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Bis (tri-o-tolylphosphine) palladium (II) Dichloride Bis (tri-o-tolylphosphine) palladium (II) Dichloride. Group: Biochemicals. Alternative Names: Dichlorobis (tri-o-tolylphosphine) palladium (II) . Grades: Highly Purified. CAS No. 40691-33-6. Pack Sizes: 2g, 5g, 10g, 25g, 50g. US Biological Life Sciences. USBiological 6
Worldwide
Bis(tri-o-tolylphosphine)palladium(II) Dichloride Coupling reaction of aryl bromides with vinylic acetates. Group: Palladium series catalysts. Alternative Names: 5531AB; SC10409; MFCD00274659 (98%); dichlorobis(tri-o-tolyl-phosphine)palladium(II); dichlorobis(tri-O-tolylphosphine)-palladium (II); DICHLOROBIS(TRI-ORTHO-TOLYLPHOSPHINE)PALLADIUM(II); FT-0696077; bis[tri(ortho-tolyl)phosphine] palladium chloride; Dichlorobis(tri-o-tolylphosphine)palladium; AK-76768. CAS No. 40691-33-6. Molecular formula: C42H42Cl2P2Pd. Mole weight: 786.066g/mol. IUPACName: dichloropalladium;tris(2-methylphenyl)phosphane. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. Cl[Pd]Cl. Catalog: ACM40691336. Alfa Chemistry. 2
Di-p-tolylphosphine Organic Phosphine Compounds. Alternative Names: BIS(4-METHYLPHENYL)PHOSPHINE;DI-P-TOLYLPHOSPHINE;DI(4-TOLYL)PHOSPHINE;Di(p-tolyl)phosphine, 98%;Di-p-tolylphosphine, 99%;Di-p-tolylphosphine, 99%(10wt%inhexane);DI-P-TOLYLPHOSPHINE (10 WT% IN HEXANE). CAS No. 1017-60-3. Molecular formula: C14H15P. Mole weight: 214.24. Purity: 0.95. IUPACName: bis(4-methylphenyl)phosphane. Canonical SMILES: CC1=CC=C(C=C1)PC2=CC=C(C=C2)C. Catalog: ACM1017603. Alfa Chemistry. 3
Tri-O-tolylphosphine oxide An impurity of Palbociclib, a selective inhibitor of cyclin-dependent kinases CDK4 and CDK6. Palbociclib is developed for the treatment of ER-positive and HER2-negative breast cancer. Synonyms: 1-bis(2-methylphenyl)phosphoryl-2-methylbenzene; Phosphine oxide, tri-o-tolyl-; Phosphine oxide, tris(2-methylphenyl)-. CAS No. 6163-63-9. Molecular formula: C21H21OP. Mole weight: 320.372. BOC Sciences 8
Tri-o-tolylphosphine tetrafluoroborate Heterocyclic Organic Compound. Alternative Names: Tri-o-tolylphosphine tetrafluoroborate, 1255640-57-3, ACMC-20ajct, CTK8C5358. CAS No. 1255640-57-3. Molecular formula: C21H21BF4P-. Mole weight: 392.18. Purity: 0.96. IUPACName: tris(2-methylphenyl)phosphane; tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F)F. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. Catalog: ACM1255640573. Alfa Chemistry. 4
Tri(o-tolyl)phosphine suzuki reaction. Group: Organic phosphine compounds. Alternative Names: 27879-EP2298767A1; 54223-EP2308880A1; 27879-EP2308880A1; TRA0055693; COIOYMYWGDAQPM-UHFFFAOYSA-N; tri-(o-tolyl) phosphine; tris-o-tolylphosphine; BCP04425; tri (2-tolyl) phosphine; tris-(2-methylphenyl)phosphine. CAS No. 6163-58-2. Molecular formula: C21H21P. Mole weight: 304.373g/mol. IUPACName: tris(2-methylphenyl)phosphane. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. ECNumber: 228-193-9. Catalog: ACM6163582. Alfa Chemistry. 2
