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Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes Synthetic pyrethriods: catalyst for the Negishi coupling of (2, 2-dihaloethenyl) cyclopropanecarboxylates. Group: Palladium series catalysts. Alternative Names: Dichloro[bis (1, 4-diphenylphosphino)butane]palladium (II). CAS No. 29964-62-3. Molecular formula: C28H28Cl2P2Pd. Mole weight: 603.8. Appearance: White like powder. Purity: 0.99. IUPACName: dichloropalladium; 4-diphenylphosphanylbutyl (diphenyl)phosphane. Canonical SMILES: C1=CC=C (C=C1) P (CCCCP (C2=CC=CC=C2) C3=CC=CC=C3) C4=CC=CC=C4. Cl[Pd]Cl. Catalog: ACM29964623-1.
Heterocyclic Organic Compound. CAS No. 1246775-56-3. Catalog: ACM1246775563.
Allylpalladium(II) chloride dimer
Precatalyst for the enantioselective hydrosilylation of olefins. Precatalyst for asymmetric allylic alkylation and amination. Used as a palladium source for cross-coupling reactions. Can be used with Trost ligands. Catalyst for the carbostannylation of alkynes. Used as a precatalyst for "-arylation of aldehydes. Group: Palladium series catalysts. Alternative Names: Di-mu-chlorodi-pi-allyldipalladium; NSC 151255; Bis(pi-allylpalladiumchloride) (VAN); MFCD00044874 (95%); Bis(mu-chloro)bis(eta3-2-propenyl)dipalladium; AK327212; 12012-95-2; Palladium, di-pi-allyldi-mu-chlorodi- (8CI); Bis((eta3-allyl)(chloro)palladium); SC10406. CAS No. 12012-95-2. Molecular formula: C6H10Cl2Pd2. Mole weight: 365.886g/mol. IUPACName: chloropalladium(1+);prop-1-ene. Canonical SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]. ECNumber: 234-579-8. Catalog: ACM12012952.
Benzylbis (triphenylphosphine) palladium (II) Chloride
Benzylbis (triphenylphosphine) palladium (II) Chloride. Group: Biochemicals. Alternative Names: Benzyl (chloro) bis (triphenylphosphine) palladium (II) . Grades: Highly Purified. CAS No. 22784-59-4. Pack Sizes: 100mg, 250mg, 500mg, 1g, 2g. US Biological Life Sciences.
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Bis(acetonitrile)palladium(II) Dichloride
Bis(acetonitrile)palladium(II) Dichloride. Uses: Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. catalyst for the aza-michael reaction of carbamates with enones. catalyst for the rearrangement of allylic imidates to allylic amides. catalyst for the nazarov cyclization of α-alkoxy dienones. catalyst for the diamination of conjugated dienes. three component michael addition, cyclization, cross-coupling reaction. c-h activation of indoles. catalyst used for the direct c-h arylation of isoxazoles at the 5 position. Group: Salt. Alternative Names: Palladium(II) chloride diacetonitrile complex. CAS No. 14592-56-4. Product ID: acetonitrile; palladium(2+); dichloride. Molecular formula: 259.43. Mole weight: C4H6Cl2N2Pd. CC#N.CC#N.[Cl-].[Cl-].[Pd+2]. RBYGDVHOECIAFC-UHFFFAOYSA-L. 99%,Pd >41.
Bis(acetonitrile)palladium(II) Dichloride
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. Catalyst for the aza-Michael reaction of carbamates with enones. Catalyst for the rearrangement of allylic imidates to allylic amides. Catalyst for the Nazarov cyclization of α-alkoxy dienones. Catalyst for the diamination of conjugated dienes. Three component Michael addition, cyclization, cross-coupling reaction. C-H activation of indoles. Catalyst used for the direct C-H arylation of isoxazoles at the 5 position. Group: Palladium series catalysts. Alternative Names: Palladium(II) chloride diacetonitrile complex. CAS No. 14592-56-4. Molecular formula: C4H6Cl2N2Pd. Mole weight: 259.43. Appearance: orange powder. Purity: 99%,Pd >41. IUPACName: acetonitrile; palladium(2+); dichloride. Canonical SMILES: CC#N.CC#N.[Cl-].[Cl-].[Pd+2]. Catalog: ACM14592564.
Bis (Benzonitrile) palladium (II) chloride
Bis (Benzonitrile) palladium (II) chloride. Group: Biochemicals. Alternative Names: Palladium(II) chloride bis(benzonitrile) complex. Grades: Highly Purified. CAS No. 14220-64-5. Pack Sizes: 500mg, 1g, 2g, 5g. US Biological Life Sciences.
