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This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds. Group: Biochemicals. Grades: Highly Purified. CAS No. 2622-14-2. Pack Sizes: 25g, 50g, 100g, 250g. Molecular Formula: C??H??P, Molecular Weight: 280.43. US Biological Life Sciences.
Worldwide
Tricyclohexylphosphine
Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds. As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry. Group: Promotional products. Alternative Names: Phosphine, tricyclohexyl-. CAS No. 2622-14-2. Molecular formula: C18H33P. Mole weight: 280.44. Appearance: liquid. Purity: 95+%. IUPACName: tricyclohexylphosphane. Canonical SMILES: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. ECNumber: 220-069-2. Catalog: ACM2622142-2.
Tricyclohexylphosphine
Tricyclohexylphosphine (Tricyclohexylphosphane) is a biological molecule. Uses: Scientific research. Group: Signaling pathways. Alternative Names: Tricyclohexylphosphane. CAS No. 2622-14-2. Pack Sizes: 25 g; 50 g; 100 g. Product ID: HY-34614.
Tricyclohexylphosphine[1, 3-bis (2, 4, 6-trimethylphenyl)-4, 5-dihydroimidazol-2-ylidene][ (phenylthio)methylene]ruthenium (II) dichloride
Metathesis catalyst, stable in air and can be used in aqueous media. Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins. Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes. Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times. Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives. Group: Ruthenium catalysts. Alternative Names: [1, 3-Bis (2, 4, 6-trimethylphenyl)-2-imidazolidinylidene]dichloro[ (phenylthio)methylene] (tricyclohexylphosphine)ruthenium. CAS No. 1155422-69-7. Molecular formula: C46H65Cl2N2PRuS. Mole weight: 881.04. Appearance: Purple brown solid. IUPACName: [1, 3-bis (2, 4, 6-trimethylphenyl) imidazolidin-2-ylidene]-dichloro- (phenylsulfanylmethylidene) ruthenium; tricyclohexylphosphane. Canonical SMILES: CC1=CC (=C (C (=C1)C)N2CCN (C2=[Ru] (=CSC3=CC=CC=C3) (Cl)Cl)C4=C (C=C (C=C4C)C)C)C. C1CCC (CC1)P (C2CCCCC2)C3CCCCC3. Catalog: ACM1155422697-1.
Iridium catalyst used for the highly enantioselective hydrogenation of α,β-unsaturated esters. Iridium catalyst used for the stereoselective catalytic hydrogenation and conjugate reduction of 4methylitaconate derivatives bearing a chiral auxiliary. Iridium catalyst used in the synthesis of thiophene-based TAK-779 analogues via C-H arylation. Iridium catalyst used in the practical synthetic approach to chiral (α-chloroalkyl)boronic esters via an iridiumcatalyzed, chemoselective hydrogenation of chloro-substituted alkenyl boronates. Iridium catalyst used in the regioselective C-H activation and hydrogen-isotope exchange of non-aromatic unsaturated functionality. Group: Heterocyclic organic compound. Alternative Names: Felkin-crabtree catalyst; pyridine; (1, 5-Cyclooctadiene) (pyridine) (tricyclohexylphosphine)-iridium (I) hexafluorophosphate, >=99.0% (C); (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate, 99%; (1Z,5Z)-cycloocta-1,5-diene; UNII-816RS2NBPN; ( (1, 2, 5, 6-eta)-1, 5-Cyclooctadiene) (pyridine) (tricyclohexylphosphine)iridium (1+) hexafluorophosphate(1-); C18H33P.C8. CAS No. 64536-78-3. Molecular formula: C31H50F6IrNP2-. Mole weight: 804.903g/mol. IUPACName: (1Z, 5Z)-cycloocta-1, 5-diene; iridium; pyridine; tricyclohexylphosphane; hexafluorophosphate. Canonical SMILES: C1CCC(CC1)P(C2CCCCC2)
Bis (tricyclohexylphosphine)[ (phenylthio)methylene]ruthenium (II) dichloride, min. 97%
Metathesis catalyst, stable in air and can be used in aqueous media. Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins. Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes. Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times. Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives. Group: Ruthenium series catalysts. Alternative Names: Bis (tricyclohexylphosphine)[ (phenylthio)methylene]ruthenium (IV) dichloride; SCHEMBL995991; BIS (TRICYCLOHEXYLPHOSPHINE)[ (PHENYLTHIO)METHYLENE]RUTHENIUM (II) DICHLORIDE; Bis (tricyclohexylphosphine)[ (phenylthio)methylene]ruthenium (II)dichloride; SC10225; 437767-65-2. CAS No. 219770-99-7. Molecular formula: C43H72Cl2P2RuS. Mole weight: 855.027g/mol. IUPACName: dichloro (phenylsulfanylmethylidene) ruthenium; tricyclohexylphosphane. Canonical SMILES: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. C1=CC=C(C=C1)SC=[Ru](Cl)Cl. Catalog: ACM219770997.