Tri(p-tolyl)phosphine suzuki reaction. Group: Organic phosphine compounds. Alternative Names: Tri-p-Tolyl Phosphine; SBB058807; ZINC59210146; tris(4-methylphenyl)phosphane; GC10061; Tri-p-tolylphosphine, 98%; Tris(4-tolyl)phosphine; CS-W012099; Phosphine, tri-p-tolyl-; X4828. CAS No. 1038-95-5. Molecular formula: C21H21P. Mole weight: 304.373g/mol. IUPACName: tris(4-methylphenyl)phosphane. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=CC=C (C=C3)C. ECNumber: 213-863-5. Catalog: ACM1038955. Alfa Chemistry. 2
Tris(4-methylphenyl)phosphine oxide Tris(4-methylphenyl)phosphine oxide. Group: Ligands for functional metal complexes. Alternative Names: Tris(p-tolyl)phosphine oxide, Tri-p-tolylphosphine Oxide, Phosphine oxide, tris(p-tolyl)-, BRN 2810669, Tris(4-methylphenyl)phosphine Oxide, CID120383, LS-106057, T0995, 4-16-00-01024 (Beilstein Handbook Reference), 797-70-6. CAS No. 797-70-6. Product ID: 1-bis(4-methylphenyl)phosphoryl-4-methylbenzene. Molecular formula: 320.36. Mole weight: C21H21OP. CC1=CC=C (C=C1)P (=O) (C2=CC=C (C=C2)C)C3=CC=C (C=C3)C. SPKBYIYIZQARNX-UHFFFAOYSA-N. 96%. Alfa Chemistry Materials 7
(1R,2R)-N,N-Bis[2-(di-p-tolylphosphino)benzyl]cyclohexane-1,2-diamine,min. 97% Heterocyclic Organic Compound. Alternative Names: 1150113-65-7, (1R,2R)-N1,N1-Bis(2-(di-p-tolylphosphino)benzyl)cyclohexane-1,2-diamine, AKOS016000574, SC11482, AK119056, KB-205308, (1R,2R)-N,N-BIS[2-(DI-P-TOLYLPHOSPHINO)BENZYL]CYCLOHEXANE-1,2-DIAMINE. CAS No. 1150113-65-7. Molecular formula: C48H52N2P2. Mole weight: 718.89. Purity: 0.96. IUPACName: (1R, 2R) -2-N, 2-N-bis[[2-bis (4-methylphenyl) phosphanylphenyl]methyl]cyclohexane-1, 2-diamine. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=CC=CC=C3CN (CC4=CC=CC=C4P (C5=CC=C (C=C5)C)C6=CC=C (C=C6)C)C7CCCCC7N. Catalog: ACM1150113657. Alfa Chemistry.
(1S,2S)-N,N-Bis(2-(di-p-tolylphosphino)benzyl)cyclohexane-1,2-diamine Phosphine Ligands. CAS No. 124727-08-4. Molecular formula: C48H52N2P2. Mole weight: 718.89. Purity: 0.98. Catalog: ACM124727084. Alfa Chemistry. 5
(1S,2S)-N,N-Bis[2-(di-p-tolylphosphino)benzyl]cyclohexane-1,2-diamine Nitrogen-Donor Ligands. CAS No. 1224727-08-5. Molecular formula: C48H52N2P2. Mole weight: 718.89. Appearance: Yellow solid. Purity: 0.98. IUPACName: 2-N, 2-N-bis[[2-bis (4-methylphenyl) phosphanylphenyl]methyl]cyclohexane-1, 2-diamine. Catalog: ACM1224727085. Alfa Chemistry. 5
2-(Di-p-tolylphosphino)benzaldehyde,min. 97% Heterocyclic Organic Compound. Alternative Names: 2-(Di-p-tolylphosphino)benzaldehyde, 1202865-03-9, ACMC-20aon9, CTK8C6147, 2-[Bis(4-methylphenyl)phosphino]benzaldehyde. CAS No. 1202865-03-9. Molecular formula: C21H19OP. Mole weight: 318.12. Purity: 0.96. IUPACName: 2-bis(4-methylphenyl)phosphanylbenzaldehyde. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=CC=CC=C3C=O. Catalog: ACM1202865039. Alfa Chemistry. 3
