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2-Quinolinecarboxalde hyde was used to synthesize 3-(2-quinolyl)-1-phenyl-2-propenone and imine-type ligands. Group: Biochemicals. Grades: Highly Purified. CAS No. 5470-96-2. Pack Sizes: 1g, 5g. Molecular Formula: C10H7NO, Molecular Weight: 157.169999999999. US Biological Life Sciences.
Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides. Group: Heterocyclic organic compound. Alternative Names: AB1005807; (R)-ShiP; AKOS015950895; Diindeno[7, 1-de:1', 7'-fg][1, 3, 2]dioxaphosphocin, 10, 11, 12, 13-tetrahydro-5-phenoxy-, (11ar)-; (aR)-7,7'-(Phenoxyphosphinidenebisoxy)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy; (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1|I,7|I-fg][1,3,2]dioxaphosphocin-5-phenoxy; 885701-71-3; Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite; 7,7'-(Phenoxyphosphinidenebisoxy)-1,1'-spirobiindan. CAS No. 656233-53-3. Molecular formula: C23H19O3P. Mole weight: 374.376g/mol. IUPACName: 12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine. Canonical SMILES: C1CC23CCC4=C2C (=CC=C4)OP (OC5=CC=CC1=C35)OC6=CC=CC=C6. Catalog: ACM656233533.
(Ra,R,R)-SIPHOS-PE
Chiral ligands for copper-catalyzed asymmetric allylic alkylation with dialkylzincs. Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones. Chiral ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes Chiral ligands for copper-catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard reagents. Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of α-alkyl vinylarenes. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines. Chiral ligands for gold-catalyzed asymmetric [2 + 2] cycloaddition reaction. Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides. Chiral ligands for palladium-catalyzed asymmetric carboamination reactions. Group: Other phosphine ligands. Alternative Names: SCHEMBL17227906; (S)-SIPHOS-PE; Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-, (11aR)-; N-Di[(R)-1-phenylethyl]-[(S)-1,1 inverted exclamation marka-spirobiindane-7,7 inverted exclamation marka-diyl]-phosphoramidite; N-Di[(R)-1-phenylethyl]-[(R)-1,1 inverted exclamation marka-spirobiindane-7,7 inverted exclamation marka-diyl]-phosphorami. CAS No. 500997-69-3. Molecular formula: C33H32NO2P. Mole weight: 505.598g/mol. IUPACName: N,N-bis[(1R)-1-phenyl
(R)-tert-Butylsulfinamide
(R)-tert-Butylsulfinamide is a chiral ligand used in pharmaceutical compositions. (R)-tert-Butylsulfinamide can be readily transformed into P,N-sulfinyl imineligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.(R)-(+)-2-Methyl-2-propanesulfinamide may be used to prepare N-(1-cyclohexylmethylidene)-2-methylpropane-2-sulfinamide via copper mediated condensation with cyclohexane carboxaldehyde. It may also be used to prepare (20E)-N-[t-butyl-(R)-sulfinyl]-3 β-(t-butyldimethylsilyloxy)-pregn-5-en-20-imine, an intermediate for the development of androgen receptor antagonists. Group: Biochemicals. Alternative Names: (R)-(+)-2-Methyl-2-propanesulfinamide; (R)-N-tert-Butanesulfinamide;(R)-tert-Butanesulfinamide; (R)-(+)-t-Butyl sulfinamide. Grades: Highly Purified. CAS No. 196929-78-9. Pack Sizes: 1g, 5g, 10g, 25g. Molecular Formula: C4H11NOS, Molecular Weight: 121.2. US Biological Life Sciences.
Worldwide
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides. Asymmetric hydrogenation of vinyl alcohols. Catalyst used for the asymmetric hydrogenation of enol phosphonates. Asymmetric hydrogenation of allylic alcohols. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Group: Heterocyclic organic compound. Alternative Names: (R,R)-1,2-Bis(2,5-dimethylphospholano)benzene; DTXSID20163641; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, kanata purity; H5W03D1HAQ; UNII-H5W03D1HAQ; (R,R)-Me-DUPHOS; AJNZWRKTWQLAJK-KLHDSHLOSA-N; (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene; (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, >=95.0%. CAS No. 147253-67-6. Molecular formula: C18H28P2. Mole weight: 306.37g/mol. IUPACName: (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane. Canonical SMILES: CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C. ECNumber: 604-579-6. Catalog: ACM147253676.
