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Bis (tri-o-tolylphosphine) palladium (II) Dichloride
Bis (tri-o-tolylphosphine) palladium (II) Dichloride. Group: Biochemicals. Alternative Names: Dichlorobis (tri-o-tolylphosphine) palladium (II) . Grades: Highly Purified. CAS No. 40691-33-6. Pack Sizes: 2g, 5g, 10g, 25g, 50g. US Biological Life Sciences.
Worldwide
Bis(tri-o-tolylphosphine)palladium(II) Dichloride
Coupling reaction of aryl bromides with vinylic acetates. Group: Palladium series catalysts. Alternative Names: 5531AB; SC10409; MFCD00274659 (98%); dichlorobis(tri-o-tolyl-phosphine)palladium(II); dichlorobis(tri-O-tolylphosphine)-palladium (II); DICHLOROBIS(TRI-ORTHO-TOLYLPHOSPHINE)PALLADIUM(II); FT-0696077; bis[tri(ortho-tolyl)phosphine] palladium chloride; Dichlorobis(tri-o-tolylphosphine)palladium; AK-76768. CAS No. 40691-33-6. Molecular formula: C42H42Cl2P2Pd. Mole weight: 786.066g/mol. IUPACName: dichloropalladium;tris(2-methylphenyl)phosphane. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. Cl[Pd]Cl. Catalog: ACM40691336.
An impurity of Palbociclib, a selective inhibitor of cyclin-dependent kinases CDK4 and CDK6. Palbociclib is developed for the treatment of ER-positive and HER2-negative breast cancer. Synonyms: 1-bis(2-methylphenyl)phosphoryl-2-methylbenzene; Phosphine oxide, tri-o-tolyl-; Phosphine oxide, tris(2-methylphenyl)-. CAS No. 6163-63-9. Molecular formula: C21H21OP. Mole weight: 320.372.
Catalyst system that exhibits high catalytic activity and enantioselectivity in the hydrogenation of enamines. Group: Ruthenium series catalysts. Alternative Names: 116128-29-1; I14-34252; (S)-Ru(OAc)2(T-BINAP); I14-34094; SC10146; AKOS015908623; Ru[(S)-T-BINAP](OCOCH3)2; (R)-Ru(OAc)2(T-BINAP); MFCD09753021. CAS No. 106681-15-6. Molecular formula: C52H48O4P2Ru. Mole weight: 899.97g/mol. IUPACName: acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CC (=O)O. CC (=O)O. [Ru]. Catalog: ACM106681156.
(R)-(+)-TolBINAP. Group: Biochemicals. Alternative Names: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl. Grades: Highly Purified. CAS No. 99646-28-3. Pack Sizes: 500mg, 1g, 2g, 5g, 10g. US Biological Life Sciences.
Worldwide
[RuCl(p-cymene)((S)-tolbinap)]Cl
1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C