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White powder. CAS No. 6922-60-7. Pack Sizes: 5g, 25g. Product ID: FR-0794. M.P. 135-136. Mole weight: 454.7.
Frinton Laboratories
2-(Di-tert-butylphosphino)biphenyl
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in a very active and general catalyst for Suzuki coupling reactions using aryl chlorides, bromides and triflates. Ligand used in palladium-catalyzed synthesis of oxindoles from α-chloroacetanilides. Effective ligand used in palladium-catalyzed arylation of thiazoles. Used in the formation of 2-benzylindolines via sequential palladium-catalyzed N-arylation/cyclization/C-arylation. Selective in the palladium-catalyzed arylation of silyl enol ethers formed from copper-catalyzed reduction of enones. Group: Organic phosphine compounds. Alternative Names: (2-Biphenylyl)-Di-Tert-Butylphosphine. CAS No. 224311-51-7. Molecular formula: C20H27P. Mole weight: 298.4. Appearance: Solid. Purity: 0.98. IUPACName: ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Density: 1 g/cm3. Catalog: ACM224311517-1.
cBRIDP
Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. Group: Heterocyclic organic compound. Alternative Names: di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine; di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl) phosphine; Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphine cBRIDP; Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphane; SCHEMBL377365; 742103-27-1; di-t-butyl-(2,2-diphenyl-1-methylcyclopropyl)-phosphine; di-t-butyl (2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; (1-Methyl-2,2-diphenylcyclopropyl)di-tert-butylphosphine. CAS No. 742103-27-1. Molecular formula: C24H33P. Mole weight: 352.502g/mol. IUPACName: ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane. Canonical SMILES: CC1 (CC1 (C2=CC=CC=C2)C3=CC=CC=C3)P (C (C) (C)C)C (C) (C)C. Catalog: ACM742103271.
Highly active gold catalyst for the intramolecular exohydrofunctionalization of allenes. Catalyst used for the hydroarylation of allenes. Catalyst used for the intramolecular cyclization of monopropargyl triols. Synthesis of pyrroles via a gold-catalyzed cascade reaction. Gold-catalyzed carboalkoxylations of 2-ethynylbenzyl ethers. Gold-catalyzed annulations of allenes with N-hydroxy anilines. Group: Gold series of catalysts. Alternative Names: SC10751; JohnPhos AuCl; [[1,1 inverted exclamation marka-Biphenyl]-2-ylbis(t-butylphosphine]chlorogold; AKOS024259177; Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I), 98%; KS-000019BH; TRA0069872; Chloro[2-(di-t-butylphosphino)biphenyl]gold(I). CAS No. 854045-93-5. Molecular formula: C20H27AuClP. Mole weight: 530.826g/mol. IUPACName: chlorogold;ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Cl[Au]. Catalog: ACM854045935.
TrixiePhos
Ligand for the Pd-catalyzed formation of oxygen heterocycles. Ligand for the intermolecular Pd-catalyzed synthesis of aryl ethers. Ligand for the intramolecular Pd-catalyzed synthesis of aryl ethers. Ligand for the synthesis of carbazoles by Pd-catalyzed double N-arylation reaction. Ligand for the Pd-catalyzed cyanation of (hetero)arylchlorides. Ligand for the Pd-catalyzed intramolecular synthesis of carbazoles via C-H functionalization. Group: Organic phosphine compounds. Alternative Names: racemic 2-(di-tert-butylphosphino)-1,1'-binaphthyl; RACEMIC-2-DI-TERT-BUTYLPHOSPHINO-1,1-BINAPHTHYL; 1,1'-binaphthyl-2-yl di-tert-butylphosphine; racemic 2-di-tert-butylphosphino-1,1'-binaphthyl; AK-48836; AX8150194; 2-(di-ter-butylphosphino)-1,1'-binaphthyl; 2-(DI-TERT-BUTYLPHOSPHINO)-1,1-BINAPHTHYL; 2-(di-t-butylphosphino)-1,1'-binaphtyl; 2-(di-tert-butylphosphino)-1,1'-binapthyl. CAS No. 255836-67-0. Molecular formula: C28H31P. Mole weight: 398.53g/mol. IUPACName: ditert-butyl-(1-naphthalen-1-ylnaphthalen-2-yl)phosphane. Canonical SMILES: CC (C) (C) P (C1=C (C2=CC=CC=C2C=C1) C3=CC=CC4=CC=CC=C43) C (C) (C) C. Catalog: ACM255836670.
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