42H48BF4P2Rh-. Mole weight: 804.503g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; (2S, 5S)-1-[2-[(2S, 5S)-2, 5-diphenylphospholan-1-yl]ethyl]-2, 5-diphenylphospholane; rhodium; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F) F. C1CC=CCCC=C1. C1CC (P (C1C2=CC=CC=C2) CCP3C (CCC3C4=CC=CC=C4) C5=CC=CC=C5) C6=CC=CC=C6. [Rh]. Catalog: ACM849950534. | |
| 1,2-Dimethylcyclohexane | 1,2-Dimethylcyclohexane is used in the preparation of rhodium nanoparticles as recyclable catalysts. Group: Biochemicals. Grades: Highly Purified. CAS No. 583-57-3. Pack Sizes: 1g, 5g. Molecular Formula: C8H16. US Biological Life Sciences. |  Worldwide |
| 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane | A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts. Group: Other phosphine ligandscoupling. Alternative Names: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane; 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane, 99%; 97739-46-3; CTK5H9495; 1,3,5,7-TETRAMETHYL-6-PHENYL-2,4,8-TRIOXA-6-PHOSPHAADAMANTANE; DTXSID50699640; AVVSJWUWBATQBX-UHFFFAOYSA-N; KS-000018KV; 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phospha-adamantane; MFCD10567051. CAS No. 97739-46-3. Molecular formula: C16H21O3P. Mole weight: 292.315g/mol. IUPACName: 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane. Canonical SMILES: CC12CC3 (OC (O1) (CC (O2) (P3C4=CC=CC=C4)C)C)C. Catalog: ACM97739463. | |
| [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | Catalyst used in the intramolecular, hydroamination of olefins. Catalyst used for reductive aminations. Group: Rhodium series of catalysts. Alternative Names: (1Z, 5Z)-Cycloocta-1, 5-diene; 4-diphenylphosphanylbutyl (diphenyl)phosphane; rhodium; tetrafluoroborate. CAS No. 79255-71-3. Molecular formula: C36H40BF4P2Rh. Mole weight: 724.4. Appearance: Powder. Purity: 0.98. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; 4-diphenylphosphanylbutyl (diphenyl)phosphane; rhodium; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F) F. C1CC=CCCC=C1. C1=CC=C (C=C1) P (CCCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. [Rh]. Catalog: ACM79255713-1. | |
| 1, 5-Cyclooctadiene (hydroquinone)rhodium (I) tetrafluoroborate | A phosphorous free pre-catalyst for the efficient 1,4-conjugate addition of arylboronic acids to enones. A pre-catalyst for addition of arylboronic acids to aryl aldehydes. With aluminum isopropoxide forms a self-supported heterogeneous catalyst for the stereoselective polymerization of phenylacetylene to cis-poly(phenylacetylene). Group: Rhodium series of catalysts. Alternative Names: 120967-70-6; CYCLOOCTADIENE(HYDROQUINONE)RHODIUM (I) TETRAFLUOROBORATE; 1, 5-CYCLOOCTADIENE (HYDROQUINONE)RHODIUM (I) TETRAFLUOROBORATE; MFCD09753039; SC10113; 1, 5-Cyclooctadiene (hydroquinone)rhodium (I)tetrafluoroborate. CAS No. 120967-70-6. Molecular formula: C14H18BF4O2Rh-. Mole weight: 408.005g/mol. IUPACName: benzene-1,4-diol;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. C1CC=CCCC=C1. C1=CC(=CC=C1O)O. [Rh]. Catalog: ACM120967706. | |
| Acetylacetonatobis (cyclooctene)rhodium (I), min. 97% | Rhodium source used in combination with phosphine ligands to catalyze the 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Rhodium source for the catalytic addition of arylboronic acids to N-tert-butanesulfinyl imino esters. Group: Rhodium series of catalysts. Alternative Names: ACETYLACETONATOBIS (CYCLOOCTENE)RHODIUM (I); 34767-55-0; MFCD06658137; SC10118; ACETYLACETONATOBIS (CYCLOOCTENE)RHODIUM (I);BIS(CYCLOOCTENE)(2,4-PENTANEDIONATO)RHODIUM. CAS No. 34767-55-0. Molecular formula: C21H36O2Rh. Mole weight: 423.422g/mol. IUPACName: cyclooctane;(Z)-4-hydroxypent-3-en-2-one;rhodium. Canonical SMILES: CC(=CC(=O)C)O. C1CCC[CH][CH]CC1. C1CCC[CH][CH]CC1. [Rh]. Catalog: ACM34767550. | |
| Acetylacetonatobis (ethylene)rhodium (I) | Rhodium series of catalysts. Alternative Names: Bis(ethylene)rhodium(I) acetylacetonate. CAS No. 12082-47-2. Molecular formula: C9H16O2Rh. Mole weight: 259.13. Appearance: Orange crystal or crystalline powder. Purity: 0.98. IUPACName: ethene;(Z)-4-hydroxypent-3-en-2-one;rhodium. Canonical SMILES: CC(=CC(=O)C)O.C=C.C=C.[Rh]. ECNumber: 235-147-1. Catalog: ACM12082472-1. | |
| Benzyl 2-Chloroethyl Ether | Benzyl 2-Chloroethyl Ether is used in the synthesis of phosphane ligands with novel linker units that are complexed with rhodium to be used as building blocks for dendrimer catalysts. Also used in the formation of 2,6-diphenylpyrazine molecule derivatives which display cytotoxic properties. Group: Biochemicals. Alternative Names: Benzyl 2-chloroethyl Ether; 1-(Benzyloxy)-2-chloroethane; 2-Benzyloxy-1-chloroethane; 2-Phenylmethyloxyethyl Chloride; Benzyl 2-Chloroethyl Ether; NSC 11269; α-(2-Chloroethoxy)toluene. Grades: Highly Purified. CAS No. 17229-17-3. Pack Sizes: 1g. US Biological Life Sciences. | Worldwide |
| Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluoroborate salt | Rhodium Catalysts. CAS No. 1228149-03-8. Mole weight: 1204.75. Catalog: ACM1228149038. | |
| Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate | . Uses: Transition metal catalysts. Synonyms: Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, (OC-6-11)-hexafluoroantimonate(1-) (1:1); 1,5-Cyclooctadiene, rhodium complex; Antimonate(1-), hexafluoro-, (OC-6-11)-, bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(1+); Bis(1,5-cyclooctadiene)rhodium hexafluoroantimonate; Bis(1,5-cyclooctadiene)rhodium(1+) hexafluoroantimonate; Bis(1,5-cyclooctadiene)rhodium(1+) hexafluoroantimonate(1-); Bis(cyclooctadiene)rhodium hexafluoroantimonate. Grades: ≥95%. CAS No. 130296-28-5. Molecular formula: C16H24Rh.F6Sb. Mole weight: 555.02. |  |
| Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | Asymmetric Reactions; C-H Activation; Hydroformylation; Hydrogenation→Asymmetric Hydrogenation; Hydrosilylation; Isomerization. Group: Rhodium series of catalysts. Alternative Names: Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate. CAS No. 35138-22-8. Molecular formula: C16H24BF4Rh. Mole weight: 406.07. Appearance: Orange red crystalline powder. Purity: 0.99. IUPACName: (1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. C1CC=CCCC=C1. C1CC=CCCC=C1. [Rh]. ECNumber: 460-220-1. Catalog: ACM35138228-2. | |
| Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate | Asymmetric Reactions; C-H Activation; Hydroformylation; Hydrogenation→Asymmetric Hydrogenation. Group: Rhodium series of catalysts. Alternative Names: (1Z, 5Z)-cycloocta-1, 5-diene; rhodium; trifluoromethanesulfonate. CAS No. 99326-34-8. Molecular formula: C17H24F3O3RhS. Mole weight: 468.34. Appearance: Red brown powder. Purity: 0.99. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; rhodium; trifluoromethanesulfonate. Canonical SMILES: C1CC=CCCC=C1. C1CC=CCCC=C1. C(F)(F)(F)S(=O)(=O)[O-]. [Rh]. Catalog: ACM99326348-2. | |
| Bis(diethylamino)phenylphosphine | Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites. Group: Heterocyclic organic compound. Alternative Names: Phenylphosphonous tetraethyldiamide; Phosphonous diamide,N,N,N',N'-tetraethyl-P-phenyl-; Phenylbis(diethylamino)phosphine; TC-167706; SCHEMBL2226790; N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine; Bis(diethylamino)phenylphosphine, 97%; AC1L39YI; ACMC-20almr; ZINC404189. CAS No. 1636-14-2. Molecular formula: C14H25N2P. Mole weight: 252.342g/mol. IUPACName: N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine. Canonical SMILES: CCN(CC)P(C1=CC=CC=C1)N(CC)CC. Catalog: ACM1636142. | |
| Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate | Bis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution. Group: Rhodium series of catalysts. Alternative Names: 36620-11-8; Bis(norbornadiene)rhodium(I) tetrafluoroborate; [rh(nbd)2]bf4; SC-49716; Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate; ANW-41403; MFCD00671775; Bis (norbornadiene) (tetrafluoroborato)rhodium; bis(norbomadiene)rhodium (I) tetrafluoroborate; Bis(norbornadiene)rhodium (I) tetrafluoroborate. CAS No. 36620-11-8. Molecular formula: C14H16BF4Rh-. Mole weight: 373.991g/mol. IUPACName: bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate. Canonical SMILES: [B-](F)(F)(F)F. C1C2C=CC1C=C2. C1C2C=CC1C=C2. [Rh]. Catalog: ACM36620118. | |
| Bromotris(triphenylphosphine)rhodium | Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes. Rhodium- catalyzed hydrophosphinylation. Group: Rhodium series of catalysts. Alternative Names: bromide; Bromotris (triphenylphosphine)rhodium; EINECS 239-050-5; Bromotris (triphenylphosphine)rhodium (I); Jsp002843; phosphine, triphenyl-, bromide, rhodium salt(3:1); RL01906; AC1Q1R7U; triphenylphosphane. CAS No. 14973-89-8. Molecular formula: C54H45BrP3Rh-. Mole weight: 969.685g/mol. IUPACName: rhodium;triphenylphosphane;bromide. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Br-]. [Rh]. ECNumber: 239-050-5. Catalog: ACM14973898. | |
| Carbonyl (acetylacetonato) (triphenylphosphine)rhodium (I), 99% | Rhodium catalyzed addition of fluorinated acid chlorides to alkynes. Group: Rhodium series of catalysts. Alternative Names: Rhodium (triphenylphosphine) carbonylacetylacetonate. CAS No. 25470-96-6. Molecular formula: C24H22O3PRh. Mole weight: 492.31. Appearance: yellow crystals. Purity: Rh ≥20.9%. Catalog: ACM25470966. | |
| Carbonylhydridotris (triphenylphosphine)rhodium (I) | Catalyst. Group: Rhodium series of catalysts. Alternative Names: IETKMTGYQIVLRF-UHFFFAOYSA-N; 17185-29-4; SC10368; Tris(triphenylphosphine)rhodium(I) carbonyl hydride; Tris (triphenylphosphine)carbonylrhodium hydride; trans-Carbonyl (hydrido)tris (triphenylphosphine)rhodium; CARBONYLTRIS (TRIPHENYLPHOSPHINE)RHODIUM (1) HYDRIDE; Carbonyltris (triphenylphosphine)rhodium (I) hydride; Tris(triphenylphosphine)rhodium(I) carbonyl hydride, 97%; TRIS(TRIPHENYLPHOSPHINE)RHODIUM CARBONYL HYDRIDE. CAS No. 17185-29-4. Molecular formula: C55H45OP3Rh. Mole weight: 917.791g/mol. IUPACName: carbon monoxide;rhodium;triphenylphosphane. Canonical SMILES: [C-]#[O+]. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Rh]. ECNumber: 241-230-3. Catalog: ACM17185294. | |
