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[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride is used as a catalyst in the asymmetric synthesis of UK 370106 (U700620); an MMP-3 inhibitor. It is also highly effective in the hydrogenation of 2-(6'-methoxy-2'-naphthyl)propenoic acid and β-ketoesters. Group: Biochemicals. Grades: Highly Purified. CAS No. 130004-33-0. Pack Sizes: 100mg, 250mg. Molecular Formula: C54H46Cl2P2Ru. US Biological Life Sciences.
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2-Nitro-4-cymene
2-Nitro-4-cymene. Group: Biochemicals. Grades: Highly Purified. CAS No. 943-15-7. Pack Sizes: 2g, 5g, 10g, 25g. US Biological Life Sciences.
Chloro (p-cymene)[ (1R, 2R)- (-)-2-amino-1, 2-diphenylethyl (methylsulfonylamido)]ruthenium (II) RuCl(p-cymene)[(R,R)-MsDpen]
Catalyst used in the asymmetric hydrogenation of N-alkyl and N-aryl ketimines. Group: Heterocyclic organic compound. CAS No. 1097730-63-6. Molecular formula: C25H31ClN2O2RuS. Mole weight: 560.1. Purity: 0.96. Catalog: ACM1097730636.
Chloro (p-cymene)[ (1S, 2S)- (-)-2-amino-1, 2-diphenylethyl ( (methylsulfonylamido)]ruthenium (II) RuCl(p-cymene)[(S,S)-MsDpen]
Catalyst used in the asymmetric hydrogenation of N-alkyl and N-ketimines. Catalyst used in the asymmetric hydrogenation of N-alkyl ketimines. Group: Ruthenium catalysts. Alternative Names: (S,S)-N-Methylsulfonyl-1,2-diphenylethanediamine(chloro)(p-cyMene)ruthenium(II). CAS No. 329371-25-7. Molecular formula: C25H31ClN2O2RuS. Mole weight: 560.1. Appearance: Orange solid. Purity: 0.98. Catalog: ACM329371257-1.
Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen. Group: Ruthenium series catalysts. Alternative Names: (R)-RUCL[P-CYMENE(H8-BINAP)]CL; [RUCL(P-CYMENE)((S)-H8-BINAP)]CL; SC10137; MFCD09753016; CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; [RUCL(P-CYMENE)((R)-H8-BINAP)]CL. CAS No. 944451-26-7. Molecular formula: C54H54Cl2P2Ru. Mole weight: 936.944g/mol. IUPACName: dichlororuthenium;[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. C1CCC2=C (C1)C=CC (=C2C3=C (C=CC4=C3CCCC4)P (C5=CC=CC=C5)C6=CC=CC=C6)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Ru]Cl. Catalog: ACM944451267.
Dichloro(p-cymene)ruthenium(II) dimer 99+. ≥97% (32.9-33.01% Ru). Group: Biochemicals. Grades: Reagent Grade. Pack Sizes: 1g, 5g, 25g. US Biological Life Sciences.
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Dichloro (p-cymene) tricyclohexylphosphineruthenium (II) , min. 97%
Noels metathesis catalyst component with (trimethylsilyl)diazomethane for ring opening polymerization reactions. Catalyst for the controlled atom transfer radical polymerization of acrylates. Group: Ruthenium series catalysts. Alternative Names: DICHLORO (P-CYMENE) TRICYCLOHEXYLPHOSPHINERUTHENIUM (II) ; 145381-23-3; MFCD06798308; SC10253; DICHLORO[ (1, 2, 3, 4, 5, 6-H) -1-METHYL-4- (1-METHYLETHYL) BENZENE] (TRICYCLOHEXYLPHOSPHINE) RUTHENIUM. CAS No. 145381-23-3. Molecular formula: C28H47Cl2PRu. Mole weight: 586.628g/mol. IUPACName: dichlororuthenium;1-methyl-4-propan-2-ylbenzene;tricyclohexylphosphane. Canonical SMILES: CC1=CC=C(C=C1)C(C)C. C1CCC(CC1)P(C2CCCCC2)C3CCCCC3. Cl[Ru]Cl. Catalog: ACM145381233.
