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[ (2Z) -2- [ (3S, 5R) -3, 5-Bis [ [ (1, 1-di methyl ethyl) di methyl silyl] oxy] -2- methyl enecyclohexylidene] ethyl] diphenylphosphineOxide is used as a reagent in the preparation of hydroxymethylated dihydroxyvitamin D3 analogs which have antitumor and transactivation activity. Group: Biochemicals. Grades: Highly Purified. CAS No. 81522-68-1. Pack Sizes: 10mg, 50mg. Molecular Formula: C33H51O3PSi2, Molecular Weight: 582.9. US Biological Life Sciences.
Used for production of peptide thioester. Group: Biochemicals. Alternative Names: (Chloromethyl)diphenyl-phosphine Oxide. Grades: Highly Purified. CAS No. 1806-49-1. Pack Sizes: 100mg. US Biological Life Sciences.
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(Diethoxymethyl) DiphenylphosphineOxide
(Diethoxymethyl) DiphenylphosphineOxide. Group: Biochemicals. Grades: Highly Purified. CAS No. 20570-20-1. Pack Sizes: 25mg, 50mg, 100mg, 250mg, 500mg. US Biological Life Sciences.
(Diethoxymethyl) DiphenylphosphineOxide ≥97% (HPLC). Group: Biochemicals. Grades: Reagent Grade. CAS No. 20570-20-1. Pack Sizes: 100mg, 250mg, 1g. US Biological Life Sciences.
Worldwide
(Mercaptomethyl) diphenylphosphineOxide
Used for production of peptide thioester. Group: Biochemicals. Alternative Names: Ethanethioic Acid S-[ (Diphenylphosphinyl) methyl] Ester. Grades: Highly Purified. CAS No. 324753-14-2. Pack Sizes: 50mg. US Biological Life Sciences.
Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphineoxide to alkynes. Rhodium- catalyzed hydrophosphinylation. Group: Rhodium series of catalysts. Alternative Names: bromide; Bromotris (triphenylphosphine)rhodium; EINECS 239-050-5; Bromotris (triphenylphosphine)rhodium (I); Jsp002843; phosphine, triphenyl-, bromide, rhodium salt(3:1); RL01906; AC1Q1R7U; triphenylphosphane. CAS No. 14973-89-8. Molecular formula: C54H45BrP3Rh-. Mole weight: 969.685g/mol. IUPACName: rhodium;triphenylphosphane;bromide. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Br-]. [Rh]. ECNumber: 239-050-5. Catalog: ACM14973898.
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO) is a monoacylphosphine oxide based photoinitiator that can be incorporated in a variety of polymeric matrixes for efficient curing and color stability of the resin. Uses: Tpo can be used in the photo-crosslinking of pmma composite, which can further be used as a gate insulator in organic thin film transistors (otfts). it can also be used in the formation of uv curable urethane-acrylate coatings. it may also be used in the photoinduced reaction for the formation of organophosphine compounds, which potentially find their usage as ligands with metal catalysts and reagents. Alternative Names: 2,4,6-Trimethylbenzoylphenyl phosphinate, (Diphenylphosphoryl) (mesityl)methanone, (2,4,6-Trimethylbenzoyl)diphenylphosphineoxide. CAS No. 75980-60-8. Molecular formula: C22H21O2P. Mole weight: 348.37. Appearance: White or cream powder. Purity: 95%+. IUPACName: Diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone. Canonical SMILES: CC1=CC (=C (C (=C1)C)C (=O)P (=O) (C2=CC=CC=C2)C3=CC=CC=C3)C. Density: 1.17 g/cm³. ECNumber: 278-355-8. Catalog: ACM75980608-2.
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO) is a monoacylphosphine oxide based photoinitiator that can be incorporated in a variety of polymeric matrixes for efficient curing and color stability of the resin. Uses: Tpo can be used in the photo-crosslinking of pmma composite, which can further be used as a gate insulator in organic thin film transistors (otfts). it can also be used in the formation of uv curable urethane-acrylate coatings. it may also be used in the photoinduced reaction for the formation of organophosphine compounds, which potentially find their usage as ligands with metal catalysts and reagents. Group: Polymerization reagents. Alternative Names: 2,4,6-Trimethylbenzoylphenyl phosphinate, (Diphenylphosphoryl) (mesityl)methanone, (2,4,6-Trimethylbenzoyl)diphenylphosphineoxide. CAS No. 75980-60-8. Pack Sizes: Packaging 10, 50 g in poly bottle. Product ID: Diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone. Molecular formula: 348.37. Mole weight: C22H21O2P. CC1=CC (=C (C (=C1)C)C (=O)P (=O) (C2=CC=CC=C2)C3=CC=CC=C3)C. InChI=1S/C22H21O2P/c1-16-14-17 (2) 21 (18 (3) 15-16) 22 (23) 25 (24, 19-10-6-4-7-11-19) 20-12-8-5-9-13-20/h4-15H, 1-3H3. VFHVQBAGLAREND-UHFFFAOYSA-N. 95%+.