| Chloro(1,5-cyclooctadiene)rhodium(I) dimer | Catalyst for coupling 1,3-dienes with activate methylene compounds. Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones. Rhodium source for asymmetric reductive aldol reaction. Cis-hydroboration of terminal alkynes. Rhodium source for [5 + 2] additions. Highly enantioselective for [2+2+2] carbocyclization reactions. Enantioselective hydroboration of cyclopropenes. Group: Rhodium series of catalysts. Alternative Names: Bis(cycloocta-1,5-diene)dichlorodirhodium. CAS No. 12092-47-6. Molecular formula: C16H24Cl2Rh2. Mole weight: 493.08. Appearance: Orange yellow powder. Purity: 0.98. IUPACName: (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride. Canonical SMILES: C1CC=CCCC=C1. C1CC=CCCC=C1. [Cl-]. [Cl-]. [Rh]. [Rh]. ECNumber: 235-157-6. Catalog: ACM12092476-2. | |
| Chlorobis(cyclooctene)rhodium(I) dimer | Rhodium series of catalysts. Alternative Names: Cyclooctene;rhodium;dichloride. CAS No. 12279-09-3. Molecular formula: C32H56Cl2Rh2. Mole weight: 717.5. Appearance: Orange to red crystal. Purity: 98%+. IUPACName: cyclooctene;rhodium;dichloride. Canonical SMILES: C1CCCC=CCC1. C1CCCC=CCC1. C1CCCC=CCC1. C1CCCC=CCC1. [Cl-]. [Cl-]. [Rh]. [Rh]. Catalog: ACM12279093-1. | |
| Chlorobis(ethylene)rhodium(I) Dimer | Rhodium series of catalysts. Alternative Names: Chlorobis(ethylene)rhodium(I) Dimer;12081-16-2;micro-Dichlorotetraethylene dirhodium(I); Dichlorotetra(ethylene)dirhodium(I); QPOCZCJMFQWGSP-UHFFFAOYSA-L; AKOS015964160. CAS No. 12081-16-2. Molecular formula: C8H16Cl2Rh2-2. Mole weight: 388.927g/mol. IUPACName: ethene;rhodium;dichloride. Canonical SMILES: C=C. C=C. C=C. C=C. [Cl-]. [Cl-]. [Rh]. [Rh]. ECNumber: 235-145-0. Catalog: ACM12081162. | |
| Chlorotris (triphenylphosphine)rhodium (I) | Chlorotris (triphenylphosphine)rhodium (I). CAS No. 4694-95-2. Product ID: PE-0335. Molecular formula: RhCl[P(C6H5)3]3. Mole weight: 925.23 g/mol. Category: Catalysts. Product Keywords: Pharmaceutical Excipients; Catalysts; Chlorotris (triphenylphosphine)rhodium (I); PE-0335; 4694-95-2; RhCl[P(C6H5)3]3; Wilkinsons catalyst; 4694-95-2. Appearance: Magenta crystals. Synonym(s): Wilkinsons catalyst. Precious Metal Content(dry basis): 0.111. |  |
| Diiodo(p-cymene)ruthenium(II) dimer | Our company can provide customers with rich supported precious metal catalyst products such as palladium series, platinum series, rhodium series and ruthenium series. Our catalysts not only have high catalytic efficiency, strong selectivity, and recyclability, but also can be used in organic reactions such as hydrogenation, dehydrogenation, amination, and cyclization. In addition, some products can also be used as raw materials for various precious metal compounds. The company has formed a series of proprietary and characteristic process technologies, and is currently undergoing process improvement and upgrading. In short, our catalytic products can be widely used in medicine, new chemical materials, pesticides, dyes and pigments, environmental protection, new energy, electronics, basic chemicals and other fields. Uses: ·for ruthenium-catalyzed hydrogenation; ·for the preparation of wolfoss-type ferrocene aryl diphosphine ligands; ·for enantioselective hydrogenation of ketones and alkenes. Group: Ruthenium series catalysts. Alternative Names: Di-μ-iodobis(p-cymene)iodoruthenium(II). CAS No. 90614-07-6. Molecular formula: C20H30I4Ru2. Mole weight: 978.19 g/mol. Appearance: Solid. Purity: 0.97. Canonical SMILES: I[Ru]1[I][Ru](I)[I]1. C[C]2[CH][CH][C]([CH][CH]2)C(C)C. C[C]3[CH][CH][C]([CH][CH]3)C(C)C. Catalog: ACM90614076-2. | |
| Di-μ-chloro-tetracarbonyldirhodium(I) | Catalyst used for a wide range of cycloadditions reactions. Group: Rhodium series of catalysts. Alternative Names: Rhodium carbonyl chloride(I). CAS No. 14523-22-9. Molecular formula: [Rh(CO)2Cl]2. Mole weight: 388.76. Appearance: orange-red crystals. Purity: Rh 52.9%. Catalog: ACM14523229. | |
| Hydridotetrakis (triphenylphosphine)rhodium (I) | Starting material for the preparation of a rhodium/phosphine complex used in the synthesis of diarylsulfides from aryl fluorides and sulfur/organopolysulfides. Group: Rhodium series of catalysts. Alternative Names: Rhodium;triphenylphosphane. CAS No. 18284-36-1. Molecular formula: C72H60P4Rh. Mole weight: 1152. Appearance: Powder. Purity: 0.99. IUPACName: rhodium;triphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Rh]. Catalog: ACM18284361-1. | |
| Methoxy(cyclooctadiene)rhodium(I) dimer | Rhodium series of catalysts. Alternative Names: (1Z,5Z)-Cycloocta-1,5-diene;methanol;rhodium. CAS No. 12148-72-0. Molecular formula: C18H32O2Rh2. Mole weight: 486.3. Appearance: Yellow powder. Purity: 0.98. IUPACName: (1Z,5Z)-cycloocta-1,5-diene;methanol;rhodium. Canonical SMILES: CO. CO. C1CC=CCCC=C1. C1CC=CCCC=C1. [Rh]. [Rh]. Catalog: ACM12148720-1. | |