1. Ligand used in the preparation of highly active metal catalysts for the polymerization of ethylene (ref 1, M=Ni, Pd) and olefins (ref 2, M=Pd; ref 3, M= Hf, Zr) Ligand for the iron catalyzed polymerization of styrene acrylate monomers Ligand for Yttrium complex that catalysis the ring-opening polymerization of cyclic esters Ligand for rare-earth dichloro and bis(alkyl) complexes for isoprene polymerization Ligand for cobalt catalyzed alkene hydroboration Ligand for nickel catalyzed alkene hydrosilylation. Group: Heterocyclic organic compound. Alternative Names: N-(2,6-diisopropylphenyl)-N-{2-[(2,6-diisopropylphenyl)imino]-1-methylpropylidene}amine; N-((E,2E)-2-[(2,6-Diisopropylphenyl)imino]-1-methylpropylidene)-2,6-diisopropylaniline #; TRA0127768; N,N inverted exclamation marka-Bis(2,6-diisopropylphenyl)-2,3-butanediimine; J-400165; AKOS025295710; N2,N3-bis[2,6-di(propan-2-yl)phenyl]butane-2,3-diimine; (N,N'E,N,N'E)-N,N'-(butane-2,3-diylidene)bis(2,6-diisopropylaniline); 74663-77-7; ZINC15230312. CAS No. 74663-77-7. Molecular formula: C28H40N2. Mole weight: 404.642g/mol. IUPACName: 2-N,3-N-bis[2,6-di(propan-2-yl)phenyl]butane-2,3-diimine. Canonical SMILES: CC (C)C1=C (C (=CC=C1)C (C)C)N=C (C)C (=NC2=C (C=CC=C2C (C)C)C (C)C)C. Catalog: ACM74663777.
2,6-Bis[1-(2-methylphenylimino)ethyl]pyridine
Ligand for iron catalyzed ethene polymerization, activated and heterogenized with a co-catalyst consisting of partially hydrolyzed trimethylaluminum on silica gel Ligand for chromium catalyzed of ethylene oligomerization Ligand for rhodium bis(imino)pyridine complex, that generates nanoparticles and effectively catalyses dehalogenation and hydrogenation of aromatic Compounds. Group: Heterocyclic organic compound. Alternative Names: N,N'-(2,6-Pyridinediyldiethylidyne)bis[2-methylbenzenamine. CAS No. 210537-32-9. Molecular formula: C23H23N3. Mole weight: 341.45. Appearance: Yellow powder. Purity: 0.98. IUPACName: 1-[6-[C-methyl-N-(2-methylphenyl)carbonimidoyl]pyridin-2-yl]-N-(2-methylphenyl)ethanimine. Canonical SMILES: CC1=CC=CC=C1N=C (C)C2=NC (=CC=C2)C (=NC3=CC=CC=C3C)C. Catalog: ACM210537329-1.
2-Bromobenzamide
2-Bromobenzamide has been used in microwave assisted one-pot synthesis of substituted 3- (phenylmethylene) isoindolin-1-ones, palladium-catalyzed synthesis of phenanthridinones and synthesis of new water-soluble iminophosphorane ligand. Group: Biochemicals. Grades: Highly Purified. CAS No. 4001-73-4. Pack Sizes: 10g, 25g, 50g, 100g. US Biological Life Sciences.
Lanthanide chelator, Caged Lanthanide NMR Probe 5 (CLaNP-5) readily attachable to a protein surface via two cysteine residues. It is designate as a protein probe to deliver unambiguous high quality structural restraints in studies on protein-protein and protein-ligand interactions. Chelating agent. Group: Biochemicals. Alternative Names: Methanesulfonothioic Acid S1,S1'-[[4,10-Bis[(1-oxido-2-pyridinyl)methyl]-1,4,7,10-tetraazacyclododecane-1,7-diyl]bis[(1-oxo-2,1-ethanediyl)imino-2,1-ethanediyl]] Ester Ditrifluoroacetate; CLaNP-5. Grades: Highly Purified. CAS No. 947326-26-3. Pack Sizes: 1mg. US Biological Life Sciences.