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap] Catalyst system that exhibits high catalytic activity and enantioselectivity in the hydrogenation of enamines. Group: Ruthenium series catalysts. Alternative Names: RU(OAC)2[(R)-TOLBINAP]; 106681-15-6; Ru[(S)-T-BINAP](OCOCH3)2; Diacetato[(S)-(-)-2,2 inverted exclamation marka-bis(di-p-tolylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); DIACETATO[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II); 116128-29-1; I14-34094; Diacetato[(R)-2,2 inverted exclamation marka-bis(di-p-tolylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); DIACETATO[(R)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II). CAS No. 116128-29-1. Molecular formula: C52H48O4P2Ru. Mole weight: 899.97g/mol. IUPACName: acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CC (=O)O. CC (=O)O. [Ru]. Catalog: ACM116128291. Alfa Chemistry. 2
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap] Catalyst system that exhibits high catalytic activity and enantioselectivity in the hydrogenation of enamines. Group: Ruthenium series catalysts. Alternative Names: 116128-29-1; I14-34252; (S)-Ru(OAc)2(T-BINAP); I14-34094; SC10146; AKOS015908623; Ru[(S)-T-BINAP](OCOCH3)2; (R)-Ru(OAc)2(T-BINAP); MFCD09753021. CAS No. 106681-15-6. Molecular formula: C52H48O4P2Ru. Mole weight: 899.97g/mol. IUPACName: acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CC (=O)O. CC (=O)O. [Ru]. Catalog: ACM106681156. Alfa Chemistry. 2
Dichloro[(R)-(+)-2,2-bis(di-p-tolylphosphino)-1,1-binaphthyl](2-aminomethylpyridine)ruthenium(II) RuCl2(AMPY)[(R)Tol-Binap] Efficient catalyst used in the asymmetric hydrogenation of tert-alkyl ketones. Group: Ruthenium catalysts. Alternative Names: (R)-Tol-Binap RuCl2 AMPY;MFCD22988922;(S)-Tol-Binap RuCl2 AMPY; 858116-31-1; 857678-55-8; Dichloro[(R)-(+)-2, 2'-bis(di-p-tolylphosphino)-1, 1'-binaphthyl](2-aminomethylpyridine)ruthenium(II) RuCl2(AMPY)[(R)Tol-Binap]; Dichloro[2-(aminomethyl)pyridine][(R)-2, 2'-bis(di-p-tolylphosphino)-1, 1'-binaphthyl]ruthenium(II). CAS No. 858116-31-1. Molecular formula: C54H48Cl2N2P2Ru. Mole weight: 958.91g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; pyridin-2-ylmethanamine. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. C1=CC=NC (=C1)CN. Cl[Ru]Cl. Catalog: ACM858116311. Alfa Chemistry. 2
Dichloro[(S)-(-)-2,2-bis(di-p-tolylphosphino)-1,1-binaphthyl](2-aminomethylpyridine)ruthenium(II) RuCl2(AMPY)[(S)-Tol-Binap] Efficient catalyst used in the asymmetric hydrogenation of tert-alkyl ketones. Group: Ruthenium catalysts. Alternative Names: (R)-Tol-Binap RuCl2 AMPY;MFCD22988922;(S)-Tol-Binap RuCl2 AMPY; 858116-31-1; 857678-55-8; Dichloro[(R)-(+)-2, 2'-bis(di-p-tolylphosphino)-1, 1'-binaphthyl](2-aminomethylpyridine)ruthenium(II) RuCl2(AMPY)[(R)Tol-Binap]; Dichloro[2-(aminomethyl)pyridine][(R)-2, 2'-bis(di-p-tolylphosphino)-1, 1'-binaphthyl]ruthenium(II). CAS No. 857678-55-8. Molecular formula: C54H48Cl2N2P2Ru. Mole weight: 958.91g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; pyridin-2-ylmethanamine. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. C1=CC=NC (=C1)CN. Cl[Ru]Cl. Catalog: ACM857678558. Alfa Chemistry. 2