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Bis (Benzonitrile) palladium (II) chloride ≥95%, (26% Palladium content)
Bis (Benzonitrile) palladium (II) chloride ≥95%, (26% Palladium content). Group: Biochemicals. Grades: Reagent Grade. CAS No. 14220-64-5. Pack Sizes: 1g, 5g. US Biological Life Sciences.
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Bis(benzonitrile)palladium(II) Dichloride
Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides. Catalyst for the aza-Michael reaction of carbamates with enones. Catalyst for the rearrangement of allylic imidates to allylic amides. Catalyst for the Nazarov cyclization of α-alkoxy dienones. Catalyst for the diamination of conjugated dienes. Three component Michael addition, cyclization, cross-coupling reaction. C-H activation of indoles. Group: Palladium series catalysts. Alternative Names: ST24046185; bis(benzonitrile)-palladium(II) chloride; J-007619; bis(chloranyl)palladium; MFCD00013123 (95+%); SCHEMBL63930; Bis(phenylnitrile)dichloropalladium; NSC635160; PdCl2(PhCN)2; bis(benzonitrile)dichloro-palladium (II). CAS No. 14220-64-5. Molecular formula: C14H10Cl2N2Pd. Mole weight: 383.568g/mol. IUPACName: benzonitrile;dichloropalladium. Canonical SMILES: C1=CC=C(C=C1)C#N. C1=CC=C(C=C1)C#N. Cl[Pd]Cl. ECNumber: 238-085-3. Catalog: ACM14220645.
Bis (ethylenediamine) palladium (II) chloride
Bis (ethylenediamine) palladium (II) chloride. Group: Biochemicals. Alternative Names: Bis (ethylenediamine) dichloropalladium (II) . Grades: Highly Purified. CAS No. 13963-53-6. Pack Sizes: 250mg, 500mg, 1g. US Biological Life Sciences.
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Bis(tri-o-tolylphosphine)palladium(II) Dichloride
Coupling reaction of aryl bromides with vinylic acetates. Group: Palladium series catalysts. Alternative Names: 5531AB; SC10409; MFCD00274659 (98%); dichlorobis(tri-o-tolyl-phosphine)palladium(II); dichlorobis(tri-O-tolylphosphine)-palladium (II); DICHLOROBIS(TRI-ORTHO-TOLYLPHOSPHINE)PALLADIUM(II); FT-0696077; bis[tri(ortho-tolyl)phosphine] palladiumchloride; Dichlorobis(tri-o-tolylphosphine)palladium; AK-76768. CAS No. 40691-33-6. Molecular formula: C42H42Cl2P2Pd. Mole weight: 786.066g/mol. IUPACName: dichloropalladium;tris(2-methylphenyl)phosphane. Canonical SMILES: CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. CC1=CC=CC=C1P (C2=CC=CC=C2C)C3=CC=CC=C3C. Cl[Pd]Cl. Catalog: ACM40691336.
Bis(triphenylphosphine)palladium(II) Dichloride
Bis(triphenylphosphine)palladium(II) Dichloride. Uses: Precatalyst for the carbonylative cyclization of malonate derivatives. catalyst used in the double allylation of activated olefins. precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans. precatalyst for the homocoupling of terminal alkynes. precatalyst in the cross-coupling of alkynylsilanols and aryl halides. catalyst for direct pd-catalyzed alkynylation of n-fused heterocycles. catalyst for a tandem heck reaction/c-h functionalization. catalyst for direct arylation of tautomerizable heterocycles. Group: Salt. Alternative Names: TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(II) dichloride; bis(triphenylphosphine) palladium (II) chloride; FC0823; EINECS 237-744-2. CAS No. 13965-03-2. Product ID: palladium(2+); triphenylphosphane; dichloride. Molecular formula: 701.904g/mol. Mole weight: C36H30Cl2P2Pd. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Cl-]. [Pd+2]. InChI=1S/2C18H15P. 2ClH. Pd/c2*1-4-10-16 (11-5-1) 19 (17-12-6-2-7-13-17) 18-14-8-3-9-15-18; ; ; /h2*1-15H; 2*1H; /q; ; ; ; +2/p-2. YNHIGQDRGKUECZ-UHFFFAOYSA-L.