Worldwide
Acetylacetonatobis (cyclooctene)rhodium (I), min. 97%
Rhodium source used in combination with phosphine ligands to catalyze the 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Rhodium source for the catalytic addition of arylboronic acids to N-tert-butanesulfinyl imino esters. Group: Rhodium series of catalysts. Alternative Names: ACETYLACETONATOBIS (CYCLOOCTENE)RHODIUM (I); 34767-55-0; MFCD06658137; SC10118; ACETYLACETONATOBIS (CYCLOOCTENE)RHODIUM (I);BIS(CYCLOOCTENE)(2,4-PENTANEDIONATO)RHODIUM. CAS No. 34767-55-0. Molecular formula: C21H36O2Rh. Mole weight: 423.422g/mol. IUPACName: cyclooctane;(Z)-4-hydroxypent-3-en-2-one;rhodium. Canonical SMILES: CC(=CC(=O)C)O. C1CCC[CH][CH]CC1. C1CCC[CH][CH]CC1. [Rh]. Catalog: ACM34767550.
AH 11110 hydrochloride
The hydrochloride salt form of AH 11110, which is an α1B-adrenoceptor ligand and has been found to exhibit interaction with α1-adrenoceptors as well as α2-adrenoceptors. Synonyms: AH 11110 hydrochloride; AH11110 hydrochloride; AH-11110 hydrochloride; 4-Imino-1-(2-phenylphenoxy)-4-piperidinebutan-2-ol hydrochloride. Grades: ≥98% by HPLC. CAS No. 179388-65-9. Molecular formula: C21H26N2O2.HCl. Mole weight: 374.91.
Aminopeptidase N Ligand (CD13), NGR peptide
It is a peptide with NGR (Asn-Gly-Arg) motif, which has a disulfide bridge linking cys1 and cys5, and is known to have antimicrobial properties in addition to the presence of KLA sequences. The peptide binds to CD13 on tumor cells and shows strong cytotoxicity and activity against tumor cells. This peptide shows dose-dependent antiproliferation against tumor cells and induces cell cylce arrest at G2/M phases and apoptosis of the tumor cells. Peptides containing the NGR motif are useful in the delivery of cytotoxic drugs, pro-apoptotic peptides, and tumor necrosis factor (TNF) into tumor vasculature. Synonyms: H-Cys-Asn-Gly-Arg-Cys-Gly-OH (Disulfide bridge: Cys1-Cys5); L-cysteinyl-L-asparagyl-glycyl-L-arginyl-L-cysteinyl-glycine (1->5)-disulfide; N-{[(4R,5E,7S,8E,11E,13S,14E,16R)-16-Amino-7-(3-carbamimidamidopropyl)-6,9,12,15-tetrahydroxy-13-(2-hydroxy-2-iminoethyl)-1,2-dithia-5,8,11,14-tetraazacycloheptadeca-5,8,11,14-tetraen-4-yl](hydroxy)methylene}glycine. Grades: ≥95%. Molecular formula: C20H34N10O8S2. Mole weight: 606.67.
Versatile ligand for the palladium-catalyzed amination of aryl and heteroaryl chlorides with primary aryl and alkylamines, cyclic and acyclic amines, lithium amide, N-H imines, hydrazones and ammonia. Group: Heterocyclic organic compound. Alternative Names: 2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine; 2-(Di-1-adamantylphosphino)-N,N-dimethylaniline; Me-Dalphos. CAS No. 1219080-77-9. Molecular formula: C28H40NP. Mole weight: 421.6. Appearance: Solid. Purity: 0.98. IUPACName: 2-[bis(1-adamantyl)phosphanyl]-N,N-dimethylaniline. Canonical SMILES: CN (C)C1=CC=CC=C1P (C23CC4CC (C2)CC (C4)C3)C56CC7CC (C5)CC (C7)C6. Catalog: ACM1219080779-1.
Iminodiacetic acid
500g Pack Size. Group: Amines, Building Blocks, Ligands, Organics. Formula: HN(CH2CO2H)2. CAS No. 142-73-4. Prepack ID 32314250-500g. Molecular Weight 133.1. See USA prepack pricing.