Dichloro (p-cymene)triphenylphosphineruthenium (II) dichloromethane adduct, min. 98%
Ruthenium catalyst used for the hydrogenation of carbon dioxide. Ruthenium catalyst used for a selective monoarylation reaction in water. Group: Ruthenium catalysts. Alternative Names: 52490-94-5; Dichloro (p-cymene) (triphenylphosphane)ruthenium (II); MFCD28144560; Dichloro (p-cymene)triphenylphosphineruthenium (II) dichloromethane adduct. CAS No. 52490-94-5. Molecular formula: C29H31Cl4PRu. Mole weight: 653.411g/mol. IUPACName: dichloromethane;dichlororuthenium;1-methyl-4-propan-2-ylbenzene;triphenylphosphane. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C (Cl)Cl. Cl[Ru]Cl. Catalog: ACM52490945.
Diiodo(p-cymene)ruthenium(II) dimer
Our company can provide customers with rich supported precious metal catalyst products such as palladium series, platinum series, rhodium series and ruthenium series. Our catalysts not only have high catalytic efficiency, strong selectivity, and recyclability, but also can be used in organic reactions such as hydrogenation, dehydrogenation, amination, and cyclization. In addition, some products can also be used as raw materials for various precious metal compounds. The company has formed a series of proprietary and characteristic process technologies, and is currently undergoing process improvement and upgrading. In short, our catalytic products can be widely used in medicine, new chemical materials, pesticides, dyes and pigments, environmental protection, new energy, electronics, basic chemicals and other fields. Uses: ·for ruthenium-catalyzed hydrogenation; ·for the preparation of wolfoss-type ferrocene aryl diphosphine ligands; ·for enantioselective hydrogenation of ketones and alkenes. Group: Ruthenium series catalysts. Alternative Names: Di-μ-iodobis(p-cymene)iodoruthenium(II). CAS No. 90614-07-6. Molecular formula: C20H30I4Ru2. Mole weight: 978.19 g/mol. Appearance: Solid. Purity: 0.97. Canonical SMILES: I[Ru]1[I][Ru](I)[I]1. C[C]2[CH][CH][C]([CH][CH]2)C(C)C. C[C]3[CH][CH][C]([CH][CH]3)C(C)C. Catalog: ACM90614076-2.
m-Cymene
m-Cymene. Group: other glass and ceramic materials. Alternative Names: 1-Isopropyl-3-methylbenzene; meta-isopropyltoluene; 3-Isopropyltoluene; M-CYMENE; 1-Methyl-3-isopropylbenzene; 1-Isopropyl-3-methylbenzene,3-Isopropyltoluene; m-Isopropyltoluene; m-Cymol; 3-Methylisopropylbenzene; m-Methylisopropylbenzene. CAS No. 535-77-3. Product ID: 1-methyl-3-propan-2-ylbenzene. Molecular formula: 134.22. Mole weight: C10H14. CC1=CC(=CC=C1)C(C)C. XCYJPXQACVEIOS-UHFFFAOYSA-N. ?95%.
(p-Cymene)bis (mesitylcarboxylato)ruthenium (II)
Ruthenium Catalysts. Alternative Names: Ru(MesCO2)2(p-cymene). CAS No. 1251667-99-8. Molecular formula: C30H36O4Ru. Mole weight: 561.68. Appearance: Light yellow to yellow to orange powder to crystal. Purity: 98%+. Canonical SMILES: CC1=CC=C(C=C1)C(C)C. CC1=CC(=C(C(=C1)C)C(=O)[O-])C. CC1=CC(=C(C(=C1)C)C(=O)[O-])C. [Ru+2]. Catalog: ACM1251667998-1.