Bis(triphenylphosphine)palladium(II) Dichloride
Precatalyst for the carbonylative cyclization of malonate derivatives. Catalyst used in the double allylation of activated olefins. Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans. Precatalyst for the homocoupling of terminal alkynes. Precatalyst in the cross-coupling of alkynylsilanols and aryl halides. Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles. Catalyst for a tandem Heck reaction/C-H functionalization. Catalyst for direct arylation of tautomerizable heterocycles. Group: Palladium series catalysts. Alternative Names: TRANS-BIS-(TRIPHENYLPHOSPHINE)PALLADIUM DICHLORIDE; 13965-03-2; 28966-81-6; AC1L36TY; SC-01002; LS-192238; bis(triphenylphosphine) palladiuml(II) dichloride; bis(triphenylphosphine) palladium (II) chloride; FC0823; EINECS 237-744-2. CAS No. 13965-03-2. Molecular formula: C36H30Cl2P2Pd. Mole weight: 701.904g/mol. IUPACName: palladium(2+); triphenylphosphane; dichloride. Canonical SMILES: C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. C1=CC=C (C=C1)P (C2=CC=CC=C2)C3=CC=CC=C3. [Cl-]. [Cl-]. [Pd+2]. ECNumber: 237-744-2. Catalog: ACM13965032.
Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common starting material in palladium chemistry - palladium-based catalysts are of particular value in organic synthesis. It is prepared by chlorination of palladium. Uses: C-h activation; carbonylation; cross coupling reactions with arenes→mizoroki heck coupling reaction; oxidation. Group: Electrolytes. Alternative Names: Palladiumchloride (PdCl2); dichloropalladium; Palladium(II) Chloride. CAS No. 7647-10-1. Product ID: dichloropalladium. Molecular formula: 177.31. Mole weight: Cl2Pd. Cl[Pd]Cl. InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2. PIBWKRNGBLPSSY-UHFFFAOYSA-L. Metal purity 99.95.
Palladium(II) chloride
Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common starting material in palladium chemistry - palladium-based catalysts are of particular value in organic synthesis. It is prepared by chlorination of palladium. Uses: C-h activation; carbonylation; cross coupling reactions with arenes→mizoroki heck coupling reaction; oxidation. Group: Metal & ceramic materials. Alternative Names: Palladiumchloride (PdCl2); dichloropalladium; Palladium(II) Chloride. CAS No. 7647-10-1. Molecular formula: Cl2Pd. Mole weight: 177.31. Appearance: Dark brown powder. Purity: Metal purity 99.95. IUPACName: dichloropalladium. Canonical SMILES: Cl[Pd]Cl. Density: 4. ECNumber: 231-596-2. Catalog: ACM7647101-3.
Palladium (II) Chloride
PALLADIUM (II) CHLORIDE, 99.9% pure, -8 mesh, (Synonym: Palladium Dichloride), Formula: PdCl2. CAS No. 1947-10-1. Noah Chemicals San Antonio, Texas. ISO 9001:2015 Certified. Request a Quote Today!
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Palladium (II) Chloride
Palladium (II) Chloride. Grades: 99.9% Extremely High (>=99%). CAS No. 7647-10-1. Order Number: 2806.
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Palladium(II)(π-cinnamyl) Chloride Dimer
Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds. Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides. Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols. Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes. Group: Palladium series catalysts. Alternative Names: 12131-44-1;Palladium(|Eth-cinnamyl) chloride dimer;AK136149;PALLADIUM(PI-CINNAMYL) CHLORIDE DIMER;Di- -chlorobis[(1,2,3- )-1-phenyl-2-propen-1-yl]dipalladium;Di-|I-chlorobis[(1,2,3-|C)-1-phenyl-2-propen-1-yl]dipalladium;Di-|I-chlorobis[(1,2,3-|C)-1-phenyl-2-propenyl]dipalladium(II);Di-mu-chlorobis[(1,2,3-eta)-1-phenyl-2-propen-1-yl]dipalladium. CAS No. 12131-44-1. Molecular formula: C18H18Cl2Pd2. Mole weight: 518.082g/mol. IUPACName: palladium(2+);prop-2-enylbenzene;dichloride. Canonical SMILES: C=C[CH-]C1=CC=CC=C1. C=C[CH-]C1=CC=CC=C1. [Cl-]. [Cl-]. [Pd+2]. [Pd+2]. Catalog: ACM12131441.
Ligand for palladium-catalyzed synthesis of oxindoles by amide ?-arylation. Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides. Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols. Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates. Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases. Group: Organic phosphine compounds. Alternative Names: 1,1-Bis(dicyclohexylphosphino)ferrocene; 1,1-Bis(Dicyclohexylphosphino)Ferrocene; 1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE. CAS No. 146960-90-9. Molecular formula: C34H52FeP2. Mole weight: 578.57. Appearance: Orange-red powder. Purity: 0.98. IUPACName: dicyclohexyl(cyclopentyl)phosphane; iron. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. [Fe]. Catalog: ACM146960909.
