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1, 1'-Bis (di-tert-butylphosphino) ferrocene. Group: Biochemicals. Grades: Highly Purified. CAS No. 84680-95-5. Pack Sizes: 1g, 2g, 5g, 10g, 25g. Molecular Formula: 2C13H23P·Fe. US Biological Life Sciences.
Worldwide
1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis(di-tert-butylphosphino)ferrocene is used in method for preparing bis-Aromatic compound through Suzuki coupling reaction. Group: Organic phosphine compounds. Alternative Names: 1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene; 1,1'-Bis(di-tert-butylphosphino)ferrocene; 1,1'-Bis[bis(tert-butyl)phosphino]ferrocene; DTBPF. CAS No. 84680-95-5. Molecular formula: C26H44FeP2. Mole weight: 474.42. Appearance: Solid. Purity: 0.98. IUPACName: 1,1-Bis(di-tert-butylphosphino)ferrocene. Catalog: ACM84680955-1.
[1, 1'-Bis (di-tert-butylphosphino) ferrocene] dichloropalladium (II)
[1, 1'-Bis (di-tert-butylphosphino) ferrocene] dichloropalladium (II) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives. Group: Biochemicals. Grades: Highly Purified. CAS No. 95408-45-0. Pack Sizes: 500mg, 1g. Molecular Formula: C26H44Cl2FeP2Pd. US Biological Life Sciences.
Worldwide
[1, 1'-Bis (di-tert-butylphosphino) ferrocene]palladium (II) Dichloride
[1, 1'-Bis (di-tert-butylphosphino) ferrocene]palladium (II) Dichloride. Group: Biochemicals. Alternative Names: [1, 1'-Bis (di-tert-butylphosphino) ferrocene] dichloropalladium (II) ; Dichloro[1, 1'-bis (di-tert-butylphosphino) ferrocene]palladium (II) . Grades: Highly Purified. CAS No. 95408-45-0. Pack Sizes: 100mg, 250mg, 500mg, 1g, 2g. US Biological Life Sciences.
Worldwide
[1, 1'-Bis (di-tert-butylphosphino)ferrocene]palladium (II) Dichloride
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride is used as a catalyst for the preparation of chalcones. Group: Palladium series catalysts. Alternative Names: PdCl2(dtbpf). CAS No. 95408-45-0. Molecular formula: C26H44Cl2FeP2Pd. Mole weight: 651.75. Appearance: dark red crystals. Purity: Pd ≥16.3%. IUPACName: Dichloro[1, 1-Bis (di-Tert-Butylphosphino)Ferrocene]Palladium (II). Catalog: ACM95408450.
Ligand used in the preparation of active Pd catalysts for C-C, C-N and C-O bond formation. Ligand used in Pd-catalyzed α-arylation of azlactones. Pd-catalyzed α-arylation of esters, amides and aldehydes. Group: Organic phosphine compounds. Alternative Names: Q-PHOS; CTC-Q-PHOS; 1,2,3,4,5-pentaphenyl-1-di-tert-butylphosphinoferrocene; 1,2,3,4,5-Pentaphenyl-1-(di-tert-butylphosphino)ferrocene. CAS No. 312959-24-3. Molecular formula: C48H47FeP. Mole weight: 710.72. Purity: 0.96. IUPACName: 1,2,3,4,5-PENTAPHENYL-1-(DI-TERT-BUTYLPHOSPHINO)FERROCENE. Catalog: ACM312959243.
2-(Di-tert-butylphosphino)-1,1'-binaphthyl 98% TrixiePhos is a reagent used as ligand in palladium-catalyzed C-O, C-N, and C-C bond forming reactions. Group: Biochemicals. Grades: Highly Purified. CAS No. 255836-67-0. Pack Sizes: 100mg, 250mg. Molecular Formula: C28H31P, Molecular Weight: 398.52. US Biological Life Sciences.