Iminodiacetic acid
Iminodiacetic acid, HN(CH2CO2H)2, often abbreviated to IDA, is a dicarboxylic acid amine (the nitrogen atom forms a secondary amino group, not an imino group as the name suggests). The iminodiacetate anion can act as a tridentate ligand to form a metal complex with two, fused, five membered chelate rings. The proton on the nitrogen atom can be replaced by a carbon atom of a polymer to create an ion-exchange resin, such as chelex 100.IDA forms stronger complexes than the bidentate ligand glycine and weaker complexes than the tetradentate ligand nitrilotriacetic acid. It can also act as a bidentate ligand through its two carboxylate groups. Several technetium-99m complexes are used in cholescintigraphy scans (also known as hepatobiliary iminodiacetic acid scans) to evaluate the health and function of the gallbladder.Iminodiacetic acid is an important intermediate in one of the two main industrial processes used to manufacture the herbicide glyphosate. It is also used in capillary electrophoresis for modulating peptide mobility. Group: Heterocyclic organic compound. Alternative Names: 2-(carboxymethylamino)acetic acid;Iminodiacetic acid;2,2-Azanediyldiacetic acid;Glycine, N-(carboxymethyl)-. CAS No. 142-73-4. Molecular formula: C4H7NO4. Mole weight: 133.1. Appearance: White crystal. Density: 1.436 g/cm³. ECNumber: 205-555-4. Catalog: ACM142734.
(-)-Inosine Dehydroxy-N-(6-iminohexyl)-2,2,2-trifluoroacetamide is an intermediate in synthesizing N6-(6-Aminohexyl)-FAD, a Flavine Adenine Dinucleotide (FAD) derivative. Attachment of a ligand to the 6-Aminohexyl side chain of this compound, can be used as a FAD-labelled conjugate to measure the concentration of the free ligand in a competitive binding immunoassay. Synonyms: N-(6-((9-((2R,3R,4S,5R)-3,4-Dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-9H-purin-6-yl)amino)hexyl)-2,2,2-trifluoroacetamide; N-[8-(Acetylamino)?octyl]?-adenosine Trifluoroacetamide. Molecular formula: C18H25F3N6O5. Mole weight: 462.42.
(-)-Inosine Dehydroxy-N-(6-iminohexyl)-2,2,2-trifluoroacetamide Phosphate is an intermediate in synthesizing N6-(6-Aminohexyl)-FAD, a Flavine Adenine Dinucleotide (FAD) derivative. Attachment of a ligand to the 6-Aminohexyl side chain of this compound, can be used as a FAD-labelled conjugate to measure the concentration of the free ligand in a competitive binding immunoassay. Synonyms: ((2R,3S,4R,5R)-3,4-Dihydroxy-5-(6-((6-(2,2,2-trifluoroacetamido)hexyl)amino)-9H-purin-9-yl)tetrahydrofuran-2-yl)methyl Dihydrogen Phosphate. Molecular formula: C18H26F3N6O8P. Mole weight: 542.4.
MB-07133
MB-07133 is a novel cytarabine (araC) prodrug. It uses the HepDirect technology to target production of the active form of araC, araC triphosphate (araCTP), to the liver. It has the potential to be both efficacious and well tolerated in HCC patients. It was developed by Ligand and in clinic phase 3 trials. Uses: Mb-07133 has the potential to be both efficacious and well tolerated in hcc patients. Synonyms: MB 07133; MB07133; 4-Imino-1-{5-O-[2-oxo-4-(pyridin-4-yl)-1,3,2lambda~5~-dioxaphosphinan-2-yl]pentofuranosyl}-1,4-dihydropyrimidin-2-ol. Grades: 98%. CAS No. 685111-92-6. Molecular formula: C17H21N4O8P. Mole weight: 440.34.
Netropsin Dihydrochloride
It is a basic cytotoxic polypeptide produced by the strain of Streptomyces netropsis. It is a DNA minor groove binding ligand. Synonyms: Congocidin Dihydrochloride; Sinanomycin Dihydrochloride; Netropsin Dihydrochloride; Congocidine Dihydrochloride; N'-(2-amidinoethyl)-4-(2-guanidinoacetamido)-1,1'-dimethyl-N,4'-Bi[pyrrole-2-carboxamide] Dihydrochloride; 4-[[2-[ (Aminoiminomethyl) amino]acetyl]amino]-N-[5-[[ (3-amino-3-iminopropyl) amino]carbonyl]-1-methyl-1H-pyrrol-3-yl]-1-methyl-1H-pyrrole-2-carboxamide Dihydrochloride. Grades: ≥98%. CAS No. 18133-22-7. Molecular formula: C18H26N10O3.2HCl. Mole weight: 503.40.