[1, 1'-Bis (di-cyclohexylphosphino) ferrocene]dichloropalladium (II)
1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides. Group: Palladium series catalysts. Alternative Names: PdCl2(dcypf). CAS No. 917511-90-1. Molecular formula: C34H52Cl2FeP2Pd. Mole weight: 755.9. Appearance: red crystalline powder. Purity: Pd >14.0%. IUPACName: dichloropalladium; dicyclohexyl(cyclopentyl)phosphane; iron. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. C1CCC (CC1)P (C2CCCCC2)[C]3[CH][CH][CH][CH]3. Cl[Pd]Cl. [Fe]. Catalog: ACM917511901.
In-situ deprotonation leads to metal carbene species which acts as a catalyst in a variety of C-C and C-N bond forming reactions. Ligand used in the nickel or palladium-catalyzed coupling of aryl chlorides and amines. Ligand used for the palladium-catalyzed arylation of esters and amides. Ligand used for the palladium-catalyzed intermolecular amination of Csp3-H Bonds. Ligand used for the nickel-catalyzed hydrogenation of olefins. Group: Organic phosphine compounds. Alternative Names: 1,3-Bis(2,6-Diisopropylphenyl)-4,5-Dihydro-1H-Imidazol-3-Ium Tetrafluoroborate. CAS No. 282109-83-5. Molecular formula: C27H39BF4N2. Mole weight: 478.4. Appearance: White powder. Purity: 0.98. IUPACName: 1,3-bis[2,6-di(propan-2-yl)phenyl]-4,5-dihydroimidazol-1-ium;tetrafluoroborate. Canonical SMILES: [B-] (F) (F) (F)F. CC (C)C1=C (C (=CC=C1)C (C)C)N2CC[N+] (=C2)C3=C (C=CC=C3C (C)C)C (C)C. Catalog: ACM282109835-1.
Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates. Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolate coupling. Ligand used for the chemoselective amination of aryl chlorides. Ligand used for the Pd-catalyzed borylation of aryl chlorides, for the formation of trifluoroborates. Ligand used for the Pd-catalyzed amination of vinyl halides and triflates. Ligand used for the Pd-catalyzed three-component synthesis of indoles. Ligand used for the Pt-catalyzed regioselective hydrosilylation of functionalized terminal arylalkynes. Ligand used for the Pd-catalyzed synthesis of carbazoles. Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes. Ligand used for the direct arylation of picoline N-oxide. Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents. Catalyst for a phosphine-catalyzed Heine reaction. Ligand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes. Ligand used for the silver-catalyzed hydrogenation of aldehydes. Ligand used for the palladium-catalyzed cyanation of heterycyclic halides. Group: Organic phosphine compounds. Alternative Names: Dicyclohexyl(2', 4', 6'-Triisopropylbiphenyl-2-Yl)Phosphine. CAS No. 564483-18-7. Molecular formula: C33H49P. Mole weight: 476.72. Appearance: Solid. Purity: 0.98. IUPACName: dicyclohexyl-[2-[2,4,
Versatile Ligand for the Pd-catalyzed coupling of secondary arylamines and alkylamines. Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero)arylchlorides. Synthesis of ladder-type π-conjugated heteroacenes via palladium-catalyzed double N-arylation and intramolecular O-arylation. A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles, Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst. Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes. Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides. Ligand used for the palladium-catalyzed coupling of alkyl boronates. Group: Organic phosphine compounds. Alternative Names: AX8074362; MFCD06798294 (95%); X3474RY19E; CTK8B4848; ANW-46517; 2-DICYCLOHEXYLPHOSPHINO-2',6'-DI-I-PROPOXY-1,1'-BIPHENYL; RW2258; dicyclohexyl-[2-(2,6-diisopropoxyphenyl)phenyl]phosphane; AC-28790; Dicyclohexyl(2', 6'-diisopropoxy-[1, 1'-biphenyl]-2-yl)phosphine. CAS No. 787618-22-8. Molecular formula: C30H43O2P. Mole weight: 466.646g/mol. IUPACName: dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane. Canonical SMILES: CC (C)OC1=C (C (=CC=C1)OC (C)C)C2=CC=CC=C2P (C3CCCCC3)C4CCCCC4. ECNumber: 616-653-5. Catalog: ACM787618228.