Useful ligand for the Pd-catalyzed amination reaction. Ligand used for the Pd-catalyzed arylation of phenols. Useful ligand for the Suzuki-Miyaura coupling. Ligand used for the Sonagashira reaction of aryl bromides. Group: Other phosphine ligands. Alternative Names: CTK8C6146; [cataCXium(R) POMetB]; SC11196; 2-(Di-tert-butylphosphanyl)-1-(2-methoxyphenyl)-1H-pyrrole; 1-(2-Methoxyphenyl)-2-(di-tert-butylphosphino)-1H-pyrrole; ZINC40450111; CATACXIUM(R) POMETB; 2-(Di.-tert.-butylphosphino)-1-(2-methoxy-phenyl)-1H-pyrrole; AKOS016000550; ACMC-20aon8. CAS No. 1053658-91-5. Molecular formula: C19H28NOP. Mole weight: 317.413g/mol. IUPACName: ditert-butyl-[1-(2-methoxyphenyl)pyrrol-2-yl]phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CN1C2=CC=CC=C2OC)C (C) (C)C. Catalog: ACM1053658915.
2-(Di-tert-butylphosphino)-1-phenylindole
Useful ligand for the Pd-catalyzed amination reaction. Ligand used for the Pd-catalyzed arylation of phenols. Useful ligand for the Suzuki-Miyaura coupling. Ligand used for the Sonagashira reaction of aryl bromides. Group: Heterocyclic organic compound. Alternative Names: ACMC-20aon6; CATACXIUM(R) PINTB; SC11197; N-PHENYL-2-(DI-T-BUTYLPHOSPHINO)INDOL; CTK5D9325; AKOS016012152; 1-Phenyl-2-(ditert-butylphosphino)-1H-indole; MFCD06798302; 740815-37-6; BP-12235. CAS No. 740815-37-6. Molecular formula: C22H28NP. Mole weight: 337.44. IUPACName: ditert-butyl-(1-phenylindol-2-yl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC2=CC=CC=C2N1C3=CC=CC=C3)C (C) (C)C. Catalog: ACM740815376.
Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles. Ligand used in the Pd-catalyzed synthesis of phenols from aryl halides and KOH. Ligand used in the Pd-catalyzed of benzoic acids from aryl halides and CO2. Ligand used in the Pd-catalyzed trifluoromethylation of vinyl sulfonates. Ligand used in the Pd-catalyzed arylation of nitroacetates. Ligand used in the Pd-catalyzed Suzuki-Miyaura cross-coupling of allylboronates and aryl halides. Ligand used in the Pd-catalyzed cyanation of (hetero)arylchlorides and bromides. Ligand used in the Pd-catalyzed C-N cross coupling of sulfinamides and aryl halides. Ligand used in the Pd-catalyzed arylation of cyanamides. Group: Organic phosphine compounds. Alternative Names: DTXSID70469549; t-Bu XPhos; FT-0689983; TC-121258; 2-Di-tert-butylphosphino-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropylbiphenyl; tBuXPhos; ditert-butyl-[2-(2,4,6-triisopropylphenyl)phenyl]phosphane; ZINC56961724; 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl; 2-(di-tert-butylphosphino)-2', 4',6'-triisopropylbiphenyl. CAS No. 564483-19-8. Molecular formula: C29H45P. Mole weight: 424.653g/mol. IUPACName: ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=CC=CC=C2P (C (C) (C)C)C (C) (C)C)C (C)C. Catalog: ACM5644
2- (Di-tert-butylphosphino) biphenyl (also known as JohnPhos) is a Buchwald ligand that is highly efficient in palladium-catalyzed reactions. Group: Biochemicals. Grades: Highly Purified. CAS No. 224311-51-7. Pack Sizes: 500mg, 1g. Molecular Formula: C20H27P, Molecular Weight: 298.399999999999. US Biological Life Sciences.