Diacetatobis (tricyclohexylphosphine)palladium (II)
Amination→Buchwald-Hartwig Aminaton; Cross Coupling Reactions with Arenes→Mizoroki Heck Coupling Reaction. Group: Catalysts for pharmaceuticalamination. CAS No. 59840-38-9. Molecular formula: C40H72O4P2Pd. Mole weight: 785.35. Purity: Metal purity 99.95. Catalog: ACM59840389-1.
Dichloro[1, 3-bis (2, 4, 6-trimethylphenyl)-2-imidazolidinylidene] (3-phenyl-1H-inden-1-ylidene) (tricyclohexylphosphine)ruthenium (II)
Catalyst used for the Atom Transfer Radical Polymerization (ATRP) of vinyl monomers. Group: Ruthenium series catalysts. Alternative Names: 536724-67-1; Dichloro[1, 3-bis (2, 4, 6-trimethylphenyl)-2-imidazolidinylidene] (3-phenyl-1H-inden-1-ylidene) (tricyclohexylphosphine)ruthenium (II); BCP13985; TRICYCLOHEXYLPHOSPHINE[3-PHENYL-1H-INDEN-1-YLIDENE][1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]RUTHENIUM(II) DICHLORIDE; MFCD08667892; [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium; Neolyst M 2; TRICYCLOHEXYLPHOSPHINE[3-PHENYL-1H-INDEN-1-YLIDENE][1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]RUTHENIUM (II) DICHLORIDE, MIN. 95% NEOLYST M2; AKOS032948007; SCHEMBL2230761. CAS No. 536724-67-1. Molecular formula: C54H69Cl2N2PRu. Mole weight: 949.104g/mol. IUPACName: [1, 3-bis(2, 4, 6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium; tricyclohexylphosphane. Canonical SMILES: CC1=CC (=C (C (=C1)C)N2CCN (C2=[Ru] (=C3C=C (C4=CC=CC=C43)C5=CC=CC=C5) (Cl)Cl)C6=C (C=C (C=C6C)C)C)C. C1CCC (CC1)P (C2CCCCC2)C3CCCCC3. Catalog: ACM536724671.
Dichloro (2-thienylmethylene)bis (tricyclohexylphosphine)ruthenium (II)
Alkene Metathesis→Cross Metathesis; Alkene Metathesis→Ring Closing Metathesis; Alkene Metathesis→Self Metathesis. Group: Catalysts for pharmaceutical. CAS No. 1190427-44-1. Molecular formula: C41H70Cl2P2RuS. Mole weight: 828.98. Appearance: violet to brown. Purity: Metal purity 99.95. Catalog: ACM1190427441.
Dichlorobis(tricyclohexylphosphine) palladium (II)
Dichlorobis (tricyclohexylphosphine)palladium (II) is a biochemical reagent that can be used as a biological material or organic compound for life science related research. Uses: Scientific research. Group: Biochemical assay reagents. CAS No. 29934-17-6. Pack Sizes: 1 g; 5 g. Product ID: HY-W033312.
Dichloro (p-cymene) tricyclohexylphosphineruthenium (II) , min. 97%
Noels metathesis catalyst component with (trimethylsilyl)diazomethane for ring opening polymerization reactions. Catalyst for the controlled atom transfer radical polymerization of acrylates. Group: Ruthenium series catalysts. Alternative Names: DICHLORO (P-CYMENE) TRICYCLOHEXYLPHOSPHINERUTHENIUM (II) ; 145381-23-3; MFCD06798308; SC10253; DICHLORO[ (1, 2, 3, 4, 5, 6-H) -1-METHYL-4- (1-METHYLETHYL) BENZENE] (TRICYCLOHEXYLPHOSPHINE) RUTHENIUM. CAS No. 145381-23-3. Molecular formula: C28H47Cl2PRu. Mole weight: 586.628g/mol. IUPACName: dichlororuthenium;1-methyl-4-propan-2-ylbenzene;tricyclohexylphosphane. Canonical SMILES: CC1=CC=C(C=C1)C(C)C. C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. Cl[Ru]Cl. Catalog: ACM145381233.
Dichloro (tricyclohexylphosphine) [ (tricyclohexylphosphoranyl) methylidene]ruthenium (II) tetrafluoroborate