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Ligand/palladium catalyst for general Suzuki-Miyaura cross-coupling reactions. Ligand/palladium catalyst for the Suzuki-Miyaura coupling of aryltrifluoroborates with aryl chlorides. Ligand/palladium catalyst for the Suzuki-Miyaura reaction of heteroaryl halides and heteroaryl boronic acids and esters. Ligand/palladium catalyst for the Kumada-Corriu cross-coupling reaction. Ligand/palladium catalyst for the borylation of aryl halides with pinacol borane. Suzuki couplings involving amino acids. Synthesis of biaryl derivatives of 4-hydroxyphenyl glycine, tyrosine and tryptophan. Synthesis of substituted adamantylzinc reagents using Mg-insertion in the presence of zinc chloride. Highly efficient catalyst for the palladium-catalyzed Suzuki-Miyura reaction of heteroaryl halides and heteroaryl boronic acids and esters. Group: Organic phosphine compounds. Alternative Names: S-PHOS. CAS No. 657408-07-6. Molecular formula: C26H35O2P. Mole weight: 410.53. Appearance: Solid. Purity: 0.98. IUPACName: dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane. Canonical SMILES: COC1=C (C (=CC=C1)OC)C2=CC=CC=C2P (C3CCCCC3)C4CCCCC4. Catalog: ACM657408076-1.
2-(Dicyclohexylphosphino)biphenyl
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in Suzuki coupling reactions involving aryl chlorides, bromides and triflates. Useful ligand for the Pd-catalyzed oxidation of alcohols in the presence of chlorobenzenes. Useful ligand for the Pd-catalyzed amination with ammonia equivalents. Ligand for the gold(I)-catalyzed intramolecular [4+2] cycloadditions involving 1,3-enynes and arylalkynes with alkenes. Ligand used in the palladium-catalyzed borylation of aryl bromdies. Ligand used in the palladium-catalyzed siliylation of aryl chlorides. Group: Organic phosphine compounds. Alternative Names: Cyclohexyl JohnPhos. CAS No. 247940-06-3. Molecular formula: C24H31P. Mole weight: 350.48. Appearance: Solid. Purity: 0.98. IUPACName: dicyclohexyl-(2-phenylphenyl)phosphane. Canonical SMILES: C1CCC (CC1)P (C2CCCCC2)C3=CC=CC=C3C4=CC=CC=C4. ECNumber: 480-030-2. Catalog: ACM247940063-1.
2-(Di-tert-butylphosphino)biphenyl
Ligand used in the palladium-catalyzed synthesis of aromatic amines from aryl chlorides, bromides and triflates. Ligand employed in a very active and general catalyst for Suzuki coupling reactions using aryl chlorides, bromides and triflates. Ligand used in palladium-catalyzed synthesis of oxindoles from α-chloroacetanilides. Effective ligand used in palladium-catalyzed arylation of thiazoles. Used in the formation of 2-benzylindolines via sequential palladium-catalyzed N-arylation/cyclization/C-arylation. Selective in the palladium-catalyzed arylation of silyl enol ethers formed from copper-catalyzed reduction of enones. Group: Organic phosphine compounds. Alternative Names: (2-Biphenylyl)-Di-Tert-Butylphosphine. CAS No. 224311-51-7. Molecular formula: C20H27P. Mole weight: 298.4. Appearance: Solid. Purity: 0.98. IUPACName: ditert-butyl-(2-phenylphenyl)phosphane. Canonical SMILES: CC (C) (C)P (C1=CC=CC=C1C2=CC=CC=C2)C (C) (C)C. Density: 1 g/cm3. Catalog: ACM224311517-1.
(2E)-2,4-Pentadienoic Acid Methyl Ester
(2E)-2,4-Pentadienoic Acid Methyl Ester is the methyl ester derivative of (2E)-2,4-Pentadienoic Acid (P268350) and is used as a reagent in the synthesis of opp-Dibenzoporphyrins as light-harvesters for Dye-Sensitized Solar Cells (DSSCs). Also used as a reagent in the preparation of allyl chlorides and allylboronates as substrates for stereoselective palladium-catalyzed allyl-allyl cross-coupling. Group: Biochemicals. Grades: Highly Purified. CAS No. 2409-87-2. Pack Sizes: 250mg, 2.5g. Molecular Formula: C6H8O2, Molecular Weight: 112.13. US Biological Life Sciences.
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(2E)-2,4-Pentadienoic Acid Methyl Ester-d3
(2E)-2,4-Pentadienoic Acid Methyl Ester-d3 is the isotope labelled analog of (2E)-2,4-Pentadienoic Acid Methyl Ester (P268360); the methyl ester derivative of (2E)-2,4-Pentadienoic Acid (P268350) used as a reagent in the synthesis of opp-Dibenzoporphyrins as light-harvesters for Dye-Sensitized Solar Cells (DSSCs). Also used as a reagent in the preparation of allyl chlorides and allylboronates as substrates for stereoselective palladium-catalyzed allyl-allyl cross-coupling. Group: Biochemicals. Grades: Highly Purified. Pack Sizes: 10mg, 100mg. Molecular Formula: C6H5D3O2, Molecular Weight: 115.15. US Biological Life Sciences.