Worldwide
2-(Di-tert-butylphosphino)biphenyl
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in a very active and general catalyst for Suzuki coupling reactions using aryl chlorides, bromides and triflates. Ligand used in palladium-catalyzed synthesis of oxindoles from α-chloroacetanilides. Effective ligand used in palladium-catalyzed arylation of thiazoles. Used in the formation of 2-benzylindolines via sequential palladium-catalyzed N-arylation/cyclization/C-arylation. Selective in the palladium-catalyzed arylation of silyl enol ethers formed from copper-catalyzed reduction of enones. Group: Organic phosphine compounds. Alternative Names: (2-Biphenylyl)-Di-Tert-Butylphosphine. CAS No. 224311-51-7. Molecular formula: C20H27P. Mole weight: 298.4. Appearance: Solid. Purity: 0.98. IUPACName: ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Density: 1 g/cm3. Catalog: ACM224311517-1.
Gold Catalysts. Alternative Names: Bis(trifluoromethylsulfonyl)azanide; ditert-butyl-(2-phenylphenyl)phosphanium; gold(1+). CAS No. 1036000-94-8. Molecular formula: C22H28AuF6NO4PS2. Mole weight: 776.5. Purity: 0.98. Canonical SMILES: CC (C) (C)[PH+] (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. C (F) (F) (F)S (=O) (=O)[N-]S (=O) (=O)C (F) (F)F. [Au+]. Catalog: ACM1036000948-1.
2-(Di-tert-butylphosphino)dimethylaminobenzene
Ligand for the Copper-Catalyzed Suzuki-Miyaura Coupling of Arylboronate Esters and Aryl Iodides Ligand for the Copper-Catalyzed Coupling of Triaryl- and Trialkylindium reagents with Aryl Iodides and Bromides. Group: Other phosphine ligands. CAS No. 415941-58-1. Mole weight: 265.37. Catalog: ACM415941581.
[2- (Di-tert-butylphosphinomethyl) -6- (diethylaminomethyl) pyridine] carbonylchlorohydridoruthenium (II)
Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone. Group: Ruthenium series catalysts. Alternative Names: Carbonylchlorohydrido[6- (di-t-butylphosphinomethyl)-2- (N, N-diethylaminomethyl)pyridine]ruthenium (II); 863971-62-4. CAS No. 863971-62-4. Molecular formula: C20H37ClN2OPRu. Mole weight: 489.023g/mol. IUPACName: chlororuthenium;N-[[6-(ditert-butylphosphanylmethyl)pyridin-2-yl]methyl]-N-ethylethanamine;formaldehyde. Canonical SMILES: CCN (CC)CC1=NC (=CC=C1)CP (C (C) (C)C)C (C) (C)C. C=O. Cl[Ru]. Catalog: ACM863971624.
Ligand used in the cobalt-catalyzed alkenylzincation of unfunctionalized alkynes. Ligand used in the cobalt-catalyzed alkylboration of alkenes. Ligand used in the palladium-catalyzed N-alkylation of amines using primary and secondary alcohols. Ligand used in the palladium-catalyzed methylation of alkynyl C(sp)-H bonds with dimethyl sulfonium ylides. Group: Organic phosphine compounds. Alternative Names: AX8240548; ditert-butyl-(5-ditert-butylphosphanyl-9,9-dimethylxanthen-4-yl)phosphane; SCHEMBL1315091; 4,5-bis(di-t-butylphosphino)-9,9-dimethylxanthene; 9,9-Dimethyl-4,5-bis(di-tert-butylphosphino)xanthene; FT-0728449; ZINC12359415; t-Bu-Xantphos; CS-W009619; DB-009564. CAS No. 856405-77-1. Molecular formula: C31H48OP2. Mole weight: 498.672g/mol. IUPACName: ditert-butyl-(5-ditert-butylphosphanyl-9,9-dimethylxanthen-4-yl)phosphane. Canonical SMILES: CC1 (C2=C (C (=CC=C2)P (C (C) (C)C)C (C) (C)C)OC3=C1C=CC=C3P (C (C) (C)C)C (C) (C)C)C. Catalog: ACM856405771.