| Norbornadiene Rhodium(I) Chloride Dimer | Rhodium series of catalysts. Alternative Names: bicyclo[2.2.1]hepta-2,5-diene; Bis((2,3,5,6-eta)-bicyclo(2.2.1)hepta-2,5-diene)di-mu-chlorodirhodium; rhodium(2+); Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer; AC1L3FOH; EINECS 235-510-4. CAS No. 12257-42-0. Molecular formula: C14H16Cl2Rh. Mole weight: 358.087g/mol. IUPACName: bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride. Canonical SMILES: C1C2C=CC1C=C2. C1C2C=CC1C=C2. [Cl-]. [Cl-]. [Rh+2]. ECNumber: 235-510-4. Catalog: ACM12257420. | |
| (Pentamethylcyclopentadienyl)rhodium (III) Dichloride Dimer | Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids. Catalyst used in the asymmetric transfer hydrogenation of imines in water. Facile rhodium-catalyzed synthesis of fluorinated pyridines. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates. Group: Rhodium series of catalysts. Alternative Names: Bis (pentamethylcyclopentadienylrhodium dichloride). CAS No. 12354-85-7. Molecular formula: C20H30Cl4Rh2. Mole weight: 618.07. Appearance: crimson powder. Purity: Rh ≥32.7%. Catalog: ACM12354857. | |
| (R)-4, 12-Bis(4-methoxyphenyl)-[2. 2]-paracyclophane(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% | Catalyst use in the efficient, enantioselective synthesis of β,β-disubstituted carboxylic acids. Group: Rhodium catalysts. Alternative Names: (S)-4, 12-Bis(4-methoxyphenyl)-[2. 2]-paracyclophane(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate; [(S)-4, 12-Bis[di(4-methoxyphenyl)phosphino][2. 2]paracyclophane](1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate; [Rh COD (S)-AnPhanephos]BF4, Rh 10.4%; [Rh COD (R)-AnPhanephos]BF4, Rh 10.4%; [(R)-4, 12-Bis[di(4-methoxyphenyl)phosphino][2. 2]paracyclophane](1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate. CAS No. 1038932-67-0. Molecular formula: C52H54BF4O4P2Rh-. Mole weight: 994.657g/mol. IUPACName: [11-bis(4-methoxyphenyl)phosphanyl-5-tricyclo[8.2.2.24, 7]hexadeca-1(12), 4, 6, 10, 13, 15-hexaenyl]-bis(4-methoxyphenyl)phosphane;(1Z, 5Z)-cycloocta-1, 5-diene;rhodium;tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F)F. COC1=CC=C (C=C1)P (C2=CC=C (C=C2)OC)C3=C4CCC5=CC (=C (CCC (=C3)C=C4)C=C5)P (C6=CC=C (C=C6)OC)C7=CC=C (C=C7)OC. C1CC=CCCC=C1. [Rh]. Catalog: ACM1038932670. | |
| (R)-(-)-4, 12-Bis(diphenylphosphino)[2. 2]paracyclophane(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% | Catalyst use in the asymmetric synthesis of an imidazole-substituted delta-amino acid. Group: Rhodium catalysts. Alternative Names: MFCD16294983;849950-56-7;[Rh COD (R)-Phanephos]BF4;[Rh COD (R)-Phanephos]BF4, Rh 11. 8%; (S)-(+)-4, 12-Bis(diphenylphosphino)[2. 2]paracyclophane(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate; [(R)-4, 12-Bis(diphenylphosphino)[2. 2]paracyclophane](1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate. CAS No. 849950-56-7. Molecular formula: C48H46BF4P2Rh-. Mole weight: 874.553g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; (11-diphenylphosphanyl-5-tricyclo[8.2.2.24, 7]hexadeca-1(12), 4, 6, 10, 13, 15-hexaenyl)-diphenylphosphane; rhodium; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F)F. C1CC=CCCC=C1. C1CC2=C (C=C (CCC3=C (C=C1C=C3)P (C4=CC=CC=C4)C5=CC=CC=C5)C=C2)P (C6=CC=CC=C6)C7=CC=CC=C7. [Rh]. Catalog: ACM849950567. | |
| Rhodium on alumina | Rhodium metal fume is a reddish-gray to black dust-like powder. mp: 1966° C, bp: 3727°C. Insoluble in water. Bulk rhodium is a white or blueish-white, hard, ductile, malleable metal. The appearance and other properties of insoluble Rh compounds varies depending upon the specific compound.;DryPowder, OtherSolid;GREY-TO-BLACK POWDER.;Appearance and odor vary depending upon the specific soluble rhodium compound.;Metal: White, hard, ductile, malleable solid with a bluish-gray luster. Uses: At ordinary temperatures rhodium is stable in air. when heated above 600°c, it oxidizes to rh2o3, forming a dark oxide coating on its surface. the gray crystalline sesquioxide has a corundom-like crystal structure. the sesquioxide, rh2o3 , decomposes back to its elements when heated above 1,100°c. however, on further heating the metal starts to lose its weight similar to platinum, probably due to. Group: Fuel cell catalysts. Product ID: rhodium. Molecular formula: 102.9055g/mol. Mole weight: Rh. [Rh]. InChI=1S/Rh. MHOVAHRLVXNVSD-UHFFFAOYSA-N. |  |
| Rhodium on carbon | Rhodium metal fume is a reddish-gray to black dust-like powder. mp: 1966° C, bp: 3727°C. Insoluble in water. Bulk rhodium is a white or blueish-white, hard, ductile, malleable metal. The appearance and other properties of insoluble Rh compounds varies depending upon the specific compound.;DryPowder, OtherSolid;GREY-TO-BLACK POWDER.;Appearance and odor vary depending upon the specific soluble rhodium compound.;Metal: White, hard, ductile, malleable solid with a bluish-gray luster. Uses: At ordinary temperatures rhodium is stable in air. when heated above 600°c, it oxidizes to rh2o3, forming a dark oxide coating on its surface. the gray crystalline sesquioxide has a corundom-like crystal structure. the sesquioxide, rh2o3 , decomposes back to its elements when heated above 1,100°c. however, on further heating the metal starts to lose its weight similar to platinum, probably due to. Group: Fuel cell catalysts. Product ID: rhodium. Molecular formula: 102.9055g/mol. Mole weight: Rh. [Rh]. InChI=1S/Rh. MHOVAHRLVXNVSD-UHFFFAOYSA-N. | |