DPO-1, a blocker of IKur ultrarapid delayed rectifier potassium current and KV1.5 channels, has been found to exhibit activities in preventing atrial arrhythmia. Synonyms: [1S- (1α , 2α , 5β ) ]-[5-Methyl-2- (1-methylethyl) cyclohexyl]diphenylphosphineoxide. Grades: ≥99% by HPLC. CAS No. 43077-30-1. Molecular formula: C22H29OP. Mole weight: 340.44.
m-CBPPO
Organic Light Emitting Diode (OLED). Alternative Names: (4'-(9H-Carbazol-9-yl)-2,2'-dimethyl-[1,1'-biphenyl]-4-yl)diphenylphosphineoxide. CAS No. 1206906-21-9. Molecular formula: C38H30NOP. Mole weight: 547.62 g/mol. Catalog: ACM1206906219.
Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions Useful ligand for palladium-catalyzed synthesis of butatrenes. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes. Ruthenium-catalyzed synthesis of indoles. Ruthenium-catalyzed oxidative cyclization. Rhodium-catalyzed boron arylation. Group: Organic phosphine compounds. Alternative Names: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1, 1'-[[1, 1'-BIPHENYL]-2, 2'-DIYL]BIS[1, 1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577. CAS No. 84783-64-2. Molecular formula: C36H28P2. Mole weight: 522.568g/mol. IUPACName: [2- (2-diphenylphosphanylphenyl) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM84783642.
[[2-Di (phenyl) phosphanylacetyl]oxyamino]azanium; di (prop-2-enyl) phosphinate
2-(Diphenylphosphinyl)ethanamine (CAS# 33921-17-4 ) is a useful research chemical. Synonyms: diphenyl 2-aminoethylphosphine oxide; 2-(Diphenylphosphoryl)ethan-1-amine. CAS No. 33921-17-4. Molecular formula: C14H16NOP. Mole weight: 245.26.
Acetylthiomethyl-diphenylphosphine borane complex
Traceless Staudinger ligation reagent with borane protecting group. The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine. After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond. Used in the synthesis of cyclic peptides. Group: Heterocyclic organic compound. Alternative Names: AGN-PC-005LSK, boron;S-(diphenylphosphanylmethyl) ethanethioate, Acetylthiomethyl-diphenylphosphine borane complex, 446822-71-5. CAS No. 446822-71-5. Molecular formula: C15H18BOPS. Mole weight: 288.15. Purity: 0.96. IUPACName: boron;S-(diphenylphosphanylmethyl) ethanethioate. Canonical SMILES: [B]. CC(=O)SCP(C1=CC=CC=C1)C2=CC=CC=C2. Catalog: ACM446822715-1.
(-) -Dichloro[ (4S) -4- (i-propyl) -2-{ (S) -2- (diphenylphosphino) ferrocenyl}oxazoline] (triphenylphosphine) ruthenium (II)
Catalyst used for the oxidative kinetic resolution of racemic alcohols. Catalyst used for the extremely high enantioselective transfer hydrogenation of ketones and the oxidative kinetic resolution of alcohols. Catalyst used for the asymmetric hydrosilylation of ketones and imine. Group: Ruthenium series catalysts. Alternative Names: Naud Catalyst SK-N003-2z. CAS No. 212133-11-4. Molecular formula: C46H43Cl2FeNOP2Ru. Mole weight: 915.7. Appearance: orange-brown powder. Purity: 0.96. IUPACName: (-)-Dichloro[(4S)-4-(i-propyl)-2-{(S)-2-(diphenylphosphino)ferrocenyl}. Catalog: ACM212133114.
Useful as a ligand in the Pd-catalyzed formation of diaryl amines. Has been recently applied to the C3 benzylation of indoles. Has been recently applied to the monoallylation of ammonia. Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids. Ligand used in carbonylation of aryl iodides. Ligand used in the direct C-H arylation of benzothiodiazoles. Ligand used in stereo-retentive azacyclization of propargylic carbonates. Ligand used in palladium catalyzed benzyne trimerization. Group: Organic phosphine compounds. CAS No. 166330-10-5. Molecular formula: C36H28OP2. Mole weight: 538.567g/mol. IUPACName: [2- (2-diphenylphosphanylphenoxy) phenyl]-diphenylphosphane. Canonical SMILES: C1=CC=C (C=C1) P (C2=CC=CC=C2) C3=CC=CC=C3OC4=CC=CC=C4P (C5=CC=CC=C5) C6=CC=CC=C6. Catalog: ACM166330105.
[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%
Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Iridium catalysts. Alternative Names: MFCD20922908;Krische Ir Catalyst: (S)-SEGPHOS, 4-cyano-3-nitrobenzoate ligated, AldrichCPR;[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3- -2-propenyl]Ir(III);[(R)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3--2-propenyl]Ir(III);1208092-27-6. CAS No. 1208092-27-6. Molecular formula: C49H36IrN2O8P2-. Mole weight: 1034.998g/mol. IUPACName: 4-cyano-3-nitrobenzene-6-ide-1-carboxylic acid; [4-(5-diphenylphosphanyl-1, 3-benzodioxol-4-yl)-1, 3-b
[(S)-(-)-5, 5'-Bis(diphenylphosphino)-4, 4'-bi-1, 3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1, 2, 3-η-2-propenyl]iridium(III), min. 97%
1. Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level. 2. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols. 3. Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level. 4. Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level. 5. Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols. 6. Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level. Group: Heterocyclic organic compound. CAS No. 1221768-92-8. Molecular formula: C49H35IrN2O8P2. Mole weight: 1033.98. Catalog: ACM1221768928.