(Nitrosoimino) bisacetic Acid Diethyl Ester
(Nitrosoimino) bisacetic Acid Diethyl Ester is an nitrosylated derivative of Iminodiacetic Acid, an anion that can act as a tridentate ligand to form metal complexes with five membered chelate rings. Group: Biochemicals. Alternative Names: NSC 15009; N-(2-Ethoxy-2-oxoethyl)-N-nitrosoglycine Ethyl Ester. Grades: Highly Purified. CAS No. 5438-83-5. Pack Sizes: 5mg. US Biological Life Sciences.
1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols. 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters. 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes. 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins. 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction. Group: Heterocyclic organic compound. CAS No. 145964-33-6. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM145964336.
RGD peptide
RGD peptide is an inhibitor of integrin-ligand interactions. Synonyms: H-Gly-Arg-Gly-Asp-Asn-Pro-OH; RGD peptide (GRGDNP); glycyl-L-arginyl-glycyl-L-alpha-aspartyl-L-asparagyl-L-proline; (S)-1-((6S,12S,15S)-1-amino-15-(2-amino-2-oxoethyl)-6-(2-aminoacetamido)-12-(carboxymethyl)-1-imino-7,10,13-trioxo-2,8,11,14-tetraazahexadecane)pyrrolidine-2-carboxylic acid. Grades: 98%. CAS No. 114681-65-1. Molecular formula: C23H38N10O10. Mole weight: 614.61.
(R)-Tol-BINAP
Useful ligand for palladium-catalyzed carbon-oxygen bond formation. Ligand for palladium-catalyzed α-arylation of ketones. Ligand for Cu-catalyzed asymmetric conjugate reduction. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. Enantioselective conjugate reduction of lactones and lactams. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. Catalytic Aldol reaction to ketones. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. Ligand used in the copper-catalyzed asymmetric conjugate addition of alkyl Grignard reagents on α,β-unsaturated esters. Ligand used in the copper-catalyzed asymmetric synthesis of cyclopropanes via tandem conjugate addition and intramolecular enolate trapping. Group: Heterocyclic organic compound. CAS No. 99646-28-3. Molecular formula: C48H40P2. Mole weight: 678.796g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. Catalog: ACM99646283.
[RuCl(p-cymene)((S)-tolbinap)]Cl
1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation. 2. Ligand for palladium-catalyzed α-arylation of ketones. 3. Ligand for Cu-catalyzed asymmetric conjugate reduction. 4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. 5. Enantioselective conjugate reduction of lactones and lactams. 6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. 7. Catalytic Aldol reaction to ketones. 8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. 9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. 10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. 11. Rhodium-catalyzed cross cyclotrimerization. Group: Ruthenium series catalysts. Alternative Names: SC10123; (R)-RuCl[(p-cymene)(T-BINAP)]Cl; Chloro[(R)-(+)-2,2 -bis(di-p-tolylphosphino)-1; CHLORO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM(II) CHLORIDE; MFCD09753014; (S)-RuCl[(p-cymene)(T-BINAP)]Cl; C58H54Cl2P2Ru. CAS No. 228120-95-4. Molecular formula: C58H54Cl2P2Ru. Mole weight: 984.988g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane; dichlororuthenium; 1-methyl-4-propan-2-ylbenzene. Canonical SMILES: CC1=CC=C (C=C1)C (C)C. CC1=CC=C (C=C1)P (C
(R)-(+)-XylBINAP
Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters. Ligand used in the enantioselective fluorination of oxindoles. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation. Asymmetric hydroboration of unsaturated imines. Group: Heterocyclic organic compound. CAS No. 137219-86-4. Molecular formula: C52H48P2. Mole weight: 734.904g/mol. IUPACName: [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane. Canonical SMILES: CC1=CC (=CC (=C1)P (C2=C (C3=CC=CC=C3C=C2)C4=C (C=CC5=CC=CC=C54)P (C6=CC (=CC (=C6)C)C)C7=CC (=CC (=C7)C)C)C8=CC (=CC (=C8)C)C)C. Catalog: ACM137219864.
Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols. Ligand for palladium-catalyzed asymmetric reduction of allylic esters. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins. Group: Heterocyclic organic compound. CAS No. 134484-36-9. Molecular formula: C33H25OP. Mole weight: 468.536g/mol. IUPACName: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane. Canonical SMILES: COC1=C (C2=CC=CC=C2C=C1)C3=C (C=CC4=CC=CC=C43)P (C5=CC=CC=C5)C6=CC=CC=C6. Catalog: ACM134484369.
(S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine
1. Ligand for Copper catalyzed syn-selective Mukaiyama aldol reaction. 2. Ligand for Tin catalyzed anti-selective aldol reaction. 3. Ligand for Ytterbuim catalyzed desymmetrization of meso epoxides. 4. Ligand for Copper catalyzed enantioselective addition of terminal alkynes to imines. 5. Ligand for Scandium catalyzed enantioselective syn-selective ene reactions. 6. Ligand for Copper catalysed asymmetric alkynylation of cyclic azomethine Imines. 7. Ligand for Europium catalyzed asymmetric alpha amination. 8. Ligand for Indium catalyzed enantioselective construction of spiro-fused 2-oxindole/α -methylene-γ -butyrolactones. 9. Ligand for Copper catalyzed asymmetric azide-alkyne cycloaddition to quaternary oxindoles. 10. Ligand for Iron catalyzed enantioselective nitrene transfer to sulfides. 11. Ligand for Copper catalyzed enantioselective intramolecular propargylic amination. 12. Ligand for Copper catalyzed asymmetric hydroxylation. 13. Ligand for Scandium catalyzed dearomatization of 2-naphthols by electrophilic amination. 14. Ligand for Copper catalyzed asymmetric alkynylation of oxocarbenium ions to set diaryl tetrasubstituted stereoceters. Group: Heterocyclic organic compound. Alternative Names: BP-12297; SC-44215; 2,6-BIS[(S)-4-PHENYL-2-OXAZOLIN-2-YL]PYRIDINE; RTR-007742; BR-10750; (S,S)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine; AB1011206; AJ-35446; ANW-22713; J-010994. CAS No
(S)-(-)-TolBINAP
Useful ligand for palladium-catalyzed carbon-oxygen bond formation. Ligand for palladium-catalyzed α-arylation of ketones. Ligand for Cu-catalyzed asymmetric conjugate reduction. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes. Enantioselective conjugate reduction of lactones and lactams. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters. Catalytic Aldol reaction to ketones. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols. Rhodium-catalyzed cross cyclotrimerization. Group: Heterocyclic organic compound. CAS No. 100165-88-6. Molecular formula: C48H40P2. Mole weight: 678.796g/mol. IUPACName: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane. Canonical SMILES: CC1=CC=C (C=C1)P (C2=CC=C (C=C2)C)C3=C (C4=CC=CC=C4C=C3)C5=C (C=CC6=CC=CC=C65)P (C7=CC=C (C=C7)C)C8=CC=C (C=C8)C. Catalog: ACM100165886.
(S)-(-)-XylBINAP
Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters. Ligand used in the enantioselective fluorination of oxindoles. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation. Asymmetric hydroboration of unsaturated imines. Group: Heterocyclic organic compound. CAS No. 135139-00-3. Molecular formula: C52H48P2. Mole weight: 734.904g/mol. IUPACName: [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane. Canonical SMILES: CC1=CC (=CC (=C1)P (C2=C (C3=CC=CC=C3C=C2)C4=C (C=CC5=CC=CC=C54)P (C6=CC (=CC (=C6)C)C)C7=CC (=CC (=C7)C)C)C8=CC (=CC (=C8)C)C)C. Catalog: ACM135139003.
Tetrasodium Iminodisuccinate
100g Pack Size. Group: Analytical Reagents, Building Blocks, Ligands. Formula: C8H7NNa4O8. CAS No. 144538-83-0. Prepack ID 90026266-100g. Molecular Weight 337.1. See USA prepack pricing.
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