| Rhodium oxide hydrate | Rhodium series of catalysts. Alternative Names: Rhodium(III) oxide hydrate;123542-79-0;Rhodium oxide (RH2O3),hydrate (1: ). CAS No. 123542-79-0. Molecular formula: H2O4Rh2. Mole weight: 271.823g/mol. IUPACName: oxygen(2-);rhodium(3+);hydrate. Canonical SMILES: O.[O-2].[O-2].[O-2].[Rh+3].[Rh+3]. Catalog: ACM123542790. | |
| (R,R)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane | Rhodium DIPAMP catalysts have shown high activity and enantioselectivity in the asymmetric hydrogenation of enamides, enol acetates and olefins. Group: Polydentate phosphine ligands. Alternative Names: (-)-DIPAMP; UNII-BLJ831OWLW; B3035; ST24036671; (S,S)-Ethylenebis[(2-methoxyphenyl)phenylphosphine]; AKOS008901415; OR310818; (R, R)- (-)-1, 2-Bis[2-methoxyphenyl) (phenyl)phosphino]ethane; GS-0006; (R,R)-DIPAMP. CAS No. 55739-58-7. Molecular formula: C28H28O2P2. Mole weight: 458.478g/mol. IUPACName: (R) - (2-methoxyphenyl) - [2- [ (2-methoxyphenyl) -phenylphosphanyl] ethyl] -phenylphosphane. Canonical SMILES: COC1=CC=CC=C1P (CCP (C2=CC=CC=C2) C3=CC=CC=C3OC) C4=CC=CC=C4. Catalog: ACM55739587. | |
| (R, R)- (-)-1, 2-Bis[ (o-methoxyphenyl) (phenyl)phosphino]ethane (1, 5-cyclooctadiene)rhodium (I) tetrafluoroborate, min. 95% | Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone. Efficient catalyst for the asymmetric reduction of enol acetates to esters. Catalyst used to prepare chiral 2-substituted succinic acid derivatives. Group: Rhodium series of catalysts. Alternative Names: DTXSID10448656; 56977-92-5; SC-67687; (R, R)- (-)-1, 2-bis[ (o-methoxyphenyl) (phenyl)phosphino]ethane (1,5-cyclooctadiene) rhodium (I) tetrafluroborate; (1Z, 5Z) -cycloocta-1, 5-diene, (R) - (2-methoxyphenyl) - [2- [ (2-methoxyphenyl) -phenylphosphanyl] ethyl] -phenylphosphane, rhodium, tetrafluoroborate; (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHI; BP-12198. CAS No. 56977-92-5. Molecular formula: C36H40BF4O2P2Rh-. Mole weight: 756.371g/mol. IUPACName: (1Z, 5Z) -cycloocta-1, 5-diene; (R) - (2-methoxyphenyl) - [2- [ (2-methoxyphenyl) -phenylphosphanyl] ethyl] -phenylphosphane; rhodium; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F) F. COC1=CC=CC=C1P (CCP (C2=CC=CC=C2) C3=CC=CC=C3OC) C4=CC=CC=C4. C1CC=CCCC=C1. [Rh]. Catalog: ACM56977925. | |
| [RuCl(p-cymene)((S)-tolbinap)]Cl | 1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C | |
| (S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine | Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α-dehydroaminoesters, enamides, and dimethylitaconate. Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts. Group: Heterocyclic organic compound. Alternative Names: 879083-09-7; AJ-108734; SC11376; (S)-(+)-4-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-piperidine; (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a; SCHEMBL15422481; (R)-1-(DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-YL)PIPERIDINE; 2, 2'-[ (Piperidinophosphinediyl)dioxy]-1, 1'-binaphthalene; 636559-55-2; ZINC43681909. CAS No. 284472-79-3. Molecular formula: C25H22NO2P. Mole weight: 399.43g/mol. IUPACName: 1-(12, 14-dioxa-13-phosphapentacyclo[13.8.0.02, 11.03, 8.018, 23]tricosa-1(15), 2(11), 3, 5, 7, 9, 16, 18, 20, 22-decaen-13-yl)piperidine. Canonical SMILES: C1CCN (CC1)P2OC3=C (C4=CC=CC=C4C=C3)C5=C (O2)C=CC6=CC=CC=C65. Catalog: ACM284472793. | |
| (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% | Highly enantioselective hydrogenation of β-alkyl-substituted (E)-β-(acylamino)-acrylates. Group: Rhodium catalysts. CAS No. 1174131-02-2. Molecular formula: C46H46BF4N2O4P2Rh. Mole weight: 942.53. Catalog: ACM1174131022. | |
| (S)-(+)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% | Catalyst for the enantioselective hydrogenation of unsaturated amino acid derivatives. Group: Rhodium catalysts. Alternative Names: (R)- (-)-4, 12-Bis (di-3, 5-xylylphosphino)[2. 2]paracyclophane (1, 5-cyclooctadiene)rhodium (I)tetrafluoroborate; [Rh COD (R)-Xyl-Phanephos]BF4; 1174218-30-4; MFCD09264280; [(S)-4, 12-Bis[di(3, 5-xylyl)phosphino][2. 2]paracyclophane](1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; [(R)-4, 12-Bis[di(3, 5-xylyl)phosphino][2. 2]paracyclophane](1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate. CAS No. 1174218-30-4. Molecular formula: C56H62BF4P2Rh-. Mole weight: 986.769g/mol. IUPACName: [11-bis(3, 5-dimethylphenyl)phosphanyl-5-tricyclo[8.2.2.24, 7]hexadeca-1(12), 4, 6, 10, 13, 15-hexaenyl]-bis(3, 5-dimethylphenyl)phosphane;(1Z, 5Z)-cycloocta-1, 5-diene;rhodium;tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F)F. CC1=CC (=CC (=C1)P (C2=CC (=CC (=C2)C)C)C3=C4CCC5=CC (=C (CCC (=C3)C=C4)C=C5)P (C6=CC (=CC (=C6)C)C)C7=CC (=CC (=C7)C)C)C. C1CC=CCCC=C1. [Rh]. Catalog: ACM1174218304. | |
