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RockPhos Ligand used in the palladium-catalyzed C-O bond forming reactions of secondary and primary alcohols with a range of aryl halides. Heterocyclic halides and, for the first time, electron-rich aryl halides can be coupled with secondary alcohols. Group: Organic phosphine compounds. Alternative Names: ZINC95910984; 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2'-4'-6'-tri-i-propyl-1,1'-biphenyl; RockPhos, 97%; di-tert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane; Y-200021; Di-tert-butyl(2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-3-methoxy-6-methyl-[1,1 inverted exclamation marka-biphenyl]-2-yl)phosphine; CVLLAKCGAFNZHJ-UHFFFAOYSA-N; 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopropyl-1,1'-biphenyl; SCHEMBL12929986; AX8242285. CAS No. 1262046-34-3. Molecular formula: C31H49OP. Mole weight: 468.706g/mol. IUPACName: ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. Catalog: ACM1262046343. Alfa Chemistry. 2
Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] Palladium precatalyst used for the arylation of an aliphatic alcohol. Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions. Palladium precatalyst used for the intermolecular C-O bond formation with secondary and primary alcohols. Group: Palladium catalysts. Alternative Names: RockPhos Pd G3;[RockPhos Palladacycle]; MFCD27952542; 2009020-38-4; Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl)(2'-amino-1, 1'-biphenyl-2-yl)palladium(II). CAS No. 2009020-38-4. Molecular formula: C44H63NO4PPdS-. Mole weight: 839.445g/mol. IUPACName: ditert-butyl-[6-methoxy-3-methyl-2-[2, 4, 6-tri(propan-2-yl)phenyl]phenyl]phosphane; methanesulfonic acid;palladium;2-phenylaniline. Canonical SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. CS (=O) (=O)O. C1=CC=C ([C-]=C1)C2=CC=CC=C2N. [Pd]. Catalog: ACM2009020384. Alfa Chemistry. 2

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