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1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide is an ionic liquid which can be used to prepare AMIMTFSI-propylene carbonate based electrolyte, with potential application in lithium-ion batteries. It also finds application in alkanes/alkenes separation process. Group: Battery materials. Alternative Names: AMIMTFSI. CAS No. 655249-87-9. Product ID: bis(trifluoromethylsulfonyl)azanide; 1-methyl-3-prop-2-enylimidazol-1-ium. Molecular formula: 403.31. Mole weight: C9H11F6N3O4S2. C[N+]1=CN (C=C1)CC=C. C (F) (F) (F)S (=O) (=O)[N-]S (=O) (=O)C (F) (F)F. 1S/C7H11N2. C2F6NO4S2/c1-3-4-9-6-5-8(2)7-9; 3-1(4, 5)14(10, 11)9-15(12, 13)2(6, 7)8/h3, 5-7H, 1, 4H2, 2H3; /q+1; -1. DHMWATGUEVQTIY-UHFFFAOYSA-N. >98.0%(HPLC).
Catalyst for the aziridination of olefins. Mild catalyst, superior to CuCl, in the methylenetriphenylphosphorane methyleneation of aldehydes and ketones. Copper(I) catalyzed alkylation of aryl and alkenylsilanes. Copper-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide. Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide. Carboxylation of organoboronic esters with potassium methylcarbonate under copper catalysis. Catalytic anti-Markovnikov hydrobromination of alkynes. Copper-catalyzed borylative cross-coupling of allenes and imines. Group: Heterocyclic organic compound. CAS No. 578743-87-0. Molecular formula: C27H36ClCuN2. Mole weight: 487.6. Purity: >98.0%(T). IUPACName: Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I). Catalog: ACM578743870.
(2-Methylallyl)palladium(II) chloride dimer
Catalyst for: &bull Asymmetric allylic alkylation reactions &bull Suzuki-Miyaura reactions &bull Reductive cleavage reactions &bull Reaction of alkenyloxiranes with carbon monoxide. Group: Palladium series catalysts. Alternative Names: Chloro(2-methylallyl)palladium(II) dimer. CAS No. 12081-18-4. Molecular formula: [CH2=C(CH3)CH2PdCl]2. Mole weight: 393.94. Appearance: yellow powder. Purity: 0.99. IUPACName: dichloropalladium; 2-methanidylprop-1-ene; palladium(2+). Catalog: ACM12081184.
Catalyst used in the enantioselective fluorination of β-ketoesters. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. Group: Heterocyclic organic compound. Alternative Names: Acetonitrile;dichlorotitanium;[(4R, 5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2, 2-dimethyl-1, 3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol. CAS No. 197389-47-2. Molecular formula: C47H36Cl2O4Ti. Mole weight: 824.63. Appearance: Yellow powder. IUPACName: acetonitrile;dichlorotitanium;[(4R, 5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2, 2-dimethyl-1, 3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol. Canonical SMILES: CC#N. CC1 (NC (C (O1)C (C2=CC=CC3=CC=CC=C32) (C4=CC=CC5=CC=CC=C54)O)C (C6=CC=CC7=CC=CC=C76) (C8=CC=CC9=CC=CC=C98)O)C. Cl[Ti]Cl. Catalog: ACM197389472-2.
Catalyst used in the enantioselective fluorination of β-ketoesters. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. Group: Heterocyclic organic compound. Alternative Names: 328123-04-2;(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM (IV) DICHLORIDE; MFCD04973054; SC10833; Tetraphenyl-TADDOL-DME-titaniumdichloride; 123D042; (4R, 5R)-(-)-2, 2-Di-Me-tetraphenyl-1, 3-dioxolane-4, 5-dimethanolato[1, 2-bis(diMeO)ethane]Ti(IV) dichloride CH3CN adduct;(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha'. CAS No. 328123-04-2. Molecular formula: C37H45Cl2NO6Ti. Mole weight: 718.535g/mol. IUPACName: acetonitrile; cyclohexa-1, 3-dien-1-yl-[(4R, 5R)-5-[hydroxy(diphenyl)methyl]-2, 2-dimethyl-1, 3-dioxolan-4-yl]-phenylmethanol; dichlorotitanium; 1, 2-dimethoxyethane. Canonical SMILES: CC#N. CC1 (OC (C (O1)C (C2=CC=CC=C2) (C3=CC=CC=C3)O)C (C4=CC=CCC4) (C5=CC=CC=C5)O)C. COCCOC. Cl[Ti]Cl. Catalog: ACM328123042.