| Silver Trifluoromethane sulfonate | Silver Trifluoromethane sulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes. Group: Biochemicals. Alternative Names: Silver triflate; Trifluoromethane sulfonic acid silver salt. Grades: Highly Purified. CAS No. 2923-28-6. Pack Sizes: 10g, 25g, 50g, 100g. Molecular Formula: CHF3O3S, Molecular Weight: 256.94. US Biological Life Sciences. | Worldwide |
| (S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane | Rhodium DIPAMP catalysts have shown high activity and enantioselectivity in the asymmetric hydrogenation of enamides, enol acetates and olefins. Group: Heterocyclic organic compound. Alternative Names: Ethylenebis[(S)-(o-anisyl)(phenyl)phosphine]; MFCD05863547; (S,S)-DIPAMP, >=95%; AB1011200; (1S,2S)-(+)-Bis[(2-methoxyphenyl)phenylphosphino]ethane; UNII-HS6F5EW3U6; OR310819; ST24036672. CAS No. 97858-62-3. Molecular formula: C28H28O2P2. Mole weight: 458.478g/mol. IUPACName: (S) - (2-methoxyphenyl) - [2- [ (2-methoxyphenyl) -phenylphosphanyl] ethyl] -phenylphosphane. Canonical SMILES: COC1=CC=CC=C1P (CCP (C2=CC=CC=C2) C3=CC=CC=C3OC) C4=CC=CC=C4. Catalog: ACM97858623. | |
| (S, S)- (+)-1, 2-Bis[ (o-methoxyphenyl) (phenyl)phosphino]ethane (1, 5-cyclooctadiene)rhodium (I) tetrafluoroborate, min. 95% | Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone. Efficient catalyst for the asymmetric reduction of enol acetates to esters. Catalyst used to prepare chiral 2-substituted succinic acid derivatives. Group: Rhodium series of catalysts. Alternative Names: 71423-54-6; MFCD01074456; (S, S)- (+)-1, 2-BIS[ (O-METHOXYPHENYL) (PHENYL)PHOSPHINO]ETHANE (1, 5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE; RH- (S, S) -DIPAMP; SC10327; (1Z, 5Z) -cycloocta-1, 5-diene, (S) - (2-methoxyphenyl) - [2- [ (2-methoxyphenyl) -phenylphosphanyl] ethyl] -phenylphosphane, rhodium, tetrafluoroborate; [ ( (S, S) -1, 2-BIS [ (2-METHOXYPHENYL) (PHENYL) PHOSPHINO] ETHANE) (1, 5. CAS No. 71423-54-6. Molecular formula: C36H40BF4O2P2Rh-. Mole weight: 756.371g/mol. IUPACName: (1Z, 5Z) -cycloocta-1, 5-diene; (S) - (2-methoxyphenyl) - [2- [ (2-methoxyphenyl) -phenylphosphanyl] ethyl] -phenylphosphane; rhodium; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F) F. COC1=CC=CC=C1P (CCP (C2=CC=CC=C2) C3=CC=CC=C3OC) C4=CC=CC=C4. C1CC=CCCC=C1. [Rh]. Catalog: ACM71423546. | |
| (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP* | Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides. Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates. Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones. Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes. Ligand for the silver-catalyzed asymmetric nitroso aldol reaction. Group: Polydentate phosphine ligandsphosphorus catalysts. Alternative Names: (S, S)-(+)-2, 3-Bis(t-butylmethylphosphino)quinoxaline; 1107608-80-9; (S, S)-2, 3-Bis(tert-butylmethylphosphino)quinoxaline; (S, S)-QuinoxP*; SCHEMBL2559367; 2, 3-Bis[(S)-tert-butylmethylphosphino]quinoxaline; J-002473; (S, S)-(+)-2, 3-Bis(tert-butylmethylphosphino)quinoxaline. CAS No. 1107608-80-9. Molecular formula: C18H28N2P2. Mole weight: 334.384g/mol. IUPACName: (S)-tert-butyl-[3-[tert-butyl(methyl)phosphanyl]quinoxalin-2-yl]-methylphosphane. Canonical SMILES: CC (C) (C)P (C)C1=NC2=CC=CC=C2N=C1P (C)C (C) (C)C. Catalog: ACM1107608809. | |
| Tetrakis[5-t-butyl-phthaloyl-N-(S)-tert-leucinato]dirhodium bis(ethyl acetate) adduct Rh2(S-tertPTTL)4 | Catalyst used for the asymmetric, intermolecular C-H insertion of 1,4-cyclohexadiene with α-alkyl-α-diazoesters. Catalyst used for a catalytic cyclopropanation using diazooxindole. Catalyst used for the asymmetric, intramolecular C-H insertion of sulfonyldiazoacetates. Catalyst used for the enantioselective synthesis of 2-arylbicyclo[1.1.0]butane carboxylates. Access to the [3.2.2] nonatriene structural frameworks via an intramolecular cyclopropenation/Buchner reaction/Cope rearrangement cascade. Catalyst used for the cyclopropanation of styrene with dimethyl-α -diazobenzylphosphonate. Group: Rhodium catalysts. CAS No. 1884452-99-6. Molecular formula: C72H88N4O16Rh2. Mole weight: 1471.3. Catalog: ACM1884452996. | |
| Tetrakis[N-1,8-naphthalenedicarbonyl-(S)-tert-leucinato]dirhodium bis(ethyl acetate) adduct | . Uses: Transition metal catalysts. Synonyms: Rhodium, tetrakis[μ-[(αS)-α-(1,1-dimethylethyl)-1,3-dioxo-1H-benz[de]isoquinoline-2(3H)-acetato-κO2:κO2']]di-, (Rh-Rh); Tetrakis[N-1,8-naphthalene dicarbonyl-(S)-tert-leucinato] Dirhodium Bis(ethyl acetate) Adduct; Rh2(S-NTTL)4; Rh2[(S)-NTTL]4. Grades: ≥95%. CAS No. 575456-77-8. Molecular formula: C72H64N4O16Rh2. Mole weight: 1447.11. | |
| Tetrakis[ (R) - (+) -N- (p-dodecylphenylsulfonyl) prolinato]dirhodium (II) Rh2(R-DOSP)4 | Catalyst used for tandem asymmetric cyclopropanation/Cope rearrangement. Catalyst used for an asymmetric [4 + 3] cycloaddition. Group: Rhodium series of catalysts. Alternative Names: AKOS015909399; 178879-60-2; Tetrakis[ (R) - (+) -N- (p-dodecylphenylsulfonyl) prolinato]dirhodium (II) , AldrichCPR; MFCD04974245; TETRAKIS[ (R) - (+) -N- (4-DODECYLPHENYLSULFONYL) PROLINATO]DIRHODIUM (II) ; TETRAKIS[ (R) - (+) -N- (P-DODECYLPHENYLSULFONYL) PROLINATO]DIRHODIUM (II). CAS No. 178879-60-2. Molecular formula: C92H148N4O16Rh2S4. Mole weight: 1900.259g/mol. IUPACName: (2R)-1-(4-dodecylphenyl)sulfonylpyrrolidine-2-carboxylic acid;rhodium. Canonical SMILES: CCCCCCCCCCCCC1=CC=C (C=C1)S (=O) (=O)N2CCCC2C (=O)O. CCCCCCCCCCCCC1=CC=C (C=C1)S (=O) (=O)N2CCCC2C (=O)O. CCCCCCCCCCCCC1=CC=C (C=C1)S (=O) (=O)N2CCCC2C (=O)O. CCCCCCCCCCCCC1=CC=C (C=C1)S (=O) (=O)N2CCCC2C (=O)O. [Rh]. [Rh]. Catalog: ACM178879602. | |