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4-Chloro-2,6-dimethylaniline
4-chloro-2,6-dimethylaniline was chosen as a substrate of medium in palladium-catalyzed cyanations of aryl chlorides. Group: Solvents. Alternative Names: 4-Chlor-2,6-dimethyl-anilin 2,6-dimethyl-4-chloroaniline 5-Chlor-2-amino-m-xylol. CAS No. 24596-18-7. Molecular formula: C8H10ClN. Mole weight: 155.63. IUPACName: 4-chloro-2,6-dimethylaniline. Canonical SMILES: CC1=CC(Cl)=CC(C)=C1N. Density: 1.1±0.1 g/cm3. Catalog: ACM24596187.
(4-Dimethylaminophenyl)di-tert-butylphosphine
(4-Dimethylaminophenyl)di-tert-butylphosphine. Uses: Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic light-emitting diode (oled) materials. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Product ID: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Molecular formula: 265.381g/mol. Mole weight: C16H28NP. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. InChI=1S/C16H28NP/c1-15 (2, 3)18 (16 (4, 5)6)14-11-9-13 (10-12-14)17 (7)8/h9-12H, 1-8H3. IQTHEAQKKVAXGV-UHFFFAOYSA-N.
(4-Dimethylaminophenyl)di-tert-butylphosphine
Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions. Group: Organic phosphine compounds. Alternative Names: ZINC34638584; IQTHEAQKKVAXGV-UHFFFAOYSA-N; DTXSID10471005; KS-000005K1; AX8243611; 4-(di-t-butylphosphino)-N,N-dimethylaniline; APhos, 95%; (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; AKOS016012292; BIS(TERT-BUTYL)4-DIMETHYLAMINOPHENYLPHOSPHINE. CAS No. 932710-63-9. Molecular formula: C16H28NP. Mole weight: 265.381g/mol. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Catalog: ACM932710639.
4-Formylphenylboronic acid
Reagent used for: Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water ; Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides ; Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids ; Triethylamine-catalyzed three-component Hantzsch condensations ; Copper-catalyzed nitrations ; Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta ; Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides ; Palladium-catalyzed aerobic oxidative cross-coupling reactions Reagent used in Preparation of; Sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells; A novel protein synthesis inhibitor active against Gram-positive bacteria. Synonyms: Boronic acid, (4-formylphenyl)-; 4-Boronobenzaldehyde; p-formylphenylboronic acid; MFCD00151823; 4-benzaldehyde boronic acid; 4-(Dihydroxyboryl)benzaldehyde; CHEMBL140254. Grades: 95 %. CAS No. 87199-17-5. Molecular formula: C7H7BO3. Mole weight: 149.94.
Allyl[1, 3-bis (2, 6-diisopropylphenyl) -2-imidazolidinylidene]chloropalladium (II)
Catalyst for the cross-coupling of aryl chlorides or bromides with aromatic amines. Catalyst for the α-arylation of ketones. Catalyst for anaerobic alcohol oxidation. Group: Heterocyclic organic compound. Alternative Names: ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM (II); Allylchloro[1, 3-bis (2, 6-di-i-propylphenyl)-4, 5-dihydroimidazol-2-ylidene]palladium (II), 97%; ALLYLCHLORO[1, 3-BIS- (DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]PALLADIUM (II). CAS No. 478980-01-7. Molecular formula: C30H43ClN2Pd. Mole weight: 573.55. Purity: 0.96. IUPACName: Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylide. Catalog: ACM478980017.
Catalyst for the cross-coupling of aryl chlorides with boronic acids. Catalyst for the diamination of conjugated dienes and trienes. Catalyst for the dehalogenation of aryl chlorides. Catalyst for anaerobic alcohol oxidation. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. Group: Organic phosphine compounds. Alternative Names: Palladium, [1, ?3-bis [2, ?6-bis (1- methyl ethyl) ?phenyl] ?-1, ?3-dihydro-2H-imidazol-2-ylide ne ] ?chloro ( η 3-2-propen-1-yl) ?-. CAS No. 478980-03-9. Molecular formula: C30H42ClN2Pd. Mole weight: 572.54. Appearance: white solid. Purity: 98%, Pd>18.5%. Catalog: ACM478980039.
Ammonium tetrachloropalladate (II)
Ammonium tetrachloropalladate (II). Group: Biochemicals. Alternative Names: Palladium(II)-ammonium chloride. Grades: Highly Purified. CAS No. 13820-40-1. Pack Sizes: 1g, 2g, 5g, 10g, 25g. Molecular Formula: (NH4)2PdCl4. US Biological Life Sciences.