[NH2Me2][(RuCl((R)-tolbinap))2(μ -Cl)3] Catalyst system for asymmetric hydrogenation. Group: Ruthenium series catalysts. Alternative Names: Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II); (S)-[(RuCl(T-BINAP))2(|I-Cl)3[NH2Me2]; (S)-[(RuCl(T-BINAP))2(mu-Cl)3[NH2Me2]; NH2ME2][(RUCL((S)-TOLBINAP))2(MU-CL)3; (R)-[(RUCL(T-BINAP))]2(MU-CL)3[NH2ME2]; (R)-[(RuCl(T-BINAP))2(|I-Cl)3[NH2Me2]; (R)-[(RuCl(T-BINAP))2(mu-Cl)3[NH2Me2]; (S)-[(RUCL(T-BINAP))2(MU-CL)3[NH2ME2]]; 749935-02-2. CAS No. 749935-02-2. Molecular formula: C98H91Cl5NP4Ru2+. Mole weight: 1786.098g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; N-methylmethanamine; ruthenium; trichloronioruthenium(1-); chloride; hydrochloride. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CNC. Cl. [Cl-]. [ClH+][Ru-] ([ClH+])[ClH+]. [Ru]. Catalog: ACM749935022. Alfa Chemistry. 2
[NH2Me2][(RuCl((S)-tolbinap))2(μ -Cl)3] Catalyst system for asymmetric hydrogenation. Group: Ruthenium series catalysts. Alternative Names: MFCD09753034; J-018209; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); (S)-[(RuCl (T-BINAP))2( -Cl)3[NH2Me2]; (S)-[(RuCl (T-BINAP))2(mu-Cl)3[NH2Me2]. CAS No. 309735-86-2. Molecular formula: C98H88Cl5NP4Ru2. Mole weight: 1783.074g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; N-methylmethanamine; hydrochloride. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. CNC. Cl. Cl[Ru]Cl. Cl[Ru]Cl. Catalog: ACM309735862. Alfa Chemistry. 2
(R)-(+)-TolBINAP (R)-(+)-TolBINAP. Group: Biochemicals. Alternative Names: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl. Grades: Highly Purified. CAS No. 99646-28-3. Pack Sizes: 500mg, 1g, 2g, 5g, 10g. US Biological Life Sciences. USBiological 8
Worldwide
[RuCl(p-cymene)((S)-tolbinap)]Cl 1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C… Alfa Chemistry. 2
[(S)-Tol-binap rucl benzene]Cl Ruthenium Complexes. Alternative Names: Dichloro(benzene)[(S)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II). CAS No. 126085-10-7. Molecular formula: C54H46Cl2P2Ru. Mole weight: 928.9. Purity: 0.98. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. C1=CC=CC=C1. [Cl-]. Cl[Ru+]. Catalog: ACM126085107. Alfa Chemistry. 4
trans-Bis (acetato)bis[o- (di-o-tolylphosphino)benzyl]dipalladium (II) Heck olefination of haloarenes. Group: Palladium series catalysts. Alternative Names: HERRMANN'S PALLADACYCLE; I14-33199; trans-Di-|I-acetatobis[2-[bis (2-methylphenyl) phosphino]benzyl]dipalladium; CATACXIUM(R) C; Herrmann inverted exclamation markas palladacycle; trans-Bis (acetato) bis[2-[bis (2-methylphenyl) phosphino]benzyl]dipalladium (II) ; AKOS015908997; trans-Bis (acetato)bis[o- (di-o-tolylphosphino)benzyl]dipalladium (II); J-525029; Herrmann-Beller palladacycle. CAS No. 172418-32-5. Molecular formula: C46H48O4P2Pd2-2. Mole weight: 939.674g/mol. IUPACName: acetic acid;(2-methanidylphenyl)-bis(2-methylphenyl)phosphane;palladium. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3[CH2-]. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3[CH2-]. CC (=O)O. CC (=O)O. [Pd]. [Pd]. Catalog: ACM172418325. Alfa Chemistry. 2

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