| TMEDA (1,5-cyclooctadiene) rhodium(I)/dichloro(1,5-cyclooctadiene)rhodium(I) complex | Rhodium Catalysts. Alternative Names: (1Z, 5Z)-Cycloocta-1, 5-diene;dichlororhodium(1-);rhodium;N, N, N', N'-tetramethylethane-1, 2-diamine. CAS No. 108559-48-4. Molecular formula: C22H40Cl2N2Rh2. Mole weight: 609.3. Purity: 0.98. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene;dichlororhodium(1-);rhodium;N, N, N', N'-tetramethylethane-1, 2-diamine. Canonical SMILES: CN(C)CCN(C)C. C1CC=CCCC=C1. C1CC=CCCC=C1. Cl[Rh-]Cl. [Rh]. Catalog: ACM108559484-1. | |
| Tris(triphenylphosphine)rhodium(I) chloride | A homogeneous hydrogenation catalyst which operates under mild conditions. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reactions. Alkyne hydro-phosphorylation Heck-type reaction with α,β-unsaturated esters. Alkyne arylation Allylic alcohol-olefin coupling. Terminal alkenes from ketones. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. Reductive deprotection of silyl groups. Group: Rhodium series of catalysts. Alternative Names: Chlorotris- (triphenylphosphino)-rhodium. CAS No. 14694-95-2. Molecular formula: C54H45ClP3Rh. Mole weight: 925.21. Appearance: Magenta crystal. Purity: 0.98. IUPACName: rhodium;triphenylphosphane;chloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Rh]. ECNumber: 238-744-5. Catalog: ACM14694952-1. | |
| 1, 2-Bis [ (s, s) -2, 5-diphenylphospholano] ethane- (1, 5-cycloocta-diene) rhodium (I) tetrafluoroborate | An asymmetric hydrogenation catalyst. Group: Biochemicals. Grades: Highly Purified. Pack Sizes: 5mg. US Biological Life Sciences. | Worldwide |
| 1,3-Dicyclohexylbenzimidazolium chloride | Catalyst in rhodium-N-heterocyclic carbene complex-catalyzed O-arylation of phenols with arylbromides Reactant in preparation of Pd-PEPPSI complexes for catalysis of cross-coupling reactions. Group: Carbon-donor ligands. Alternative Names: 1,3-Dicyclohexylbenzimidazolium chloride;1034449-15-4;1,3-Dicyclohexylbenzimidazolium chloride, 95%; SCHEMBL1045366; CTK8F2972; DTXSID50584845; MFCD08705248; OR450041; 1, 3-Dicyclohexyl-1H-benzimidazol-3-ium chloride. CAS No. 1034449-15-4. Molecular formula: C19H27ClN2. Mole weight: 318.889g/mol. IUPACName: 1,3-dicyclohexylbenzimidazol-3-ium;chloride. Canonical SMILES: C1CCC (CC1)N2C=[N+] (C3=CC=CC=C32)C4CCCCC4. [Cl-]. Catalog: ACM1034449154. | |
| (1, 5-Cyclooctadiene) [ (α R, α R) -2, 2'-bis (α -N, N-dimethylaminophenylmethyl) - (S, S) -1, 1'-bis (diphenylphosphino) ferrocenyl]rhodium (I) tetrafluoroborate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation; Hydrogenation→Transfer Hydrogenation. Group: Catalysts for pharmaceutical. CAS No. 673458-82-7. Molecular formula: C60H62N2BF4FeP2Rh. Mole weight: 1118.66. Appearance: orange. Purity: Metal purity 99.95. Catalog: ACM673458827. | |
| (1, 5-Cyclooctadiene) [ (α R, α R) -2, 2'-bis (a-N, N-dimethylaminophenylmethyl) - (S, S) -1, 1'-bis[di- (3, 5-dimethyl-4-methoxyphenyl) phosphino]ferrocenyl]rhodium (I) tetrafluoroborate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation; Hydrogenation→Transfer Hydrogenation. Group: Catalysts for pharmaceutical. CAS No. 827596-70-3. Molecular formula: C72H86N2BF4FeO4P2Rh. Mole weight: 1350.98. Appearance: red. Purity: Metal purity 99.95. Catalog: ACM827596703. | |
| (1, 5-Cyclooctadiene) [ (R) -1-dicyclohexylphosphino-2-[ (R) -α - (N, N-dimethylamino) -o- (dicyclohexylphosphinophenyl) methyl]ferrocenyl]rhodium (I) tetrafluoroborate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation; Hydrogenation→Transfer Hydrogenation. Group: Catalysts for pharmaceutical. CAS No. 827596-68-9. Molecular formula: C51H75NBF4FeP2Rh. Mole weight: 1109.66. Appearance: orange. Purity: Metal purity 99.95. Catalog: ACM827596689. | |
| (1, 5-Cyclooctadiene) [ (R) -1-diphenylphosphino-2-[ (R) -α - (N, N-dimethylamino) -ortho- (diphenylphosphinophenyl) methyl]ferrocenyl]rhodium (I) tetrafluoroborate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation; Hydrogenation→Transfer Hydrogenation. Group: Catalysts for pharmaceuticalasymmetric reactions. CAS No. 673458-84-9. Molecular formula: C51H51NBF4FeP2Rh. Mole weight: 985.47. Appearance: orange. Purity: Metal purity 99.95. Catalog: ACM673458849-1. | |
| (1, 5-Cyclooctadiene) [ (R) -1-[ (R) -2- (2'-diphenylphosphinophenyl) ferrocenyl]-ethyldi- (bis-3, 5-trifluoromethylphenyl) phosphine]rhodium (I) tetrafluoroborate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation; Hydrogenation→Transfer Hydrogenation. Group: Catalysts for pharmaceuticalasymmetric reactions. CAS No. 673458-88-3. Molecular formula: C54H44BF16FeP2Rh. Mole weight: 1228.42. Appearance: red orange. Purity: Metal purity 99.95. Catalog: ACM673458883-2. | |
