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It is the major component in the second generation spinosyn family of bio-insecticides marketed as spinetoram. It is a semi-synthetic compound prepared by selective ethylation and hydrogenation of spinosyn J, and it is also an insecticide. Synonyms: 3-Ethoxy-5,6-dihydro-spinosyn J; XDE-175-J; [2R-(2R*, 3aR*, 5aR*, 5bS*, 9S*, 13S*, 14R*, 16aS*, 16bR*)]-2-[(6-Deoxy-3-O-ethyl-2, 4-di-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R, 5S, 6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2, 3, 3a, 4, 5, 5a, 5b, 6, 9, 10, 11, 12, 13, 14, 16a, 16b-hexadecahydro-14-methyl-1H-as-Indaceno[3, 2-d]oxacyclododecin-7, 15-dione; (2R, 3aR, 5aR, 5bS, 9S, 13S, 14R, 16aS, 16bR)-2-[(6-Deoxy-3-O-ethyl-2, 4-di-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R, 5S, 6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2, 3, 3a, 4, 5, 5a, 5b, 6, 9, 10, 11, 12, 13, 14, 16a, 16b-hexadecahydro-14-methyl-1H-as-indaceno[3, 2-d]oxacyclododecin-7, 15-dione. Grades: >95% by HPLC. CAS No. 187166-40-1. Molecular formula: C42H69NO10. Mole weight: 748.00.
Spinetoram L
It is the minor component in the second generation spinosyn family of bio-insecticides marketed as spinetoram. It is a semi-synthetic compound prepared by selective ethylation and hydrogenation of spinosyn L, and it is also an insecticide. Synonyms: 3-Ethoxy-spinosyn L; 3'-O-Ethylspinosyn L; XDE 175L; (2S, 3aR, 5aS, 5bS, 9S, 13S, 14R, 16aS, 16bS)-2-[(6-Deoxy-3-O-ethyl-2, 4-di-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R, 5S, 6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2, 3, 3a, 5a, 5b, 6, 9, 10, 11, 12, 13, 14, 16a, 16b-tetradecahydro-4, 14-dimethyl-1H-as-indaceno[3, 2-d]oxacyclododecin-7, 15-dione. Grades: >95% by HPLC. CAS No. 187166-15-0. Molecular formula: C43H69NO10. Mole weight: 760.01.
3-Ethoxy-5,6-dihydro-spinosyn J 17-pseudoaglycone
It is an acid degradation product produced by selective hydrolysis of the more labile forosamine saccharide in the 17-position of 3-ethoxy-5,6-dihydrospinosyn J, the major component of the commercial product, spinetoram. It has only weak activity as an insecticide. Synonyms: 2-[(6-deoxy-3-O-ethyl-2, 4-di-O-methyl-α-L-mannopyranosyl)oxy]-9-ethyl-2R, 3, 3aR, 4, 5, 5aR, 5bS, 6, 9S, 10, 11, 12, 13S, 14R, 16aS, 16bR-hexadecahydro-13-hydroxy-14-methyl-1H-as-indaceno[3, 2-d]oxacyclododecin-7, 15-dione. Grades: >95% by HPLC. CAS No. 2055494-09-0. Molecular formula: C34H54O9. Mole weight: 606.79.
3-Ethoxy-spinosyn L 17-pseudoaglycone
It is an acid degradation product produced by selective hydrolysis of the more labile forosamine saccharide in the 17-position of 3-ethoxy-5,6-dihydrospinosyn J, the minor component of the commercial product, spinetoram. It has only weak activity as an insecticide. Grades: >95% by HPLC. Molecular formula: C35H54O9. Mole weight: 618.80.
Dihydrospinosyn A aglycone
It is an acid degradation product produced by hydrolysis of both saccharide groups of 3-ethoxy-5,6-dihydrospinosyn J, the major component of the commercial insecticide, spinetoram. It has only weak activity as an insecticide and the saccharides are considered essential for potent activity. It is commonly used as an insecticide for agricultural chemicals. Synonyms: (2R, 3aR, 5aR, 5bS, 9S, 13S, 14R, 16aS, 16bR)-9-ethyl-2, 3, 3a, 4, 5, 5a, 5b, 6, 9, 10, 11, 12, 13, 14, 16a, 16b-hexadecahydro-2, 13-dihydroxy-14-methyl-1H-as-indaceno[3, 2-d]oxacyclododecin-7, 15-dione. Grades: >95% by HPLC. CAS No. 727695-12-7. Molecular formula: C24H36O5. Mole weight: 404.54.
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