(4-Dimethylaminophenyl)di-tert-butylphosphine. Group: Biochemicals. Alternative Names: 4-(Di-tert-butylphosphino)-N,N-dimethylaniline. Grades: Highly Purified. CAS No. 932710-63-9. Pack Sizes: 500mg, 1g, 2g, 5g, 10g. US Biological Life Sciences.
Worldwide
(4-Dimethylaminophenyl)di-tert-butylphosphine
(4-Dimethylaminophenyl)di-tert-butylphosphine. Uses: Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic light-emitting diode (oled) materials. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Product ID: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Molecular formula: 265.381g/mol. Mole weight: C16H28NP. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. InChI=1S/C16H28NP/c1-15 (2, 3)18 (16 (4, 5)6)14-11-9-13 (10-12-14)17 (7)8/h9-12H, 1-8H3. IQTHEAQKKVAXGV-UHFFFAOYSA-N.
(4-Dimethylaminophenyl)di-tert-butylphosphine
Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic phosphine compounds. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Molecular formula: C16H28NP. Mole weight: 265.381g/mol. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Catalog: ACM932710639.
Bis (tri-tert-butylphosphine) palladium (0)
Bis (tri-tert-butylphosphine) palladium (0) . Group: Biochemicals. Alternative Names: Bis[tris (1, 1-dimethylethyl) phosphine]palladium; Bis (tri-tert-butylphosphine) palladium; Bis (tri-tert-butylphosphine) palladium (0) ; Bis (tri-tert-butylphosphino) palladium; Bis[tris (tert-butyl) phosphine]palladium; Palladium Bis(tri-tert-butylphosphine); BIs[tris (1, 1-dimethylethyl) phosphine]palladium. Grades: Highly Purified. CAS No. 53199-31-8. Pack Sizes: 500mg. Molecular Formula: C24H54P2Pd, Molecular Weight: 511.05. US Biological Life Sciences.
Worldwide
Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst
Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone. Group: Ruthenium series catalysts. Alternative Names: 863971-63-5; Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N, N-diethylaminomethyl)-1, 6-dihydropyridine]ruthenium(II); DTXSID40856225; Ruthenium(2+) hydride (2E)-2-[ (di-tert-butylphosphanyl)methylidene]-6-[ (diethylamino)methyl]-2H-pyridin-1-ide--carbon monooxide (1/1/1/1). CAS No. 863971-63-5. Molecular formula: C20H35N2OPRu. Mole weight: 451.557g/mol. IUPACName: carbon monoxide; N-[[(6E)-6-(ditert-butylphosphanylmethylidene)pyridin-1-id-2-yl]methyl]-N-ethylethanamine; hydride; ruthenium(2+). Canonical SMILES: [H-]. CCN (CC)CC1=CC=CC (=CP (C (C) (C)C)C (C) (C)C)[N-]1. [C-]#[O+]. [Ru+2]. Catalog: ACM863971635.
Highly active gold catalyst for the intramolecular exohydrofunctionalization of allenes. Catalyst used for the hydroarylation of allenes. Catalyst used for the intramolecular cyclization of monopropargyl triols. Synthesis of pyrroles via a gold-catalyzed cascade reaction. Gold-catalyzed carboalkoxylations of 2-ethynylbenzyl ethers. Gold-catalyzed annulations of allenes with N-hydroxy anilines. Group: Gold series of catalysts. Alternative Names: SC10751; JohnPhos AuCl; [[1,1 inverted exclamation marka-Biphenyl]-2-ylbis(t-butylphosphine]chlorogold; AKOS024259177; Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I), 98%; KS-000019BH; TRA0069872; Chloro[2-(di-t-butylphosphino)biphenyl]gold(I). CAS No. 854045-93-5. Molecular formula: C20H27AuClP. Mole weight: 530.826g/mol. IUPACName: chlorogold;ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Cl[Au]. Catalog: ACM854045935.