| (1, 5-Cyclooctadiene) [ (R) -1-[ (R) -2- (diphenylphosphino) ferrocenyl]-ethyldi- tert -butylphosphino]rhodium(I) tetrafluoroborate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation; Hydrogenation→Transfer Hydrogenation; Ring Opening Reaction. Group: Catalysts for pharmaceuticalasymmetric reactions. CAS No. 673458-86-1. Molecular formula: C40H52BF4FeP2Rh. Mole weight: 840.35. Appearance: orange. Purity: Metal purity 99.95. Catalog: ACM673458861-1. | |
| (1S, 4S)-2, 5-Diphenylbicyclo[2, 2, 2]octa-2, 5-diene | (1S, 4S)-2, 5-Diphenylbicyclo[2, 2, 2]octa-2, 5-diene is widely used as a catalyst in various syntheses such as asymmetric preparation of allylsilanes by rhodium/chiral diene-catalyzed 1,4-addition of alkenyl (hydroxymethylphenyl) dimethylsilanes. Group: Biochemicals. Grades: Highly Purified. CAS No. 850409-83-5. Pack Sizes: 25mg, 50mg. Molecular Formula: C20H18, Molecular Weight: 258.36. US Biological Life Sciences. | Worldwide |
| 2,6-Bis[1-(2-methylphenylimino)ethyl]pyridine | Ligand for iron catalyzed ethene polymerization, activated and heterogenized with a co-catalyst consisting of partially hydrolyzed trimethylaluminum on silica gel Ligand for chromium catalyzed of ethylene oligomerization Ligand for rhodium bis(imino)pyridine complex, that generates nanoparticles and effectively catalyses dehalogenation and hydrogenation of aromatic Compounds. Group: Heterocyclic organic compound. Alternative Names: N,N'-(2,6-Pyridinediyldiethylidyne)bis[2-methylbenzenamine. CAS No. 210537-32-9. Molecular formula: C23H23N3. Mole weight: 341.45. Appearance: Yellow powder. Purity: 0.98. IUPACName: 1-[6-[C-methyl-N-(2-methylphenyl)carbonimidoyl]pyridin-2-yl]-N-(2-methylphenyl)ethanimine. Canonical SMILES: CC1=CC=CC=C1N=C (C)C2=NC (=CC=C2)C (=NC3=CC=CC=C3C)C. Catalog: ACM210537329-1. | |
| 2-(Dicyclohexylphosphino)-N,N-diisopropyl-1H-indole-1-carboxamide | CHLORONORBORNADIene TRIPHENYLPHOSPHINERHODium (I) is versatile polymer-bound catalyst used for the selective hydrogenation of polyolefins. The supported rhodium catalyst exhibits similar selectivity to its homogeneous counterpart. In most cases, rhodium leaching is negligible. Group: Heterocyclic organic compound. Alternative Names: SCHEMBL17513080; MFCD20257903; ZINC86032091; 1067175-36-3; 2-(Dicyclohexylphosphino)-N, N-bis(1-methylethyl)-1H-indole-1-carboxamide; 2-(Dicyclohexylphosphino)-N, N-diisopropyl-1H-indole-1-carboxamide, 97%. CAS No. 1067175-36-3. Molecular formula: C27H41N2OP. Mole weight: 440.612g/mol. IUPACName: 2-dicyclohexylphosphanyl-N,N-di(propan-2-yl)indole-1-carboxamide. Canonical SMILES: CC (C)N (C (C)C)C (=O)N1C2=CC=CC=C2C=C1P (C3CCCCC3)C4CCCCC4. Catalog: ACM1067175363. | |
| 3-Di-i-propylphosphoranylidene-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)rhodium(I), min. 95% | Zwitterionic hydrogenation, hydrosilylation and hydroboration catalyst soluble in non-polar solvents. Group: Heterocyclic organic compound. Alternative Names: MFCD09264278;540492-55-5. CAS No. 540492-55-5. Molecular formula: C27H48NPRh-2. Mole weight: 520.567g/mol. Canonical SMILES: [CH3-]. [CH3-]. CC (C)P (=C1C (CC2C1C=CC=C2)N (C)C)C (C)C. C1CC=CCCC=C1. [Rh]. Catalog: ACM540492555. | |
| Antioxidant 168 | Precursor to a palladacyclic catalyst for Suzuki, Stille and Heck processes. Ligand for Pd-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes. Ligand for Pt-catalyzed intramolecular silaboration of alkenes. Ligand for Ni-catalyzed aminocarbonylation of aryl halides. Ligand for the Au-catalyzed [4+2] intramolecular cycloaddition of allene-dienes. Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent. Alternative Names: Phenol,2,4-bis(1,1-dimethylethyl,phosphite(3:1). CAS No. 31570-04-4. Molecular formula: C42H63O3P. Mole weight: 646.92. Appearance: White solid. Purity: 0.98. Catalog: ACM31570044. | |
| Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate | Asymmetric Reactions; Hydrogenation→Asymmetric Hydrogenation. Group: Catalysts for pharmaceutical. CAS No. 404573-66-6. Molecular formula: C48H36BF24Rh. Mole weight: 1182.49. Appearance: orange. Purity: Metal purity 99.95. Catalog: ACM404573666. | |
| Chloro(1,5-cyclooctadiene)rhodium(I) dimer | Chloro(1,5-cyclooctadiene)rhodium(I) dimer. Uses: Catalyst for coupling 1,3-dienes with activate methylene compounds. rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones. rhodium source for asymmetric reductive aldol reaction. cis-hydroboration of terminal alkynes. rhodium source for [5 + 2] additions. highly enantioselective for [2+2+2] carbocyclization reactions. enantioselective hydroboration of cyclopropenes. Group: Salt. Alternative Names: Bis(cycloocta-1,5-diene)dichlorodirhodium. CAS No. 12092-47-6. Product ID: (1Z,5Z)-cycloocta-1,5-diene; rhodium; dichloride. Molecular formula: 493.08. Mole weight: C16H24Cl2Rh2. C1CC=CCCC=C1. C1CC=CCCC=C1. [Cl-]. [Cl-]. [Rh]. [Rh]. InChI=1S/2C8H12. 2ClH. 2Rh/c2*1-2-4-6-8-7-5-3-1; /h2*1-2, 7-8H, 3-6H2; 2*1H; /p-2/b2*2-1-, 8-7-. PDJQCHVMABBNQW-MIXQCLKLSA-L. 98%. | |
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