[RuCl(p-cymene)((R)-binap)]Cl
An efficient catalytic asymmetric synthesis of a β²-amino acid on a multikilogram scale. Group: Ruthenium series catalysts. Alternative Names: [rucl((r)-binap)(p-cymene)]cl; (R)-RuCl[(p-cymene)(BINAP)]Cl; KS-00000UEV; AKOS015914587; C44H32P2.C10H14.2ClH.Ru; dichlororuthenium; (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUMCHLORIDE; CTK8E6960; I14-41481; Chloro[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl](p-cymene)ruthenium(II) chloride. CAS No. 145926-28-9. Molecular formula: C54H46Cl2P2Ru. Mole weight: 928.88g/mol. IUPACName: dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Ru]Cl. Catalog: ACM145926289.
RuCl(p-cymene)[(R,R)-Ts-DPEN]
This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Alternative Names: Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II). CAS No. 192139-92-7. Molecular formula: C21H21ClN2O2RuS.C10H14. Mole weight: 636.21. Appearance: Orange yellow powder. Purity: 0.98. Catalog: ACM192139927.
Ligand used in the asymmetric hydrogenation of amino ketones. Group: Ruthenium series catalysts. Alternative Names: CHLORO[(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; CBZXDZCPCDMKJU-UHFFFAOYSA-L; [RuCl(p-cymene) ((S)-xylbinap)]Cl; Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((R)-xylbinap)]Cl; [1-[2-bis(3, 5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3, 5-dimethylphenyl)phosphane, dichlororuthenium, 1-methyl-4-propan-2-ylbenzene; Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride; SC10125; (R)-RuCl[(p-cymene)(DM-BINAP)]Cl. CAS No. 944451-24-5. Molecular formula: C62H62Cl2P2Ru. Mole weight: 1041.096g/mol. IUPACName: [1-[2-bis(3, 5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3, 5-dimethylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC (=CC (=C1)P (C2=C (C3=CC=CC=C3C=C2)C4=C (C=CC5=CC=CC=C54)P (C6=CC (=CC (=C6)C)C)C7=CC (=CC (=C7)C)C)C8=CC (=CC (=C8)C)C)C. Cl[Ru]Cl. Catalog: ACM944451245.
[RuCl(p-cymene)((S)-binap)]Cl
This catalyst has shown to effect the highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Group: Ruthenium series catalysts. Alternative Names: I14-41481; Chloro[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl](p-cymene)ruthenium(II) chloride; X3706; 130004-33-0; C44H32P2.C10H14.2ClH.Ru; [rucl((r)-binap)(p-cymene)]cl; MFCD00134456; (S)-RuCl[(p-cymene(BINAP)]Cl; Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride; CTK8E6960. CAS No. 130004-33-0. Molecular formula: C54H46Cl2P2Ru. Mole weight: 928.88g/mol. IUPACName: dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=CC=C7)C8=CC=CC=C8. Cl[Ru]Cl. Catalog: ACM130004330.
[RuCl(p-cymene)((S)-tolbinap)]Cl
1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C
This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Alternative Names: Methyl-4-(1-methylethyl)benzene]-ruthenium; RuCl(p-cymene)[(S,S)-Ts-DPEN]; RuCl(p-cymene)[(R,R)-TsDPEN]; RuCl[(S,S)-Tsdpen](p-cymene). CAS No. 192139-90-5. Molecular formula: C31H35ClN2O2RuS. Mole weight: 636.21. Appearance: Orange brown crystalline powder. Purity: 0.99. Catalog: ACM192139905-1.
1-Isopropenyl-3-methylbenzene
1-Isopropenyl-3-methylbenzene is an interemediate in synthesizing m-Cymene (C989765), a miscellaneous reagent used in organic synthesis for oxygenation of alkylbenzenes with methylacridinium ion via photoinduced electron transfer. Group: Biochemicals. Grades: Highly Purified. CAS No. 1124-20-5. Pack Sizes: 50mg, 250mg. Molecular Formula: C10H12. US Biological Life Sciences.