Dichlorobis[2- (di-t-butylphosphino)ethylamine]ruthenium (II), min. 97%
Exceptionally active catalyst for the hydrogenation of ketones and imines under mild conditions. Selective hydrogenation of C = O bonds over C = C bonds. Group: Ruthenium series catalysts. Alternative Names: 1092372-91-2; Dichlorobis[2- (di-tert-butylphosphino)ethylamine]ruthenium (II); DICHLOROBIS[2- (DI-T-BUTYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II); Dichlorobis (2- (di-tert-butylphosphino)ethylamine)ruthenium (II), 97%; Dichlorobis[2- (di-tert-butylphosphino)ethylamine]ruthenium (II), 97%; SCHEMBL9939258; MFCD07782003; SC10244; Dichlorobis[2-(di-t-butylphosphino)ethylamine]ruthenium (II). CAS No. 1092372-91-2. Molecular formula: C20H48Cl2N2P2Ru. Mole weight: 550.536g/mol. IUPACName: 2-ditert-butylphosphanylethanamine; dichlororuthenium. Canonical SMILES: CC(C)(C)P(CCN)C(C)(C)C. CC(C)(C)P(CCN)C(C)(C)C. Cl[Ru]Cl. Catalog: ACM1092372912.
Me4tButylXphos
Ligand for the palladium-catalyzed amidation of aryl chlorides. Ligand for the palladium-catalyzed synthesis of phenols from aryl halides. Ligand for the palladium-catalyzed coupling of aryl halides and secondary alcohols. Group: Organic phosphine compounds. Alternative Names: Di-tert-butyl[3,4,5,6-tetramethyl-2',4',6'-tri(propan-2-yl)[1,1'-biphenyl]-2-yl]phosphane; Di-tert-butyl(2',4',6'-triisopropyl-3,4,5,6-tetramethyl-[1,1'-biphenyl]-2-yl)phosphine; Tetramethyl Di-tbutyl X-Phos; MFCD09038436; 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAMETHYL-2',4',6'-TRI ISOPROPYLIBIPHENYL; di-tert-butyl(2',4',6'-triisopropyl-3,4,5,6-tetramethyl-[1,1'-biphenyl]-2-yl)phosphane; 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&; 2-(di-tert-butylphosphino)-2',4',6'-triisopropyl-3,4,5,6-tetramethyl-1,1'-biphenyl; CS-W001169; ZINC56961829. CAS No. 857356-94-6. Molecular formula: C33H53P. Mole weight: 480.761g/mol. IUPACName: ditert-butyl-[2,3,4,5-tetramethyl-6-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC1=C (C (=C (C (=C1C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C)P (C (C) (C)C)C (C) (C)C)C)C. Catalog: ACM857356946.
(R) - (-) -1-[ (S) -2-Diphenylphosphino) ferrocenyl]ethyldi-t-butylphosphine
(R) - (-) -1-[ (S) -2-Diphenylphosphino) ferrocenyl]ethyldi-t-butylphosphine is used as a catalyst in the synthesis of Sitagliptin, a potent inhibitor for the treatment of type 2 diabetes. Group: Biochemicals. Alternative Names: 2- (1- (Di-tert-butylphosphino) ethyl) -1- (diphenylphosphino) ?Ferrocene; Josiphos SL-J002-1; [ (R) -1- [ (S) -2- (Di-tert-butylphosphino) ferrocenyl] ethyl] ?Diphenylphosphine. Grades: Highly Purified. CAS No. 155830-69-6. Pack Sizes: 50mg. US Biological Life Sciences.