Acarbose-N-allyl Formate Tridecaacetate
Acarbose-N-allyl Formate Tridecaacetate is an intermediate formed in the synthesis of α-D-Glucosyl Acarbose Impurity, a homolog of Acarbose for use in the treatment of chronic diseases such as inflammatory (including allergic) diseases, metastatic cancers and infection by pathogenic agents including bacteria, viruses or parasites. Synonyms: (3R,4S,5R,6R)-6-(Acetoxymethyl)-5-(((2R,3R,4S,5R,6R)-3,4-diacetoxy-6-(acetoxymethyl)-5-(((2R,3R,4S,5R,6R)-3,4-diacetoxy-5-(((allyloxy)carbonyl)((1S,4S,5S,6S)-4,5,6-triacetoxy-3-(acetoxymethyl)cyclohex-2-en-1-yl)amino)-6-methyltetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2,3,4-triyl triacetate. Molecular formula: C55H73NO33. Mole weight: 1276.16.
Allyl Ester of Atorvastatin Cyclic (Fluorophenyl) Impurity
Intermediate in the preparation of Atorvastatin degradation products. Group: Biochemicals. Alternative Names: 1 β-(4-Fluorophenyl)hexahydro- β , 7-dihydroxy-7- (1-methylethyl)-1α -phenyl-7α -[ (phenylamino)carbonyl]-3H-oxireno[3, 4]pyrrolo[2, 1-b][1, 3]oxazine-3-butanoic Acid Allyl Ester; Allyl-ATV-cycloFP. Grades: Highly Purified. CAS No. 1316643-57-8. Pack Sizes: 1mg. US Biological Life Sciences.
Worldwide
Atorvastatin Allyl Ester
Atorvastatin derivative. Group: Biochemicals. Alternative Names: 2-(4-Fluorophenyl)- β , δ -dihydroxy-5- (1-methylethyl)-3-phenyl-4-[ (phenylamino)carbonyl]-1H-pyrrole-1-heptanoic Acid 2-Propenyl Ester; ( βR,δR)-2-(4-Fluorophenyl)- β , δ -dihydroxy-5- (1-methylethyl)-3-phenyl-4-[ (phenylamino)carbonyl]-1H-pyrrole-1-heptanoic Acid 2-Propen-1-yl Ester. Grades: Highly Purified. CAS No. 915092-85-2. Pack Sizes: 25mg. US Biological Life Sciences.
Worldwide
Atorvastatin Lactam Allyl Ester
Intermediate in the preparation of Atorvastatin degradation products. Group: Biochemicals. Alternative Names: ( βR,δR)-5-(4-Fluorophenyl)-2,3-dihydro- β , δ -dihydroxy-3- (1-methylethyl)-2-oxo-4-phenyl-3-[ (phenylamino)carbonyl]-1H-pyrrole-1-heptanoic Acid Allyl Ester. Grades: Highly Purified. Pack Sizes: 1mg. US Biological Life Sciences.
Worldwide
Boc-3,4-dichloro-D-phenylalanine
Boc-3,4-dichloro-D-phenylalanine is used to prepare fluorinated β-aminoacyl 1,2,4-triazolo[4,3-a]piperazine amides as dipeptidyl peptidase IV inhibitors and antidiabetic agents. It is also used in the synthesis of N-[(R,R)-(E)-1-(3,4-dichlorobenzyl)-3-(2-oxoazepan-3-yl)carbamoyl]allyl-N-methyl-3,5-bis(trifluoromethyl)benzamide as a potent and orally active dual neurokinin NK1/NK2 receptor antagonist. Synonyms: Boc-D-Phe(3,4-DiCl)-OH; Boc-D-Phe(3,4-Cl2)-OH; (R)-Boc-2-amino-3-(3,4-dichlorophenyl)propionic acid; Boc-D-Phe(3,4-Cl2)-OH; (R)-2-((tert-Butoxycarbonyl)amino)-3-(3,4-dichlorophenyl)propanoic acid; D-Phenylalanine, 3,4-dichloro-N-[(1,1-dimethylethoxy)carbonyl]-; Boc-D-3,4-Dichlorophenylalanine; AK162594; N-BOC-3,4-DICHLORO-D-PHENYLALANINE. Grades: ≥ 98% (HPLC). CAS No. 114873-13-1. Molecular formula: C14H17Cl2NO4. Mole weight: 334.20.