Worldwide
Biphenyl-4-sulfonyl chloride
Biphenyl-4-sulfonyl chloride is a HDAC inhibitor with synthetic applications in palladium-catalyzed desulfitative C-arylation. Synonyms: 4-phenylbenzenesulfonyl chloride. Grades: ≥ 95 %. CAS No. 1623-93-4. Molecular formula: C12H9ClO2S. Mole weight: 252.72.
Bis (di-tert-butyl (4-dimethylaminophenyl) phosphine) dichloropalladium (II)
Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides. Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate. Group: Palladium series catalysts. Alternative Names: 4-Ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium. CAS No. 887919-35-9. Molecular formula: C32H56Cl2N2P2Pd. Mole weight: 708.1. Appearance: Powder. Purity: 0.98. IUPACName: 4-ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium. Canonical SMILES: CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. CC (C) (C)P (C1=CC=C (C=C1)N (C)C)C (C) (C)C. Cl[Pd]Cl. Catalog: ACM887919359-2.
Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) is also used in the preparation of G6P-T1 translocase inhibitors used in the treatment of diabetes. Also, its used to prepare new dibenzofulvenes. Uses: Introduced as an easier to handle pd/p(t-bu)3-based catalyst for the negishi cross-coupling of aryl/vinyl chlorides. a versatile catalyst for the cross-coupling of aryl and vinyl chlorides. catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases. useful catalyst for the cross-coupling of heteroaromatic carboxylic acids. pd-catalyzed newnan-kwart rearrangement of o-aryl thiocarbamates. cross-coupling of silanolates and halides. elimination/isomerization of enol triflates derived from β-ketoesters. Group: Palladium series catalysts. Alternative Names: palladium,tritert-butylphosphane;Pd(t-Bu3P)2. CAS No. 53199-31-8. Molecular formula: C24H54P2Pd. Mole weight: 511.064g/mol. Appearance: Off white crystalline solid. IUPACName: palladium;tritert-butylphosphane. Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C. CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Pd]. Catalog: ACM53199318.
Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) is also used in the preparation of G6P-T1 translocase inhibitors used in the treatment of diabetes. Also, its used to prepare new dibenzofulvenes. Uses: Introduced as an easier to handle pd/p(t-bu)3-based catalyst for the negishi cross-coupling of aryl/vinyl chlorides. a versatile catalyst for the cross-coupling of aryl and vinyl chlorides. catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases. useful catalyst for the cross-coupling of heteroaromatic carboxylic acids. pd-catalyzed newnan-kwart rearrangement of o-aryl thiocarbamates. cross-coupling of silanolates and halides. elimination/isomerization of enol triflates derived from β-ketoesters. Group: Polymerization reagents. Alternative Names: palladium,tritert-butylphosphane; Pd(t-Bu3P)2. CAS No. 53199-31-8. Product ID: palladium; tritert-butylphosphane. Molecular formula: 511.064g/mol. Mole weight: C24H54P2Pd. CC(C)(C)P(C(C)(C)C)C(C)(C)C. CC(C)(C)P(C(C)(C)C)C(C)(C)C. [Pd]. InChI=1S/2C12H27P.Pd/c2*1-10(2, 3)13(11(4, 5)6)12(7, 8)9;/h2*1-9H3; : MXQOYLRVSVOCQT-UHFFFAOYSA-N.
BrettPhos
Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines. Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading. Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines. Ligand for the Suziki-Miyaura coupling of tosylates and mesylates. Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides. Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides. Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids. Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation. Group: Organic phosphine compounds. Alternative Names: C35H53O2P; dicyclohexyl-(2',4',6'-triisopropyl-3,6-dimethoxy-biphenyl-2-yl)-phosphane; BrettPhos; 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl; ZINC43220891; ST24046493; 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISOPROPYL-3,6-DIMETHOXYBIPHENYL; AS-19342; 2-(Dicyclohexylphosphino)3,6-dimethoxy-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation. CAS No. 1070663-78-3. Molecular formula: C35H53O2P. Mole weight: 536.781g/mol. IUPACName: dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane. Canonical SMILES: CC (C)C1=CC (=C (C (=C1)C (C)C)C2=C (C=CC (=C2P (C3CCCCC3)C4CCCCC4)OC)OC)C (C)C. Catalog: ACM1070663783.