Worldwide
RockPhos
Ligand used in the palladium-catalyzed C-O bond forming reactions of secondary and primary alcohols with a range of aryl halides. Heterocyclic halides and, for the first time, electron-rich aryl halides can be coupled with secondary alcohols. Group: Organic phosphine compounds. Alternative Names: ZINC95910984; 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2'-4'-6'-tri-i-propyl-1,1'-biphenyl; RockPhos, 97%; di-tert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane; Y-200021; Di-tert-butyl(2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-3-methoxy-6-methyl-[1,1 inverted exclamation marka-biphenyl]-2-yl)phosphine; CVLLAKCGAFNZHJ-UHFFFAOYSA-N; 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopropyl-1,1'-biphenyl; SCHEMBL12929986; AX8242285. CAS No. 1262046-34-3. Molecular formula: C31H49OP. Mole weight: 468.706g/mol. IUPACName: ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC1=C (C (=C (C=C1)OC)P (C (C) (C)C)C (C) (C)C)C2=C (C=C (C=C2C (C)C)C (C)C)C (C)C. Catalog: ACM1262046343.
tBuBrettPhos
Ligand used in the Pd-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides. Ligand used in the Pd-catalyzed O-arylation of ethyl acetohydroximates. Ligand used in the Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics. Ligand used in the Pd-catalyzed cross-coupling of amides and aryl mesylates. Group: Organic phosphine compounds. Alternative Names: ditert-butyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane; Di(tert-butyl)(2 inverted exclamation mark ,4 inverted exclamation mark ,6 inverted exclamation mark -triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine; ZINC71773515; REWLCYPYZCHYSS-UHFFFAOYSA-N; di-tert-butyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphane; 2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl,min. 98% t-butylbrettphos; tBuBrettPhos, 97%; t-BuBrett-Phos; T-BUTYLBRETTPHOS; CS-W011518. CAS No. 1160861-53-9. Molecular formula: C31H49O2P. Mole weight: 484.705g/mol. IUPACName: ditert-butyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=C (C=CC (=C2P (C (C) (C)C)C (C) (C)C)OC)OC)C (C)C. Catalog: ACM1160861539.
t-BuDavePhos
Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines. Ligand used for selective Pd-catalyzed silylation of aryl chlorides. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. Group: Organic phosphine compounds. Alternative Names: 2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179. CAS No. 224311-49-3. Molecular formula: C22H32NP. Mole weight: 341.479g/mol. IUPACName: 2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2N (C)C)C (C) (C)C. Catalog: ACM224311493.
Ligand for the Pd-catalyzed formation of oxygen heterocycles. Ligand for the intermolecular Pd-catalyzed synthesis of aryl ethers. Ligand for the intramolecular Pd-catalyzed synthesis of aryl ethers. Ligand for the synthesis of carbazoles by Pd-catalyzed double N-arylation reaction. Ligand for the Pd-catalyzed cyanation of (hetero)arylchlorides. Ligand for the Pd-catalyzed intramolecular synthesis of carbazoles via C-H functionalization. Group: Organic phosphine compounds. Alternative Names: racemic 2-(di-tert-butylphosphino)-1,1'-binaphthyl; RACEMIC-2-DI-TERT-BUTYLPHOSPHINO-1,1-BINAPHTHYL; 1,1'-binaphthyl-2-yl di-tert-butylphosphine; racemic 2-di-tert-butylphosphino-1,1'-binaphthyl; AK-48836; AX8150194; 2-(di-ter-butylphosphino)-1,1'-binaphthyl; 2-(DI-TERT-BUTYLPHOSPHINO)-1,1-BINAPHTHYL; 2-(di-t-butylphosphino)-1,1'-binaphtyl; 2-(di-tert-butylphosphino)-1,1'-binapthyl. CAS No. 255836-67-0. Molecular formula: C28H31P. Mole weight: 398.53g/mol. IUPACName: ditert-butyl-(1-naphthalen-1-ylnaphthalen-2-yl)phosphane. Canonical SMILES: CC (C) (C) P (C1=C (C2=CC=CC=C2C=C1) C3=CC=CC4=CC=CC=C43) C (C) (C) C. Catalog: ACM255836670.
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