(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*
Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides. Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates. Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones. Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes. Ligand for the silver-catalyzed asymmetric nitroso aldol reaction. Cu-catalyzed enantioconvergent allyllic borylation. Cu-catalyzed enantioselective cyclopropylation. Group: Heterocyclic organic compound. Alternative Names: AK173366; 866081-62-1; (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline; (R,R)-QuinoxP; (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline. CAS No. 866081-62-1. Molecular formula: C18H28N2P2. Mole weight: 334.384g/mol. IUPACName: (R)-tert-butyl-[3-[tert-butyl(methyl)phosphanyl]quinoxalin-2-yl]-methylphosphane. Canonical SMILES: CC (C) (C)P (C)C1=NC2=CC=CC=C2N=C1P (C)C (C) (C)C. Catalog: ACM866081621.
(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP*
Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides. Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds. Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates. Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones. Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes. Ligand for the silver-catalyzed asymmetric nitroso aldol reaction. Group: Polydentate phosphine ligandsphosphorus catalysts. Alternative Names: (S, S)-(+)-2, 3-Bis(t-butylmethylphosphino)quinoxaline; 1107608-80-9; (S, S)-2, 3-Bis(tert-butylmethylphosphino)quinoxaline; (S, S)-QuinoxP*; SCHEMBL2559367; 2, 3-Bis[(S)-tert-butylmethylphosphino]quinoxaline; J-002473; (S, S)-(+)-2, 3-Bis(tert-butylmethylphosphino)quinoxaline. CAS No. 1107608-80-9. Molecular formula: C18H28N2P2. Mole weight: 334.384g/mol. IUPACName: (S)-tert-butyl-[3-[tert-butyl(methyl)phosphanyl]quinoxalin-2-yl]-methylphosphane. Canonical SMILES: CC (C) (C)P (C)C1=NC2=CC=CC=C2N=C1P (C)C (C) (C)C. Catalog: ACM1107608809.
(S)-tert-Butyl 5-(((R)-1-(tert-Butoxy)-3-mercapto-1-oxopropan-2-yl)amino)-2-((tert-butoxycarbonyl)amino)-5-oxopentanoate is an intermediate in the synthesis of L-γ-Glutamyl-(S)-Allyl-Cysteine, which is an extract from garlic used in the production of inflammatory mediators. Synonyms: 2-Methyl-2-propanyl (2S)-2-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-5-({(2R)-1-[(2-methyl-2-propanyl)oxy]-1-oxo-3-sulfanyl-2-propanyl}amino)-5-oxopentanoate. CAS No. 2112809-06-8. Molecular formula: C21H38N2O7S. Mole weight: 462.60.
Trimethylsulfonium Iodide
Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. Group: Battery materials dye-sensitized solar cell (dssc) materials. Alternative Names: S111 I. CAS No. 2181-42-2. Product ID: trimethylsulfanium; iodide. Molecular formula: 204.07. Mole weight: C3H9IS. C[S+](C)C.[I-]. InChI=1S/C3H9S.HI/c1-4(2)3; /h1-3H3; 1H/q+1; /p-1. VFJYIHQDILEQNR-UHFFFAOYSA-M. >98.0%T.
Trimethylsulfonium Iodide
Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. Group: Heterocyclic organic compound. Alternative Names: S111 I. CAS No. 2181-42-2. Molecular formula: C3H9IS. Mole weight: 204.07. Appearance: White to Almost white powder to crystal. Purity: >98.0%T. IUPACName: trimethylsulfanium;iodide. Canonical SMILES: C[S+](C)C.[I-]. ECNumber: 218-555-4. Catalog: ACM2181422.
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