Butyldi-1-adamantylphosphine
Ligand for the Pd-catalyzed Suzuki coupling reaction. Ligand for the Pd-catalyzed formation of α-aryl ketones. Ligand for the Pd-catalyzed aminations Ligand for the Pd-catalyzed Heck reaction. Ligand used for arylation of benzoic acids. Ligand for the formylation of aryl bromides. Ni-catalyzed denitrogenative alkyne insertion reactions of triazoles. Ligand for palladium-catalyzed aminocarbonylation of aryl halides Palladium-catalyzed direct arylation of oxazole at C-5 with aryl bromides, chlorides, and triflates Palladium-catalyzed carbonylative sonogashira coupling of aryl bromides. Alternative Names: Butyldi-1-adamantylphosphine. CAS No. 321921-71-5. Molecular formula: C24H39P. Mole weight: 358.54. Appearance: White solid. Purity: 0.98. Catalog: ACM321921715.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl]palladium (II)
Catalyst used in the α-arylation of ketones. Catalyst used in the Suzuki cross-coupling of aryl chlorides with boronic acid-substituted benzofurans. Group: Palladium catalysts. CAS No. 1779569-06-0. Molecular formula: C46H64ClPPd. Mole weight: 789.85. Appearance: Orange powder. Catalog: ACM1779569060-1.
Chloro (1-t-butylindenyl)[2- (dicyclohexylphosphino)-2', 6'-di-i-propoxy-1, 1'-biphenyl]palladium (II)
Catalyst used in the Buchwald-Hartwig cross-coupling of substituted aryl chlorides with secondary amines. Group: Palladium catalysts. CAS No. 1779569-08-2. Molecular formula: C43H58ClO2PPd. Mole weight: 779.77. Appearance: Orange powder. Catalog: ACM1779569082-1.
Extremely active palladium catalyst for Suzuki-Miyaura coupling of aryl chlorides. Group: Palladium catalysts. CAS No. 1905460-13-0. Molecular formula: C41H48ClN3Pd. Mole weight: 724.71. Appearance: Pale yellow powder. Purity: 0.97. Catalog: ACM1905460130-1.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- [bis (4-fluorophenyl] phosphino] ferrocenyl] ethyldi-tert-butylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (bis (4-fluorophenyl) phosphinoferrocenyl]ethyl (di-t-butylphosphine) }nickel (II) is used for: 1.Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. 4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-37-3. Mole weight: 774.69. Catalog: ACM2049086373.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldicyclohexylphosphine] nickel (II)
Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions. Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-35-1. Mole weight: 802.88. Catalog: ACM2049086351.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (dicyclohexylphosphino) ferrocenyl] ethyldiphenylphosphine] nickel (II)
Chloro (4-cyanophenyl) { (R) -1-[ (S) -2- (dicyclohexylphosphino) ferrocenyl]ethyl (diphenylphosphine)}nickel(II) is useful in these fields: Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-36-2. Mole weight: 790.79. Catalog: ACM2049086362.
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II)
Chloro (4-cyanophenyl) [ (R) -1- [ (S) -2- (diphenylphosphino) ferrocenyl] ethylditertbutylphosphine] nickel (II) has the following various uses:1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts. Group: Nickel catalysts. CAS No. 2049086-34-0. Mole weight: 738.71. Catalog: ACM2049086340.
Di(1-adamantyl)-2-dimethylaminophenylphosphine
Versatile ligand for the palladium-catalyzed amination of aryl and heteroaryl chlorides with primary aryl and alkylamines, cyclic and acyclic amines, lithium amide, N-H imines, hydrazones and ammonia. Group: Heterocyclic organic compound. Alternative Names: 2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine; 2-(Di-1-adamantylphosphino)-N,N-dimethylaniline; Me-Dalphos. CAS No. 1219080-77-9. Molecular formula: C28H40NP. Mole weight: 421.6. Appearance: Solid. Purity: 0.98. IUPACName: 2-[bis(1-adamantyl)phosphanyl]-N,N-dimethylaniline. Canonical SMILES: CN (C)C1=CC=CC=C1P (C23CC4CC (C2)CC (C4)C3)C56CC7CC (C5)CC (C7)C6. Catalog: ACM1219080779-1.
Dichlorobis (triphenylphosphine) Palladium (II)
Dichlorobis (triphenylphosphine) Palladium (II) is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of metallacyclic complexes which show antiinflammatory and antifungal properties. Group: Biochemicals. Alternative Names: Bis (triphenylphosphine) dichloropalladium; Bis (triphenylphosphine) palladiumChloride; Bis (triphenylphosphine) palladium Dichloride; Bis (triphenylphosphine) palladium (II) Chloride; Bis (triphenylphosphine) palladium (II) Dichloride; Bis (triphenylphosphino) palladiumChloride; Dichlorobis (triphenylphosphine) palladium; Dichlorobis (triphenylphosphine) palladium (II) ; NSC 122924; Palladiumbis (triphenylphosphine) Dichloride. Grades: Highly Purified. CAS No. 13965-03-2. Pack Sizes: 2.5g. US Biological Life Sciences.
Worldwide
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%