Worldwide
2,3-dihydroxy-2,3-dihydro-p-cumate dehydrogenase
Involved in the p-cymene degradation pathway in Pseudomonas putida. Group: Enzymes. Enzyme Commission Number: EC 1.3.1.58. CAS No. 176591-33-6. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1328; 2,3-dihydroxy-2,3-dihydro-p-cumate dehydrogenase; EC 1.3.1.58; 176591-33-6. Cat No: EXWM-1328.
K19 Dye is an amphiphilic ruthenium sensitizer with a good molar extinction coefficient, which remains stable under thermal stress and light soaking. It can be synthesized by forming a reaction mixture of 4,4'-Bis(p-hexyloxystyryl)-2,2'-bipyridine, dichloro(p-cymene)ruthenium(II) dimer, and 4,4'-dicarboxylic acid-2,2'-bipyridine. It shows an overall power conversion efficiency (PCE) of 11% and can be used as an active material in electrochemical applications.]. Uses: Electron transfer from k-19 dye to the conduction band of titania is completed within 20 fs while charge recombination has a half-life of 800 μs. the high extinction coefficient of this sensitizer enable realization of a new generation thin-film dye-sensitized solar cells (dscs) yielding high conversion efficiency at full sunlight, even with viscous electrolytes based on ionic liqs. or nonvolat. Group: Organic solar cell (opv) materials. Alternative Names: Ru(4,4-dicarboxylic acid-2,2 inverted exclamation marka-bipyridine)(4,4 inverted exclamation marka-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)2. CAS No. 847665-45-6. Pack Sizes: 250 mg in glass insert. Molecular formula: 1022.21. Mole weight: C52H52N6O6RuS2. CCCCCCOC1=CC=C (C=C1)C=CC2=CC (=NC=C2)C3=NC=CC (=C3)C=CC4=CC=C (C=C4)OCCCCCC. C1=CN=C (C=C1C (=O)O)C2=NC=CC (=C2)C (=O)O. C (=[N-])=S. C (=[N-])=S. [Ru+2]. InChI=1S/C38H44N2O2. C12H8N2O4. 2CNS. Ru/c1-3-5-7-9-27-41-35-19-15-31 (16-20-35)11-13-33-23-25-39-37 (2
K19 Dye
K19 Dye is an amphiphilic ruthenium sensitizer with a good molar extinction coefficient, which remains stable under thermal stress and light soaking. It can be synthesized by forming a reaction mixture of 4,4'-Bis(p-hexyloxystyryl)-2,2'-bipyridine, dichloro(p-cymene)ruthenium(II) dimer, and 4,4'-dicarboxylic acid-2,2'-bipyridine. It shows an overall power conversion efficiency (PCE) of 11% and can be used as an active material in electrochemical applications.]. Uses: Electron transfer from k-19 dye to the conduction band of titania is completed within 20 fs while charge recombination has a half-life of 800 μs. the high extinction coefficient of this sensitizer enable realization of a new generation thin-film dye-sensitized solar cells (dscs) yielding high conversion efficiency at full sunlight, even with viscous electrolytes based on ionic liqs. or nonvolatile solvents, making solar cell devices exhibit excellent stability under light soaking. Group: Dye sensitizers. Alternative Names: Ru(4,4-dicarboxylic acid-2,2 inverted exclamation marka-bipyridine)(4,4 inverted exclamation marka-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)2. CAS No. 847665-45-6. Molecular formula: C52H52N6O6RuS2. Mole weight: 1022.21. Appearance: Black powder. Canonical SMILES: CCCCCCOC1=CC=C (C=C1)C=CC2=CC (=NC=C2)C3=NC=CC (=C3)C=CC4=CC=C (C=C4)OCCCCCC. C1=CN=C (C=C1C (=O)O)C2=NC=CC (=C2)C (=O)O. C (=[N-])=S. C (=[N-])=S. [Ru+2]. Catalog: ACM847665456-1.